Features of electrical properties of BE-C(Fe) biocarbons carbonized in the presence of an Fe-containing catalyst

The effect of partial graphitization on electrical and galvanomagnetic properties of BE-C(Fe) biomorphic carbons produced by beech wood carbonization at temperatures of 850–1600°C in the presence of an iron-containing catalyst is studied. The use of an Fe catalyst at Т _carb ≥ 1000°C leads to the formation of nanoscale graphite-phase inclusions; its total volume and nanocrystallite sizes increase with Т _carb. The data on the carrier concentration and mobility are obtained. It was shown that partially graphitized BE-C(Fe) carbons with Т _carb ≥ 1000°C in the conductivity type and magnetoresistance features relate to highly disordered metal systems whose conductivity can be described taking into account the contribution of quantum corrections, mainly the correction caused by the electron–electron interaction. It is shown that nonmonotonic dependences of the Hall constant R on the magnetic field are characteristic of BE-C(Fe) samples with 1000 ≤ Т _carb < 1600°C, which is most probably caused by the contribution of various carrier groups, i.e., electrons and holes. In BE-C(Fe) samples with Т _carb = 1600°C, the Hall coefficient corresponds to the metal state, which is associated with conducting medium homogenization resulting from the formation of a significant graphite phase volume.     

Elastic and inelastic properties of SiC/Si biomorphic composites and biomorphic SiC based on oak and eucalyptus

This paper reports on the results of a comparative investigation into the elastic and microplastic properties of biomorphic SiC/Si composites and biomorphic SiC prepared by pyrolysis of oak and eucalyptus with subsequent infiltration of molten silicon into a carbon matrix and additional chemical treatment to remove excess silicon. The acoustic studies were performed by the composite oscillator technique using resonant longitudinal vibrations at frequencies of about 100 kHz. It is shown that, in biomorphic SiC (as in biomorphic SiC/Si) at small-amplitude strains ε, adsorption and desorption of the environmental (air) molecules determine to a considerable extent the Young’s modulus E and the internal friction (decrement of acoustic vibrations δ) and that the changes in E and δ at these amplitudes are irreversible. The stress-microplastic strain curves are constructed from the acoustic data for the materials under study at temperatures of 100 and 290 K.     

Folding-model analysis of elastic and inelastic α-particle scattering using a density-dependent force

A folding model with a density-dependent form of the semi-realistic M3Y effective interaction is applied to α-particle scattering. A previous analysis of elastic scattering at 140 and 172 MeV is now applied to data at other energies from 25 to 120 MeV. The model is also extended to inelastic scattering, using both the collective model and a valence-plus-core-polarization model for the transition densities. The proton transition densities were normalized to measured B(EL) values. When necessary, the neutron transition densities were rescaled to fit the (α, α′) data, providing a source of information on the neutron contributions. The neutron transition multipole moments thus obtained are compared to those derived from (p, p′) data at 800 MeV, as well as from other sources.     

The analysis of elastic and inelastic scattering of alpha particles using a folding potential

The elastic and inelastic scattering of alpha particles from Cd and Te isotopes are analysed in terms of a single folding model in which the scattering potential is approximated by folding an effectiveα-nucleon interaction into the mass distribution of the target nuclei. Excellent fits are obtained to the elastic scattering data. However, to obtain equally good fits to inelastic scattering data arbitrary adjustments of the effective interaction are required.     

Effect of proton and laser irradiation on the elastic and inelastic properties of a V-Ti-Cr alloy

The behavior of Young’s modulus E and the decrement of ultrasonic vibrations δ in a V-4Ti-4Cr alloy is studied during proton (8-MeV protons, dose rate 10⁴ Gy/s) or IR laser (YAG: Nd³⁺ laser, wavelength 1.06 μm, intensity up to 10² W/cm²) irradiation. Measurements are performed using the method of a composite piezoelectric oscillator (longitudinal 100-kHz resonance vibrations). The sizes of the irradiated surface regions of a sample in the proton and laser experiments are the same in order to provide the same thermal conditions in the sample-quartz transducer system. The amplitude, time, and temperature dependences of E and δ are measured before and after preliminary plastic deformation, as well as before, during, and after irradiation of a sample. The process of postdeformation aging (the kinetics of recovery of internal friction after deformation) during proton irradiation is shown to differ substantially from that during laser irradiation. The specific features detected can be explained by the more intense evolution of the defect structure during proton irradiation. Analysis shows that radiation annealing is related to the ionizing component of proton irradiation, which excites the electronic subsystem of the metallic alloy and, thus, creates hot electrons and plasmons. The electron excitations relax at lattice defects (dislocations) and increase the dislocation mobility; this results in a relatively rapid decrease in the dislocation density and in a more significant (as compared to the laser irradiation) decrease in the level of internal stresses in the material. __________ Translated from Fizika Tverdogo Tela, Vol. 46, No. 8, 2004, pp. 1409–1415. Original Russian Text Copyright ? 2004 by Kardashev, Plaksin, Stepanov, Chernov.     

