Insight into Heterogeneity Effects in Methane Hydrate Dissociation via Pore-Scale Modeling

A large number (1253) of high-quality streaming potential coefficient (\(C_\mathrm{sp})\) measurements have been carried out on Berea, Boise, Fontainebleau, and Lochaline sandstones (the latter two including both detrital and authigenic overgrowth forms), as a function of pore fluid salinity (\(C_\mathrm{f})\) and rock microstructure. All samples were saturated with fully equilibrated aqueous solutions of NaCl (10\(^{-5}\) and 4.5 mol/dm\(^{3})\) upon which accurate measurements of their electrical conductivity and pH were taken. These \(C_\mathrm{sp}\) measurements represent about a fivefold increase in streaming potential data available in the literature, are consistent with the pre-existing 266 measurements, and have lower experimental uncertainties. The \(C_\mathrm{sp}\) measurements follow a pH-sensitive power law behaviour with respect to \(C_\mathrm{f}\) at medium salinities (\(C_\mathrm{sp} =-\,1.44\times 10^{-9} C_\mathrm{f}^{-\,1.127} \), units: V/Pa and mol/dm\(^{3})\) and show the effect of rock microstructure on the low salinity \(C_\mathrm{sp}\) clearly, producing a smaller decrease in \(C_\mathrm{sp}\) per decade reduction in \(C_\mathrm{f}\) for samples with (i) lower porosity, (ii) larger cementation exponents, (iii) smaller grain sizes (and hence pore and pore throat sizes), and (iv) larger surface conduction. The \(C_\mathrm{sp}\) measurements include 313 made at \(C_\mathrm{f} > 1\) mol/dm\(^{3}\), which confirm the limiting high salinity \(C_\mathrm{sp}\) behaviour noted by Vinogradov et al., which has been ascribed to the attainment of maximum charge density in the electrical double layer occurring when the Debye length approximates to the size of the hydrated metal ion. The zeta potential (\(\zeta \)) was calculated from each \(C_\mathrm{sp}\) measurement. It was found that \(\zeta \) is highly sensitive to pH but not sensitive to rock microstructure. It exhibits a pH-dependent logarithmic behaviour with respect to \(C_\mathrm{f}\) at low to medium salinities (\(\zeta =0.01133 \log _{10} \left( {C_\mathrm{f} } \right) +0.003505\), units: V and mol/dm\(^{3})\) and a limiting zeta potential (zeta potential offset) at high salinities of \({\zeta }_\mathrm{o} = -\,17.36\pm 5.11\) mV in the pH range 6–8, which is also pH dependent. The sensitivity of both \(C_\mathrm{sp}\) and \(\zeta \) to pH and of \(C_\mathrm{sp}\) to rock microstructure indicates that \(C_\mathrm{sp}\) and \(\zeta \) measurements can only be interpreted together with accurate and equilibrated measurements of pore fluid conductivity and pH and supporting microstructural and surface conduction measurements for each sample.     

Characterization for elastic constants of fused deposition modelling-fabricated materials based on the virtual fields method and digital image correlation

Fused deposition modelling (FDM), a widely used rapid prototyping process, is a promising technique in manufacturing engineering. In this work, a method for characterizing elastic constants of FDM-fabricated materials is proposed. First of all, according to the manufacturing process of FDM, orthotropic constitutive model is used to describe the mechanical behavior. Then the virtual fields method (VFM) is applied to characterize all the mechanical parameters \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) using the full-field strain, which is measured by digital image correlation (DIC). Since the principal axis of the FDM-fabricated structure is sometimes unknown due to the complexity of the manufacturing process, a disk in diametrical compression is used as the load configuration so that the loading angle can be changed conveniently. To verify the feasibility of the proposed method, finite element method (FEM) simulation is conducted to obtain the strain field of the disk. The simulation results show that higher accuracy can be achieved when the loading angle is close to \(30^{\circ }\). Finally, a disk fabricated by FDM was used for the experiment. By rotating the disk, several tests with different loading angles were conducted. To determine the position of the principal axis in each test, two groups of parameters \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) are calculated by two different groups of virtual fields. Then the corresponding loading angle can be determined by minimizing the deviation between two groups of the parameters. After that, the four constants \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) were determined from the test with an angle of \(27^{\circ }\).     

