共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
Pascale Tavarès Marek M. Kubicki Philippe Meunier Bernard Gautheron Gabriel Dousse Hélène Lavayssière Jacques Satgé 《Transition Metal Chemistry》1992,17(3):220-223
o-Thiatelluraphenylenezirconocene complexes were obtained in good yield by reaction of dilithiumo-benzenthiatelluride with zirconocene dichlorides. These compounds represent the first examples of heterodichalcogenaphenylene
bent metallocences. They were characterized by spectroscopic methods and the effect on the n.m.r. results of stepwise substitution
of one and two Te atoms for S is discussed.
X-ray crystal structure analysis was performed for one representative complex. The structure is very similar to that previously
reported for a diselenaphenylene complex, but the disorder observed for chalcogen atoms prevents an accurate comparison of
the geometrical parameters with other related compounds. 相似文献
3.
4.
Toshie Tahara Yoshitsugu Sakuda Mitsuaki Kodama Yoshimasa Fukazawa Shô Itô Kazuyoshi Kawazu Shuhei Nakajima 《Tetrahedron letters》1980,21(19):1861-1862
The structures of xantholides A and B were deduced on the basis of IR and NMR spectra, and confirmed by X-ray analysis. Xantholide A inhibited the larval growth of Drosophila melanogaster. 相似文献
5.
Cecilio Marquez Rosa M. Rabanal Serafin Valverde Liliana Eguren Aurea Perales José Fayos 《Tetrahedron letters》1981,22(29):2823-2826
Lolin, a new diterpene of the -clerodane type has been isolated from Teucrium capitatum. The X-ray structure and spectroscopic data of lolin is given. 相似文献
6.
Cecilio Marquez Rosa M. Rabanal Serafiin Valverde Liliana Eguren Aurea Perales Jos Fayos 《Tetrahedron letters》1980,21(52):5039-5042
Two diterpenes, capitatin 4 and teucapitatin 5 have been isolated from Teucrium capitatum. The X-ray structure of 4, including absolute stereochemistry, is given. Diterpene 4 has been chemically related to picropolin 1 and picropolinone 2, thereby establishing the absolute stereochemistry of these two neoclerodane-type diterpenes. 相似文献
7.
《Journal of organometallic chemistry》1986,317(3):267-275
The solid state structure of trimethylsilylmethyllithium has been determined by single crystal X-ray diffraction techniques. The compound crystallizes in the monoclinic system, space group P21/n. Cell dimensions were determined as follows: a 10.931(3), b 18.397(6), c 21.490(8) Å, β 96.0(2)°, V 4298(2) Å3, Z = 4, and a final Rf 5.1% based on 2203 data with σ(I) ≥ 2.5σ(I). The compound is formed by hexameric units, {LiCH2Si(CH3)3}6, with two distinct classes of LiLi distances of 2.46 and 3.18 Å. There are also two LiC distances av 2.20 and 2.27 Å. The LiH distances to the methylene H atoms have been determined and are short varying between 2.0 and 2.3 Å to the closest lithium atom. The structure, including possible LiH interactions, is discussed and compared with the other known hexameric aggregates. 相似文献
8.
The structure and absolute configuration of a novel diterpenoid (MEAH) has been determined. 相似文献
9.
El Antri A Messouri I Bouktaib M El Alami R Bolte M El Bali B Lachkar M 《Molecules (Basel, Switzerland)》2004,9(8):650-657
Two tetrahydroisoquinoline alkaloids were extracted from the alkaloid fraction of a methanol extract of the seeds of Calycotome Villosa Subsp. intermedia. Their structures were established as (R)-1-hydroxymethyl-7-8-dimethoxy-1,2,3,4-tetrahydro- isoquinoline (1) and (S)-7-hydroxymethyl-2-3-dimethoxy-7,8,9,10-tetrahydroisoquinoline chloride (2) by spectroscopic techniques and X-ray diffraction analysis. 相似文献
10.
12.
13.
14.
A.K. Ganguly Y-T. Liu O. Sarre R.S. Jaret A.T. McPhail K.K. Onan 《Tetrahedron letters》1980,21(49):4699-4702
The X-ray crystal structure of rosaramicin is reported. 相似文献
15.
The crystal structure of 3-methyluracil has been determined ab initio by conventional monochromatic X-ray powder diffraction data. The crystal data are: orthorombic, a=6.6294(1), b=13.1816(3), c=6.53938(9) (Å), V=571.45(3) (Å3), space group Pbnm, Z=8. The structure was solved by direct methods and the final Rietveld refinement converged to Rp=0.0398, Rwp=0.0528, RBragg=0.0294. The crystal structure exhibits endless chains of planar molecules, connected via head-to-tail N-H?O hydrogen bonds. 相似文献
16.
Bis(1,1-diphenylhydrazido(1-))ruthenium(IV) porphyrins, [Ru(IV)(Por)(NHNPh2)2] (Por = TPP, TTP, 4-Cl-TPP, 4-MeO-TPP), were prepared in approximately 60% yields through the reaction of dioxoruthenium(VI) porphyrins, [Ru(VI)(Por)O2], with 1,1-diphenylhydrazine in ethanol. This new type of ruthenium complex has been characterized by 1H NMR, IR, UV-vis, and FABMS with elemental analysis. The crystal structure of [Ru(IV)(TTP)(NHNPh2)2], which reveals an eta1-coordination mode for both hydrazido axial ligands, has been determined. The average Ru-NHNPh2 distance and Ru-N-N angle were found to be 1.911(3) A and 141.1(3) degrees, respectively. The porphyrin ring exhibits a ruffling distortion that is unprecedentedly large for ruthenium complexes with simple porphyrinato ligands (such as TTP). This is probably due to the steric effect of the axial hydrazido(1-) ligands. 相似文献
17.
Mikio Hori Tadashi Kataoka Hiroshi Shimizu Sachio Ohno Kenichi Narita Hiroaki Takayanagi Haruo Ogura Yoichi Iitaka 《Tetrahedron letters》1979,20(44):4315-4318
The first success of an X-ray analysis of a thiabenzene derivative, 1-benzoyl-2-methyl-2-thianaphthalene is described. 相似文献
18.
19.
A securinega-type alkaloid epibubbialine was isolated from Phyllanthus niruri Linn. Its structure was established by spectroscopic methods and X-ray single-crystal diffraction analysis. Its crystal structure is reported herein for the first time. 相似文献
20.
G. Cimino S. De Rosa S. De Stefano L. Mazzarella R. Puliti G. Sodano 《Tetrahedron letters》1982,23(7):767-768
A novel bromo-compound, C11H10N5O2Br, has been isolated from the sponges Axinella verrucosa and Acanthella aurantiaca. The structure was determined as 2 on special grounds and by X-ray analysis. 相似文献