共查询到19条相似文献,搜索用时 78 毫秒
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磁熵变(△SM)与磁场(μ0H)的相关性已在很多二级相变材料中被研究并报道,但一级相变材料的磁热效应与磁场相关性还少有报道.本文在具有一级磁结构相变的Mn0.6Fe0.4NiSi0.5Ge0.5材料中研究发现△SM与μ0H存在线性相关性,并通过麦克斯韦关系式的数值分析详细讨论了这一线性相关性的来源.同时,进一步发现在低磁场时,△SM近似正比于μ0H的平方.该线性相关性同样在一级磁结构相变Ni50Mn34Co2Sn14材料中得到了印证.但由于一级磁弹相变LaFe11.7Si1.3材料相变温度具有更强的磁场依赖性,不具有△SM的线性相关性,因此,本研究表明,当磁结构相变材料的相变温度具有弱磁场依赖性时,△SM与μ0H具有线性相关性.进而,在磁场未达到相变饱和磁场以下,利用△SM与μ0H的线性相关性可以有效推测更高磁场下的△SM. 相似文献
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该主要研究了高温超导体在脉冲磁场中的磁热稳定性,与传统低温超导体相比,HTS所不同的是最不稳定的状态发生在磁通跳跃区,理论上借助E-j曲线和有限热扩散方程推导了磁通跳跃场与变场速率的关系表达式:Bj=F其规律基本与实验结果相符合,同时从实验中发现磁热不稳定性对永磁体脉冲磁化效果有巨大的影响。 相似文献
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具有优良磁热性能的材料是磁制冷技术应用的关键.本文设计制备出了一种非晶态四元Gd45Ni30Al15Co10合金条带,系统地研究了该合金的磁热性能. Co的引入增加了合金的非晶态热稳定性,扩大了过冷液相区宽度. Gd45Ni30Al15Co10非晶态合金条带的居里温度和有效磁矩分别为80 K和7.21μB,在10 K温度下饱和磁化强度达到173 A·m~2·kg-1,矫顽力为0.8 kA·m-1,具有优异的软磁性能.在5 T的外加磁场下, Gd45Ni30Al15Co10非晶态合金的磁熵变峰值和相对制冷能力分别高达10.2 J·kg-1·K-1和918 J·kg-1.该合金具有典型的二级磁相变特征,可以在较宽的温度范围... 相似文献
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研究了NaZn13型结构LaFe13-xAlxC0.1(x=1.6,1.8)间隙化合物的磁制冷能力和磁相变.利用麦克斯韦关系式计算得到,高Al含量LaFe13-xAlx碳化物的最大磁熵变值|ΔS|m低于低Al含量碳化物的最大磁熵变值.随Al含量的增加,化合物的磁熵变峰展宽,但由于磁熵变大幅降低,衡量磁制冷能力的q值随之降低.基于朗道相变原理,考虑到自旋涨落的影响,磁自由能可以展开到磁化强度的6次方项,材料的相变类型由磁化强度的4次方项系数a3(T)的符号来进行判断.随着Al含量的增加,研究的碳化物相变由弱的一级相变转为二级相变.
关键词:
13-xAlx碳化物')" href="#">LaFe13-xAlx碳化物
磁制冷能力
磁相变 相似文献
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本文报道把热能直接转换电能的热磁发电技术所用一级相变新材料Mn1.2Fe0.8P0.4Si0.6的磁性和热磁发电性能.用高能球磨机械合金化技术和固相烧结合成方法制备了Mn1.2Fe0.8P0.4Si0.6化合物.磁性测量结果表明,该化合物呈现从铁磁状态变为顺磁状态的一级相变,居里温度为337K,并伴随巨大的磁化强度的变化.根据该材料的这一特性,设计制作了热磁发电演示装置,测定了热流引起材料的相变而产生的电流,并研究了固定磁场中热致磁转变产生的电流随热流温度和样品质量的变化.研究结果表明Mn1.2Fe0.8P0.4Si0.6化合物具有很好的热磁发电性能,可作为热磁发电材料. 相似文献
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本文用本征模积分方程研究了环形等离子体中磁剪切为负时由电子温度梯度驱动的不稳定性。考虑了电子的全部动力学效应,强调了稳定性阈值附近的模式行为及相应的湍性输运,给出了磁剪切为负的临界梯度的拟合公式。 相似文献
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具有内部输运垒(ITB)的反磁剪切(RS)等离子体位形是在托卡马克中获得高参数的最具前景的途径之一。这种位形不仅改善等离子体约束,而且可以改进象气球模和新经典撕裂模等这类宏观模的稳定性。然而,反磁剪切区域的高压强可以驱动电阻交换模不稳定性,从而破坏中心区的等离子体高参数。为了研究电阻交换模不稳定性的性质,并确定其在RS等离子体中发展的区域,我们利用在HL-2A中使用中性束注入建立的RS位形来分析电阻交换模不稳定性。 相似文献
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Hydrogen absorptions of LaFe11.5Si1.5 compound in 1-atm hydrogen gas at different temperatures are investigated. The hydrogen content in the hydrogenated sample does not increase with the increase of temperature of hydrogen absorption but changes complicatedly. The characteristic of first-order transition in LaFe11.5Si1.5 compound is weakened after hydrogen absorption. It leads the peaks of magnetic entropy to become wider and the hysteresis loss to reduce significantly, but relative cooling power (RCP) is not changed considerably. 相似文献
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High-resolution transmission electron microscopy and bulk magnetometry study of LaFe11.5Si1.5 compound 下载免费PDF全文
This paper studies the microstructural and magnetic properties of LaFe11.5Si1.5 compound by means of high-resolution transmission electron microscope and bulk magnetometry measurements. The crystalline structure is accompanied with the noncrystalline and nanocrystalline structures. This characteristic is the reflection of the crystalline process held by quenching. The inverse susceptibilities diverge and deviate from Curie-Weiss law under low applied magnetic fields. This paper proposes the possible mechanism between the anomalous susceptibilities and microstructure, and offers a perspective on the magnetic properties of metastable intermetallic compounds. 相似文献
