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利用不同的测量方法,研究了MnFeP1-xAsx(0.32<x<0.66)材料巡游电子变磁性转变附近一级相变与其他物理性质变化的关系.可以发现,材料的一级相变是一个温度滞后为10K,但持续发生在至少66K的一个很大的温度区间的结构相变.磁性相变与一级相变的温度点并不对应.晶格突变与居里温度和一级相变温度点并不一一对应,属于磁致伸缩的机制,来源于磁弹性耦合.实验指出,顺磁-铁磁转变是在一级相变的过程中,由于晶格的连续变化,导致了a-b面内最近邻Fe-Fe原子间的距离增大,而非观察到的晶格突变所引起. 相似文献
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通过交流磁化率、电阻、有无磁场下的预相变应变、磁致伸缩和磁化强度测量,系统研究了近正配分比Ni505Mn245Ga25单晶的预马氏体相变特性.在自由样品中观察到预马氏体相变应变.在预相变点,沿[010]方向施加大小约为80kA/m的磁场,在晶体母相的[001]方向上获得了高达505ppm的磁致伸缩,该值是相同条件下晶体母相磁致伸缩量的5倍多.同时,报道了不同方向磁场对预相变应变干预的结果.利用软模凝结的概念和依据单晶生长的特点,分析了预相变应变产生的机理.而磁场干预预相变应变的机理是磁场增大的磁弹耦合导致的晶格形变与材料内禀形变的竞争.利用磁性测量结果证实和解释了预相变过程中[001]和[010]轴方向间进一步增大的各向异性.进而对磁场沿[001]和[010]两个晶体学方向所导致的应变特性的差别,包括最大磁致伸缩、饱和预相变应变、饱和场等,进行了分析和讨论.
关键词:
预马氏体相变
应变
磁致伸缩
磁弹耦合 相似文献
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本文报道把热能直接转换电能的热磁发电技术所用一级相变新材料Mn1.2Fe0.8P0.4Si0.6的磁性和热磁发电性能.用高能球磨机械合金化技术和固相烧结合成方法制备了Mn1.2Fe0.8P0.4Si0.6化合物.磁性测量结果表明,该化合物呈现从铁磁状态变为顺磁状态的一级相变,居里温度为337K,并伴随巨大的磁化强度的变化.根据该材料的这一特性,设计制作了热磁发电演示装置,测定了热流引起材料的相变而产生的电流,并研究了固定磁场中热致磁转变产生的电流随热流温度和样品质量的变化.研究结果表明Mn1.2Fe0.8P0.4Si0.6化合物具有很好的热磁发电性能,可作为热磁发电材料. 相似文献
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研究了MnNiGe1-xGax (x=0–0.30) 系列合金中成分、结构、马氏体相变性质和磁性的相互关系. 在较小的成分范围内, Ga取代Ge元素可有效地将马氏体相变温度降低近400 K. Ga的引入削弱了体系中的共价成键作用, 马氏体相显示出磁交换作用的增强. 相图显示, 掺杂使马氏体相变先后穿过TN 和TC 两个磁有序温度, 居里温度窗口效应在体系有存在的可能, 磁性对相变温度的成分关系有所影响. 实验观察到合金变磁转变的特性及相变行为对制备方法的敏感性. 这些特性的发现, 有利于进一步优化这类材料的磁结构和相变特性, 获得具有应用价值的新材料.
关键词:
MM’X合金
马氏体相变
磁有序温度
变磁转变 相似文献
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利用电弧炉熔炼了Ni50Mn35In15多晶样品,根据磁性测量对其马氏体相变和磁热效应进行了系统研究.结果表明,随着温度的降低,样品在室温附近先后发生了二级磁相变与一级结构相变特征的马氏体相变,导致它的磁化强度产生突变. 同时通过低温下的磁滞回线的测量发现样品存在交换偏置行为,表明低温下马氏体相中铁磁和反铁磁共存. 此外,根据Maxwell方程,计算了样品在马氏体相变温度附近的磁熵变,当温度为309K,磁场改变5 T时,样品的磁熵变可达22.3J/kgK.