On the Justification of Viscoelastic Elliptic Membrane Shell Equations

We consider a family of linearly viscoelastic shells with thickness \(2\varepsilon\), clamped along their entire lateral face, all having the same middle surface \(S=\boldsymbol{\theta}(\bar{\omega})\subset \mathbb{R}^{3}\), where \(\omega\subset\mathbb{R}^{2}\) is a bounded and connected open set with a Lipschitz-continuous boundary \(\gamma\). We make an essential geometrical assumption on the middle surface \(S\), which is satisfied if \(\gamma\) and \(\boldsymbol{\theta}\) are smooth enough and \(S\) is uniformly elliptic. We show that, if the applied body force density is \(O(1)\) with respect to \(\varepsilon\) and surface tractions density is \(O(\varepsilon)\), the solution of the scaled variational problem in curvilinear coordinates, \(\boldsymbol{u}( \varepsilon)\), defined over the fixed domain \(\varOmega=\omega\times (-1,1)\) for each \(t\in[0,T]\), converges to a limit \(\boldsymbol{u}\) with \(u_{\alpha}(\varepsilon)\rightarrow u_{\alpha}\) in \(W^{1,2}(0,T,H ^{1}(\varOmega))\) and \(u_{3}(\varepsilon)\rightarrow u_{3}\) in \(W^{1,2}(0,T,L^{2}(\varOmega))\) as \(\varepsilon\to0\). Moreover, we prove that this limit is independent of the transverse variable. Furthermore, the average \(\bar{\boldsymbol{u}}= \frac{1}{2}\int_{-1}^{1} \boldsymbol{u}dx_{3}\), which belongs to the space \(W^{1,2}(0,T, V_{M}( \omega))\), where

$$V_{M}(\omega)=H^{1}_{0}(\omega)\times H^{1}_{0}(\omega)\times L ^{2}(\omega), $$

satisfies what we have identified as (scaled) two-dimensional equations of a viscoelastic membrane elliptic shell, which includes a long-term memory that takes into account previous deformations. We finally provide convergence results which justify those equations.

     

Transitional and Turbulent Flow in a Bed of Spheres as Measured with Stereoscopic Particle Image Velocimetry

Stereoscopic particle image velocimetry has been used to investigate inertia dominated, transitional and turbulent flow in a randomly packed bed of monosized PMMA spheres. By using an index-matched fluid, the bed is optically transparent and measurements can be performed in an arbitrary position within the porous bed. The velocity field observations are carried out for particle Reynolds numbers, \({Re}_{{p}}\), between 20 and 3220, and the sampling is done at a frequency of 75 Hz. Results show that, in porous media, the dynamics of the flow can vary significantly from pore to pore. At \({Re}_{{p}}\) around 400 the spatially averaged time fluctuations of total velocity reach a maximum and the spatial variation of the time-averaged total velocity, \(u_\mathrm{tot}\) increases up to about the same \({Re}_{{p}}\) and then it decreases. Also in the studied planes, a considerable amount of the fluid moves in the perpendicular directions to the main flow direction and the time-averaged magnitude of the velocity in the main direction, \(u_{x}\), has an averaged minimum of 40% of the magnitude of \(u_\mathrm{tot}\) at \({Re}_{{p}}\) about 400. For \({Re}_{{p}} > 1600\), this ratio is nearly constant and \(u_{x}\) is on average a little bit less than 50% of \(u_\mathrm{tot}\). The importance of the results for longitudinal and transverse dispersion is discussed.     

