Dielectric properties of nano-particles of zinc sulphide

The dielectric properties of nano-particles of ZnS have been studied over a temperature range from 300 to 525 K. The dielectric constant, dielectric loss and ac conductivity of the samples are larger than those of bulk ZnS crystals. Dielectric properties of composites consisting of nano-particles of Ag of different concentrations dispersed in nano-particles of ZnS have also been studied.     

Some insights in the sonochemical preparation of cobalt nano-particles

The preparation of cobalt nano-particles from a solution of Co(CO)₃(NO) in n-decane under ultrasonication with a frequency of 20 kHz yielded cobalt particles of a size of ca. 5 nm. The presence of either silica or oleic acid in the solution reduced the particle size to ca. 3 and 2 nm, respectively. The resulting particle size is independent of the ultrasonication time, initial Co(CO)₃(NO) concentration, ultrasound intensity and solution temperature. It is postulated that bubble collapse generates multiple nucleation sites resulting in the formation of cobalt particles with a rather uniform particle size distribution.     

斜角入射沉积法制备渐变折射率薄膜的折射率分析

斜角入射沉积法是一种制备薄膜的新颖方法,它可以用来制备渐变折射率薄膜.本文首先探讨了膜料的沉积入射角为α,薄膜柱状生长倾斜角为β时的薄膜的填充系数;之后利用drude理论,分析研究了斜角入射沉积法制备渐变折射率薄膜的折射率与薄膜的入射角和生长方向的关系. 关键词： 斜角入射沉积 渐变折射率 填充系数     

Refractive index sensing by using Fano resonance enhanced two‐photon luminescence

Utilizing three‐dimensional vectorial electromagnetic simulation, we propose a new refractive index sensing mechanism based on Fano resonance enhanced two‐photon‐absorption induced luminescence (TPL). The TPL from gold nanodisk heptamer (GNDH), which is affected by the refractive index of surrounding material, is used as an example to demonstrate the sensing mechanism facilitated by Fano resonance. The sensitivity of our method is about one order of magnitude better than the conventional refractive index sensing strategy employing plasmonic Fano resonance, while the size of the sensing probe can be further reduced at the same time.

     

Photonic crystal refractive index sensing based on sandwich structure

An ultracompact refractive index sensing based on the sandwich structure of photonic crystal is presented and demonstrated with solutions of water, methylsilicone and silicone. The performances of the sensor are analyzed theoretically by using Fabry-Perot cavity mode, the change in opposite direction between the transmission of the refractive index sensing and its quality factor is derived. The experimental results are consistent with the results of theoretical analysis.     

Design and synthesis of plasmonic magnetic nanoparticles

Core–shell nanoparticles containing both iron oxide and gold are proposed for bioseparation applications. The surface plasmon resonance of gold makes it possible to track the positions of individual particles, even when they are smaller than the optical diffraction limit. The synthesis of water-dispersible iron oxide-gold nanoparticles is described. Absorption spectra show the plasmon peaks for Au shells on silica particles, suggesting that thin shells may be sufficient to impart a strong surface plasmon resonance to iron oxide-gold nanoparticles. Dark field optical microscopy illustrates the feasibility of single-particle detection. Calculations of magnetophoretic and drag forces for particles of different sizes reveal design requirements for effective separation of these small particles.     

太赫兹波段电磁超材料吸波器折射率传感特性

太赫兹超材料吸波器作为一类重要的超材料功能器件,除了可以实现对入射太赫兹波的完美吸收外,还可以作为折射率传感器实现对周围环境信息变化的捕捉与监测.通常从优化表面金属谐振单元结构和改变介质层材料和形态两个方面出发,改善太赫兹超材料吸波器的传感特性.为深入研究中间介质层对太赫兹超材料吸波器传感特性的影响,本文基于金属开口谐...     

Refractive index profiling across a candle flame using speckle techniques

Refractive index profiles have been obtained at different heights in the region above a candle flame both theoretically and experimentally by means of double and multiple exposure speckle photography. Improved fringe visibility has been achieved in the case of the multiple exposure technique giving rise to accurate measurement of the refractive index. Theoretical analysis shows that the resulting speckle pattern is equivalent to the ordinary pattern convolved with a function representing the effect of light deflection, while the interference pattern obtained is modulated by a background representing the autocorrelation function of the diffuser.     

Experimental research of liquid refractive index sensing by optical fiber and colloidal crystal's photonic band-gap

We use the changes of colloidal photonic crystal photonic band-gap center wavelength to research the refractive index sensing by experiment. The changes in the center wavelength of the colloidal crystals photonic band-gap are analyzed. A mold is designed to obtain a controllable self-assembly method, colloidal crystals are observed by scan electronic microscope (SEM) and the band-gap is measured by infrared spectrometer. The results are agreed well with the theoretical analysis. An experimental device is designed to test liquid refractive index. The couple of the fibers are used to measure the band-gap of colloidal crystals and the results are also discussed in theory. The results show that the band-gap of colloidal crystals can be used to measure the liquid refractive index. The new sensing mechanism is formed and it provides a new application of colloidal crystals in the sensing.     

