Effects of intense radiation fields on interatomic forces

The screening, by a strong radiation field, of the interatomic forces in a pair of two-level atoms is studied. The form and the intensity of these forces are obtained as functions of the detuning between the field frequency and the atomic characteristic frequency, and of the field intensity. For a particular “magic” number of radiation photons in the field, some of these interactions vanish effectively, while others are transformed in characteristic ways.     

Intense interactions of molecules with a short-wavelength electromagnetic radiation field: I. The fundamentals of the nonadiabatic theory

The intense interactions between short-wavelength (SW) electromagnetic radiation with a wavelength λ ≥ 1 Å and intensity up to 10¹⁴ W/cm² and simple and polyatomic molecules are studied with the coherent excitations of high-lying Rydberg and autoionizing states taken into account. The Hamiltonian of a system “molecule + SW radiation” is obtained by using the methods of quantum electrodynamics. Conditions for the applicability of the dipole approximation to describe the interactions of molecules with radiation of the UV, VUV, XUV, and soft X-ray range are found. The fundamentals of the theory of resonance scattering of SW radiation from diatomic, triatomic, and symmetric-and asymmetric-top polyatomic molecules are outlined.     

Radiation of Gas Layer over Hot Surface

A method is presented for evaluation the radiation flux produced by a gas layer near a heated surface, where the gas temperature depends on a distance from the surface. This method refers to small temperature gradients and operates with an effective radiation temperature for each frequency, as well as with the width of the gas absorption band. These parameters are determined by the absorption spectrum of atoms or gas molecules, and also by the shape of the spectral line for the radiative transition between certain states of atomic particles of a gas. The possibilities of this method are demonstrated by examples of emission of photons from the solar photosphere, as well as emission of CO₂ molecules in the atmospheres of the Earth and Venus.     

Закон подобия для контура спектральной линии и сечения неупругого перехода

Connection is made between the velocity dependence of the inelastic cross section and the profile of the broadened spectral line. The transition between the Born and adiabatic limits in the scattering problem corresponds to the transition between the impact and static limits in the broadening problem. Both the cases with term crossing and without term crossing are considered, corresponding to “positive” and “negative” domains of the line profile. The results obtained lead to the conclusion that line-broadening theory is useful in the calculations of inelastic cross sections, where the region of intermediate energies of the perturbing particles is included. Detailed calculations of the inelastic cross section have been made for the dipole interaction because exact solutions of the broadening problem are available for comparison in this case. Comparison is made with the results of other authors. The possibility of calculating the effect of field rotation is discussed.     

Free-carrier absorption in quantum well structures for acoustic phonon scattering

Free-carrier absorption has been studied for quantum well structures fabricated from III-V semiconducting materials where the acoustic phonon scattering is important. The energy band of carriers is assumed to be nonparabolic. We discuss the effect of acoustic phonon scattering on the free-carrier absorption for both deformation-potential coupling and piezoelectric coupling. It is found that the free-carrier absorption coefficient depends upon the polarization of the electromagnetic radiation relative to the layer plane or quantum well, the photon frequency, and the temperature. When the deformation-potential coupling is dominant, the free-carrier absorption coefficient increases with increasing temperature for photons polarized in the layer plane or perpendicular to the layer plane. However, when the piezoelectric coupling is dominant, the free-carrier absorption coefficient increases with increasing temperature for photons polarized in the layer plane, but for photons polarized perpendicularly to the layer plane, the free-carrier absorption coefficient decreases with increasing temperature. Moreover, at high temperatures such as T = 300 K, the free-carrier absorption coefficient oscillates with the film thickness in a small quantum well region and then decreases monotonically with increasing the film thickness. This is different from the result for three-dimensional semiconducting solids.     