Models of Elastic Shells in Contact with a Rigid Foundation: An Asymptotic Approach

We consider a family of linearly elastic shells with thickness \(2\varepsilon\) (where \(\varepsilon\) is a small parameter). The shells are clamped along a portion of their lateral face, all having the same middle surface \(S\), and may enter in contact with a rigid foundation along the bottom face.We are interested in studying the limit behavior of both the three-dimensional problems, given in curvilinear coordinates, and their solutions (displacements \(\boldsymbol{u}^{\varepsilon}\) of covariant components \(u_{i}^{\varepsilon}\)) when \(\varepsilon\) tends to zero. To do that, we use asymptotic analysis methods. On one hand, we find that if the applied body force density is \(O(1)\) with respect to \(\varepsilon\) and surface tractions density is \(O(\varepsilon)\), a suitable approximation of the variational formulation of the contact problem is a two-dimensional variational inequality which can be identified as the variational formulation of the obstacle problem for an elastic membrane. On the other hand, if the applied body force density is \(O(\varepsilon^{2})\) and surface tractions density is \(O(\varepsilon^{3})\), the corresponding approximation is a different two-dimensional inequality which can be identified as the variational formulation of the obstacle problem for an elastic flexural shell. We finally discuss the existence and uniqueness of solution for the limit two-dimensional variational problems found.     

Influence of hydrodynamic slip on convective transport in flow past a circular cylinder

The presence of a finite tangential velocity on a hydrodynamically slipping surface is known to reduce vorticity production in bluff body flows substantially while at the same time enhancing its convection downstream and into the wake. Here, we investigate the effect of hydrodynamic slippage on the convective heat transfer (scalar transport) from a heated isothermal circular cylinder placed in a uniform cross-flow of an incompressible fluid through analytical and simulation techniques. At low Reynolds (\({\textit{Re}}\ll 1\)) and high Péclet (\({\textit{Pe}}\gg 1\)) numbers, our theoretical analysis based on Oseen and thermal boundary layer equations allows for an explicit determination of the dependence of the thermal transport on the non-dimensional slip length \(l_s\). In this case, the surface-averaged Nusselt number, Nu transitions gradually between the asymptotic limits of \(Nu \sim {\textit{Pe}}^{1/3}\) and \(Nu \sim {\textit{Pe}}^{1/2}\) for no-slip (\(l_s \rightarrow 0\)) and shear-free (\(l_s \rightarrow \infty \)) boundaries, respectively. Boundary layer analysis also shows that the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) holds for a shear-free cylinder surface in the asymptotic limit of \({\textit{Re}}\gg 1\) so that the corresponding heat transfer rate becomes independent of the fluid viscosity. At finite \({\textit{Re}}\), results from our two-dimensional simulations confirm the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) for a shear-free boundary over the range \(0.1 \le {\textit{Re}}\le 10^3\) and \(0.1\le {\textit{Pr}}\le 10\). A gradual transition from the lower asymptotic limit corresponding to a no-slip surface, to the upper limit for a shear-free boundary, with \(l_s\), is observed in both the maximum slip velocity and the Nu. The local time-averaged Nusselt number \(Nu_{\theta }\) for a shear-free surface exceeds the one for a no-slip surface all along the cylinder boundary except over the downstream portion where unsteady separation and flow reversal lead to an appreciable rise in the local heat transfer rates, especially at high \({\textit{Re}}\) and Pr. At a Reynolds number of \(10^3\), the formation of secondary recirculating eddy pairs results in appearance of additional local maxima in \(Nu_{\theta }\) at locations that are in close proximity to the mean secondary stagnation points. As a consequence, Nu exhibits a non-monotonic variation with \(l_s\) increasing initially from its lowermost value for a no-slip surface and then decreasing before rising gradually toward the upper asymptotic limit for a shear-free cylinder. A non-monotonic dependence of the spanwise-averaged Nu on \(l_s\) is observed in three dimensions as well with the three-dimensional wake instabilities that appear at sufficiently low \(l_s\), strongly influencing the convective thermal transport from the cylinder. The analogy between heat transfer and single-component mass transfer implies that our results can directly be applied to determine the dependency of convective mass transfer of a single solute on hydrodynamic slip length in similar configurations through straightforward replacement of Nu and \({\textit{Pr}}\) with Sherwood and Schmidt numbers, respectively.     