Refractive index of a gravitational wave

The problem of the interaction of a gravitational wave with an elastic body, taking account of the secondary gravitational radiation by the vibrating particles of the body, is solved on the basis of a theory of elasticity in the general theory of relativity (GTR) constructed by the author.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 52–57, September, 1976.In conclusion, I am grateful to V. I. Rodichev and D. D. Ivanenko for their interest in this work and for their stimulating criticism.     

Dielectric supported ring-shaped metal disks on a metal film for ultrasensitive refractive index sensing

We experimentally report a magnetic plasmonic metamaterial, which is constructed with a metal ring-shaped disk array supported by a dielectric layer on a metal film for high sensitive refractive index sensing. An ultrasensitive refractive index sensitivity of about 1842?nm per refractive index unit is achieved through the reflection spectrum measurement. We attribute the high sensitivity to greatly enhanced electric field intensity and its large spatial overlapping with the surrounding medium to sense. The present plasmonic structure provides an effective way for high sensitive chip-based biochemical sensors and integrated devices.     

Refractive index measurement by spectrally resolved interferometry using a femtosecond pulse laser

We describe a measurement method of refractive indices by way of spectrally resolved interferometry using a femtosecond pulse laser. The method is dispersion insensitive and requires no prior precise knowledge of the geometrical thickness of the specimen. Not only the group but also the phase refractive index can be determined over the wide spectral range covered by the optical comb of the femtosecond pulse laser in use.     

基于椭球封闭空气腔的光纤复合法布里-珀罗结构折射率传感特性研究

提出了基于微椭球型空气腔的在线型光纤复合法布里-珀罗干涉结构,并对其折射率传感特性进行了研究.椭球型空气微腔是利用光纤熔接机对实芯光子晶体光纤和单模光纤以特定的熔接参数熔接形成.用高斯光束模型和ABCD法则分析了椭球型空气腔的腔内损耗,建立了电磁场在复合法布里-珀罗干涉结构中传播的物理模型.根据腔长比值的不同,环境折射率对干涉条纹的影响有对比度调制和波长调制,主要研究了一种波长调制型复合法布里-珀罗结构折射率传感器.仿真结果表明该折射率传感器在1—1.6范围内不出现折射率转折点;实验结果表明在1.333—1.466范围内,折射率灵敏度～37.088 nm·RIU-1,分辨率约为2.69×10-5.该光纤复合法布里-珀罗结构干涉条纹对比度高、体积小、成本低,用于折射率测量可靠性高、分辨率高、无折射率拐点、温度串扰小.     

Analytical approximations of the dispersion relation of a linear chain of metal nanoparticles

We find some useful analytical approximations of the dispersion relation of a linear chain of metal nanoparticles in the subwavelength limit where the dipolar approximation can be used. We also approximate the group velocity without a direct estimation of the derivative of the dispersion relation, that carries unavoidable error amplifications. In the end we use these results in order to get some simple recipes that evaluate the sensitivity of the dispersion relation and the propagation losses with respect to the main parameters of the chain.     

Refractive index profiling of a GRIN optical fiber using a modulated speckled sheet of light

A method for calculating the refractive index of GRIN optical fiber from its transverse interference pattern is presented.In this method the transverse interference fringe pattern through an optical fiber using a sheet of light is applied to get the refractive index profile of it. The optical fiber is not immersed in a matching liquid as used in different techniques [Barakat N, El-Hennawi HA, El-Zaiat SY, Hassan R. Pure Appl Opt 1996;5:27].In this method a sheet of He–Ne laser light is allowed to illuminate the fiber. The light sheet is divided into two parts, the first is refracted through the fiber while the second is used as a reference beam. Interference pattern will be obtained between these two rays displaying the refractive index variation along the fiber radius.The fringe shift of such interference pattern has been measured and used to calculate the deflection angle of light refracted by the fiber and the cladding. An equation is derived to calculate the refractive index profile difference ratio δn at different positions across the fiber cross section in terms of the corresponding deflection angle and is verified experimentally.The optical path difference between these two rays (refracted and reference beam divided by the fiber) has been derived and the fringe shift obtained has been used to calculate the refractive index profile of the fiber.Introducing a ground glass screen on the passage of the two light beams (refracted and reference beam divided by the fiber), two superimposed identical speckle patterns are formed leading to the formation of a third speckle pattern modulated by a grid structure displaying the optical thickness of the fiber.     

Thermodynamic calculations of linear chain molecules using a SAFT model

The recently proposed model of statistical associated-fluid theory (SAFT) by Tang, Y. and Lu, B. C.-Y. (2000, Fluid Phase Equilibria, 171, 27) is applied to phase diagram calculations of non-associating and associating linear chain molecules in which n-alkanes and n-alkenes (representing the non-associating type) and water, 1-alkanols, acids and amines (representing the associating type) are investigated. For polar molecules, the dipole-dipole interaction is taken into consideration. Overall, the proposed model yields similar accuracy to the original SAFT model, It is found that the volume and energy parameters of non-associating chain segments in the same family follow certain linear relations with the carbon number. Remarkably, these linear relations are found to hold equally well in associating chain molecules. These observations suggest that SAFT may be implemented in a more predictive manner. Furthermore, the inclusion of the contribution from dipole-dipole interaction improves the calculated values for strong polar molecules like water.     

