Pressure dependence of the soft modes in the model ferroelastics Hg2I2

The pressure dependence of the soft modes in the paraphase (boundary of the Brillouin zone, X point) and the ferrophase (center of the Brillouin zone, Γ point) is studied in the model ferroelastic crystals Hg₂I₂. An anomalous linear pressure dependence of the soft-mode frequency in the paraphase (p<p _c ) is observed. The results obtained and the nature of the ferroelastic phase transition induced in Hg₂I₂ crystals by a high hydrostatic pressure are discussed. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 4, 227–231 (25 February 1996)     

High-power single-frequency tunable solid-state lasers

Experimental results are presented on the achievement of single-frequency tunable lasing in ruby, Nd-glass, and Nd:YAG lasers with electrooptic Q switching of the cavity by the injection of an external signal. An optimization of the parameters is carried out for lasers on neodymium ions in yttrium aluminum garnet, lanthanum beryllate, chromium-doped gadolinium scandium gallium garnet, and lanthanum hexaaluminate with passive Q switching of the cavity by means of lithium fluoride shutters containing F ₂ ⁻ color centers. High-power single-frequency generation of giant pulses is achieved, with the output wavelength tunable over the half-width of the gain lines of the active media. Zh. Tekh. Fiz. 68, 74–79 (October 1998)     

Observation of a dipole contribution to the magnetoresonant soft mode in Fe3BO6

A jump in the frequency of the quasiferromagnetic soft mode in Fe₃BO₆ at the point of the spontaneous orientational phase transitions Γ₂−Γ₄ is observed experimentally. It is shown theoretically that this jump can be explained by the contribution of the dipole interaction to the expression for the quasiferromagnetic soft mode. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 5, 356–359 (10 September 1999)     

Number density and temperature measurements obtained using sensitive diode laser spectroscopy in an argon plasma

The absolute concentration and translational temperature of the 2p₁₀ and 2p₇ excited states of argon have been measured in an inductively coupled plasma chamber under a variety of operating conditions using both calibrated diode laser frequency modulation spectroscopy and cavity enhanced absorption spectroscopy. Accurate lineshape analysis of frequency modulation signals has been employed to extract the desired information, and is corroborated by cavity enhanced measurements. Temperatures are found to vary linearly with pressure from ∼400 K at 20 mTorr (2.7 Pa) to ∼510 K at 90 mTorr (12 Pa) in a 200 W discharge while concentrations peak at 3.25×10⁸ cm^-3 at 30 mTorr (4 Pa) (also in a 200 W discharge). The uncertainty in the recovered temperature is 7%, dominated by uncertainties in the calibration of the frequency scale. PACS 42.62Fi; 52.70kz     

Resistive switching in β-SrV<Subscript>6</Subscript>O<Subscript>15</Subscript>

We investigate the pressure and temperature behavior of current-dependent resistivity of β-SrV₆O₁₅. We observe a switching between states of different resistivities in the insulating state of β-SrV₆O₁₅. In the low pressure phase, the resistive switching appears at temperatures below the semiconductor-insulator transition. In the high pressure phase, under ~1.6 GPa, the switching appears in the temperature range of the phase transition. The existence of switching may imply an important role of strontium off-stoichiometry for the electrical transport in β-SrV₆O₁₅. No electric-field-induced enhancement of the conductivity is observed. However, the conduction is significantly nonlinear under ~1.6 GPa, indicating that the charge order pattern in the high pressure phase is considerably different from that of the low pressure phase.     