Displacement and Dissolution Characteristics of CO$$_{}$$/Brine System in Unconsolidated Porous Media

This study investigated the dynamic displacement and dissolution of \(\hbox {CO}_{2}\) in porous media at 313 K and 6/8 MPa. Gaseous (\(\hbox {gCO}_{2}\)) at 6 MPa and supercritical \(\hbox {CO}_{2 }(\hbox {scCO}_{2}) \) at 8 MPa were injected downward into a glass bead pack at different flow rates, following upwards brine injection. The processes occurring during \(\hbox {CO}_{2}\) drainage and brine imbibition were visualized using magnetic resonance imaging. The drainage flow fronts were strongly influenced by the flow rates, resulting in different gas distributions. However, brine imbibition proceeded as a vertical compacted front due to the strong effect of gravity. Additionally, the effects of flow rate on distribution and saturation were analyzed. Then, the front movement of \(\hbox {CO}_{2}\) dissolution was visualized along different paths after imbibition. The determined \(\hbox {CO}_{2}\) concentrations implied that little \(\hbox {scCO}_{2}\) dissolved in brine after imbibition. The dissolution rate was from \(10^{-8}\) to \(10^{-9}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) and from \(10^{-6}\) to \(10^{-8}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) for \(\hbox {gCO}_{2}\) at 6 MPa and \(\hbox {scCO}_{2 }\) at 8 MPa, respectively. The total time for the \(\hbox {scCO}_{2}\) dissolution was short, indicating fast mass transfer between the \(\hbox {CO}_{2}\) and brine. Injection of \(\hbox {CO}_{2}\) under supercritical conditions resulted in a quick establishment of a steady state with high storage safety.     

Effects of hysteresis of static contact angle (HSCA) and boundary slip on the hydrodynamics of water striders

It is known that contact lines keep relatively still on solids until static contact angles exceed an interval of hysteresis of static contact angle(HSCA), and contact angles keep changing as contact lines relatively slide on the solid.Here, the effects of HSCA and boundary slip were first distinguished on the micro-curvature force(MCF) on the seta.Hence, the total MCF is partitioned into static and dynamic MCFs correspondingly. The static MCF was found proportional to the HSCA and related with the asymmetry of the micro-meniscus near the seta. The dynamic MCF, exerting on the relatively sliding contact line, is aroused by the boundary slip. Based on the Blake–Haynes mechanism, the dynamic MCF was proved important for water walking insects with legs slower than the minimum wave speed 23 cm · s-1. As insects brush the water by laterally swinging legs backwards,setae on the front side of the leg are pulled and the ones on the back side are pushed to cooperatively propel bodies forward.If they pierce the water surface by vertically swinging legs downwards, setae on the upside of the legs are pulled, and the ones on the downside are pushed to cooperatively obtain a jumping force. Based on the dependency between the slip length and shear rate, the dynamic MCF was found correlated with the leg speed U, as F~C_1 U + C_2U~(2+ε), where C_1 and C_2 are determined by the dimple depth. Discrete points on this curve could give fitted relations as F~U~b(Suter et al., J. Exp. Biol. 200, 2523–2538, 1997). Finally,the axial torque on the inclined and partially submerged seta was found determined by the surface tension, contact angle,HSCA, seta width, and tilt angle. The torque direction coincides with the orientation of the spiral grooves of the seta,which encourages us to surmise it is a mechanical incentive for the formation of the spiral morphology of the setae of water striders.     

The Unstable Set of a Periodic Orbit for Delayed Positive Feedback

In the paper [Large-amplitude periodic solutions for differential equations with delayed monotone positive feedback, JDDE 23 (2011), no. 4, 727–790], we have constructed large-amplitude periodic orbits for an equation with delayed monotone positive feedback. We have shown that the unstable sets of the large-amplitude periodic orbits constitute the global attractor besides spindle-like structures. In this paper we focus on a large-amplitude periodic orbit \({\mathcal {O}}_{p}\) with two Floquet multipliers outside the unit circle, and we intend to characterize the geometric structure of its unstable set \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \). We prove that \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) is a three-dimensional \(C^{1}\)-submanifold of the phase space and admits a smooth global graph representation. Within \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \), there exist heteroclinic connections from \({\mathcal {O}}_{p}\) to three different periodic orbits. These connecting sets are two-dimensional \(C^{1}\)-submanifolds of \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) and homeomorphic to the two-dimensional open annulus. They form \(C^{1}\)-smooth separatrices in the sense that they divide the points of \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) into three subsets according to their \(\omega \)-limit sets.     

