共查询到19条相似文献,搜索用时 140 毫秒
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采用分光光度法测定空气中甲醛,对测定结果的不确定度进行评定。采用酚试剂分光光度法测定空气中甲醛,分析测定过程中的各项不确定度来源,包括样品采集、标准工作溶液配制、标准工作曲线拟合、测定仪器以及重复测定等引入的不确定度,计算合成不确定度,最后获得相对扩展不确定度。当空气中甲醛质量浓度为0.0244~0.2218 mg/m^3时,测定结果在95%置信区间时的相对扩展不确定度为0.1172(k=2)。不确定度主要来源于A类不确定度和系列标准工作溶液制备、标准工作曲线拟合、水中甲醛溶液标准物质的稀释引入的不确定度。 相似文献
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按YY 0308-2004要求,采用顶空气相色谱法测定了医用透明质酸钠凝胶中的乙醇残留量,依据JJF l059-1999,CNAS-GL 06,对测量结果的不确定度来源进行了系统分析,并对各不确定度分量进行了评定和量化,计算了合成标准不确定度和扩展不确定度,测定结果为(344.10±37.51)μg/g,k=2。结果表明,影响测量结果的主要因素为标准曲线拟合引入的不确定度。 相似文献
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《理化检验(化学分册)》2016,(2)
正甲醇是最简单的饱和一元醇,也是重要的化学工业基础原料和清洁液体燃料,广泛应用于有机合成、医药、农药、涂料、染料、汽车和国防等工业中。甲醇毒性较大,误饮或长期接触都会引起中毒,因此国家相关标准对空气中[1]甲醇含量和污染源甲醇排放浓度[2]都作了相应规定。相应的甲醇监测方法有HJ/T 33-1999[3]和《空气和废气监测分析方法(第四版增补版)》[4]的气相色谱法和分光光度法。在实际监测过程中,根据 相似文献
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依据CNAS-GL06,对顶空气相色谱法测定聚氯乙烯固体药用硬片中氯乙烯单体含量的测量不确定度进行系统分析,找出影响测量结果不确定度的主要因素。对各不确定度分量进行了评定和量化,计算了合成标准不确定度和扩展不确定度,聚氯乙烯固体药用硬片中氯乙烯单体含量的测定结果表示为(4.17±0.18)×10-7,k=2。 相似文献
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将5×10-8~3.2×10-6(空气中的体积含量)的SO2通入质子交换膜燃料电池(PEMFC)单电池阴极, 研究了SO2对PEMFC性能的影响. 实验得到的电压-时间(V-t)曲线和极化(V-I)曲线表明, 空气中SO2含量达到5×10-7时, 将对PEMFC的性能产生显著的和不可逆的影响, 且SO2浓度越大电池性能的下降幅度越大. 对SO2影响前后的电化学交流阻抗谱(EIS)的解析表明, 电池电荷传递阻抗(Rct)的变化可逆, 而阴极的表面状态发生了不完全可逆的变化. 循环伏安(CV)实验数据进一步证明, SO2毒化后阴极的活性电化学表面积(EAS)缩小. 相似文献
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近年来,随着环境管理力度的加强,对酸雨的监测逐步重视,监测项目除传统的pH、电导率外,又增加了K 、Na 、Ca2 、Mg2 、SO42-、Cl-、NO3-、NH4 等多项离子。大气降水中钠测定,目前主要采用火焰原子吸收光谱法[1]。由于自然界中钠的含量十分丰富,空气、水、土壤及玻璃中都含有大量的钠,这些物质对大气降水中钠测定有十分严重的影响,使测定结果产生较大的正误差,甚至使测定无法进行。本文从以下4个方面对外界影响因素加以探讨。1采样过程1.1影响因素空气中的灰尘;降水采样器材质。1.2去除影响的办法(1)采样一般使用降水自助采样器或聚乙烯… 相似文献
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X-Ray photoelectron spectroscopy (XPS) and XRF as techniques for monitoring air pollution are compared. Sulphide and oxides of sulphur (SO(2), SO(3) and SO(2-)(4)) have been determined on copper plates exposed for different lengths of time to an atmosphere containing hydrogen sulphide. The total amount of sulphur increases with the time of exposure but the sulphide reaches a constant value after 59 days. An interpretation of the mechanism of oxidation of hydrogen sulphide is offered. 相似文献
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空气净化吸附剂的制备及其吸附性能研究 总被引:3,自引:0,他引:3
随着现代工业的迅速发展,有毒废气严重危害人们的健康,治理废气污染已经成为环境保护的热点之一。本文介绍合成二个系列大孔共聚物GT和GTD,经功能基化,制得具有净化空气中的过量的CO2、SO2和NO2的吸附剂。 相似文献
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通过空气样品液化器中真空泵的作用,空气转化为液体,从而能持续提供样品流,以供离子色谱仪和伏安极谱仪检测。阐述了将空气样品液化器(PILS)与伏安极谱仪(VA)、离子色谱仪(IC)联机分析空气中气溶胶的方法,其中伏安极谱仪可以分析空气中的Zn、Cd、Pb、Cu等重金属含量,离子色谱仪可以分析空气中的Cl-、NO2-、NO3-、SO42-、Li+、Na+、NH4+、K+、Ca2+、Mg2+等阴、阳离子的含量。方法取得了很好的精密度与准确度。 相似文献
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Piyanete Sritharathikhun Mitsuko Oshima Yanlin Wei Jürgen Simon Shoji Motomizu 《Analytical sciences》2004,20(1):113-118
A simple and rapid procedure for SO2 determination in air was developed by using a flow injection analysis (FIA) system coupled with a 3-hole chromatomembrane cell (CMC). The CMC was applied for the on-line collection/concentration of SO2 from air into a solution of 2 g l(-1) triethanolamine (TEA) solution as an absorbing solution: SO2 was converted to SO3(2-) in the alkaline absorbing solution. The solution containing absorbed SO2 was introduced into the carrier stream of the FIA system. The amount of SO3(2-) in the absorbing solution was measured by spectrophotometry with a mixed reagent of pararosaniline and formaldehyde, and was converted to the concentration of SO2 in the air sample. A calibration graph prepared by using standard sodium sulfite aqueous solutions was adopted for the determination of SO3(2-) in the absorbing solution. The SO2 concentration in indoor air examined was found to be 22.7 +/- 0.2 ppbv using 20 ml of air sample with the air flow rate of 5 ml min(-1), where the relative standard deviation was 1.7%. The detection limit for aqueous solutions and air samples were 6.9 x 10(-8) M and 0.48 ppbv, respectively. The measuring time for one sample was about 10 min when a 20 ml air sample was used. The interferences from common anionic species, formaldehyde and acetaldehyde, were also examined. 相似文献