Theory of inelastic tunneling spectroscopy of a single molecule - Competition between elastic and inelastic current

A theory of inelastic electron tunneling spectroscopy of a single molecule with scanning tunneling microscope is presented using the Keldysh Green’s function method for an adsorbate-induced resonance coupled to the molecular vibration. It is found that the correction to the tunneling current is expressed in terms of the transmission probability; the correction is negative for the elastic part of the current and positive for the inelastic one. The differential conductance (dI/dV) exhibits an increase or decrease at the threshold corresponding to the opening of inelastic channel depending on the sign of the correction, and the size of this conductance jump is scaled with the vibrational damping due to electron-hole pair excitation. The lineshape of d²I/dV²-spectra calculated using a renormalized adsorbate Green’s function evolves from an antisymmetric dip to a peak through the derivative-like one as the position of the adsorbate resonance recedes from the Fermi level of the substrate.     

Structure-mediated transition in the behavior of elastic and inelastic properties of beach tree bio-carbon

Microstructural characteristics and amplitude dependences of the Young modulus E and of internal friction (logarithmic decrement δ) of bio-carbon matrices prepared from beech tree wood at different carbonization temperatures T _carb ranging from 600 to 1600°C have been studied. The dependences E(T _carb) and δ(T _carb) thus obtained revealed two linear regions of increase of the Young modulus and of decrease of the decrement with increasing carbonization temperature, namely, ΔE ～ AΔT _carb and Δδ ～ BΔT _carb, with A ≈ 13.4 MPa/K and B ≈ ?2.2 × 10^?6 K^?1 for T _carb < 1000°C and A ≈ 2.5 MPa/K and B ≈ ?3.0 × 10^?7 K^?1 for T _carb > 1000°C. The transition observed in the behavior of E(T _carb) and δ(T _carb) at T _carb = 900–1000°C can be assigned to a change of sample microstructure, more specifically, a change in the ratio of the fractions of the amorphous matrix and of the nanocrystalline phase. For T _carb < 1000°C, the elastic properties are governed primarily by the amorphous matrix, whereas for T _carb > 1000°C the nanocrystalline phase plays the dominant part. The structurally induced transition in the behavior of the elastic and microplastic characteristics at a temperature close to 1000°C correlates with the variation of the physical properties, such as electrical conductivity, thermal conductivity, and thermopower, reported in the literature.     

On the elastic and inelastic scattering of O

Elastic and inelastic scattering data on ¹⁷O on ⁴⁰Ca measured at E_1ab=61 MeV are analyzed using collective core contributions plus valence terms which are obtained with the microscopic single-folding model. The role of two-step transfers and reorientation processes is also assessed.     

On the elastic and inelastic S,P and D phase-shift analysis

An analytical method to find S, P and D phase shifts with and without absorption effects is presented. The method was tested in the π?N scattering case using experimental data at energies of 523 and 310 MeV. In the inelastic case it was found that there are three sets of $\text{T =}\text{3}\text{2}$ solutions consistent with the input data.     

Acoustic study of the elastic and inelastic properties of high-pressure polyethylene samples with different irradiation histories

The influence of vibrational deformation amplitude ε on the dynamic elasticity modulus (Young’s modulus E) and internal friction (logarithmic decrement δ) of high-pressure polyethylene samples with different histories is studied. Acoustic measurements are made by a resonance method using the longitudinal vibrations of a composite piezoelectric vibrator at a frequency of ≈ 100 kHz. The dependences E(ε) and δ(ε) are taken at room temperature. From the acoustic data, the elasticity and microplasticity of the samples are estimated. It is found that the microplasticity remains almost unaffected upon irradiation and aging, while the elasticity modulus and breaking elongation per unit length considerably depend on the history and clearly correlated with each other. The observed effects are explained by the fact that atom-atom interaction and defects inside polymer macromolecules substantially influence the elastic modulus and breaking strength, while the inelastic microplastic strain is most likely associated with molecule-molecule interaction, which is affected by irradiation insignificantly.     

