Quantum Correlations and Speed Limit of Central Spin Systems

In this article, single, and two-qubit central spin systems interacting with spin baths are considered and their dynamical properties are discussed. The cases of interacting and non-interacting spin baths are considered and the quantum speed limit (QSL) time of evolution is investigated. The impact of the size of the spin bath on the quantum speed limit for a single qubit central spin model is analyzed. The quantum correlations for (non-)interacting two central spin qubits are estimated and their dynamical behavior with that of QSL time under various conditions are compared. How QSL time could be availed to analyze the dynamics of quantum correlations is shown.     

Semi-Classical Dynamics in Quantum Spin Systems

We consider two limiting regimes, the large-spin and the mean-field limit, for the dynamical evolution of quantum spin systems. We prove that, in these limits, the time evolution of a class of quantum spin systems is determined by a corresponding Hamiltonian dynamics of classical spins. This result can be viewed as a Egorov-type theorem. We extend our results to the thermodynamic limit of lattice spin systems and continuum domains of infinite size, and we study the time evolution of coherent spin states in these limiting regimes.     

Decay of a thermofield-double state in chaotic quantum systems

Scrambling in interacting quantum systems out of equilibrium is particularly effective in the chaotic regime. Under time evolution, initially localized information is said to be scrambled as it spreads throughout the entire system. This spreading can be analyzed with the spectral form factor, which is defined in terms of the analytic continuation of the partition function. The latter is equivalent to the survival probability of a thermofield double state under unitary dynamics. Using random matrices from the Gaussian unitary ensemble (GUE) as Hamiltonians for the time evolution, we obtain exact analytical expressions at finite N for the survival probability. Numerical simulations of the survival probability with matrices taken from the Gaussian orthogonal ensemble (GOE) are also provided. The GOE is more suitable for our comparison with numerical results obtained with a disordered spin chain with local interactions. Common features between the random matrix and the realistic disordered model in the chaotic regime are identified. The differences that emerge as the spin model approaches a many-body localized phase are also discussed.     

Quantum spin dynamics of mode-squeezed Luttinger liquids in two-component atomic gases

We report on the observation of many-body spin dynamics of interacting, one-dimensional (1D) ultracold bosonic gases with two spin states. By controlling the nonlinear atomic interactions close to a Feshbach resonance we are able to induce a phase diffusive many-body spin dynamics of the relative phase between the two components. We monitor this dynamical evolution by Ramsey interferometry, supplemented by a novel, many-body echo technique, which unveils the role of quantum fluctuations in 1D. We find that the time evolution of the system is well described by a Luttinger liquid initially prepared in a multimode squeezed state. Our approach allows us to probe the nonequilibrium evolution of one-dimensional many-body quantum systems.     

Superaging and Subaging Phenomena in a Nonequilibrium Critical Behavior of the Structurally Disordered Two-Dimensional XY Model

A Monte Carlo numerical simulation of the specific features of nonequilibrium critical behavior is carried out for the two-dimensional structurally disordered XY model during its evolution from a low-temperature initial state. On the basis of the analysis of the two-time dependence of autocorrelation functions and dynamic susceptibility for systems with spin concentrations of p = 1.0, 0.9, and 0.6, aging phenomena characterized by a slowing down of the relaxation system with increasing waiting time and the violation of the fluctuation–dissipation theorem (FDT) are revealed. The values of the universal limiting fluctuation–dissipation ratio (FDR) are obtained for the systems considered. As a result of the analysis of the two-time scaling dependence for spin–spin and connected spin autocorrelation functions, it is found that structural defects lead to subaging phenomena in the behavior of the spin–spin autocorrelation function and superaging phenomena in the behavior of the connected spin autocorrelation function.     

Dynamics of mean-field spin models from basic results in abstract differential equations

The infinite-volume limit of the dynamics of (generalized) mean-field spin models is obtained through a direct analysis of the equations of motion, in a large class of representations of the spin algebra. The resulting dynamics fits into a general framework for systems with long-range interaction: variables at infinity appear in the time evolution of local variables and spontaneous symmetry breaking with an energy gap follows from this mechanism. The independence of the construction of the approximation scheme in finite volume is proven.     

The Application of Operator Formalism for Describing Experiments in Multipole Spin Systems under Multipulse Actions

An operator formalism is developed which allows multi-pulse actions on scalar-coupled spin systems with quadrupole nuclei to be analyzed. The formulas describing the evolution of angular-momentum operators under the action of a spin-spin interaction Hamiltonian are derived. The calculation of an NMR-spectrum for scalar-coupled multipole spin systems of the AX (A = 1/2, X = 1, 3/2) and AMX (M = 1, X = 1) types is presented and the polarization transfer processes under multi-pulse action are examined as examples of application of the operator formalism. A series of pulse sequences is proposed which allows individual longitudinal spin orders to be observed.     