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Nucleic acid sensing analysis has been widely applied to the fields of food quality control, environmental monitoring, and medical diagnosis. A key step in developing effective DNA-based electrochemical biosensors is to obtain a biorecognition layer on the biosensor, which can be influenced by many factors. Hence, we constructed a series of HJ24 layers on highly oriented pyrolytic graphite to investigate the relation between the configuration of the adsorbed probe HJ24 and the redox property using atomic force microscopy and voltammetry. We used HJ24 for its diagnostic value as it specifically recognizes the SH2 domain-containing phosphatase, a critical contributor in many important signaling pathways. The results demonstrated that increasing K ions induced G-quartet oxidation peak occurrence/increase([K+]?400 mmol/L), and also resulted in the formation of more compact single strand sheets([K+]?300 mmol/L). Moreover, transitions of molecule configurations and redox currents of G-quartets were observed at low concentration [K+]=12 mmol/L, which may indicate the appearance of new configurations under this condition. Besides, by analyzing atomic force microscopy(AFM) images, it was found that the different adsorbed configurations are correlated with the HJ24 concentration, the basal configuration, and the linker group on the HJ24 sequence. This information may be useful for understanding the adsorption process of HJ24 as well as for the further development of practical applications for HJ24 films on DNA electrochemical sensors, and may ultimately help improve the diagnosis and treatment of patients with SHP2-related diseases. 相似文献
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Yilmaz A Hindiyarti L Jensen AD Glarborg P Marshall P 《The journal of physical chemistry. A》2006,110(21):6654-6659
The thermal dissociation of SO3 has been studied for the first time in the 1000-1400 K range. The experiments were conducted in a laminar flow reactor at atmospheric pressure, with nitrogen as the bath gas. On the basis of the flow reactor data, a rate constant for SO3 + N2 --> SO2 + O + N2 (R1b) of 5.7 x 10(17) exp(-40000/T) cm3/(mol s) is derived for the temperature range 1273-1348 K. The estimated uncertainty is a factor of 2. The rate constant corresponds to a value of the reverse reaction of k1 approximately 1.8 x 10(15) cm6 mol(-2) s(-1). The reaction is in the fall-off region under the investigated conditions. The temperature and pressure dependence of SO2 + O (+N2) was estimated from the extrapolation of low temperature results for the reaction, together with an estimated broadening parameter and the high-pressure limit determined recently by Naidoo, Goumri, and Marshall (Proc. Combust. Inst. 2005, 30, 1219-1225). The theoretical rate constant is in good agreement with the experimental results. The improved accuracy in k(1) allows a reassessment of the rate constant for SO3 + O --> SO2 + O2 (R2) based on the data of Smith, Tseregounis, and Wang (Int. J. Chem. Kinet. 1982, 14, 679-697), who conducted experiments on a low-pressure CO/O2/Ar flame doped with SO2. At the location in the flame where the net SO3 formation rate is zero, k2 = k1[SO2][M]/[SO3]. A value of 6.9 x 10(10) cm3 mol(-1) s(-1) is obtained for k2 at 1269 K with an uncertainty a factor of 3. A recommended rate constant k2 = 7.8 x 10(11) exp(-3065/T) cm3 mol(-1) s(-1) is consistent with other flame results as well as the present flow reactor data. 相似文献