Multi-channel magnetic resonance spectroscopy through time domain multiplexing

Time domain multiplexing (TDM) is presented as a viable approach to increasing the sensitivity and efficiency of magnetic resonance spectroscopic (MRS) experiments through multi-channel signal acquisition. By switching very rapidly between coils of a receive phased array, TDM receiver extensions allow the acquisition of multiple, independent spectra through a single channel magnetic resonance console. A TDM receiver extension designed for imaging and spectroscopy is described, and the impact of this hardware extension on the processing and quantitation of MRS data is addressed. The primary complication involves the use of fixed bandwidth RF band-pass filters that can not be adjusted to match the spectral width of the desired MRS experiment.MRS sequences whose bandwidths are narrower than the bandwidth provided by TDM band-pass filters can be acquired through TDM with minimal loss of SNR as long as two constraints are met. The first constraint requires that the entire bandwidth of the band-pass filters be sampled at or more rapidly than the Nyquist rate associated with their bandwidth, to prevent extra noise from aliasing into the final spectrum. The second requirement is that spectral resolution be held constant to that of the desired experiment.Results from a two-channel multiplexed MRS experiment, conducted according to these guidelines, illustrate that TDM can be used to allow acquisition of multi-channel MRS experiments through single channel console systems with a minimal loss in SNR.     

Papyrus imaging with terahertz time domain spectroscopy

Terahertz time domain spectroscopic imaging (THz-TDSI) is a non-ionizing, non-contact and non-destructive measurement technique that has been recently utilized to study cultural heritage artifacts. We will present this technique and the results of non-contact measurements of papyrus texts, including images of hidden papyri. Inks for modern papyrus specimens were prepared using the historical binder, Arabic gum, and two common pigments used to write ancient texts, carbon black and red ochre. The samples were scanned in reflection at normal incidence with a pulse with a spectral range between 0.1 and 1.5 THz. Temporal analysis of the signals provides the depths of the layers, and their frequency spectra give information about the inks.     

Current-induced domain wall motion

The present understanding of domain wall motion induced by spin-polarized electric current is assessed by considering a subset of experiments, analytical models, and numerical simulations based on an important model system: soft magnetic nanowires. Examination of this work demonstrates notable progress in characterizing the experimental manifestations of the “spin-torque” interaction, and in describing that interaction at a phenomenological level. At the same time, an experimentally verified microscopic understanding of the basic mechanisms will require substantial future efforts, both experimental and theoretical.     

Anisotropy of domain wall resistance

The resistive effect of domain walls in FePd films with perpendicular anisotropy was studied experimentally as a function of field and temperature. The films were grown directly on MgO substrates, which induces an unusual virgin magnetic configuration composed of 60 nm wide parallel stripe domains. This allowed us to carry out the first measurements of the anisotropy of domain wall resistivity in the two configurations of current perpendicular and parallel to the walls. At 18 K, we find 8.2% and 1.3% for the domain wall magnetoresistance normalized to the wall width (8 nm) in these two respective configurations. These values are consistent with the predictions of Levy and Zhang.     

Modeling of domain wall displacement in crystals with dislocations

The domain wall displacement in ferromagnetic crystals with dislocations that produce a continuous potential field with wavelength greater than the domain wall width is investigated by the machine modeling method. It is established that the domain wall shape and the start field are determined during magnetization by the potential field characteristics that depend on the specific location of the dislocations. It is shown that the start field is proportional to the ratio between the mean stress and the variance of the potential field stress at the site of domain wall fastening. The results of the modeling agree with values of the start field obtained experimentally and the behavior of the domain wall during magnetization of iron microcrystals.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 77–83, December, 1990.     

Magnetic resonance imaging in childhood intracranial masses

Magnetic Resonance Imaging (MRI) was compared with computerized tomography (CT) in 40 pediatric and adolescent patients with intracranial mass lesions as part of an ongoing project to determine the potential of MRI as a primary and definitive imaging modality. Multiplanar, multisequence MRI surpassed CT in providing mass localization, extent of involvement, and delineating the relationship to adjacent vital structures. Further development of MRI is encouraged to overcome current inconsistencies in pathologic characterization in order for this new technology to be employed not only as a primary screening modality but also as a definitive diagnostic test.     

Charge‐transfer behavior of polyaniline single wall carbon nanotubes nanocomposites monitored by resonance Raman spectroscopy

Highly dispersed nanocomposites of polyaniline(PANI) and oxidized single wall carbon nanotubes(SWNTs) have been prepared using dodecylbenzenesulfonic acid as dispersant. The materials were characterized via resonance Raman and electronic absorption spectroscopies. The behavior of the composites as a function of the applied potential was also investigated using in situ Raman electrochemical measurements. The results obtained at E_laser = 1.17 eV suggest that a charge‐transfer process occur between PANI and semiconducting nanotubes for samples where the metallic tubes are previously oxidized. The spectroelectrochemical data show that the presence of SWNTs prevents the oxidation of PANI rings. Copyright © 2010 John Wiley & Sons, Ltd.     

