Precipitation sequences and transformation kinetics in the Al-30 wt.% Zn alloy aged below 160°C

The transformation sequences in the Al-30 wt.% Zn alloy aged below 160 °C have been investigated by X-ray diffraction and transmission electron microscopy. The sequence G.-P. zones _R has been observed between 85 and 161 °C, whereas the direct G.-P. zones to-transformation occurs below 85 °C. The identical isothermal growth kinetics of both the G.-P. zones and the _R -precipitates was found. The log-log plots yielding a set of parallel straight lines from 50 to 150 °C indicate no change in the activation energy of growth of both these precipitates. The change in the precipitation sequence led to the change in the transformation kinetics. The T-T-T curves have been measured for the formation of metastable _R -phase and for the completion of ellipsoidal G.-P. zones or of _R to-transformation. The retardation in reaching equilibrium found below 85 °C was associated with the observed change in the transformation sequence. This was explained by the different accommodation of the misfit at the interfaces between G.-P. zones or _R -precipitates and the-matrix.The authors are much indebted to Doc. Dr. V.Syneek, CSc. for stimulating discussions. Our thanks are also due to Ing. V.íma and Mr. P.Vyhlídka for the preparation and careful chemical analyses of the investigated samples. The assistance of Mr. Z.iký and Mr. V.Petr in X-ray diffraction measurements and the heat-treatment of samples is appreciated.     

The room-temperature decomposition of metastable phases precipitated in the Al-Zn alloys at 200 °C

The room-temperature decomposition of metastable phases in the Al-Zn alloys (from 25 to 50 wt. % Zn) was studied by the transmission electron microscopy and X-ray diffraction. Metastable phases, i.e. G.-P. zones, _R-and -phases, were grown at 200 °C and their decomposition into equilibrium -phase at 20 °C was investigated. Ageing times comprised 1 to 999 days.Both the decomposition mechanism and the rate of decomposition of coherent phases were found to be dependent on the particle sizes and their density reached at 200 °C. The local vacancy supersaturation around the -nucleus in a dense system of G.-P. zones leads to an enhanced growth rate of such nucleus and thus to the formation of one large -precipitate at the expense of several neighbouring G.-P. zones. The elastic stress field around this -particle promotes the further nucleation and growth of -precipitates and leads to their gradual spread throughout the matrix. The decomposition of intermediately sized _Rprecipitates results in the development of -precipitates of comparable sizes nucleated on the array of misfit dislocations at the periphery of _R-precipitates. The cooperative effect between neighbouring particles does not influence the decomposition of large _R-precipitated which split then into several smaller -particles. The rate of G.-P. zones or _R to -decomposition increases with the increasing sizes of transition precipitates and with the zinc content of the alloy. The kinetics of to -decomposition was found to be independent both on the annealing time at 200 °C and on the investigated alloy composition. This can be attributed to the constant density of misfit dislocations as nucleation sites for -precipitates along the -matrix interface and to the large mutual separation of -precipitates in all these alloys.In conclusion we would like to express our thanks to Doc. Dr. V.Syneek, CSc. for his valuable discussions and to Ing. V.íma for the preparation of Al-Zn alloys. Our thanks are also due to Mr. Z.iký for his help in the X-ray diffraction measurement and to P.Vyhlídka for the careful chemical analyses of the investigated alloys.     

A resistometric investigation of the decomposition kinetics of Al-21·8 at.% Zn solid solution at 276 °C

Under the condition of nearly equilibrium concentration of vacancies, time dependence of the amount of isothermal transformation given byy=R/R _f was investigated whereR _f is the total structural change of resistivity on completion of the whole process andR is the measured resistivity change. The investigation was done on the 21·8 at.% (40·3wt.%) Zn alloy under the condition of relatively low supersaturation of a few degrees centigrade below the metastable _R solvus line. The total transformation involves four kinetic stages: the first two stages correspond probably to diffusion-controlled growth of the _R particles from the supersaturated solid solution and to the ripening of these particles till their conversion to the cubic phase takes place. The last two kinetic stages account analogously for the particles growth and ripening. Both _R and phases were identified by the transmission electron microscopy. When separating the individual stages, the approximation byy=1–exp [–(mt) ⁿ] of the amount of transformationy was used. The approximation allowed to get the starting values of both the time and the change of the structural part of the electrical resistance for individual stages and also to derive the parametersm _i, n_i which had to be redetermined for the individual separated stages. These data made it possible to synthetize the experimental curves ofR andy vs. time for the total transformation.It is a pleasure to thank Doc. Dr. V.Syneek CSc. for stimulating the author's interest in this problem and for providing helpful discussions. I also would like to express my thanks to Ing. P.Bartuka CSc. for the transmission electron microscopic study carried out to identify the particular phases. The author is indebted to Ing.V. íma for the preparation of the investigated alloy and to Mrs. A.Mendlová and Mr. P.Vyhlídka for technical assistance.     

