Heat capacity anomalies in Fe8 single crystal

A preliminary heat capacity study of Fe₈ molecules as a function of applied magnetic field, temperature and measuring frequency is presented. The heat capacity versus temperature curve shows in zero field several peaks between 2 and 3 K. The anomalies shift to a lower temperature when a magnetic field is applied. With increasing field the peaks are smeared. No frequency dependence could be established in the measured range of ω =217–4440 Hz. We have also performed heat capacity measurements as a function of magnetic field at fixed temperature. Between 2 and 3 K a pattern of well developed peaks at discrete magnetic field values is observed. The pattern strongly changes in the small temperature range between 2.3 and 2.5 K.     

金属间化合物DyMn_2Ge_2的自发磁相变和场诱导的磁相变

在 10— 80 0K的温度范围内用X射线衍射方法测量了DyMn2 Ge2 化合物的晶格常数与温度的变化关系 ,观察到高温时DyMn2 Ge2 由顺磁状态到反铁磁状态的自发磁相变伴随着晶格常数a的负的磁弹性异常现象 .在4 2K— 2 0 0K的温度范围内测量了DyMn2 Ge2 的交流磁化率 .在交换相互作用的分子场模型近似下 ,从理论上分析讨论了DyMn2 Ge2 的低温自发磁相变和场诱导的磁相变 .计算了DyMn2 Ge2 单晶的磁化强度与温度的变化关系以及不同温度下外磁场沿晶轴c方向时的磁化曲线 .理论分析和计算结果表明 ,温度低于 33K时在DyMn2 Ge2 中观察到的场诱导的一级磁相变为由亚铁磁状态 (Fi)到中间态 (IS)相变 .     

Accumulation of cold cesium molecules via photoassociation in a mixed atomic and molecular trap

We have realized a mixed atomic and molecular trap, constituted by a Cs vapor-cell magneto-optical trap and a quadrupolar magnetic C s(2) trap, using the same magnetic field gradient. We observed the trapping of 2x 10(5) molecules, formed and accumulated in the metastable a (3)Sigma(+ )(u) state at a temperature of 30+/-10 microK through a approximately 150 ms photoassociation process. The lifetime of the trapped molecular cloud limited by the Cs background gas pressure is on the order of 1 s.     

Nonequilibrium Phase Transition in Spin-S Ising Ferromagnet Driven by Propagating and Standing Magnetic Field Wave

The dynamical response of spin-S(S=1, 3/2, 2, 3) Ising ferromagnet to the plane propagating wave, standing magnetic field wave and uniformly oscillating field with constant frequency are studied separately in two dimensions by extensive Monte Carlo simulation. Depending upon the strength of the magnetic field and the value of the spin state of the Ising spin lattice two different dynamical phases are observed. For a fixed value of S and the amplitude of the propagating magnetic field wave the system undergoes a dynamical phase transition from propagating phase to pinned phase as the temperature of the system is cooled down. Similarly in case with standing magnetic wave the system undergoes dynamical phase transition from high temperature phase where spins oscillate coherently in alternate bands of half wavelength of the standing magnetic wave to the low temperature pinned or spin frozen phase. For a fixed value of the amplitude of magnetic field oscillation the transition temperature is observed to decrease to a limiting value as the value of spin S is increased. The time averaged magnetisation over a full cycle of the magnetic field oscillation plays the role of the dynamic order parameter. A comprehensive phase boundary is drawn in the plane of magnetic field amplitude and dynamic transition temperature. It is found that the phase boundary shrinks inwards for high value of spin state S.Also in the low temperature(and high field) region the phase boundaries are closely spaced.     

Thermal Hall-Senftleben effect

A new effect is predicted, namely, the occurrence of a heat flow perpendicular to both the temperature gradient and the magnetic field in solid dielectrics with unfrozen rotational degrees of freedom of molecules. The method of moments is developed with allowance made for the processes of phonon scattering by molecules with a change in their rotational state.     

Field-induced magnetic transition in a mixed rare-earth aluminum garnet Er<Subscript>2</Subscript>HoAl<Subscript>5</Subscript>O<Subscript>12</Subscript>

The temperature dependence of the ac magnetic susceptibility of a single-crystal mixed rare-earth garnet Er₂HoAl₅O₁₂ has been investigated within the range from 1.8 to 300 K in a zero constant field and in applied bias fields of up to 9 T. In the absence of a constant magnetic field the magnetic susceptibility followed the Curie–Weiss law. The application of a constant magnetic field caused a magnetic phase transition, the temperature of which increased with increasing magnetic field. The temperature of the maximum of the ac magnetic susceptibility, which is a characteristic of the phase transition, did not show a noticeable dependence on the frequency of the alternating magnetic field.     

Observation of molecules produced from a Bose-Einstein condensate

Molecules are created from a Bose-Einstein condensate of atomic 87Rb using a Feshbach resonance. A Stern-Gerlach field is applied, in order to spatially separate the molecules from the remaining atoms. For detection, the molecules are converted back into atoms, again using the Feshbach resonance. The measured position of the molecules yields their magnetic moment. This quantity strongly depends on the magnetic field, thus revealing an avoided crossing of two bound states at a field value slightly below the Feshbach resonance. This avoided crossing is exploited to trap the molecules in one dimension.     

