Optical phase grating diffraction in a quasistatic electric field biased nematic liquid crystal film

Abstract

It is known that an optical phase grating can be obtained when two mutually coherent laser beams overlap in a nematic liquid crystal. This is mainly due to director reorientation which contributes to a large optical non-linearity. It has been suggested by Herman and Serinko that a phase grating could be obtained in nematic liquid crystals if a D.C. field is used to bias it near the critical orientational Freedericksz transition. A homeotropic MBBA film biased by an electric field at 1 kHz has been studied. Two weak Ar⁺ laser beams were incident normally to the film with a small intersection angle (?0·4?). Using the picture of a director reorientation mechanism and a degenerate four wave mixing scheme, we have obtained the dependence of the diffraction beam intensity on that of the incident beam and the strength of the biased electric field. The theoretical prediction and experimental results both show that the phase grating diffraction can be dramatically enhanced by the coupling of the electric field to the optical field in the Freedericksz transition region. This is due to the critical behaviour of the sample at that transition. The prominently improved signal-to-noise ratio is discussed.     

Investigation of alignment direction in wide view film and rubbing angle of twisted nematic liquid crystal display mode

Wide view (WV) film is an important material in the polariser. It is a hybrid-aligned, discotic liquid crystal (DLC) on an alignment layer on the tri-acetyl cellulose film, which is used as compensation film in twisted nematic (TN) mode liquid crystal display (LCD). The relation between the alignment direction of the DLC in the WV film and the rubbing direction of the polyimide on the glass substrate in the TN mode LCD was investigated. The results indicated that the contrast ratio (CR) of the TN mode LCD can be increased by adjusting this angle . When an 88°?rubbing angle was used in this work, the CR of the TN mode LCD could reach 1000:1 and the horizontal and vertical viewing angles were 170 and 160°, respectively.     

Dynamic behaviour at a nematic liquid crystal-rubbednylon interface using evanescent wave photon correlation spectroscopy

Photon correlation spectroscopy of light scattered by director fluctuations from an evanescent optical wave propagating in the nematic liquid crystal 5CB is used to study the interfacial dynamic behaviour of the liquid crystal. The intensity correlation function of light scattered by interfacial orientation fluctuations is measured by illuminating to give a short optical penetration depth within the nematic. These surface scattering correlation functions strongly differ from the bulk correlation function and are interpreted in terms of a nematic surface orientation mode arising from the coupling between the director field and the fluid velocity. It is shown that the analysis of the surface mode gives a method for measuring anchoring energies in liquid crystals. The anchoring energy obtained for rotation of the director away from the rubbing direction about an axis normal to the surface for 5CB at a rubbed nylon surface is 7.14±0.7 × 10-² ergcm-².     

Photoinduced liquid crystal blue phase by bent-shaped cis isomer of the azobenzene doped in chiral nematic liquid crystal

A photoresponsive azobenzene molecule DCAZO2 with two cholesteryl groups linked to both sides of the azobenzene group is doped in a mixture of nematic liquid crystal E7 and chiral dopant S811 (61.9 wt% E7, 36.1 wt% S811 and 2.0 wt% DCAZO2). Cooled from isotropic phase to 33.0°C, chiral nematic liquid crystal (N*LC) was formed in the sample and then the temperature was kept unchanged at 33.0°C. UV light irradiation induces the trans–cis photoisomerisation and thus an obvious phase transition. When the azobenzene groups isomerise to a cis-saturated state, the UV light was turned off and the white light was turned on at the same time. The bent-shaped cis isomer then turns back to the planar trans isomer gradually. A blue–green platelet texture representing cubic blue phase (BP) was observed and the size of the platelets was increased along with the cis–trans isomerisation. UV–vis absorption spectra indicate that the photoinduced BP exists when the isomerisation degree is between 79% and 18%, and further cis–trans isomerisation change BP back into N*LC. The large geometric structure of the cholesteryl groups and the large bent angle θ of the cis isomer are supposed to be responsible for the interesting result.     

High figure‐of‐merit nematic mixtures based on totally unsaturated isothiocyanate liquid crystals

High birefringence and low viscosity isothiocyanate liquid crystal single compounds, and eutectic mixtures based solely on unsaturated rigid core structures, are reported. Extraordinarily high values of figure‐of‐merit were observed at room temperature for the formulated nematic mixtures. Potential applications of such mixtures for laser beam steering at λ = 1.55 µm using optical phased arrays are emphasized.     