Scattering of Polarized and Natural Light by a Monolayer of Spherical Homogeneous Spatially Ordered Particles under Normal Illumination

We consider distortions of the shapes of absorption bands of strongly scattering samples in the spectra of molecules adsorbed on the surface of dispersed solids. We show that the influence of the scattering on IR spectra of dispersed samples is not reduced merely to a weakening of the intensity of the transmitted light, but, rather, the scattering affects the contour of a spectral band due to changes in the refractive index of the substance in the range of the absorption band. Using carbon dioxide adsorbed on a NaX zeolite as an example, we demonstrate two methods for taking into account the contribution of the scattering to the spectra of surface compounds: the registration of the “diffuse-transmission” spectrum and placing a sample into an immersion liquid, for which liquid oxygen is used. The obtained spectra indicate that, if the zeolite is saturated with the adsorbate, the band of the antisymmetric stretching vibration of CO₂ molecules broadens and reveals a complex structure as a result of the resonant dipole–dipole interaction between adsorbed molecules.     

Self field electromagnetism and quantum phenomena

Abstract

Quantum Electrodynamics (QED) has been extremely successful inits predictive capability for atomic phenomena. Thus the greatest hope for any alternative view is solely to mimic the predictive capability of quantum mechanics (QM), and perhaps its usefulness will lie in gaining a better understanding of microscopic phenomena. Many “paradoxes” and problematic situations emerge in QED. To combat the QED problems, the field of Stochastics Electrodynamics (SE) emerged, wherein a random “zero point radiation” is assumed to fill all of space in an attmept to explain quantum phenomena, without some of the paradoxical concerns. SE, however, has greater failings. One is that the electromagnetic field energy must be infinit eto work. We have examined a deterministic side branch of SE, “self field” electrodynamics, which may overcome the probelms of SE. Self field electrodynamics (SFE) utilizes the chaotic nature of electromagnetic emissions, as charges lose energy near atomic dimensions, to try to understand and mimic quantum phenomena. These fields and charges can “interact with themselves” in a non-linear fashion, and may thereby explain many quantum phenomena from a semi-classical viewpoint. Referred to as self fields, they have gone by other names in the literature: “evanesccent radiation”, “virtual photons”, and “vacuum fluctuations”. Using self fields, we discuss the uncertainty principles, the Casimir effects, and the black-body radiation spectrum, diffraction and interference effects, Schrodinger's equation, Planck's constant, and the nature of the electron and how they might be understood in the present framework. No new theory could ever replace QED. The self field view (if correct) would, at best, only serve to provide some understanding of the processes by which strange quantum phenomena occur at the atomic level. We discuss possible areas where experiments might be employed to test SFE, and areas where future work may lie.     

Effect of stimulated raman scattering on the formation of the random lasing spectrum of dyes

The nature of the line structure of the random lasing spectrum of vesicular films activated by dyes (rhodamine 6G, pyrromethene 597) has been analyzed. The spectral lines appear above the random lasing threshold and are manifested only within the spectrum of the amplified spontaneous radiation of dye molecules against the continuous-pedestal background. Their intensities are proportional to the product of the intensities of the pump and continuous spectrum at the frequencies of these lines, and the frequencies are exactly reproduced from pulse to pulse. The shifts of the lines are strongly correlated with the pump frequency and the frequencies of these lines coincide with the frequencies of the Raman scattering lines of dye molecules. Using these properties, it has been shown that the observed lines are due to stimulated resonant Raman scattering by dye molecules, which occurs simultaneously with the stimulated emission of these molecules. These two processes affect each other and jointly form a united nonlinear process where all of the oscillations active in Raman scattering are manifested.     