A novel strategy for producing nano-particles from date seeds and enhancing their phenolic content and antioxidant properties using ultrasound-assisted extraction: A multivariate based optimization study

Date seeds from the date palm fruit are considered as a waste and they are known to contain several bioactive compounds. Producing nanoparticles from the date seeds can enhances their effectiveness and their utilization as novel functional food ingredients. In this study, date seed nanoparticles (DSNPs) synthesized using acid (HCl) hydrolysis method (HCl concentration of 38% and hydrolysis time of 4 days) was found to have particle size between 50 and 150 nm. The obtained DSNPs were characterized by measuring particle size and particle charge (Zetasizer), morphology using scanning electron microscope (SEM), and determination of the functional groups using fourier-transform infrared spectroscopy (FTIR). DSNPs were further treated with green extraction technology [ultrasound-assisted extraction (UAE)] using water-based and methanol-based solvent for optimizing the extraction of the bioactive compounds by implementing response surface methodology (RSM). The UAE of DSNPs were analysed for set of responses including total phenolic content (TPC), total flavonoid content (TFC), 1,1-diphenyl-2-picrlthydrazyl (DPPH) radical scavenging activity, ferric ion reducing antioxidant power (FRAP), and 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radical scavenging activity. Three-factor and four-factor Box-Behnken design (BBD) of three models (Synthesis of DSNPs, UAE with water, and UAE with methanol) was performed. The results showed that in UAE of DSNPs using water-based solvent, the key independent factors effecting the TPC and TFC and antioxidant activities were S:L ratio (40:1 mg/ml) and treatment time (9 min). Whereas the methanol-based UAE of DSNPs was mostly affected by US amplitude/power (90%) and methanol concentration (80%). All models were further optimized using response optimizer in Minitab and the generated predicted values were very comparable to the actual obtained results which confirm the significance and validity of all RSM models used. The phenolic compounds identified from DSNPs consisted mainly of 3,4-Dihydroxy benzoic acid, ferulic acid, and p-coumaric acid. The present study demonstrated a successful method for synthesising DSNPs as well as documented the optimum UAE conditions to maximize the extraction of polyphenolic compounds from DSNPs and enhancing their antioxidant activities to be used in food application.     

Magnetic behaviour of nano-particles of Fe<Subscript>2.8</Subscript>Zn<Subscript>0.2</Subscript>O<Subscript>4</Subscript>

Magnetization measurements are reported on a nano-particle sample of Znsubstituted spinel ferrite Fe_2.8Zn_0.2O₄ in the temperature range 20–300 K. Analysis of small-angle neutron scattering data shows the sample to have a log-normal particle size distribution of median diameter 64.4 Å and standard deviation 0.38. Magnetization evolves over a long period of timet going nearly linearly with logt. Magnetic anisotropy, estimated by fitting M-logt curve, shows many fold increase over that of bulk particle sample. Major enhancement owes to disordered moments in surface layer. In the nano-particle state as well increasing amount of Zn causes anisotropy to decrease.     

Optical properties and biomedical applications of plasmonic nanoparticles

Nanoparticle plasmonics is a rapidly emerging research field that deals with the fabrication and optical characterization of noble metal nanoparticles of various size, shape, structure, and tunable plasmon resonances over VIS-NIR spectral band. The recent simultaneous advances in synthesis, characterization, electromagnetic simulation, and surface functionalization of plasmonic nanoparticles by biospecific molecular probes have led to a perfect publication storm in discoveries and potential biomedical applications of plasmon-resonant nanoparticle bioconjugates. Here, we present an overview of these topics. First, we discus basic wet-chemical routes to fabricate conjugates of gold, silver, or composite particles with controllable size, shape, structure and with surface functionalization by biospecific molecules. Second, we consider the single-particle dipole and multipole optics and coupled plasmonic nanoparticle arrays. Finally, we discus application of plasmonic bioconjugates to such fields as homogeneous and solid-phase assays, biomedical sensing and imaging, biodistribution and toxicity aspects, drug delivery and plasmonic photothermal therapy.     

Different nano-particles volume fraction and Hartmann number effects on flow and heat transfer of water-silver nanofluid under the variable heat flux

Nanofluid flow and heat transfer composed of water-silver nanoparticles is investigated numerically inside a microchannel. Finite volume approach (FVM) is applied and the effects of gravity are ignored. The whole length of Microchannel is considered in three sections as l₁=l₃=0.151 and l₂=0.71. The linear variable heat flux affects the microchannel wall in the length of l₂ while a magnetic field with strength of B₀ is considered over the whole domain of it. The influences of different values of Hartmann number (Ha=0, 10, 20), volume fraction of the nanoparticles (ɸ=0, 0.02, 0.04) and Reynolds number (Re=10, 50, 200) on the hydrodynamic and thermal properties of flow are reported. The investigation of slip velocity variations under the effects of a magnetic field are presented for the first time (to the best knowledge of author) while the non-dimensional slip coefficient are selected as B=0.01, 0.05, 0.1 at different states.