Properties of optically addressed liquid crystal spatial light modulators studied by mach-zehnder interferometry

In this work optically addressed liquid crystal spatial light modulators are experimentally investigated. Local reorientation of molecules in the modulator and local changes of effective refractive index n_eff (x,y) are induced by modulated light intensity I (x,y). We present preliminary results of measurements of phase shifts in optically addressed liquid crystal panels using a Mach-Zehnder interferometer. Experiments were performed for the panels filled with nematic and dye-doped nematic liquid crystals. Optical addressing was realized by Ar+ laser beam (λ = 514.5 nm) while the reading beam was supplied by He-Ne laser (632.8 nm). The operation voltage was in the range 4 - 20 V. The total phase shift under the influence of addressing light for the studied systems was 2 - 6 pagr;, sensitivity to the addressing light ∼ μW/cm² per 2π phase change and speed of response to the light was 20 ms - 30 s with total recovery time 0.5 - 120 s.     

Contrast ratio of twisted nematic liquid crystal cells and its improvement

The light leakage of twisted nematic (TN) liquid crystal displays is investigated. While the TN mode has a robust structure in regard to light scattering, due to thermal fluctuations of the liquid crystals and light leakage from imperfect rubbing defects, it maintains significant residual retardation of the liquid crystal layer in the black state. The residual retardation is induced by the azimuthally twisted liquid crystal alignment near substrate surfaces and causes major light leakage in the black state. We investigated several methods to compensate for the residual retardation, and the methods include the adjustment of the helical power of the liquid crystal material, the increase of driving voltage, the control of rubbing direction and a newly designed compensation film with a small angle twist. Though all these methods improve the contrast ratio by about 30%, each method has its own weaknesses and limitations. The development of a new compensation film would provide a good chance for future TN applications.     

Polymer dispersed liquid crystal display device for projection high definition television application

Polymer dispersed liquid crystal (PDLC) is a light scattering material that operates on the principle of electrically modulating the refractive index of the liquid crystal in an optical isotropic, transparent solid. The principle of operation of the PDLC device, the interface requirements between PDLC material and its driving circuit are studied. For high definition television (HDTV) application, a detailed comparison of PDLC vs. twisted nematic/super twisted nematic (TN/STN) display devices will be discussed. It was found that single crystal metal oxide semiconductor field effect transistor (MOSFET) is better than conventionally used thin film transistor (TFT) in driving these PDLC light valves.     

Improvement of the electro-optical properties of nematic liquid crystals doped with strontium titanate nanoparticles at various doping concentrations

ABSTRACT

In this study, we doped homogenous aligned nematic liquid crystal (NLC) systems with strontium titanate (SrTiO₃) nanoparticles (NPs), and investigated the impact of doping concentration on the NLC’s electro-optical (EO) properties. SrTiO₃ NP-doped NLC cells maintained a high optical transmittance of 77.51% to 78.41% compared to pure NLC cells (78.09%). At a 0.1 wt.% SrTiO₃ NP doping concentration, twisted-nematic (TN)-LC cells exhibited enhanced EO performance, with a reduced threshold voltage from 1.70V to 1.61V and a shorter response time from 17.03 ms to 10.66 ms without optical defects and degradations. We also observed an improvement in thermal endurance for doping concentrations of 0.05 and 0.1 wt.%.     

Beam shaping via photopatterned liquid crystals

ABSTRACT

Due to the fantastic properties and diverse applications of specific beams, optical beam shaping has attracted intensive attentions recently. Generally, these beams can be converted from Gaussian beams via particular spatial amplitude or phase control. In this work, we present a liquid crystal photopatterning technique based on dynamic microlithography with a polarisation-sensitive photoalignment agent. This technique enables the accurate, arbitrary and reconfigurable azimuthal angle control of liquid crystals, thus providing a powerful approach for the manipulation of light. By this means, the tailoring of arbitrary fine microstructures with binary or continuously space-variant liquid crystal azimuthal orientations are demonstrated. We briefly review our recent work on some specially designed patterns and corresponding specific optical fields. High-quality vortex beams, vector beams and Airy beams are generated with unprecedented flexibility in the design and control of light wavefront. Besides high efficiency, good electrical switchability and broad wavelength tolerance, the proposed devices also exhibit merits of compact size, low cost, dynamic mode conversion and polarisation controllable energy distribution, and are available for short pulse and intense light modulation. This work may pave a bright way towards beam shaping and bring new possibilities for the design of novel advanced liquid crystal photonic devices.     