关键词:
哈斯勒合金
50Mn35In15')" href="#">Ni50Mn35In15
马氏体相变
磁热效应 相似文献
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在10—800K的温度范围内用X射线衍射方法测量了DyMn2Ge2化合物的晶格常数与温度的变化关系,观察到高温时DyMn2Ge2由顺磁状态到反铁磁状态的自发磁相变伴随着晶格常数a的负的磁弹性异常现象.在4.2K—200K的温度范围内测量了DyMn2Ge2的交流磁化率.在交换相互作用的分子场模型近似下,从理论上分析讨论了DyMn2Ge2的低温自发磁相变和场诱导的磁相变.计算了DyMn2Ge2单晶的磁化强度与温度的变化关系以及不同温度下外磁场沿晶轴c方向时的磁化曲线.理论分析和计算结果表明,温度低于33K时在DyMn2Ge2中观察到的场诱导的一级磁相变为由亚铁磁状态(Fi)到中间态(IS)相变.
关键词:
稀土-过渡族金属间化合物
磁结构
磁相变 相似文献
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磁熵变(△SM)与磁场(μ0H)的相关性已在很多二级相变材料中被研究并报道,但一级相变材料的磁热效应与磁场相关性还少有报道.本文在具有一级磁结构相变的Mn0.6Fe0.4NiSi0.5Ge0.5材料中研究发现△SM与μ0H存在线性相关性,并通过麦克斯韦关系式的数值分析详细讨论了这一线性相关性的来源.同时,进一步发现在低磁场时,△SM近似正比于μ0H的平方.该线性相关性同样在一级磁结构相变Ni50Mn34Co2Sn14材料中得到了印证.但由于一级磁弹相变LaFe11.7Si1.3材料相变温度具有更强的磁场依赖性,不具有△SM的线性相关性,因此,本研究表明,当磁结构相变材料的相变温度具有弱磁场依赖性时,△SM与μ0H具有线性相关性.进而,在磁场未达到相变饱和磁场以下,利用△SM与μ0H的线性相关性可以有效推测更高磁场下的△SM. 相似文献
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在10—800K的温度范围内用X射线衍射方法测量了RMn2Ge2(R=La,Pr ,Nd,Sm,Gd,Tb和Y)的晶格常数与温度的变化关系.在各种类型的自发磁相变观察到晶格常数 的磁弹性异常现象.实验得出,自发磁相变时的磁弹性异常主要由Mn次晶格引起,并且Mn-Mn 交换相互作用能不仅与晶格常数a有关,而且与晶格常数c有关.用Kittle的交换反转模型讨 论了低温时的铁磁—反铁磁一阶相变.
关键词:
稀土金属间化合物
磁相变
磁弹性 相似文献
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由于一级相变磁制冷材料发生磁相变时有晶胞体积的突变,相变过程中有相变潜热存在,其磁化过程中有许多磁学问题有待于进一步探究.本文以LaFe13-xSix合金为研究对象,在现有对磁一级相变基础问题的分析基础上,对一级相变材料中系统熵变、等温熵变、绝热温变、热滞、磁滞、铁磁与顺磁态两相共存的温度区间和磁场区间、制冷能力的计算等磁学基础问题进行了较为细致的探究.分析表明,在忽略完全铁磁态和顺磁态对磁热效应的贡献时,Maxwell方程和Clausius-Clapeyron方程计算熵变的值具有等效性.等温磁化过程中升温和降温曲线包围的面积SABCE(磁滞的大小),实际上是升温过程和降温过程中磁场做的净功,等于相变潜热之差.磁滞和热滞的大小与磁化过程数据测量的时间有关,测量时间越长则滞后越小,当相变是平衡相变则滞后为零.另外,对温度和磁场诱导磁相变过程进行了分析,提出了一级相变磁制冷材料制冷能力的不同计算模型.本文对一级相变磁制冷材料的磁学基础问题研究有一定的参考价值. 相似文献
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Raman spectra of Cs2ZnI4 single crystal have been measured in different scattering orientations covering the successive phase transitions down to 68 K. Two second order anomalies at around ice temperature (270 K) and at ~ 92 K are observed. The anomaly around ice temperature exhibits the features of a normal-incommensurate transition evidenced by softening of a low-lying lattice phonon whose frequency decreases as the transition temperature is approached from below whereas the latter one appears to arise from usual structural distortions. 相似文献
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We used optical birefringence, X-ray and neutron diffraction methods with single crystals to study the structural phase transitions of the perowskite-type layer structures of (CH3NH3)2MeCl4 with Me=Mn, Fe. The Mn-compound shows the following structural transitions at 394 K — a continuous order-disorder phase transition from tetragonal symmetry to orthorhombic space group Abma (Cmca in reference 10); at 257 K — a discontinuous transition to a second tetragonal modification; at 95 K — a discontinuous transition to a monoclinic phase. For the Fe-compound the corresponding transition temperatures are 328 K and 231 K, respectively. A low temperature monoclinic phase could not be observed. The lattice parameters of the different modifications were determined as a function of temperature. The temperature dependent course of the order parameter has been investigated for the order—disorder transition. For both compounds, all the methods used gave the same value for the critical exponent of β = 0.315. 相似文献