Microscale localized spectroscopy with a magnetic resonance force microscope

Magnetic resonance force microscopy is combined with spin-echo spectroscopy to obtain spatially and spectrally resolved NMR signals of micrometer-scale objects. The experimental spatial resolution for the demonstration experiment on a sample consisting of Ba(ClO3)2.H2O and (NH4)2SO4 single crystals is 3.4 microm. The spectral resolution of 3.4 kHz is sample limited. Improvements in resolution and extensions of the method to more than one spatial dimension and to multidimensional spectroscopy are possible.     

Spin waves in a ferromagnet with a moving domain wall

An exact solution of the equation for spin waves propagating along the normal to the domain wall is derived for a ferromagnet with a 180° domain wall moving at constant speed, and the radiation of spin waves in rf fields is investigated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 66–69, April, 1979.     

Current-induced domain wall motion in magnetic nanowires with spatial variation

We model current-induced domain wall motion in magnetic nanowires with the variable width. Employing the collective coordinate method we trace the wall dynamics. The effect of the width modulation is implemented by spatial dependence of an effective magnetic field. The wall destination in the potential energy landscape due to the magnetic anisotropy and the spatial nonuniformity is obtained as a function of the current density. For a nanowire of a periodically modulated width, we identify three (pinned, nonlinear, and linear) current density regimes for current-induced wall motion. The threshold current densities depend on the pulse duration as well as the magnitude of wire modulation. In the nonlinear regime, application of ns order current pulses results in wall displacement which opposes or exceeds the prediction of the spin transfer mechanism. The finding explains stochastic nature of the domain wall displacement observed in recent experiments.     

Single domain wall dynamics in ferromagnetic lamination with variable conductivity

The influence of variable conductivity and thickness of two outer non-ferromagnetic layers on magnetization reversal of one central ferromagnetic layer is theoretically investigated. The model of a thin rigid 180°$180°$ domain wall moving transversely through the axially magnetized ferromagnetic layer is used to calculate induced eddy currents in lamination from which the domain wall mobility is determined. The effect of asymmetric distribution of eddy currents around moving domain wall results in acceleration of the wall near the edge of the lamination. The known domain wall mobility in ferromagnetic lamination can then be used to determine either the conductivity or the thickness of deposited outer non-ferromagnetic layers as proposed in discussion.     

Magnetoresistance in a constricted domain wall

We show that a thin Gd layer inserted between two thicker layers of permalloy contains an in-plane domain wall whose width can be controlled by varying the thickness of the Gd layer. The magnetoresistance of this structure has been measured with the current perpendicular to the plane, thus eliminating spurious contributions which have complicated previous measurements. This is the first measurement to show unambiguously that the domain wall contributes an additional resistance whose magnitude is in good agreement with theory.     

Transient dynamics of pinning of domain wall

We study the evolution of an elastic string, serving as model for a domain wall, into the pinned state at driving forces slightly below the depinning threshold force F_c. We quantify the temporal evolution of the string by an activity function A(t) representing the fraction of active nodes at time t and find three distinct dynamic regimes. There is an initial stage of fast decay of the activity; in the second, intermediate, regime, an exponential decay of activity is observed; and, eventually, the fast collapse of the string towards its final pinned state results in decay in the activity with A_r∼(t_p−t)^ψ, where t_p is the pinning time in the finite system involved.     

Spin excitations of a ferromagnetic wire with a magnetic domain wall

The spin excitation for a ferromagnetic wire with a domain wall (DW) is studied in a framework of the random phase approximation. We show that the excitation energy due to the DW is much smaller than that for the spin wave. In the spin-wave spectrum, there are lots of peaks or shoulders, which is related to the existence of the DW and the dimension of the leads. Using the results, the energy dissipation of conduction electrons is also discussed.     

Nuclear quadrupole resonance exchange spectroscopy with shaped radiofrequency pulses

Recent work on the nuclear quadrupole resonance (NQR) investigation of molecular dynamics in the solid state has relied on 2D methods. We report our studies of dynamic processes by 1D shaped pulse NQR spectroscopy. Significant advantages include considerably shorter experimental duration, clear definition of the exchange time window, and avoidance of off-resonance effects. The reorientation of the Cl₃C? group in polycrystalline chloral hydrate [Cl₃C–CH(OH)₂] is considered as a test case. This may be modelled as a three-site exchange process. An analysis of the generalised Bloch–McConnell equation is performed to formulate the kinetic matrix. The present approach involves simultaneous excitation of the sites that undergo chemical exchange by employing a suitably modulated shaped RF pulse, followed by a mixing time, and finally a suitable read pulse for signal detection. The experimental signal intensities are plotted against the mixing time to extract the kinetic parameters, i.e. the exchange rate and the spin-lattice relaxation rate. Variable temperature measurements are carried out to determine the activation parameters. Short experiment times are possible in our 1D mode, enabling a large number of runs to be readily performed as a function of mixing time and temperature. The kinetic and activation parameters obtained in the case of chloral hydrate are in good agreement with recent literature values.