Long-time Dynamics of Resonant Weakly Nonlinear CGL Equations

Consider a weakly nonlinear CGL equation on the torus \(\mathbb {T}^d\):

$$\begin{aligned} u_t+i\Delta u=\epsilon [\mu (-1)^{m-1}\Delta ^{m} u+b|u|^{2p}u+ ic|u|^{2q}u]. \end{aligned}$$

(*)

Here \(u=u(t,x)\), \(x\in \mathbb {T}^d\), \(0<\epsilon <<1\), \(\mu \geqslant 0\), \(b,c\in \mathbb {R}\) and \(m,p,q\in \mathbb {N}\). Define \(I(u)=(I_{\mathbf {k}},\mathbf {k}\in \mathbb {Z}^d)\), where \(I_{\mathbf {k}}=v_{\mathbf {k}}\bar{v}_{\mathbf {k}}/2\) and \(v_{\mathbf {k}}\), \(\mathbf {k}\in \mathbb {Z}^d\), are the Fourier coefficients of the function \(u\) we give. Assume that the equation \((*)\) is well posed on time intervals of order \(\epsilon ^{-1}\) and its solutions have there a-priori bounds, independent of the small parameter. Let \(u(t,x)\) solve the equation \((*)\). If \(\epsilon \) is small enough, then for \(t\lesssim {\epsilon ^{-1}}\), the quantity \(I(u(t,x))\) can be well described by solutions of an effective equation:

$$\begin{aligned} u_t=\epsilon [\mu (-1)^{m-1}\Delta ^m u+ F(u)], \end{aligned}$$

where the term \(F(u)\) can be constructed through a kind of resonant averaging of the nonlinearity \(b|u|^{2p}+ ic|u|^{2q}u\).

     

Delayed detached eddy simulations of fighter aircraft at high angle of attack

The massively separated flows over a realistic aircraft configuration at 40?, 50?, and 60?angles of attack are studied using the delayed detached eddy simulation(DDES).The calculations are carried out at experimental conditions corresponding to a mean aerodynamic chord-based Reynolds number of 8.93 × 10~5 and Mach number of 0.088. The influence of the grid size is investigated using two grids, 20.0×10~6cells and 31.0 × 10~6 cells. At the selected conditions, the lift,drag, and pitching moment from DDES predictions agree with the experimental data better than that from the Reynoldsaveraged Navier–Stokes. The effect of angle of attack on the flow structure over the general aircraft is also studied, and it is found that the dominated frequency associated with the vortex shedding process decreases with increasing angle of attack.     

Steady States of Fokker–Planck Equations: III. Degenerate Diffusion

This is the third paper in a series concerning the study of steady states of a Fokker–Planck equation in a general domain in \({\mathbb R}^n\) with \(L^{p}_{loc}\) drift term and \(W^{1,p}_{loc}\) diffusion term for any \(p>n\). In this paper, we give some existence results of stationary measures of the Fokker–Planck equation under Lyapunov conditions which allow the degeneracy of diffusion.     

A Simple Method for the Determination of Adsorption Kinetic Parameters Using Recycle Fixed-Bed Adsorber

This study focuses on the development of a novel analysis technique for determining the intraparticle diffusivity \((D_{\mathrm{S}})\) and fluid film mass transfer coefficient \((k_\mathrm{F})\) from a concentration history curve of a recycle fixed-bed reactor without using the linear driving force approximation and empirical equations for the estimation of \(k_\mathrm{F}\). The recycle fixed-bed method requires lesser amounts of working fluid for experiment purposes, which is an advantage over the usual fixed-bed method. Based on the characterization results of the concentration history curves, simulated by rigorous numerical calculations, a novel analysis technique was established. The \(D_{\mathrm{S}}\) value can be determined from the experimentally obtained time at which the concentration of the curve is minimal \((t_{C\mathrm{min}})\). The \(k_\mathrm{F}\) value can be determined from the \(D_{\mathrm{S}}\) value and Biot number (Bi), which can be estimated from the experimental ratio of the maximum concentration to the minimum concentration \((c_{\max }/c_{\min })\). The \(D_{\mathrm{S}}\) and \(k_\mathrm{F}\) values of phenol adsorption on an activated carbon material were determined experimentally using the proposed analysis method. This method enables the determination of reliable adsorption kinetic parameters through a simple and economical experiment. However, appropriate experimental data must be acquired under regulated experimental conditions, especially in the case of fluctuation of the concentration history curve.     

