Desorptions- und Reaktionskinetik der Erdalkalien Calcium und Strontium mit Chlor an Wolfram. Part II: Kinetics of the Elementary Steps of the Surface Reaction M + Cl ⇌ MCl (M = Ca,Sr)

Desorption- and Reactionkinetics of the Alkaline Earth Elements Calcium and Strontium with Chlorine on a Tungsten Surface — Part II: Kinetics of the Elementary Steps of the Surface Reaction M + Cl ? MCl (M = Ca, Sr) Utilizing pulsed molecular-beam-technique the kinetics of desorption of Strontium, Calcium, and Chlorine as well as that of the molecules SrCl and CaCl, which are formed at the hot tungsten surface, was investigated. Thereby, the following values were obtained for the activation energies of desorption: ? = (3.76 ± 0.05) eV, ? = (3.32 ± 0.07) eV, ? = (4.16 ± 0.05) eV, ? = (4.2 ± 0.3) eV and ? = (3.9 ± 0.3) eV. Combining these results with the steady-state-results from part I [1] the temperature dependency of the rate constants of dissociation and recombination of MCl-molecules at the tungsten surface could be determined. The values obtained for the dissociation energies D of SrCl and CaCl on tungsten are (0.5 ± 0.5) eV and (0.3 ± 0.5) eV, respectively. The molecules are stabilized on the surface by the activation barrier for dissociation D? only, which was found to be (2.8 ± 0.5) eV for SrCl and (2.3 ± 0.5) eV for CaCl.     

Die Relaxation der Geschwindigkeitsverteilungsfunktion der Elektronen im homogenen elektrischen Feld mit elastischen und anregenden Stößen. II. Das Verhalten des Elektronenensembles bei aperiodischer Feldänderung zwischen zwei stationären Zuständen

Recently the relaxation of the electron component was investigated under field-free conditions after sudden switch-off the electric field and otherwise after sudden changing the electric field to a new value of field strength. To continue these papers we consider now the relaxation process of the electron ensemble in the presence of a monotonous time variable electric field. The investigations are based on a computation of time change in the isotropic part of the velocity distribution function of the electrons and of the macroscopic parameters determined by the distribution function. The start-ing-point is the non-stationary Boltzmann equation with stationary initial states taking into consideration elastic and exciting collisions. Besides the representation of the received numerical results a physical interpretation is obtained for the duration of the whole relaxation process, for its initial stage as well as for the momentary stage of the relaxation by introduction of normalized characteristic time quantities. Further characterizing conditions are found related to the relaxation after quasi-jumplike change of the electric field and in the case of quasistationary field alteration respectively. With the introduced characteristic time quantities statements about the degree of realization of one of this limiting cases are possible for any given monotonous field. The investigations are per-formed in a low ionized non-thermal neon plasma.