Heisenberg-Integrable Spin Systems

We investigate certain classes of integrable classical or quantum spin systems. The first class is characterized by the recursively defined property P saying that the spin system consists of a single spin or can be decomposed into two uniformly coupled or disjoint subsystems with property P. For these systems the time evolution can be explicitly calculated. The second class consists of spin systems where all non-zero coupling constants have the same strength (spin graphs) possessing N − 1 independent, commuting constants of motion of Heisenberg type. These systems are shown to have the above property P and can be characterized as spin graphs not containing chains of length four as vertex-induced sub-graphs. We completely enumerate and characterize all spin graphs up to N = 5 spins. Applications to the construction of symplectic numerical integrators for non-integrable spin systems are briefly discussed.      

Measurement of small one-bond proton-carbon residual dipolar coupling constants in partially oriented (13)C natural abundance oligosaccharide samples: analysis of heteronuclear (1)J(CH)-modulated spectra with the BIRD inversion pulse

Two 2D J-modulated HSQC-based experiments were designed for precise determination of small residual dipolar one-bond carbon-proton coupling constants in (13)C natural abundance carbohydrates. Crucial to the precision of a few hundredths of Hz achieved by these methods was the use of long modulation intervals and BIRD pulses, which acted as semiselective inversion pulses. The BIRD pulses eliminated effective evolution of all but (1)J(CH) couplings, resulting in signal modulation that can be described by simple modulation functions. A thorough analysis of such modulation functions for a typical four-spin carbohydrate spin system was performed for both experiments. The results showed that the evolution of the (1)H-(1)H and long-range (1)H-(13)C couplings during the BIRD pulses did not necessitate the introduction of more complicated modulation functions. The effects of pulse imperfections were also inspected. While weakly coupled spin systems can be analyzed by simple fitting of cross peak intensities, in strongly coupled spin systems the evolution of the density matrix needs to be considered in order to analyse data accurately. However, if strong coupling effects are modest the errors in coupling constants determined by the "weak coupling" analysis are of similar magnitudes in oriented and isotropic samples and are partially cancelled during dipolar coupling calculation. Simple criteria have been established as to when the strong coupling treatment needs to be invoked.     

描述自旋体系密度算符演化的新方法

提出一种描述自旋体系密度算符演化的新方法,可统一处理核磁共振波谱学中强、弱偶合自旋体系及弱射频场存在下密度算符的演化。具体分析一些核磁共振实验:自旋轻扰、自旋锁定、偶极耦合作用、强耦合AB和ABX自旋体系的演化。     

A new application for an old concept: Constant time (CT)-REDOR for an accurate determination of second moments in multiple spin systems with strong heteronuclear dipolar couplings

In this contribution we present a constant time version of the well known REDOR pulse sequence which enables us to determine the second moments in multiple spin systems with strong dipolar couplings. From the resulting dipolar evolution curves, accurate values for the second moments can be obtained without the need to incorporate the full information about the detailed spin geometry of the multiple spin systems into the simulation protocol.     

Study of squeezing in spin clusters

The conditions under which spin squeezing occurs in an asymmetric chain of spins are discussed. The time evolution of the system is calculated for different initial conditions. The effects of the use of spin coherent states to model the initial condition are analyzed.     

Exploring the limits of polarization transfer efficiency in homonuclear three spin systems

The limits of polarization transfer efficiency are explored for systems consisting of three isotropically coupled spins 1/2 in the absence of relaxation. An idealized free evolution and control Hamiltonian is studied, which provides an upper limit of transfer efficiency (in terms of transfer amplitude and transfer time) for realistic homonuclear spin systems with arbitrary Heisenberg-type coupling constants J12, J13, and J23. It is shown that optimal control based pulse sequences have significantly improved transfer efficiencies compared to conventional transfer schemes. An experimental demonstration of optimal polarization transfer is given for the case of the carbon spin system of fully 13C labelled alanine at 62.5 MHz Larmor frequency.     

Theoretical Investigation of Lasing without Inversion in a Multiple Quantum Well System

In this study, the influence of exciton spins relaxation (ESR) on spatial evolution of amplification without population inversion in a four-level GsAs multiple quantum wells is discussed theoretically. The role of propagation distance on absorption, dispersion and group index of weak probe light in the presence and absence of ESR is then analyzed. It is found that exciton spin relaxation (spin decoherence) which resulted from many-particle interaction in semiconductors have essential roles to adjusting the absorption and dispersion properties of weak probe light. Moreover, it is realized that the propagation distance in the presence of ESR can lead to switching between subluminal and superluminal light propagation. Our study provides a suitable treatment for the next generation of all-optical systems in semiconductor nanostructures.