Phase transformations in Cu-Sn alloys containing Ni,Al, Ge,and In

After quenching from 700C and aging, Cu-Sn alloys containing Ni and Al were found to have a precipitation of-solid solution, with a DO₃ type of ordering, of metastable ,, and phases. It was established that the phase has an 4 type of ordering while the phase has the Cu₃Ti type. Observations revealed that Cu-Sn-Al alloys contained two phases, and, with an identical structure but with different ratios of electron concentration per atom.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 34–37, April, 1981.     

Perturbations of flows on Banach spaces and operator algebras

For automorphism groups of operator algebras we show how properties of the difference _t – ' _t are reflected in relations between the generators , . Indeed for a von Neumann algebraM with separable predual we show that if _t – '_t 0.28 for smallt, then = 0(+)°^-1 where is an inner automorphism ofM and is a bounded derivation ofM. If the difference _t – ' _t =O(t) ast ; 0, then = + and if _t – ' _t 0.28 for allt then =. We prove analogous results for unitary groups on a Hilbert space andC ₀,C ₀ ^* groups on a Banach space.This paper subsumes an earlier work of the same title which appeared as a report from Z.I.F. der Universität BielefeldWith partial support of the U.S. National Science Foundation     

Radiative and nonradiative transitions to an unstable state

In this paper an expression is obtained, which enables us to treat radiative and nonradiative transitions in complex molecular systems, when the final state is unstable. Expressions are give for the matrix elements E/v and E|d/dR|v , where the stable state is described by a solution with a Morse potential, and the unstable state by a solution with a Hulthen potential. The possibility of the concrete realization of such transitions is discussed in the example of excimers.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 10, pp. 70–75, October, 1974.     

Small perturbations ofC*-dynamical systems

It is shown that if is the generator of a strongly continuous oneparameter group of *-automorphisms of aC*-algebraA and is an unbounded *-derivation ofA with the same domain as , then + is also a generator for all sufficiently small real numbers .     

Higher Conformal Multifractality

We derive, from conformal invariance and quantum gravity, the multifractal spectrum f() of the harmonic measure (i.e., electrostatic potential, or diffusion field) near any conformally invariant fractal in two dimensions. It gives the Hausdorff dimension of the set of points where the potential varies with distance r to the fractal frontier as r . First examples are a random walk, i.e., a Brownian motion, a self-avoiding walk, or a critical percolation cluster. The generalized dimensions D(n) as well as the multifractal functions f() are derived, and are all identical for these three cases. The external frontiers of a Brownian motion and of a percolation cluster are thus identical to a self-avoiding walk in the scaling limit. The multifractal (MF) function f(,c) of the electrostatic potential near any conformally invariant fractal boundary, like a critical O(N) loop or a Q-state Potts cluster, is given as a function of the central charge c of the associated conformal field theory. The dimensions D _EP of the external perimeter and D _H of the hull of a critical scaling curve or cluster obey the superuniversal duality equation . Finally, for a conformally invariant scaling curve which is simple, i.e., without double points, we derive higher multifractal functions, like the universal function f ₂(,) which gives the Hausdorff dimension of the points where the potential varies jointly with distance r as r on one side of the curve, and as r on the other. The general case of the potential distribution between the branches of a star made of an arbitrary number of scaling paths is also treated. The results apply to critical O(N) loops, Potts clusters, and to the SLE process. We present a duality between external perimeters of Potts clusters and O(N) loops at their critical point, as well as the corresponding duality in the SLE process for =16.     