Magnetic quantum oscillations in the organic superconductor κ-(BEDT-TTF)2Cu[N(CN)2]Br

The interlayer magnetoresistance of the organic superconductor κ-(BEDT-TTF)₂Cu[N(CN)₂)Br is measured at ambient pressure and under pressures of up to 12.5 kbar. In addition to the slow Shubnikov-de Haas oscillations with a frequency of ≃150 T observed at P⩾5 kbar, rapid oscillations attributed to the magnetic breakdown orbit enveloping an area equal to 100% of the area of the Brillouin zone are found to emerge above B=20 T. The latter oscillations are observed at ambient pressure as well as under pressures of up to 9 kbar. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 3, 190–194 (10 August 1997) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Magneto-optical modulation of a triple-mirror laser beam

Based on calculations and experiments, a He–Ne laser has been developed with effective intracavity magnetooptical modulation at λ = 1.15 μm. A polarization-anisotropic element — a magnetic diffraction grating made of yttrium iron garnet — is mounted in a matched passive arm of the triple-mirror cavity of the laser and serves as the modulator element. Modulation is produced using the Faraday effect, which simultaneously leads to efficient diffraction of the laser radiation on the asymmetric strip domain structure of a magnetic diffraction grating and to rotation of the E vector. The Jones matrix method is used to calculate the frequency and polarization characteristics. These, along with the modulation characteristics, were also studied experimentally. It is shown that amplitude modulation at frequencies up to 180 kHz takes place for small single-pass Faraday rotation angles (θ_F). The threshold frequency is determined by the response time of the magnetizing Helmholtz coil. The depth of modulation is 50%. For θ_F > θ_t (where θ_t is the threshold), frequency modulation takes place with a deviation of up to several megahertz. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 2, pp. 188–193, March–April, 2009.     

Electrical switching and memory phenomena ino-tolidine DDQ under pressure

Electrical switching has been observed ino-tolidine-DDQ at pressures of 7.66 GPa and fields ∼3×10⁵ V/m withσ _ON/σ _OFF≈10³ at a temperature of 300 K. The switching is found to be of the memory type and the sample can be driven back to the low conducting state by applying ac pulses of sufficient magnitude but independent of frequency.     

On microwave transition radiation

The energy of the radiation emitted by an ultrarelativistic (1 GeV) electron at a transition from vacuum into yttrium iron garnet I₃Fe₅O₁₂ at the ferromagnetic resonance frequency (vacuum wavelength 3 cm) is estimated. The energy at this frequency was found to be 10⁻¹³ eV·s. If modern electron accelerators are used (particle current 10 mA), then for 1 s the energy at the ferromagnetic resonance frequency will be of the order of 1 J·s, so that the effect could have practical applications. Zh. Tekh. Fiz. 68, 122–123 (February 1998)     

Study of ferrobielastic twinning in quartz under conditions of uniaxial pressure by the compound acoustic resonator method

The compound acoustic resonator method is used to study the phenomenon of the ferrobielastic transition in single crystals of quartz subjected to uniaxial pressure. Toward this end, a layered structure consisting of an aluminum film/zinc oxide film/aluminum film sandwich was deposited on one of the surfaces of an X-cut plane-parallel quartz plate. This structure served as an electromechanical transducer in such a way that the entire system acted as a multifrequency acoustic resonator. Uniaxial pressure was applied perpendicular to the direction of propagation of the acoustic waves and caused a growth of the frequencies of the resonance peaks of the structures, indicating a change in the velocity of the acoustic waves. The ferrobielastic phase transition, which arises at some threshold pressure (the ferrobielastic switching effect), is characterized by a discontinuous drop in the frequencies of the resonance peaks. The variation of the resonator frequency both below and above the switching threshold correlates with the variation of the so-called “natural” sound velocity determined by the pressure-dependent elasticity constants of the material. The observed frequency jump of the resonance peaks is due mainly to the relatively abrupt change in the dimensions of the crystal. The results of the acoustic measurements allow reliable recording of the switching effect and a study of its properties. Fiz. Tverd. Tela (St. Petersburg) 39, 290–294 (February 1997)     

Surface polaritons in a dielectric at a boundary with a metal in a static electric field

The existence of surface polaritons in a dielectric at a boundary with an ideal metal or superconductor in a static electric field is predicted. The frequency regions in which polaritons exist are substantially different for opposite orientations of the electric field, so that a change in the direction of the field signifies “switching on” or “switching off” of surface polaritons with a fixed frequency. Pis'ma Zh. éksp. Teor. Fiz. 68, No. 12, 876–880 (25 December 1998)     