Nematic Liquid Crystals as Media for Real-Time Holography

We report on a novel type of orientational photorefractive devices consisting of dye-doped or pure nematic liquid crystals. These systems can be employed as the recording media for real-time (dynamic) holography. Optical addressing of liquid crystal molecules is facilitated due to the natural tendency of molecular self-assembling in nematics and their easy reorientation upon action of an electric field. This field can be produced by incoming light via photoconductivity either in the bulk or at the surface of the nematic liquid crystal layer. We present an experimental study of dynamic self-diffraction of light on thin phase holograms formed in a nematic liquid crystal panel. Optically addressed spatial light modulators designed by us can be the active elements of image processing systems and in this communication we demonstrate the optical correlator performing image recognition.     

Mole fraction dependence of physical properties for a binary cyanobiphenyl liquid crystal system

The physical properties of a binary liquid crystal system were investigated, namely the transition temperatures, birefringence and viscoelastic constants measured by using thermal optical microscopy, differential scanning calorimetry and light scattering techniques with coherent laser light beams. These properties were sometimes found to exhibit linear dependence on the mole fractions of the components. Our results indicate that a required property is obtainable by the regulation of the molar ratio as if the length of the alkyl chain connected with a cyanobiphenyl core group were variable; i.e. the apparent chain length could be controlled.     

Intra-cell ionic properties of twisted nematic liquid crystal cells

Under 1-kHz and low-frequency driving, we report our investigation of intra-cell ionic properties of two twisted nematic (TN) liquid crystal (LC) cells made of same LC mixture but different polyimide (PI) materials for LC alignments. A heterodyne interferometry system was used to measure the phase retardations of the TN cells versus applied voltages at 1 kHz. We also measured the phase retardations and currents of the TN cells versus time by applying a mid-grayscale voltage of 1.3 V at 0.1 Hz to the cells. Related to the above-measured data, we have developed equations to characterise the field-driven transports of mobile charge carriers within the PI films independently from that within the LC medium of same TN cell to obtain time-dependent in-cell voltages of mobile charge carries across the LC mixture and across two PI-alignment films, respectively. Our experimental methods can be used to optimise LC mixtures and PI materials for low-refresh-rate thin-film-transistor-driven liquid crystal displays (LCDs) for low power and provide bases for further investigations on mobile-charge-carrier generation and transport within thin in-cell PI-alignment films as well as within the LC mixture of same LC cell.     

Image analysis method to study electro-optic parameters of nematogens

This paper demonstrated the image analysis technique for the investigation of electro-optic behaviour of homogeneously aligned nematic liquid crystals p-n alkyl benzoic acids (nBA) where n = 5 and 6 under the application of direct current (DC) electric field. Textures of the liquid crystals in the mesophase region of particular temperature were recorded in three monochromatic image planes at the wavelengths of 635 (red), 530 (green) and 475 nm (blue) as a function of applied DC voltage. Electro-optic properties such as transmittance, birefringence, phase retardation and contrast ratio were measured by analysing the optical intensities of the recorded textures using MATLAB software. The changes in the textural features and formation of new textures as a function of voltage provided information for better understanding of the electro-optic characteristics of liquid crystals. Results of this study were compared with the data of the other standard techniques: laser source (633 nm) experiment and United Detector Technology (UDT) sensor of model UV- 35P silicon photo diode which uses white light as source and filters the wavelengths using three colour filters of wavelengths 635, 530 and 475nm.     

Photocontrolled manipulation of a microscale object: a rotational or translational mechanism

In this paper the photocontrolled manipulation of solid materials on the surface of a liquid crystalline thin film is described. Three different types of films namely cholesteric liquid crystal (ChLC), compensated nematic liquid crystal (NLC) and nematic LC were used. The rotational and translational manipulation of the microscale solid object was induced by irradiation of light and mode of manipulation (either translational or rotational) was changed by changing the isomer of the azobenzene compound used to make the film. Rotational motion of the object was observed on the ChLC and compensated NLC films containing chirally pure azobenzene compound. The direction of rotational motion was controlled either by changing the optical isomer of the chiral azobenzene or by changing the irradiating light (from ultraviolet to visible). When racemic mixture of the chiral azobenzene compound was used, a translational motion of the object was observed. Even though the direction of the translational motion can be controlled by controlling irradiation position, more facile and precise manipulation of the objects was possible by spatially controlled irradiation of Ar(+) laser and diode UV laser.     