An experimental study of He elastic,inelastic and charge-exchange scattering from Li

A target of ⁶Li was bombarded with the ³He beam from the University of Illinois cyclotron. Differential cross sections for the elastic scattering, the inelastic scattering to the first two excited states of ⁶Li, and the (³He, t) charge-exchange reaction to the ground state of ⁶Be were determined over angular ranges of approximately 20° to 115° (c.m.) at ³He energies of 24.6 MeV and 27.0 MeV. (The weak inelastic transition to the 3.56 MeV state of ⁶Li, ordinarily obscured by a background of three-body break-up, was observed by requiring a coincidence at most angles between the scattered ³He and the ⁶Li recoil.) The ratio of the integrated charge-exchange cross section between 55° and 115° to the integrated inelastic cross section for this transition (both with ΔT = 1) is somewhat less than expected from isospin considerations (i.e., about 1.6 instead of 2.0).     

Comparison of elastic and inelastic scattering of phonons by a three-level spin system

Expressions for the phonon relaxation time due to elastic and inelastic scattering by small concentrations of paramagnetic ions having a simple three-level Zeeman-type spectrum are obtained. Both resonant and nonresonant processes can occur and the frequency dependence of each is examined for a model applicable to Fe²⁺ ions in MgO. Comparison with a Green function theory of coupled spin-phonon modes is made.     

Analysis of elastic properties of a spherical shell using a semiconductor laser autodyne

The possibility of using a semiconductor laser autodyne for estimating the elastic properties of a spherical shell simulating the eyeball is investigated. Estimation is based on the determination of the parameters of motion of a segment of a spherical shell under the action of a pneumatic pulse. The results lead to the conclusion that the ratio of the deflection to the acceleration of the shell is a constant quantity weakly depending on the pressure of pneumatic pulses and on the distance between their source and the shell.     

Structural, elastic, phonon and electronic properties of a MnPd alloy

The structural, elastic, phonon and electronic properties of a MnPd alloy have been investigated using the first-principles calculation. The calculated lattice constants and electronic structure agree well with the experimental results. The microscopic mechanism of the diffusionless martensitic transition from the paramagnetic B2 (PM-B2) phase to the antiferromagnetic L10 (AFM-L10) phase through the intermediate paramagnetic L10 (PM-L10 ) phase has been explored theoretically. The obtained negative shear modulus C′= (C11-C12)/2 of the PM-B2 phase is closely related to the instability of the cubic B2 phase with respect to the tetragonal distortions. The calculated phonon dispersions for the PM-L10 and AFM-L10 phases indicate that they are dynamically stable. However, the AFM-L10 phase is energetically most favorable according to the calculated total energy order, so the PM-L10 →AFM-L10 transition is caused by the magnetism rather than the electron-phonon interaction. Additionally, the AFM-L10 state is stabilized through the formation of a pseudo gap located at the Fermi level. The calculated results show that the CuAu-I type structure in the collinear antiferromagnetic state is dynamically and mechanically stable, thus is the low temperature phase.     

Neutron elastic and inelastic scattering from 28Si, 32S and 34S

Differential cross sections for the elastic and inelastic scattering of neutrons from the sd-shell nuclei ²⁸Si, ³²S and ³⁴S have been measured in the 20–26 MeV region. The data are analyzed in terms of the rotation-vibration (²⁸Si) and anharmonic vibration (^{32, 34}S) collective models. Isoscalar E2, E3 and E4 transition matrix elements are obtained from the normalized multipole moments of the real potential and the results are compared with those obtained from electromagnetic probes and from nuclear structure theoretical calculations.     

Opposite spin asymmetry of elastic and inelastic scattering of nonequilibrium holes injected into a ferromagnet

The spin asymmetry of elastic and inelastic scattering of nonequilibrium holes injected into Co thin films is examined using a p-type magnetic tunnel transistor. Spin-dependent transmission yields a positive or negative magnetocurrent depending on Co thickness and hole energy. Up to a critical thickness of about 3 nm, (quasi)elastic scattering dominates with a short attenuation length (<1 nm) and preferential attenuation of holes in the majority spin bands, consistent with spin-wave emission. At a larger Co thickness, inelastic scattering dominates with a larger attenuation length ( approximately 4 nm) and opposite spin asymmetry.     

Mechanism of elastic and inelastic proton scattering on a 15C nucleus in diffraction theory

The amplitudes for elastic and inelastic proton scattering on the neutron-rich nucleus ¹⁵C (to its J ^?? = 5/2⁺ level in the latter case) in inverse kinematics were calculated within Glauber diffraction theory. First- and second-order terms were taken into account in the multiple-scattering operator. The ¹⁵C wave function in the multiparticle shell model was used. This made it possible to calculate not only respective differential cross sections but also the contribution of proton scattering on nucleons occurring in different shells. The differential cross sections for elastic and inelastic scattering were calculated at the energies of 0.2, 0.6, and 1 GeV per nucleon.