PAC Measurements on New Ferromagnetic Compound Pd2TiSn

Magnetic hyperfine field (mhf) acting on ¹⁸¹Ta at the Ti site has been investigated in the alloy Pd₂TiSn by Perturbed Angular Correlation (PAC) measurements using the (133–482) keV – cascade in ¹⁸¹Ta following the ^– decay of ¹⁸¹Hf. The magnetic hyperfine field was measured as a function of temperature in the range of 45–1000K. The magnetization measurements were carried out with a vibrating sample magnetometer. The interpretation of the experimental results is based on the assumption that the probe nuclei occupy both the regular Ti sites as well as the Ti atom sites randomly distributed on the Pd sublattice.     

The maximum entropy principle as a consequence of the principle of Laplace

The maximum entropy principle states that the probability distribution which best represents our information is the one which maximizes the entropy with the given evidence as constraints. We prove that this principle is implied from the Laplace principle of equiprobabilities applied to the setS of allN-term sequences of results which are compatible with the given evidence. We generalize to the information gain method of Kullback.     

Kinetics of Atomic Cascade in Light Exotic Atoms

The magnetic hyperfine field B _hf for Cd in the Heusler alloy Pd₂MnSn at the site of chemically introduced Ag has been investigated by PAC following the ^– decay of ¹¹¹Ag. Sign and temperature dependence of B _hf have been determined. Comparison of the result B _hf(T=0)=+8.0(1) T with earlier data and ab-initio band structure calculations leads to the conclusion that the Ag activity has been incorporated at the Mn site.     

Synthesis of peptidomimetics using a polymer-bound Boc-linker

Boc-resin-bound -hydroxy--amino-aldehydes are accessible starting from N-terminally bound amino acidesters by using Dondoni's C₁-homologationreaction sequence. The conversion of these synthons totwo different peptide mimetics – 2-hydroxy-1,3-ethyl-diamines and -hydroxy--amino-vinyl sulfones – hasbeen investigated. The successful transfer of thecomplex -amino acid homologation reactionsequence into solid-phase chemistry demonstrates thepotentials of the Boc-resin for synthesis of peptidomimetics.     

Linear Theory of the Beam-Wave Interaction in the Arbitrary Cylindrical Cerenkov Device

The hot dispersion equation in Cerenkov devices has been derived and analyzed numerically using the self-consistent linear theory. In principle, the linear analysis can be applied to efficiently calculating all kinds of beam-wave interaction in various Cerenkov devices composed of axisymmetric slow-wave structures (SWS) with arbitrary periodic profile. Then the results for Cerenkov devices with three typical SWS profiles are presented.     

Interactions between dislocations and γ/γ' interfaces in superalloys

In situ transmission electron microscopy observations of the dislocation motion at vicinity of the /' interfaces in a Ni-base superalloy have been performed. They allow to identify the elemental mechanisms, under stress and at different temperatures, of the deformation propagation across the interfaces. It is shown that some of the mechanisms already analyzed in the literature occur. Moreover, new processes are revealed such as the formation of small dislocation pile-ups on the /' interfaces. Such a configuration, which increases the local stress, favors the overcoming of the interface.These observations together with new considerations on stresses are taken into account for proposing a new equilibrium equation for a dislocation abutting on a /' interface. This equation involves all the stress components acting on a dislocation: the applied stress, the misfit stress, the friction stress, the stress concentration due to the dislocation pile-up and the image stress.     

On the initial layer solution of the Boltzmann equation with small Knudsen number

We extend our method of systematic removal of secular terms in a singular perturbation treatment of the Boltzmann equation with small Knudsen numbers to the initial layer. The requirement that the solution through the initial layer should connect smoothly to the normal solution removes an ambiguity noted in our previous paper. We show that removal of secular terms improves Grad's solution for the initial layer and reintroduces soundlike modes associated with higher moments, first found by Wang Chang and Uhlenbeck.     

Investigation of Rust Formed on Steel Surfaces and Related Oxyhydroxides

In order to indentity the corrosion products formed on steel surfaces from ⁵⁷Fe Mössbauer spectroscopy, detailed Mössbauer parameters have been determined for various kinds of iron-oxyhydroxides: -FeOOH, -FeOOH, -FeOOH and -FeOOH. ⁵⁷Fe Mössbauer measurements of the iron oxyhydroxides indicate the following results. Fe occupies a single site in -FeOOH, but below the Néel temperature as at e.g., 300 K the Mössbauer spectrum is always broad, showing a distribution of the strength of the magnetic exchange interactions. Its shape depends on the grain-size and synthetic methods of the specimen. Fe occupies 3 sites in -FeOOH. High-purity reagents of -FeOOH always contain small amounts of -FeOOH and their Néel temperatures depend on the synthetic methods of the specimen. Mössbauer spectroscopy of the synthetic -FeOOH shows very broad distribution of the hyperfine magnetic fields.     