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Large magnetic entropy change near room temperature in the LaFe11.5Si1.5H1.3 interstitial compound 总被引:2,自引:0,他引:2 下载免费PDF全文
The LaFe11.5Si1.5H1.3 interstitial compound has been prepared. Its Curie temperature TC (288 K) has been adjusted to around room temperature, and the maximal magnetic entropy change (|ΔS|~17.0 J·kg-1·K-1 at TC) is larger than that of Gd (|ΔS|~9.8 J·kg-1·K-1 at TC=293 K) by ~73.5% under a magnetic change from 0 to 5 T. The origin of the large magnetic entropy change is attributed to the first-order field-induced itinerant-electron metamagnetic transition. Moreover, the magnetic hysteresis of LaFe11.5Si1.5H1.3 under the increase and decrease of the field is very small, which is favourable to magnetic refrigeration application. The present study suggests that the LaFe11.5Si1.5H1.3 compound is a promising candidate as a room-temperature magnetic refrigerant. 相似文献
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研究了金属化合物LaFe_(11.5)Al_(1.5)H_x(x=0,0.12,0.6,1.3),LaFe_(11.5)Al_(1.5)B_y(y=0.1,0.2,0.3)和LaFe_(11.5)Al_(1.5)C_z(z=0.1,0.2,0.3,0.4,0.5)的磁性、结构和磁热效应.金属化合物样品均形成了良好的NaZn_(13)型单相结构.基于固相-气相反应或者固相-固相反应引入间隙H,B,C原子后,磁性基态从反铁磁态变为铁磁态,饱和磁化强度(M_s)和居里温度(T_c)均呈升高趋势.值得注意的是:随着B和C含量的增加,化合物的相变性质由弱一级相变过渡至二级相变;而随着H含量的增加,相变性质却从二级相变过渡至弱一级相变.同时,化合物LaFe_(11.5)Al_(1.5)H_x,LaFe_(11.5)Al_(1.5)B_y和LaFe_(11.5)Al_(1.5)C_z均呈现出相当大的磁熵变.在0—5 T的外磁场作用下,LaFe_(11.5)Al_(1.5)H_(1.3),LaFe_(11.5)Al_(1.5)B_(0.1)和LaFe_(11.5)Al_(1.5)C_(0.2)的最大磁熵变分别达到12.3,9.6和10.8 J/kg·K.此外,在0—5 T的外磁场作用下,LaFe_(11.5)Al_(1.5)H_(0.6)的制冷能力达到259.2 J/kg,LaFe_(11.5)Al_(1.5)B_(0.1)的制冷能力达到116.4 J/kg,而LaFe_(11.5)Al_(1.5)C_(0.1)的制冷能力达到230.4 J/kg. 相似文献
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The ErCo2 compound is prepared by arc-melting and its entropy changes are calculated using Maxwell relation. Its entropy change reaches 38 J/(kg·K) and its refrigerant capacity achieves 291 J/kg at 0-5 T. The mean field approximation is used to calculate the magnetic entropy of ErCo2 compound. Results estimated by using the Maxwell relation deviate from mean field approximation calculations in ferrimagnetic state; however, the data obtained by the two ways are consistent in the vicinity of phase transition or at higher temperatures. This indicates that entropy changes are mainly derived from magnetic degree of freedom, and the lattice has almost no contribution to the entropy change in the vicinity of phase transition but its influence is obvious in the ferrimagnetic state below TC. 相似文献
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Hong-wei Zhang Jun Shen Qiao-yan Dong Tong-yun Zhao Yang-xian Li Ji-rong Sun Bao-gen Shen 《Journal of magnetism and magnetic materials》2008
LaFe11.83Si1.17 compound shows a first-order transition from paramagnetic to ferromagnetic state. When measurement is carried out from low to high temperature in an increasing field, there is a spike of 51 J/kg K at 174.8 K, followed by a plateau of 20 J/kg K in the curve of entropy change versus temperature determined by the Maxwell relation. However, the nature of the spike is fictitious, which is caused by an obvious superheat of the ferromagnetic state when the Maxwell relation or the Clausius–Clapeyron equation is used to evaluate the entropy change. 相似文献
