共查询到20条相似文献,搜索用时 15 毫秒
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Philipp Michael Prof. Dr. Wolfgang H. Binder 《Angewandte Chemie (International ed. in English)》2015,54(47):13918-13922
“Click” chemistry represents one of the most powerful approaches for linking molecules in chemistry and materials science. Triggering this reaction by mechanical force would enable site‐ and stress‐specific “click” reactions—a hitherto unreported observation. We introduce the design and realization of a homogeneous Cu catalyst able to activate through mechanical force when attached to suitable polymer chains, acting as a lever to transmit the force to the central catalytic system. Activation of the subsequent copper‐catalyzed “click” reaction (CuAAC) is achieved either by ultrasonication or mechanical pressing of a polymeric material, using a fluorogenic dye to detect the activation of the catalyst. Based on an N‐heterocyclic copper(I) carbene with attached polymeric chains of different flexibility, the force is transmitted to the central catalyst, thereby activating a CuAAC in solution and in the solid state. 相似文献
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Stefan Hilf Nils Hanik Andreas F. M. Kilbinger 《Journal of polymer science. Part A, Polymer chemistry》2008,46(9):2913-2921
Amphiphilic block copolymers can be conveniently prepared via convergent syntheses, allowing each individual polymer block to be prepared via the polymerization technique that gives the best architectural control. The convergent “click‐chemistry” route presented here, gives access to amphiphilic diblock copolymers prepared from a ring opening metathesis polymer and polyethylene glycol. Because of the high functional group tolerance of ruthenium carbene initiators, highly functional ring opening metathesis polymerization (ROMP) polymer blocks can be prepared. The described synthetic route allows the conjugation of these polymer blocks with other end‐functional polymers to give well‐defined and highly functional amphiphilic diblock copolymers. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2913–2921, 2008 相似文献
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Stoichiometrically Controlled Revocable Self‐Assembled “Spiro” versus Quadruple‐Stranded “Double‐Decker” Type Coordination Cages
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Sreenivasulu Bandi Dr. Amlan K. Pal Prof. Dr. Garry S. Hanan Prof. Dr. Dillip Kumar Chand 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(41):13122-13126
The simple combination of PdII with the tris‐monodentate ligand bis(pyridin‐3‐ylmethyl) pyridine‐3,5‐dicarboxylate, L , at ratios of 1:2 and 3:4 demonstrated the stoichiometrically controlled exclusive formation of the “spiro‐type” Pd1L2 macrocycle, 1 , and the quadruple‐stranded Pd3L4 cage, 2 , respectively. The architecture of 2 is elaborated with two compartments that can accommodate two units of fluoride, chloride, or bromide ions, one in each of the enclosures. However, the entry of iodide is altogether restricted. Complexes 1 and 2 are interconvertible under suitable conditions. 相似文献
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Chih‐Chia Cheng Chih‐Feng Huang Ying‐Chieh Yen Feng‐Chih Chang 《Journal of polymer science. Part A, Polymer chemistry》2008,46(19):6416-6424
This article describes a DNA‐like polymer that exhibits the ability to self‐assemble through hydrogen bonding. We synthesized poly[1‐(4‐vinylbenzyl)thymine] (PVBT) and 9‐hexadecyladenine (A‐C16) through an atom transfer radical polymerization (ATRP) and alkylation, respectively. Biocomplementary PVBT/A‐C16 hierarchical supramolecular complexes formed in dilute DMSO solution through nucleobase recognition, that is, hydrogen bonding interactions between the thymine (T) groups of PVBT and the adenine (A) group of A‐C16; evidence for this molecular recognition was also gained from dynamic light scattering studies. 1H NMR titration studies in CDCl3 showed that T–A complexes formed rapidly on the NMR time scale with high association constants (up to 534 M?1). Moreover, FTIR spectroscopic, differential scanning calorimetry, wide‐angle X‐ray diffraction, and small‐angle X‐ray scattering analyses provided further details into the nature of the self‐assembly of these systems. In the bulk state, these complexes self‐assemble into well‐ordered lamellar structures; the changing d‐spacing distance (ranging from 4.98 to 2.32 nm) at different A‐C16 loadings reveals that the molecular structures of the PVBT/A‐C16 complexes are readily tailored. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6416–6424, 2008 相似文献
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Dr. Yves‐Marie Legrand Dan Dumitrescu Dr. Arnaud Gilles Eddy Petit Dr. Arie van der Lee Dr. Mihail Barboiu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(15):4946-4950
Shatruk and Alabugin propose an alternative structural model for the observed electron density that we have attributed to the photochemical formation of 1,3‐dimethylcyclobutadiene in a protective solid crystalline matrix. The main criticism from Shatruk and Alabugin concerns the modeling of the disorder in the calixarene cavity and in particular the neglect of a residual electron density close to the O1 atom. We published (Chem. Eur. J. 2011 , 17, 10021) our opinion concerning this “ignored peak” in the Supporting Information of the paper. The current response to the Correspondence demonstrates that Shatruk and Alabugin have over‐modeled our data by assigning a small electron density peak, which is hardly more than the density corresponding to a hydrogen atom, to an under‐occupied oxygen site, using inappropriate refinement contraints. 相似文献
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Sinoj Abraham Chang‐Sik Ha Carl A. Batt Il Kim 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3570-3579
Stable and aggregation‐free “gold nanoparticle–polymeric micelle” conjugates were prepared using a new and simple protocol enabled by the hydrogen bonding between surface‐capping ligands and polymeric micelles. Individual gold nanoparticles were initially capped using a phosphatidylthio–ethanol lipid and further conjugated with a star poly(styrene‐block‐glutamic acid) copolymer micelle using a one‐pot preparation method. The morphology and stability of these gold–polymer conjugates were characterized using transmission electron microscopy (TEM) and UV–vis spectroscopy. The self‐assembly of this class of polymer‐b‐polypeptide in aqueous an medium to form spherical micelles and further their intermicelle reorganization to form necklace‐like chains was also investigated. TEM and laser light scattering techniques were employed to study the morphology and size of these micelles. Polymeric micelles were formed with diameters in the range of 65–75 nm, and supermicellular patterns were observed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3570–3579, 2007 相似文献
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Edwin P. Chan Jeffrey M. Karp Robert S. Langer 《Journal of Polymer Science.Polymer Physics》2011,49(1):40-44
Surface wrinkles are interesting since they form spontaneously into well‐defined patterns. The mechanism of formation is well‐studied and is associated with the development of a critical compressive stress that induces the elastic instability. In this work, we demonstrate surface wrinkles that dynamically change in response to a stimulus can improve interfacial adhesion with a hydrogel surface through the dynamic evolution of the wrinkle morphology. We observe that this control is related to the local pinning of the crack separation pathway facilitated by the surface wrinkles during debonding, which is dependent on the contact time with the hydrogel. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010 相似文献
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