Some results for the exponential interaction in two or more dimensions

We show that for the regularized exponential interaction :e : ind space-time dimensions the Schwinger functions converge to the Schwinger functions for the free field ifd>2 for all or ifd=2 for all such that ||>₀.Partially sponsored by the I.H.E.S. through the Stiftung Volkswagenwerk     

A solution spectrum of the nonlinear Schrödinger equation. II

It was shown in a previous communication that the nonlinear Schrödinger equation exhibits a spectrum of eigenfunctions of the form = _k,A _k (coshkx) ^–k and = _k B _k (coshkx) ^–k–1sinhkx, and the corresponding eigenvalues of the energy are related to a band structure with a characteristic energy gap as a significant feature. In the present paper, it is shown that a further spectrum exists exhibiting the general structure = _k=0 A _k(cosh kx)^–k–1/2and = _k=0 B_k(cosh kx)^–k–3/2sinhkx and yielding also a band structure. An extension of the solution spectrum to a nonlinear Klein-Gordon equation and a nonlinear Dirac equation does not imply essential difficulties, and the corresponding characteristic band structure has to be related to a mass spectrum.     

Upper bounds onT c for one-dimensional Ising systems

We present upper bounds on the critical temperature of one-dimensional Ising models with long-range,l/n interactions, where 1<2. In particular for the often studied case of =2 we have an upper bound onT _c which is less than theT _c found by a number of approximation techniques. Also for the case where is small, such as =1.1, we obtain rigorous bounds which are extremely close, within 1.0%, to those found by approximation methods.     

Lattice vibrations in ordered and disordered thiourea

The critical dynamics of the Syozi model for dilute ferromagnetism is considered by the use of master equations. The dynamics is soluble as it is assumed that the time scale of motion on the sublattice on which the impurities move is so much faster than on the other sublattice that fast relaxing variables may be adiabatically eliminated, leaving a new soluble master equation. It is found that the linear and non-linear relaxation of magnetization exponents ^(l) and ^(nl) increase on dilution to ^(l)/(1–) and ^(nl)/(1–) respectively ( is the specific heat exponent for the pure system, which itself changes on dilution to –/(1–)). Thus if the exponents for the pure system obey the scaling law of Rácz and Fisher ^(nl)= ^(l)– ( is the magnetization exponent which changes on dilution to /(1–)) then so do the exponents for the diluted system. Similarly the exponent for spin diffusion changes on dilution to /(1–).     

InGaAs/GaAs multiple-quantum-well modulators and switches

The design, fabrication and characterization of electrooptical modulators and switches based on pseudomorphic InGaAs/GaAs multiple-quantum-well (MQW) structures is presented. The absorption and refractive index changes (, n) of In_0.2Ga_0.8As/GaAs MQW structures due to the quantum-confined Stark effect are examined in detail. The figures of merit /₀ and n/₀ give information on the design of modulation and switching devices. Based on these results, we develop two types of efficient and high-speed modulators, vertical and waveguide modulators, and for the first time an InGaAs/GaAs intersectional X-type switch. Recent experimental results for each device are presented.     

Low-temperature and long-time anomalies of a damped quantum particle

The time evolution of a damped quantum particle is discussed. Dissipation is modeled by the bilinear coupling to a set of harmonic oscillators. Using a functional integral technique that accounts for initial correlations between the particle and the reservoir, one can express the dynamics of the damped particle entirely in terms of equilibrium correlation functions. The long-time behavior of these correlations is determined for memory damping arising from the coupling to a reservoir with spectral densityI() at low frequencies, where > 0. The time evolution of nonequilibrium initial states of the damped particle is discussed. At finite temperatures an initially localized state is found to spread subdiffusively or superdiffusively, depending on . For > 2 the damping becomes ineffective for long times, and the width of a state grows kinematically. At zero temperature and for < 1, an initially localized state remains localized for all times. For 1 the state spreads, but with a slower rate than at finite temperatures. Study of arbitrary initial states indicates that the process is ergodic at finite temperatures only for 2 and at zero temperature for 1 2.     

