共查询到20条相似文献,搜索用时 15 毫秒
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《Tetrahedron letters》1987,28(23):2583-2586
TiCl4 mediated cyclization of allyl-pulegols led to halogeno-naphtalenes. 相似文献
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E. G. Mesropyan G. B. Ambartsumyan A. A. Avetisyan A. S. Galstyan I. R. Arutyunova 《Russian Journal of Organic Chemistry》2005,41(1):67-69
1-Phenoxy-3-piperidinopropan-2-ol, 1-(5-methyl-1,3-benzothiazol-2-ylsulfanyl)-3-phenoxypropan-2-ol, 1-(2-hydroxy-3-phenoxypropyl)azepan-2-one, 1,1′-(6-chloro-1,3-benzothiazol-2-ylimino)bis(3-phenoxypropan-2-ol), 1-(1,3-benzothiazol-2-ylsulfanyl)-3-phenoxypropan-2-ol, 1,1′-(piperazine-1,4-diyl)bis(3-phenoxypropan-2-ol), and 1,3-bis(2-hydroxy-3-phenoxypropyl)barbituric acid were synthesized by condensation of 1,2-epoxy-3-phenoxypropane with the corresponding amines and thiols.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 1, 2005, pp. 70–72.Original Russian Text Copyright © 2005 by Mesropyan, Ambartsumyan, Avetisyan, Galstyan, Arutyunova. 相似文献
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A. V. Kuzenkov 《Chemistry of Heterocyclic Compounds》2003,39(11):1492-1495
Through the reaction of (2-aryloxiran-2-yl)pyridines with triazole or imidazole a series of novel 2-azolyl-1-pyridylethan-1-ols has been synthesized with different positioning of the nitrogen atom in the pyridine fragment for pharmacological and agrochemical screening. The compounds prepared showed high fungicidal activity. 相似文献
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Sajal Kanti Mal 《Tetrahedron letters》2004,45(2):277-279
The novel Pd-catalyzed tandem cyclization of 1-bromohexa-1,5-dien-3-ols, prepared from the corresponding β-bromo-vinylaldehydes to cyclopentenone derivatives has been developed. 相似文献
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Abstract 1,4-dicyclohexyl-butan-1-ols with a lateral hydroxyl group in the middle part of the molecule exhibit higher clearing temperatures than those of the respective compounds whithout this lateral group. A smectic B-like texture and a low temperature additional phase X were found by microscopic and calorimetric investigations. A further unexpected result was the strong increase of the dielectric constant at the SB/X transition. These preliminary results are explained in terms of hydrogen bridges. 相似文献
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1,4-dicyclohexyl-butan-1-ols with a lateral hydroxyl group in the middle part of the molecule exhibit higher clearing temperatures than those of the respective compounds whithout this lateral group. A smectic B-like texture and a low temperature additional phase X were found by microscopic and calorimetric investigations. A further unexpected result was the strong increase of the dielectric constant at the SB/X transition. These preliminary results are explained in terms of hydrogen bridges. 相似文献
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Jayanta K. Ray Raju Singha Devalina Ray Paramita Ray Davuluri Yogeswara Rao Anakuthil Anoop 《Tetrahedron letters》2019,60(13):931-935
An unprecedented Pd-catalyzed intramolecular Heck cyclization has been investigated on halogenated diene scaffolds undergoing various mode of cyclization and termination leading to the formation of structurally differing fused cyclopenta(e)none and aromatic analogue. The discrimination in the fate of palladium intermediates formed in situ undergoing Heck cyclization preferentially arises out of the difference in reaction temperature as well as substrate architecture. Sequential Heck reaction of 1-Bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol derivatives followed by oxidation or termination via sp2 CH activation in aromatic ring led to the formation of fused cyclopentanes. However, the similar reaction at elevated temperature showed predominance towards the formation of aromatic analogues via one pot cyclization and dehydroxylation. The mechanism for the formation of cyclopentanone fused with cyclopropane ring system is supported by density functional theory based calculations. 相似文献
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Allylic alcohols can be successfully oxidized into the corresponding α, β-unsaturated aldehydes by two new types polymer-supported oxidizing reagents which do not oxidize saturated alcohols under similar condition. 相似文献
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Rashmi S. Kulkarni Nagendrappa Gopalpur Sowmya H. B. Vijaya Kumar Sunil S. More 《合成通讯》2014,44(3):331-339
The article describes a convenient and efficient synthetic route for the construction of 2-aroylbenzofuran-3-ols from readily available diverse methyl salicylates and phenacyl bromides using K2CO3 as catalyst in dimethylformamide as solvent at room temperature. The reaction involves two steps, which occur in quick succession within 1 h to deliver the product with reasonably high yields. All the synthesized 2-aroylbenzofuran-3-ols (4a–u) were subjected for their antimicrobial studies, and some of these have shown prominent activity.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
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L. S. Stanishevskii I. G. Tishchenko V. I. Tyvorskii L. A. Khil'manovich A. S. Zakharevskii A. V. Miklevich 《Chemistry of Heterocyclic Compounds》1973,9(11):1303-1306
The reaction of esters of 4-R-3-methyl-2,3,4,5-diepoxyvaleric acids with secondary amines leads to the formation of esters of 4-R-5-dialkylamino-4-hydroxy-3-methyl-2,3-epoxyvaleric acids. The reduction of the latter with lithium tetrahydroaluminate and the cyclization of the reduction products in the presence of p-toluenesulfonic acid has given 2-dialkylaminoethyltetrahydrofuran-3-ols, the methiodides of which possess ganglion-blocking activity.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1443–1446, November, 1973. 相似文献
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