强激光照射下,α-LiIO3晶体中晶格振动的多模激发和模之间的相互作用

本文叙述了用调Q倍频YAG脉冲激光照射α-LiIO₃晶体,在不同的散射配置下,获得了各种散射谱图。实验表明,当用e光入射时,可以比用o光入射激发起更多不同模的晶格振动;获得了E₂模的很强的一阶、二阶斯托克斯散射线和反斯托克斯散射线,E₁模Polariton的一阶、二阶、三阶斯托克斯线和反斯托克斯线,还获得了反斯托克斯频率区一条频移为469cm^-1的新线,认为是不同模的Polariton之间的相互作用引起的。最后,提到实验中初步观察到的晶体拉曼活性的“疲劳现象”。 关键词：     

Effects of collisions on linear and non-linear spectroscopic line shapes

A fundamental physical problem is the determination of atom-atom, atom-molecule and molecule-molecule differential and total scattering cross sections. In this work, a technique for studying atomic and molecular collisions using spectroscopic line shape analysis is discussed. Collisions occuring within an atomic or molecular sample influence the sample's absorptive or emissive properties. Consequently the line shapes associated with the linear or non-linear absorption of external fields by an atomic system reflect the collisional processes occuring in the gas. Explicit line shape expressions are derived characterizing linear or saturated absorption by two- or three-level “active” atoms which are undergoing collisions with perturber atoms. The line shapes may be broadened, shifted, narrowed, or distorted as a result of collisions which may be “phase-interrupting” or “velocity-changing” in nature. Systematic line shape studies can be used to obtain information on both the differential and total active atom-perturber scattering cross sections.     

Polarization Properties of Quantum Cyclotron Radiation

We present a simplified formulae system describing the polarization properties of the quantum cyclotron radiation by a nonrelativistic thermal electron in a very strong magnetic field. In this system, each of the derived quantities, including the Einstein coefficients, the absorption cross sections, and scattering cross sections, as well as the absorption coefficients by plasma, is divided into the perpendicularly and parallelly polarized components. The results, especially the absorption and scattering cross sections of resonant frequency photons, are potentially important in x-ray and γ-ray astronomy, particularly in the study of gamma-ray bursts and pulsars.     

Influence of substance characteristics on the interaction parameters of high-energy photons with free electrons

Various types of interaction of high-energy photons with free electrons in substances have been studied. It is shown that photon absorption by electrons, coherent photon scattering, noncoherent photon scattering, and electron-stopping after interaction with photons can be observed in substances. The dependence of the photon-wavelength variation after interaction with electrons on substance parameters and electron propagation velocity is obtained.     

Aspects of frequency redistribution for non-coherent scattering in a turbulent medium

The scattering of line photons in a turbulent medium is reexamined. We take into account the fact that a photon absorbed in a turbulent element having some velocity will be reemitted by the same element and keeps in that way a certain “memory” of its absorption. Adding the contributions of all turbulent elements at a given point, we construct new redistribution functions describing this correlation. They give the probability that a photon with frequency x in the direction n is absorbed and reemitted at frequency x^′ in the direction n^′. A preliminary discussion of the problem is given in an astrophysical context.     

Nuclear ground states dressed with rf photons in Mössbauer–Zeeman 57Fe spectroscopy

We have applied the “dressed” state concept, developed in quantum electronics, to the situation in which spin 1/2 ground-state nuclear levels are coupled by rf photons. In particular, we have studied Mössbauer spectroscopy when there is Zeeman splitting of the nuclear levels and a further interaction due to an applied rf-radiation field when the rf frequency is in the neighborhood of the ground-state splitting. The dressed-state approach treats the coupling of the ground nuclear Zeeman levels, due to a radio frequency field, by considering the total system made up of: nucleus, static magnetic field, and rf field as one global quantum system. The energy levels and corresponding eigenstates of the system are calculated as a function of the rf frequency and the magnitude of the rf magnetic flux density. Mössbauer spectra are calculated for the ⁵⁷Fe case in which the source is subjected to both the static and radiation fields while the absorber nuclear levels are unsplit.

     

Cherenkov radiation by particles traversing the background radiation

High-energy particles traversing the Universe through cosmic microwave background radiation can, in principle, emit Cherenkov radiation. It is shown that the energy threshold for this radiation is extremely high and its intensity would be too low due to the low density of the “relic photons gas” and very weak interaction of two photons.     