Orientational Ordering of a Liquid-Crystal Suspension of Carbon Nanotubes in a Magnetic Field

A statistical theory is proposed to describe a suspension of carbon nanotubes in a nematic liquid crystal. The mean-field approach is used, and dispersion attraction, the excluded volume effects, the diamagnetism of liquid crystal molecules, and the strong diamagnetism of nanotubes are taken into account. The influence of the volume fraction of impurity, temperature, and magnetic field on the orientational ordering of a liquid crystal matrix and carbon nanotubes is studied. The concentration and temperature phase transitions in the suspension are investigated for various magnetic fields. The concentration and field shifts of the point of the phase transition between nematic and isotropic or paranematic phases are studied.     

Thermal averaging of the spin-rotation coupling in small molecules leads to an isotropic NMR shielding

It has been known for over 70 years that nuclear spins couple to molecular rotation via a Zeeman interaction. This spin–rotation coupling can be observed as a discrete splitting in molecular beam magnetic resonance experiments, but is quenched by molecular collisions at higher pressures. We show that because of differential thermal population of M_J levels at high magnetic fields, the spin rotation coupling retains a small isotropic component at high field. For all but the smallest molecules at very low temperature, the residual coupling is temperature independent and linear in the magnetic field; it therefore closely mimics the chemical shift. The ‘super spin rotation’ shift may in the future be a necessary correction to ultra – high precision computations of the NMR chemical shielding of small molecules in gases and liquids.     

Heat capacity and entropy of two electrons quantum dot in a magnetic field with parabolic interaction

The thermodynamic properties of two electrons in two dimensional parabolic GaAs quantum dot are studied where both the magnetic field and the e–e interaction are fully considered. The e–e interaction has been treated by a model potential which makes the Hamiltonian exactly solvable. The energy spectrum is used to calculate the canonical partition function, and then we obtain the thermodynamic properties; mean energy, heat capacity and entropy as a function of temperature (T) and magnetic field (B).A steep transition from zero to 4k_B is observed in the heat capacity as a function of temperature for small values of magnetic field and saturates within a small temperature range, also the heat capacity has a peak-like structure at low temperature, while for high magnetic field heat capacity develops a shoulder at 2k_B then it approaches the saturation value with further increase in temperature. The entropy increases with increasing temperature, but at higher temperature, it remains almost independent of the magnetic field. It is shown that, at low magnetic field values, the effect of magnetic field on heat capacity is tangible and it attains a constant value with further increase in magnetic field. Entropy is almost linearly proportional with increasing magnetic field strength.     

Magnetic properties of the HoMn2Ge2 intermetallic compound

The magnetic properties of a tetragonal intermetallic compound, namely, HoMn₂Ge₂, are investigated experimentally and theoretically. The experimental temperature dependences of the initial magnetic susceptibility and the lattice parameters are obtained in alternating and static magnetic fields. The magnetization curves are measured in strong magnetic fields up to 50 T. The parameters of the crystal field and Ho-Mn and Mn-Mn exchange interactions are determined, and the temperature dependence of the magnetic field of the phase transition from an antiferromagnetic phase to a ferromagnetic phase in a magnetic field aligned along the tetragonal axis is calculated.     

Magnetic structure changes in amorphous RE-Fe2 alloys as detected by ultrasonic measurements

The velocity of ultra sound as a function of magnetic field was measured from room temperature to 80 K in amorphous DyFe₂ and TbFe₂. Shear waves polarized parallel to the magnetic field had lower velocities than those polarized perpendicular to the field. The velocity as a function of field reached a minimum in parallel case at a field which increased as the temperature was lowered. The difference between the perpendicular and parallel moduli at 25 kOe has a maximum at roughly one-third the Curie temperature in both samples. A discussion is presented to the relation between these effects and the nature of the magnetic structure of rare earth-iron amorphous materials.     

Two-dimensional oscillator in a magnetic field

The energy and eigenstate spectrum of a charged particle in the electric field of a 2D anisotropic oscillator and in a uniform magnetic field is considered. The exact analytic solution to the problem is obtained for an arbitrary magnetic field strength. The characteristic features of variation of the energy spectrum depending on the magnetic field strength are analyzed. The results of this study are of interest for the quantum-mechanical theory of magnetism and can be used to simulate the magnetic properties of atoms and molecules.     