Spectroscopic ellipsometric characterization of organic films obtained via organic vapor phase deposition

Thin films of Tris(8-hydroxyquinoline)-aluminum(III) (Alq₃) and N,N-Di-[(1-naphthyl)-N,N-diphenyl]-(1,1-biphenyl)-4,4-diamine (-NPD ) were deposited on large-area silicon substrates by means of the recently developed organic vapor phase deposition (OVPD) method. Variable-angle spectroscopic ellipsometry was used to measure the optical constants of OVPD Alq₃ and -NPD layers in the 0.8–5 eV energy range. The absorption onset which defines the lower limit of the optical band gap was found to be at 2.65 eV and 2.9 eV for Alq₃ and -NPD , respectively. Additionally, the thicknesses of the layers as well as the thickness profiles of the organic thin films were determined along the 8 diameter of the wafers. The thickness analysis revealed large-area uniform deposition of the films. PACS 78.20.Ci; 81.70.Fy; 81.15.-z     

Theα-α′ phase transition of hydrogen in elastically anisotropic cubic metals

The formulation of the statistical mechanics of the - phase transition in hydrogenmetal-systems is extended in such a way as to include the elastic anisotropy of the host crystal. The corresponding reduction of symmetry leads to qualitative modifications of the results. Depending on hydrogen concentration and temperature, phases with homogeneous,C ₃- andC ₂-symmetric equilibrium hydrogen distributions are formed. The transitions between these phases are investigated, and the relation of their orders and the corresponding changes in symmetry is studied. Differences between isotropic and anisotropic systems are discussed.     

Calculation of hyperfine interactions measured by magnetic decoupling in oxygen ions

Magnetic hyperfine interactions in highly stripped oxygen ions recoiling in vacuum have been measured with perturbed angular correlations. The second excited state of¹⁶O(I =3^–,E _X=6.13 MeV, =26.6 psec, |g|=0.55) was produced with the nuclear reactions¹⁹F(p,)¹⁶O and¹⁶O(,)¹⁶O and the angular correlation of the -rays observed in coincidence with particles emitted at 180°. Five recoil velocities between 1.0 and 3.3% c produced average ion charge states from 2.1 to 5.5. The perturbation of the angular correlation and hence the decoupling of the hyperfine interactions was observed as a function of an external axial magnetic field varied between 0 and 33 kG. The perturbation is expected to arise primarily from hyperfine interactions of unpaired 1s electrons with smaller contributions from 2s electrons and other configurations. The maximum external field was strong enough to decouple all hyperfine interactions except that of the 1s electrons. The decoupling curves obtained were successfully fitted by calculations using the hyperfine interactions of the pertinent atomic Hartree-Fock-Slater orbitals.Supported in part by the National Science Foundation.     

Nelson's symmetry and the infinite volume behavior of the vacuum inP(φ)2

LetH _l be the Hamiltonian in aP()₂ theory with sharp space cutoff in the interval (–l/2,l/2). LetE _l =inf(H _l ), (l)=–E _l /l, and let _l be the vacuum forH _l . discuss properties of (l) and _l . In particular, asl, there are finite constants <0 and such that (l), ((l)–)l, and hence (l)=+/l+o(l ^–1). Moreover exp(–c ₁ l) _{l 1}exp(–c ₂ l) forc ₁,c ₂ positive constants, where _{l 1} is theL ¹(Q, d₀) norm of ₁ with respect to the Fock vacuum measure. We also present a new proof of recent estimates of Glimm and Jaffe on local perturbations ofH _l in the infinite volume limit.Research sponsored by AFOSR under Contract No. F44620-71-C-0108.On leave from Istituto di Fisica Teorica, Universitá di Napoli and Istituto Nazionale di Fisica Nucleare, Sezione di Napoli.A. Sloan Foundation Fellow.     

Natural boundaries for area-preserving twist maps

We consider KAM invariant curves for generalizations of the standard map of the form (x, y)=(x+y, y+f(x)), wheref(x) is an odd trigonometric polynomial. We study numerically their analytic properties by a Padé approximant method applied to the function which conjugates the dynamics to a rotation +. In the complex plane, natural boundaries of different shapes are found. In the complex plane the analyticity region appears to be a strip bounded by a natural boundary, whose width tends linearly to 0 as tends to the critical value.     

Decomposition of an Fe-Cr 38 wt.% chromium stainless steel at 475 °C

The physical changes occurring at 475 °C in an Nb and Al stabilized stainless steel containing 38 wt.% Cr have been studied by Mössbauer spectroscopy. The specimen started to decompose when held at 475 °C. Decomposition still continues after 500 hours into a paramagnetic Cr-rich -phase and a nearly pure Fe -phase. The magnetic field distribution of the initial sample indicates that considerable decomposition has already taken place into an -phase with an estimated 15 at.% iron, and an iron-rich -phase with an estimated 18 at.% Cr.