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Neutron powder diffraction studies showed that the ordered perovskites Ba2BiSbO6 (BBS) and BaSrBiSbO6 (BSBS) crystallize in a rhombohedral structure with the space group R3¯. The room-temperature lattice parameters are a=6.0351(2) Å; α=60.202(1)° and a=5.9809(2) Å; α=60.045(2)°, respectively. BBS exhibits a dielectric anomaly near room temperature which may be related to structural transition from the R3¯ to low-temperature monoclinic I2/m symmetry. BSBS shows a dielectric anomaly near 723 K which coincides with a phase transition from the rhombohedral to cubic (Fm3¯m) structure. In contrast to BBS, BSBS does not undergo structural transition below room temperature. 相似文献
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通过对La0.3Ca0.7Mn1-xWxO3(x=0.00,0.04,0.08,0.12,0.15)多晶样品M-T曲线、M-H曲线及ESR谱的测量,研究了Mn位W掺杂对电荷有序体系La0.3Ca0.7MnO3磁结构的影响.结果表明,当掺杂量为0.00≤x≤0.08时,体系存在电荷有序(CO)相,AFM/CO态共存于相变温度以下,电荷有序温度TCO随着W掺杂量的增加而增加;x=0.04时,样品在低温下为FM相与AFM/CO相共存,在CO相建立前、后均有FM从PM中分离出来;当x≥0.12时,CO态融化,在极低温度下存在顺磁-铁磁(PM-FM)相变.
关键词:
磁结构
电荷有序
融化
Mn位掺杂 相似文献
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The low temperature specific heat and thermal conductivity of (Cu50Zr50)94Al6 bulk metallic glass have been studied experimentally. A low temperature anomaly in the specific heat is observed in this alloy. It is also found that in addition to Debye oscillators, the localized vibration modes whose vibration density of state has a Gaussian distribution should be considered to explain the low temperature phonon specific heat anomaly. The phonon thermal conductivity dependence on temperature for the sample does not show apparent plateau characteristics as other glass materials do; however, the influence of the resonant scattering from the localized modes on the lattice thermal conductivity is prominent in the bulk metallic glass at low temperatures. 相似文献
16.
We investigate the structural, transport, and magnetic properties of Mn1−xMgxV2O4(0≤x≤0.8) to study the role of the A-site magnetism in vanadate spinels. With increasing Mg2+ concentration, the lattice parameters shrink and the hopping energy for electrons increases, whereas both the magnetic transition temperature and the structural transition temperature decrease gradually. The two temperatures become closer and eventually equal to each other at x=0.2. For x>0.2 the first order transition disappears and the magnetic ground state switches from a long range ordered ferrimagnetic state to a glassy state. The transition temperature of the glassy state continues to decrease with further increase of Mg content, which is attributed to the dilution in the magnetism on A sites. 相似文献
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Magnetic properties and magnetocaloric effect of compound PrFe 12 B 6 are investigated.The coexistence of hard phase PrFe 12 B 6 and soft phase α-Fe causes interesting phenomena on the curves for the temperature dependence of magnetization.PrFe 12 B 6 experiences a first order phase transition at the Curie temperature 200 K,accompanied by an obvious lattice contraction,which in turn results in a large magnetic entropy change.The Maxwell relation fails to give the correct information about magnetic entropy change due to the first order phase transition nature.The large magnetic entropy changes of PrFe 12.3 B 4.7 obtained from heat capacity method are 11.7 and 16.2 J/kg.K for magnetic field changes of 0-2 T and 0-5 T respectively. 相似文献
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Phase transitions of single-crystal M2 [Pt(CN)4]3 · 21H2O are investigated under temperature variation using X-ray diffraction, polarized emission and DSC-measurements. At a temperature Ttrans a jump was observed in lattice parameters and in optical transition energies. The transition is connected with an occurence of a latent transition enthalpy. This indicates a displacive phase transition of first order. Optical and X-ray data can be correlated. 相似文献