Oxygen guest molecules in the nanopores of nanographite-network

Magnetic properties of nanographite-network-based nanoporous carbon having high surface area are investigated in the presence of magnetic oxygen guest molecules. The nanographite domains (stacked nanographene sheets) of 2-3 nm average in-plane size have localized spins of non-bonding π-electron state (edge-state) in the zigzag-shaped periphery of individual nanographene sheets. The electron paramagnetic resonance signal of edge-state spins is found to be highly sensitive to the presence of magnetic oxygen molecules. The line-width variation in the limit of lower oxygen pressure (1-20 Pa) shows that the magnetic interaction of oxygen can be divided into two temperature regimes, viz., the regime below 100 K, where chemisorption of oxygen is effective and the regime above 100 K, where only physisorption of oxygen takes place. Here, 100 K marks the energy of physisorption of oxygen molecules on nanographene, which is higher than the condensation energy of oxygen molecules represented by the boiling point of oxygen, 90 K, owing to the capillary effect. Above 100 K, magnetically active physisorbed oxygen molecules work to increase the line-width, which is governed by the dipolar field with oxygen molecules. The presence of a maximum in the line-width around 150 K, which is higher than 100 K, suggests the diffusion motion of oxygen molecules reduces the strength of exchange interaction between the edge-state spins and the oxygen spins as the temperature is elevated.     

Compensation of effective field in the field-induced superconductor kappa-(BETS)2FeBr4 observed by 77Se NMR

We report results of 77Se NMR frequency shift in the normal state of the organic charge-transfer salt kappa-(BETS)2FeBr4 which shows magnetic field-induced superconductivity (FISC). From a simple mean-field analysis, we determined the field and the temperature dependences of the magnetization m(pi) of the pi conduction electrons on BETS molecules. We found that the Fe spins are antiferromagnetically coupled to the pi electrons and determined the exchange field to be J = -2.3T/microB. The exchange field from the fully saturated Fe moments (5 microB) is compensated by an external field of 12 T. This is close to the central field of the FISC phase, consistent with the Jaccarino-Peter local field-compensation mechanism for FISC [Phys. Rev. Lett. 9, 290 (1962)].     

液晶分子理论

本文从修改了的Kobayashi-McMillan哈密顿量出发,(1)在平均场近似下计算了长棒形液晶分子的相图;(2)计算了取向关联函数;(3)对Muta等的同系物液晶磁双折射实验结果做了分析处理,并首次给出了同系物液晶磁双折射实验的定性解释;(4)计算表观指数Δ,得到Δ=1.40;(5)提出了一种与Marcelja关于液晶奇偶效应理论不同的新解释,并首次计算了过冷温度T^*的奇偶效应。 关键词：     

强磁场对Mn-Sb包晶合金相变及凝固组织的影响

以Mn-56.5 wt%Sb包晶合金为研究对象, 进行了不同磁场、不同冷速条件下的凝固实验. 通过对液相线温度、包晶温度的考察, 发现强磁场可以提高Mn-56.5 wt%Sb合金的液相线温度, 且该上升值随磁感应强度的增加而增加, 当所施加的磁感应强度为11.5 T时, 液相线温度升高大约3 ℃, 但施加磁场后包晶反应温度没有明显改变. 对该合金的凝固组织进行定量金相分析发现, 施加磁场后MnSb相明显减少, 该结果与磁场对相变温度的影响相一致. 另外通过X射线衍射分析发现, 强磁场诱发包晶反应生成相MnSb的c轴垂直于磁场方向取向, 而Mn₂Sb相的(311)面平行于磁场方向取向. 对不同冷速凝固的Mn-56.5 wt%Sb合金组织进行定量金相分析结果显示, 强磁场对合金凝固过程的作用效果受到冷却速度的影响. 随着冷却速度的增加, 强磁场对该合金凝固组织中MnSb相的相对含量变化影响效果减弱. 关键词： 强磁场 包晶合金 凝固 相变温度     

Effect of magnetic fields on out-of-plane orientations of nematic liquid crystalline polymers under simple shear flow

The effect of magnetic fields on out-of-plane orientations of liquid crystalline polymers (LCPs) under simple shear flows is numerically analyzed using the Doi–Hess equation. The evolution equation for the probability distribution function of the LCP molecules is directly solved without any approximation closure. The initial director is parallel to the vorticity direction. Two cases of the magnetic fields are considered (1) the magnetic field parallel to the flow direction, and (2) the magnetic field parallel to the velocity gradient direction. For both cases a log-rolling orientation state is detected at low shear rates. However, the director is quickly aligned along the direction of magnetic fields because of the deformation of molecules. The field affects on the scalar order parameter rather than the major orientation direction for the magnetic field parallel to the flow direction. On the other hand regarding the magnetic field along the vorticity gradient direction, the effect of the magnetic field is more remarkable on the major orientation in comparison with the effect on the scalar order parameter. Also it is be found that the order parameter is increased obviously with increasing the magnetic fields. It is an efficient way to improve the performance of LCP materials.     

Magnetocaloric and barocaloric effects in a Gd5Si2Ge2 compound

The first-order phase transition in Gd5Si2Ge2 is sensitive to both magnetic field and pressure.It may indicate that the influences of the magnetic field and the pressure on the phase transition are virtually equivalent.Moreover,theoretical analyses reveal that the total entropy change is almost definite at a certain Curie temperature no matter whether the applied external field is a magnetic field or a pressure.The entropy change curve can be broadened dramatically under pressure,and the refrigerant capacity is improved from 284.7 J/kg to 447.0 J/kg.