Quantum beats in excitons in Cu2O

A theoretical study is carried out of quantum beats (QB) in the time-dependent intensities of absorption of a test pulse and of spontaneous luminescence in a Cu₂O crystal under conditions of double optical resonance. It is assumed that pumping is effected by a CO₂-laser pulse which dynamically couples the exciton levels 1s(Γ ₅ ⁺ ) and 2p(Γ ₄ ⁻ ,Γ ₅ ⁻ ,Γ ₃ ⁻ Γ ₂ ⁻ ) and splits them into two or three pairs of quasi-energy levels. The frequency of the test pulse is in resonance with the frequency Γ ₅ ⁺ of the exciton. The corresponding intensities for various directions of the electric vector of the pump field E _L, the polarization vector ξ, and the wave vector q of the test pulse are obtained. The frequency of the quantum beats is twice the Rabi frequency, which for different values of E _L, ξ and q contains different sets of matrix elements of the dipole transitions between the levels 1s(Γ ₅ ⁺ ) and 2p(Γ ₄ ⁻ ,Γ ₅ ⁻ ,Γ ₃ ⁻ Γ ₂ ⁻ ). Thus, by measuring the period of the quantum beats it is possible to determine the unknown matrix elements of the indicated transitions. Fiz. Tverd. Tela (St. Petersburg) 39, 844–847 (May 1997)     

Stimulated Brillouin scattering of CO2 radiation in compressed xenon

Stimulated Brillouin scattering (STBS) and phase conjugation of CO₂ laser radiation have been demonstrated experimentally for the first time in compressed xenon (59 atm at 21°C) located inside the low-Q cavity of this laser. The nonlinear medium was exposed to the action of counterpropagating focused multimode radiation beams. The difference between the frequencies of the longitudinal cavity modes was set at the frequency of the acoustic wave (v _s=32.2±0.3 MHz) excited as a result of STBS by 9.584 μm radiation. The duration of the radiation pulse τ _L was close to the acoustic phonon lifetime (τ _L<τ _ph≈3× 10⁻⁶s). The excitation of STBS was manifested experimentally as the locking of longitudinal modes, an increase in power and energy, and also an increase in the duration of the lasing pulse and a reduction in the divergence to the diffraction limit. Zh. éksp. Teor. Fiz. 116, 1941–1946 (December 1999)     

Pressure dependence of the weak itinerant ferromagnetism of Y(Co1-xAlx)2

Abstract

Y(Co_1-xAl_x)₂ is a weak itinerant ferromagnet for 0.12 < x < 0.20 with a maximum Curie point of about 25 K near x = 0.15. The pressure dependence of the Curie point for samples with 0.14 < x < 0.18 was measured in the temperature and pressure range 5–25 K and 0–8 kbar using a liquid filled lock cell. It was found that T_c was linear in pressure and extrapolated to OK at P_c = 9 ± 1 kbar for all samples. The volume expansion from YCo₂ to x = 0.15 is equivalent to a chemical pressure of -40 kbar so ferromagnetism cannot occur at the lattice constant of YCo₂.     

Ionic switching in mehanochemically synthesized Ag2S-Sb2S3 amorphous superionic conductor

Highly ionically conducting amorphous samples of Ag₂S·xSb₂S₃ (x=0.15−0.40) are mechanochemically synthesized and characterized by X-ray diffraction (XRD), DTA/DSC, electrical and electrochemical methods. The electrical conductivity measurements are carried out as a function of frequency (5 Hz – 13 MHz) and temperature (300 – 380 K). While the ac conductivity of x=0.40 composition obeys the well-known power law σ (ω)=σ (0) + A ωⁿ over the whole frequency range, the x=0.30 sample obeys the above relation only at lower temperatures. The compositions x=0.20 and 0.15 do not follow the famous dispersion relation at higher (MHz) frequencies. The conductivity isotherms of these a-SICs do not superimpose upon application of Summerfield scaling. The scaling behaviour and the variation of ac conductivity with frequency for x=0.20 and 0.15 are explained in terms of switching from the predominantly ionic (at lower frequencies) to the predominantly electronic conduction (at higher frequencies). Paper presented at the 2nd International Conference on Ionic Devices, Anna University, Channai, India, Nov. 28–30, 2003.     