     

The CIDNP kinetics in recombination of successive radical pairs

A theory of chemically induced dynamic nuclear polarization (CIDNP) formed in recombination of successive radical pairs (PRs) is developed. The theory is based on that of RP recombination with the spin Hamiltonian instantaneously changing in time. With kinematics approximation it is shown that general relations for CIDNP are fully expressed via the quadratures of Green functions, which characterize the molecular motion of reagents. Analytical formulae for the time dependence of CIDNP both of primary and secondary RPs have been derived in the strong magnetic field approximation (S-T₀ approximation); field dependences of stationary CIDNP effect for some model cases have been analyzed. For long-lived systems the sensitivity of secondary RP CIDNP to the singlet-triplet evolution of primary RP has been demonstrated. It is shown that sometimes the correct analysis of the effect calls for taking into account the reactivity anisotropy.     

Analytical and Numerical Studies of the One-Dimensional Spin Facilitated Kinetic Ising Model

The one-dimensional spin facilitated kinetic Ising model is studied analytically using the master equation and by simulations. The local state of the spins (corresponding to mobile and immobile cells) can change depending on the state of the neighbored spins, which reflects the high cooperativity inherent in glassy materials. The short-time behavior is analyzed using a Fock space representation for the master equation. The hierarchy of evolution equations for the averaged spin state and the time dependence of the spin autocorrelation function are calculated with different methods (mean-field theory, expansion in powers of the time, partial summation) and compared with numerical simulations. The long-time behavior can be obtained by mapping the one-dimensional spin facilitated kinetic Ising model onto a one-dimensional diffusion model containing birth and death processes. The resulting master equation is solved by van Kampen's size expansion, which leads to a Langevin equation with Gaussian noise. The predicted autocorrelation function and the global memory offer in the long-time limit a screened algebraic decay and a stretched exponential decay, respectively, consistent with numerical simulations.     

Geometry of multiple-spin systems as reflected in 13C-{1H} dipolar spectra measured at Lee-Goldburg cross-polarization

Theoretical calculation and analysis of (13)C-{(1)H} dipolar spectra of small-size spin clusters is presented. Dipolar spectra simulated using the time-independent average Hamiltonian are compared with the dipolar profiles obtained by 2D and 3D (1)H-(13)C correlation experiments employing Lee-Goldburg off-resonance cross-polarization (LG-CP). It is demonstrated that the structural parameters such as interatomic distances as well as mutual orientation of internuclear vectors can be derived from the dipolar profiles of simple spin clusters. Simplified analysis of the dipolar spectra based on isolated-like spin-pair approach can be used only if interacting spin cluster is reduced to the three-spin system in which the angle between both internuclear vectors ranges from 45 degrees to 135 degrees . For other local arrangements of spin systems the produced dipolar spectra must be analyzed with high caution. Contributions of all interacting spins to dipolar evolution of (13)C magnetization are mutually mixed and cannot be easily separated. However, simplification of the dipolar spectra is achieved by selective excitation. Enhanced selectivity of LG-CP transfer due to the initial (1)H chemical-shift-evolution period makes it possible to construct the dipolar spectra from (1)H-(13)C cross-peak intensities for every detected (1)H-(13)C spin-pair. Consequently, isolated-like spin pair evolution of the detected (1)H-(13)C coherence dominates to the resulting dipolar profile, while the influence of other interacting spins is suppressed. However, this suppression is not quite complete and analysis of the selective dipolar spectra based on isolated-like spin-pair approach cannot be used generally. Especially evolution of long-range (1)H-(13)C coherence is still significantly affected by spin states of other coupled hydrogen atoms.     

Quantum logical operations for spin 3/2 quadrupolar nuclei monitored by quantum state tomography

This article presents the realization of many self-reversible quantum logic gates using two-qubit quadrupolar spin 3/2 systems. Such operations are theoretically described using propagation matrices for the RF pulses that include the effect of the quadrupolar evolution during the pulses. Experimental demonstrations are performed using a generalized form of the recently developed method for quantum state tomography in spin 3/2 systems. By doing so, the possibility of controlling relative phases of superimposed pseudo-pure states is demonstrated. In addition, many aspects of the effect of the quadrupolar evolution, occurring during the RF pulses, on the quantum operations performance are discussed. Most of the procedures presented can be easily adapted to describe selective pulses of higher spin systems (>3/2) and for spin 1/2 under J couplings.     

Numerical studies of electron transfers in two-dimensional multiple quantum dots

Quantum dynamical properties of electron transfers through multiple quantum dots (QDs) are numerically investigated. The QDs are modeled as two-dimensional electron systems and the conductive properties are calculated from the time evolution of the electron wavefunctions. In addition, we propose a new technique dealing with the electron-electron correlation and demonstrate the dynamical simulations of the Coulomb blockade as well as the spin blockade.