Manifestation of Intermolecular Interactions in the IR Spectra of 8-Azasteroids

We have investigated the intermolecular interactions of 8-aza-D-homogona-1,3,5(10),13-tetrane-12,17a-dione and 2,3-dimethoxy-8-azagone-1,3,5(10),13-tetran-12,17-dione with CHCl₃, binary solvents CHCl₃–CH₃OH, CCl₄–CHCl₃, and CCl₄–CH₃OH and also in the solid phase, which manifest themselves in the IR spectra. When the C=O groups of the studied 8-azasteroids form hydrogen bonding with the OH groups of alcohol, the frequencies (C=O) change insignificantly. We have found that they are higher than the corresponding frequencies in the IR absorption spectra of solid-phase samples, which is attributable not only to the effect of the medium but also to the possible shortened contacts of the C=O groups with the CH₃ and CH₂ groups of the molecules under study.     

The Quantum Evolution of the Closed Friedman Universe with “Bouncing Off”

The homogeneous and isotropic closed Friedmanuniverse evolution in higher-order gravity theories isconsidered. The model takes into account vacuumpolarisation of conformal and nonconformal fields. That leads to the following addition in the Einsteinlagrangian: R² ln |R/R₀|. Near theregular minimum of the scale factor the model has ananalytical solution depending on an integration constantC. If |R/R₀| > 1, the solution passes through the regularminimum, experiences inflation with a decreasing valueof R and approaches to the critical value R =R₀. In the interval |R/R₀| < 1,the solutions have non-linear oscillations (i.e. the scalaronstage). On this stage of the evolution the universe isfilled with relativistic plasma. The continuoustransition through the critical point R = R₀is possible in only one type of solution, the separatrix.Though other solutions have no features in this point,they experience the discontinuity in derivatives of R.It is unsuitable since higher-order gravity theories are considered. Thus the measure of continuoussolutions giving a hot universe is negligible. Howeversolutions of the model can be continued in the imaginarytime. In such a case the Euclidean action will have a non-zero value because of the spaceclosed boundedness of the universe and the finiteness ofthe imaginary time interval (instanton). The last allowsus to calculate the probability of the quantum tunnelling of the Friedman universe from theinflation region into the scalaron region.     

Gravitational Waves in Matter

The theory of gravitational waves in matter is given. This covers the questions of constitutive relation, number of independent polarizations, index of refraction, reflection and refraction at an interface, etc. The theory parallels the familiar optics of electromagnetic waves in material media, but there are some striking differences. The use of the Campbell-Morgan formalism in which the gauge-invariant tidal force dyads E and B rather than the gauge-dependent metric perturbations are the unknowns is essential. The main justification of the theory at the moment is as a theoretical exercise worth doing. The assumption: size L of the medium gravitational wave length (infinite medium) rules out application to the already well-understood detection problem, but there may be an application to gravitational wave propagation through molecular gas clouds of galactic or inter-galactic size.     

High-spin isomer in 93Mo

The high-spin states of ⁹³Mo have been studied by a ⁸²Se( ¹⁶O, 5n) ⁹³Mo reaction at a beam energy of 100 MeV using techniques of in-beam -ray spectroscopy. Measurements of -t, --t coincidences, -ray angular distributions and -ray linear polarizations were performed. The high-spin isomer was found as a (39/2^-) state at about 9.7 MeV. The near-yrast states in ⁹³Mo were interpreted using the weak-coupling picture of a d_5/2 neutron to a neutron magic core nucleus ⁹²Mo.     

Specific Fluorescence Properties and Picosecond Transient Absorption of 8-Azasteroids

The specific fluorescence properties as well as picosecond transient absorption features have been studied for two 8-azasteroids. It is shown that at various excitation wavelengths the essentially different final excited electronic states are realized. Because of the multicenter character of 8-azasteroids the spectroscopic data obtained may be analyzed on a basis of the mesomeric tautomerism model taking into account the dynamic combination of cis- and trans-configurations. The dependence of fluorescence spectral characteristics on the solvent nature is a manifestation of intermolecular H-bond interactions.     

Luminescence of Trivalent Thulium Ions in Complexes with β-Diketones

It is established that a fairly intense luminescence of thulium can be observed in solutions (suspensions of residues) of different-ligand complexes that include -diketone and an organic base. The luminescence characteristics of Tm compounds are determined in the series of acetyl acetone derivatives with different substituents, including fluorinated ones, of different length and structure. A relationship is found between I, , and of the Tm complexes and the character of the substituents in a -diketone molecule.     