Frequency-stabilized Nd:YVO4 thin-disk laser

We have developed a Nd:YVO₄ thin-disk laser at 914 nm with single-frequency operation and active frequency stabilization to a low-finesse reference cavity. The spectral density of laser frequency noise is analysed by means of noise measurements at the error point of the frequency control loop. To address the 3¹S₀→3³P₁ magnesium intercombination line at 457 nm, we use an external frequency doubling stage based on periodically poled KTiOPO₄ for the generation of more than 150-mW output power at 457 nm. Optical beat signal measurements at 457 nm with a frequency-stable dye laser show a short-time line width of the thin-disk laser of less than 100 kHz. PACS 42.55.Xi; 42.60.Lh; 42.62.Fi; 42.65.Ky     

Extracting microwave energy from a cavity by mode conversion at a coupling window

A study is made of the production of high power nanosecond rf pulses by extracting microwave energy from an oversized cavity by means of conversion, at a coupling window, of the high-Q working mode to an auxiliary mode which is strongly coupled to an external load. It is shown that microwave rf pulse compressors with copper storage cavities and energy extraction by mode conversion at a coupling window can provide gains of 5–13 dB with output signal durations of 20–150 ns and peak powers of 5–10 MW in the 3-cm band and 50–100 MW in the 10-cm band. Rf pulses lasting 30 ns with peak powers of 0.5 MW have been obtained experimentally at a frequency of 9.4 GHz with a gain of 9 dB. Zh. Tekh. Fiz. 68, 92–96 (July 1998)     

Superconductivity in the Ti-D system under pressure

The pressure dependence of the superconducting transition temperature in TiD_0.74 has been measured up to 30 GPa in a diamond high-pressure chamber. It is found that the deuteride TiD_0.74 becomes a superconductor at pressures corresponding to the transition to the high-pressure ζ phase, with a transition temperature that increases from 4.17 to 4.43 K in the interval P=14–30 GPa. The value extrapolated to atmospheric pressure T _c (0)=4.0 K is significantly lower than the superconducting transition temperature (T _c =5.0 K) measured earlier in the metastable state obtained by quenching TiD_0.74 under pressure. It is assumed that the significant difference of the extrapolated value from the superconducting transition temperature in the metastable state after quenching under pressure is caused by a phase transition on the path from the stability region of the ζ phase under pressure to the region of the metastable state at atmospheric pressure. Fiz. Tverd. Tela (St. Petersburg) 40, 2153–2155 (December 1998)     

Very high resolution CO laser spectrometer and first sub-Doppler line-shape studies near 60 THz (5 μm)

2 laser standards. Using this technique, we can tune the CO laser frequency with absolute frequency control within the gain profile of each laser transition. The frequency uncertainty is smaller than 15 kHz, corresponding to Δν/ν=2.5×10^-10. Moreover, we obtain a reduction of the CO laser linewidth by a factor of 2 down to 65 kHz, corresponding to a spectral resolution of δν/ν=1×10^-9. With this outstanding accuracy and resolution we studied the shape of saturation dips in rovibrational lines of CO and carbonyl sulfide (OCS) at low pressure (<5 Pa). The self-pressure-broadening rate of CO was found to be γ_c=+83(7) kHz/Pa in this pressure region. This value is about four times higher than values resulting from previous measurements at much higher pressures. To our knowledge the measurements described here are the first line-shape studies with sub-Doppler resolution in the 5 μm spectral region. Received: 4 November 1996