偶氮聚合物表面起伏光栅用于液晶定向研究

液晶显示具有低功耗、高画质、轻巧等优点，广泛应用于各种平板显示装置．使液晶分子能在显示器中均匀的定向排列是液晶显示的关键技术之一．液晶定向技术的主要方法有摩擦法、SiOx等氧化物或Au、Pt等金属蒸镀法、紫外偏振光(或激光)辐照法等．所谓摩擦法，即通过将基片在均匀移动的丝绒布表面摩擦来实现的．一般认为摩擦法是通过摩擦在基板表面形成的微沟槽来诱导     

Study of Field Induced Transition (FiT) and Analysis of Crystallization Kinetics in the Nematic Phase of an Interhydrogen Bonded Nanoliquid Crytsal

An interhydrogen bonded liquid crystal with complementary hydrogen bonding between succenic acid (SA) and pentyloxy benzoic acid (5OBA) referred as SA + 5OBA has been synthesized and characterized. Multiwalled carbon nanotubes (MWCNT) are dispersed in SA + 5OBA and the resultant complex is referred as SA + 5OBA+MWCNT. Both complexes exhibit liquid crystallinity with the presence of nematic phase. FTIR and NMR studies confirms the formation of the interhydrogen bonds. Transition temperatures and enthalpy values are obtained by DSC studies. Considerable hyteresis in dielectric permittivity has been observed in SA + 5OBA + MWCNT, which enable it to be used in device applications. An interesting observation in SA + 5OB A + MWCNT complexes is the field induced transition (FiT) in nematic phase, which is studied by conductance, permittivity, and helicoidal structure deformations. This complex can be used in light modulation applications. The liquid crystalline behavior together with the rate of crystallization in nematic phase of pure and MWCNT dispersed hydrogen bonded complex are discussed in relation to the kinetophase (which occurs prior to the crystallization). The molecular mechanism and dimensionality in the crystal growth are computed from the Avrami equation. The characteristic crystallization time (t*) at each crystallization temperature is deduced from the individual plots of log t and ΔH. The influence of MWCNT on crystallization kinetics in the nematic phase of an interhydrogen bonded liquid crystal is discussed.     

Application of photosensitive polyimides as alignment layer to optical switching devices of a nematic liquid crystal

We have explored the change in alignment of a nematic liquid crystal, 4'-pentyl-4-cyanobiphenyl (5CB) with three types of photosensitive polyimide as the alignment layer by photoirradiation at 366 nm. The photosensitive polyimide alignment layer induced a reversible change in alignment of 5CB. It was observed that the 5CB molecules became aligned from homogeneous alignment to homeotropic on photoirradiation with a d.c. electric field as a bias, and reversed to the homogeneous state when photoirradiation was ceased. This result indicates that optical switching could be repeated by on and off switching of the excitation light at 366 nm. The optical switching of the nematic liquid crystal might be mainly due to a photophysical change in the polyimide surface which is affected by the chemical structures of the polyimides at the temperature at which 5CB exhibits a nematic phase. The optical switching of nematic liquid crystals with photosensitive polyimides as the alignment layer is a novel driving method for nematic liquid crystals.     

Short wavelength light reflecting films from side‐chain liquid crystal homopolymers with chiral spacers

A series of acrylate monomers with alkoxy tails of varying lengths are synthesised and polymerised. The butoxy analogue had a stable enantiotropic cholesteric liquid crystalline phase which formed a grandjean texture when prepared as a thin film between glass slides. The polymer was mixed with a low molar mass nematic liquid crystal in various proportions and the pitch of the chiral nematic phases were determined using a cano‐wedge cell technique. The polymer prepared from (S)‐2‐(4‐butoxyphenyl‐4′‐benzoyloxy)‐1‐methyl ethyl acrylate had a pitch length of 113 nm which indicates that the polymer film could be employed in optical devices requiring selective reflection of light with short wavelengths in the region of 170 nm. Copyright © 2001 John Wiley & Sons, Ltd.     

A small-angle X-ray scattering study of nanoparticle assembly in an aligned nematic liquid crystal

The assembly of colloidal particles in a nematic liquid crystal has been investigated using small-angle X-ray scattering. The structure and orientation of nanoparticle assemblies in bulk samples of aligned nematic liquid crystal have been determined. The method offers some advantages over optical microscopy, which is usually restricted to investigations of thin cells and micron-sized particles. The scattering from chains of particles has been calculated, and comparison with experimental results has shown that suspensions of 48 and 105 nm diameter silica nanoparticles formed highly ordered structures perpendicular to the liquid crystal director, consistent with quadrupolar defect-induced assembly.