Inertial Sensitivity of Porous Microstructures

Fluid flows through porous media are subject to different regimes, ranging from linear creeping flows to unsteady, chaotic turbulence. These different flow regimes at the pore scale have repercussions at larger scales, with the macroscale drag force experienced by a fluid moving through the medium becoming a nonlinear function of the average velocity beyond the creeping flow regime. Accurate prediction of the transition between different flow regimes is an important challenge with repercussions onto many engineering applications. Here, we are interested in the first deviation from Darcy’s law, when inertia effects become sizeable. Our goal is to define a Reynolds number, \(Re_{\mathrm{C}}\), so that the inertial deviation occurs when \(Re_{\mathrm{C}}\sim 1\) for any microstructure. The difficulty in doing so is to reduce the multiple length scales characterizing the geometry of the porous structure to a single length scale, \(\ell \). We analyze the problem using the method of volume averaging and identify a length scale in the form \(\ell =C_\lambda \sqrt{\nicefrac {K_\lambda }{\epsilon _\beta }}\), with \(C_\lambda \) a parameter that indicates the sensitivity of the microstructure to inertia. The main advantage of this definition is that an explicit formula for \(C_\lambda \) is given; \(C_\lambda \) is computed from a creeping flow simulation in the porous medium; and \(Re_{\mathrm{C}}\) can be used to predict the transition to a non-Darcian regime more accurately than by using Reynolds numbers based on alternative length scales. The theory is validated numerically with data from flow simulations for a variety of microstructures.     

Further Dense Properties of the Space of Circle Diffeomorphisms with a Liouville Rotation Number

In continuation of Matsumoto’s paper (Nonlinearity 25:1495–1511, 2012) we show that various subspaces are \(C^{\infty }\)-dense in the space of orientation-preserving \(C^{\infty }\)-diffeomorphisms of the circle with rotation number \(\alpha \), where \(\alpha \in {\mathbb {S}}^1\) is any prescribed Liouville number. In particular, for every odometer \({\mathcal {O}}\) of product type we prove the denseness of the subspace of diffeomorphisms which are orbit-equivalent to \({\mathcal {O}}\).     

A Nonlinear Korn Inequality Based on the Green-Saint Venant Strain Tensor

A nonlinear Korn inequality based on the Green-Saint Venant strain tensor is proved, whenever the displacement is in the Sobolev space \(W^{1,p}\), \(p\geq 2\), under Dirichlet conditions on a part of the boundary. The inequality can be useful in proving the coercivity of a nonlinear elastic energy.     

Existence of $$C^{k}$$-Invariant Foliations for Lorenz-Type Maps

Under conditions similar to those in Shashkov and Shil’nikov (Differ Uravn 30(4):586–595, 732, 1994) we show that a \(C^{k+1}\) Lorenz-type map T has a \(C^{k}\) codimension one foliation which is invariant under the action of T. This allows us to associate T to a \(C^{k}\) one-dimensional transformation.     

Dynamics in phase transitions of TASEP coupled with multi-lane SEPs

In this paper, we study a traffic model constituted by totally asymmetric simple exclusion process (TASEP) and two-lane simple exclusion processes (SEP). Then we generalize it to study TASEP coupled with multiple SEP lanes. Numerical results by the mean-field approximation have been presented to show the dynamics of TASEP competing with multi-lane SEPs. Complemented by simulation results, numerical results show that phase diagrams and current diagrams qualitatively vary with current splitting parameter \({\theta _i}\), hopping rate \({D_i}\) (\({D'_i}\)) and the global density \(n_{\mathrm{p}}\).