Optical resonant processes in thin excited films

It is shown that coherent processes of elastic scattering of resonant radiation form a “buffer” electromagnetic field near the boundary of excited media. This part of radiation is not governed by the standard refractive index, but precisely this part of radiation forms the beams reflected and refracted by the excited medium. The presence of the “buffer” field causes the suppression of stimulated emission near the boundary and leads to the appearance of a frequency angular broadening of the beam transmitted through a thin film of excited atoms at an oblique angle.     

Spectral characteristic study of Raman transition interaction in optically pumped FIR laser

The spectral characteristic of an optically pumped NH3 molecules FIR laser has been studied by a F-P interferometer and a Michelson interferometer. It was verified that when NH3 molecules were pumped by CO2-9R(16) line, a emission by Raman transitions of two photons was produced. When the gas pressure of NH3 increased, the interaction of the Raman transitions rose, then the emission was enhanced and the width of spectral lines were broadened. The experimental results are in good agreement with the theoretical calculations.Authors gratifully acknowledge to Mrs. Chen Baoqiong and Prof. Qiu Bingsheng for their technical assistance and helpful discussions.     

On the theory of frequency-shifted secondary emission of light-harvesting molecular systems

The expressions are obtained for the intensity of the frequency-shifted secondary emission of a chromophore playing the role of a reaction center in the simplest model three-chromophore molecular “lightharvesting” antenna, which is constructed and oriented in space so that the incident photons coherently excite two of its chromophore pigments. The quantum-field formalism was used, which takes into account the generalized (quantum-electrodynamic) dipole-dipole, as well as radiative and nonradiative dissipative interactions between pigments and the reaction center of the antenna. The special features of the excitation spectrum of the Raman scattering line and the frequency-shifted fluorescence spectrum of the reaction center of the molecular antenna under study are discussed. A comparison of the expressions obtained for the excitation and fluorescence spectra and with the corresponding expressions obtained for a bichromophore molecular system, which differs from a three-chromophore antenna by the absence of one of the pigments, revealed the properties of the mechanism of action of light-harvesting molecular antennas that have not been found earlier. In particular, it is shown that “the light-harvesting” caused by the collective dissipative interactions of pigments with the reaction center of the antenna can substantially exceed a sum of contributions from separate pigments.     

Recording of a hologram by using the second-order nonlinearity

The observation of “spatial-modulation” resonances of saturated absorption in the interaction of iodine-127 vapors with a superposition of frequency-nondegenerate TEM₀₁ and TEM₁₀ transverse modes of a linear laser is reported. The modulation of the total radiation power of the probing wave, recorded at twice the beating frequency of transverse modes of the laser, is interpreted to be the result of the transformation of modulation of the spatial distribution of the field into its amplitude modulation under the action of nonlinearly absorbing iodine vapors. Resonances of saturated absorption of the weak line R(127)11-5 of iodine-127 (633 nm) in an extracavity cell are observed by the method proposed.     

Surface-Enhanced Hyper-Raman Spectroscopy

Abstract

Hyper-Raman scattering (HRS), first theoretically predicted by Decius and Rauch in 1959 [l] and experimentally demonstrated by Terhune et al. in 1965 [2], is a nonlinear optical process involving two incident photons (ω₀) and one emitted photon (ω). The emitted hyper- Raman photon frequencies are Raman-shifted relative to the second harmonic frequency (2ω₀) of the incident laser radiation [3–6]. The energy difference (2ω₀ – w) corresponds to one of the characteristicvibrational frequencies of the scattering medium or molecule. In Fig. 1 is given a schematic illustration of resonant and nonresonant HRS. The primary advantage of this nonlinear optical technique lies in its more relaxed selection rules compared with IR and Raman [7,8]. AlllR-active vibrational modes are hyper-Raman allowed, and those modes inactive in both IR and Raman (i.e., the “silent” modes) may be active in hyper-Raman scattering.