Preparation, Luminescence Properties, and Application of Scintillators Based on Lu3Al5O12:Ce Single‐Crystal Films

The possibility of obtaining scintillators with a high effective atomic number of the element Z _ef based on Lu₃Al₅O₁₂:Ce³⁺ singlecrystal films (SCF) on doping with La³⁺ and Sc³⁺ ions on Y₃Al₅O₁₂ substrates has been investigated. It is established that the SCF of (LuLaY)₃Al₅O₁₂:Ce³⁺ (Z _ef = 58.9 and = 6.67 g/cm²) does not rank below those of Y₃Al₅O₁₂:Ce³⁺ (Z _ef = 29 and = 4.52 g/cm²) in the conversion efficiency of radiation at the band with _max = 515 nm. This allows their use as screens of xray images with a space resolution of 0.75–1.00 m. It is suggested that in the SCF of Lu₃Al₅O₁₂ the isoelectronic impurities of lanthanum and scandium form radiative recombination centers of the type La_Lu, Sc_Lu, and ScAl as well as the centers Lu as a consequence of the effect of replacement of some Lu³⁺ ions by the La³⁺ ions to octanodes of the garnet lattice. The low efficiency of Ce³⁺ radiation in the SCF of (LuSc)₃(AlSc)₅O₁₂:Ce is explained by substantial losses due to excitation of the recombination luminescence in the UV region of the centers formed by the isoelectronic impurities of scandium and to the possible existence of the channel of energy excitation dissipation related to the transitions between extrema of the allowed energy bands and activator levels.     

Space Videophotometric System for Recording Optical Radiations in the Earth Atmosphere

This paper describes the VFS-3M videophotometric system designed for automatic remote recording of images and parameters of optical radiations following lightning discharges from aboard the Russian segment of the International space station. The characteristics of the system and the possibilities of recording such types of radiation as Red Sprites and Blue Jets are given.     

Interfacial free energies and solute diffusivities from data on Ostwald ripening

Using recent theoretical modifications of the kinetic constants characterizing Ostwald ripening, it is demonstrated that accurate values of the interfacial free energy, , and solute diffusivities, D, can be obtained from experimental data when the kinetics of particle growth are measured in conjunction with independent measurements of either the decrease of the matrix supersaturation or the increase in volume fraction with aging time. The accuracy of is limited only by the assumption that the matrix phase is an ideal solid solution, and is effectively independent of the influence of equilibrium volume fraction, _e, on the kinetics of coarsening. Analyses of the available data on the coarsening of -type (Ni₃X) precipitates in binary Ni–Al, Ni–Si and Ni–Ti alloys yield values of =6.9±0.3, 10.2±3.0 and 13.0 mJ/m², respectively, assuming ideal solution thermodynamics; a more realistic thermodynamic model for the Ni–Al solid solution raises the value of in Ni–Al alloys to 8.1±0.2 mJ/m². Proportional increases probably obtain in the other two alloys. The accuracy with which D can be evaluated from comparable data depends theoretically on _e. However, analyses of the same data yield values of D in very good agreement with the results of conventional diffusion experiments. This is consistent with the absence of an effect of _e on the kinetics of Ostwald ripening in these alloys over the ranges of _e investigated.     

Thickness dependence of temperature coefficient of resistance of MnBi films

In-situ measurements of the temperature coefficient of resistance of electron-beam evaporated MnBi films are reported for the thickness range 30–180 nm. The thickness dependence of the temperature coefficient of resistance curves are plotted for different weight ratios, annealing times and substrate temperatures. The temperature coefficient of resistance shows marked size effect, and is negative for lower thicknesses (<100nm) and positive for higher thicknesses. The experimental data is in good agreement with the Mayadas-Shatzkes theory. The thickness dependence of the Curie temperature also indicates marked size effect.     

Specific Features of Light Scattering in [N(CH3)4]2CuCl4 Crystals with an Incommensurable Phase

We present the results of investigation of the optical birefringence and intensity of the main light beam that passed through an [N(CH₃)₄]₂CuCl₄ crystal under the conditions of viscous interaction of the incommensurable structure with defects. A nonmonotonic temperature dependence of the basic signal is revealed. The observed temperature dependence of the intensity (in the form of irregular steps) is related to different periods of the incommensurable structure. In transitions between adjacent metastable states the periodicity of the incommensurable structure changes. It is shown that in transition regions for the central beam one observes an anomalous decrease in the light intensity due to the appearance of a perturbation lattice with the wave vector q.     

Determination of Microwave Parameters of Isotropic Mediums by Using an Open Quasi-Optical Spherical Resonator

The technique for determination of dielectric parameters of substances is submitted on a base of using a high-Q whispering gallery oscillations in a quasi-optical spherical resonator. The function ability of a method is shown on an example of measurement of permittivity for several substances in the 8 mm wave band.