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Xiang Chen Yungui Chen Yongbai Tang 《Journal of magnetism and magnetic materials》2011,323(24):3177-3183
The phase relation of LaFe11.5Si1.5 alloys annealed at different high-temperature from 1223 K (5 h) to 1673 K (0.5 h) has been studied. The powder X-ray diffraction (XRD) patterns show that large amount of 1:13 phase begins to form in the matrix alloy consisting of α-Fe and LaFeSi phases when the annealing temperature is 1423 K. In the temperature range from 1423 to 1523 K, α-Fe and LaFeSi phases rapidly decrease to form 1:13 phase, and LaFeSi phase is rarely observed in the XRD pattern of LaFe11.5Si1.5 alloy annealed at 1523 K. With annealing temperature increasing from 1573 to 1673 K, the LaFeSi phase is detected again in the LaFe11.5Si1.5 alloy, and there is La5Si3 phase when the annealing temperature reaches 1673 K. There almost is no change in the XRD patterns of LaFe11.5Si1.5 alloys annealed at 1523 K for 3-5 h. According to this result, the La0.8Ce0.2Fe11.5−xCoxSi1.5 (0≤×≤0.7) alloys are annealed at 1523 K (3 h). The analysis of XRD patterns shows that La0.8Ce0.2Fe11.5xCoxSi1.5 alloys consist of the NaZn13-type main phase and α-Fe impurity phase. With the increase of Co content from x=0 to 0.7, the Curie temperature TC increases from 180 to 266 K. Because the increase of Co content can weaken the itinerant electron metamagnetic transition, the order of the magnetic transition at TC changes from first to second-order between x=0.3 and 0.5. Although the magnetic entropy change decreases from 34.9 to 6.8 J/kg K with increasing Co concentration at a low magnetic field of 0-2 T, the thermal and magnetic hysteresis loss reduces remarkably, which is very important for the magnetic refrigerant near room temperature. 相似文献
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Magnetic transitions and magnetoresistance effect of the HfFe_6Ge_6-type Y_{0.9}La_{0.1}Mn_6Sn_6 compound have been investigated in the temperature range of 5-380K. The sample displays antiferromagnetic behaviour in the whole temperature range below Néel temperature T_N=309K. The metamagnetic transition from antiferromagnetism to ferromagnetism can be induced by an applied field. The metamagnetic transition field decreases monotonically from 2T at 5K to 0.4T at 300K. The giant magnetoresistance effect is observed with the metamagnetic behaviour, such as -10.4% at 245K under a field of 5T. 相似文献
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Large magnetic entropy change and magnetic properties in La (Fel-xMnx)ll.TSil.3Hy compounds 下载免费PDF全文
Magnetic properties and magnetic entropy change in La(Fe_{1-x}Mn_x)_{11.7}Si_{1.3}H_y compounds have been investigated. A significant increase of the Curie temperature T_C and a small increase of the saturation magnetizations μ_S have been observed after the introduction of interstitial H, which caused a slight volume expansion. The first-order field-induced itinerant-electron metamagnetic (IEM) transition remains and brings about a large magnetic entropy change around room temperatures for the compounds. The maximal magnetic entropy change is about 23.4, 17.7 and 15.9J/kg·K under a magnetic field change from 0 to 5T for x=0.01, 0.02 and 0.03, respectively. Therefore, the compounds appear to be potential candidates for magnetic refrigerants around room temperatures. 相似文献