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1.
Tijen Tanyalcin Diler Aslan Yusuf Kurtulmus Nalan Gökalp Kamil Kumanlioğlu 《Accreditation and quality assurance》2000,5(9):383-387
In this study the reference intervals for folate and vitamin B12 were estimated according to the National Committee for Clinical Laboratory Standards Approved Guideline C28-A and International
Federation of Clinical Chemistry recommendations. The study included 155 women and 124 men between ages 18–40. The health
status was confirmed by history, physical examination and a questionnaire. The central 95% reference intervals of serum folate
and vitamin B12 for women, determined non-parametrically, were found to be 3.9–18.1 ng/ml and 101–666.7 pg/ml, respectively.
The reference values of serum folate and vitamin B12 for men were also found to be 2,5–17.6 ng/ml and 100–699.57 pg/ml, respectively.
We did not observe subclass differences between females and males.
Received: 15 April 2000 · Accepted: 15 April 2000 相似文献
2.
12-Epinapelline and its N-oxide have been isoated from the epigeal part ofAconitum baicalense Turcz. ex Rapaics (A. Czekanovskyi Steinb.). The structures of these compounds have been determined with the aid of two-dimensional1H and13C NMR spectroscopy, and IR and mass spectrometry.
Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii,
No. 6, pp. 888–892. November–December, 1993. 相似文献
3.
A. V. Tarantin V. A. Glushkov K. Yu. Suponitskii A. A. Kudryashov O. A. Maiorova A. G. Tolstikov 《Russian Journal of Organic Chemistry》2010,46(10):1479-1489
Glyoxylate and arylglyoxal imines based on 12-aminodehydroabietic acid undergo hetero-Diels—Alder (Povarov) reaction with
ethyl vinyl ether, cyclopentadiene, and indene to give, respectively, methyl (8aR,9R,12aS)-3-aroyl-5-isopropyl–9,12a-dimethyl–7,8,8a,9,10,11,12,12a-octahydronaphtho[1,2-f]quinoline-9-carboxylates, methyl (7R,10aS,10dR,13aS)-1-aroyl–3-isopropyl–7,10a-dimethyl–2,5,6,6a,7,8,9,10,10a,10d,13,13a-dodecahydro-1H-naphtho[1,2-f]cyclopenta[c]quinoline-7-carboxylates, and methyl (6aS,11bS,11eS,15R,15aR)-6-aroyl–4-isopropyl–11e,15-dimethyl–2,5,6,6a,7,11b,11e,12,13,14,15,15a-1H-dodecahydroindeno[2,1-c]-naphtho[1,2-f]quinoline-15-carboxylates. 相似文献
4.
Fan Sun Denis Laillé Thierry Gloriant 《Journal of Thermal Analysis and Calorimetry》2010,101(1):81-88
In this study, the thermal analysis of the ω nanophase transformation from a quenched metastable β Ti–12Mo alloy composition
(mass%) was investigated by electrical resistivity and dilatometry measurements. The activation energy was observed to be
121 ± 20 kJ mol−1 (from resistivity measurements) and 114 ± 12 kJ mol−1 (from dilatometry measurements) during the early stage of the transformation process. The kinetic of the ω nanophase transformation
was modelized by using the classical Johnson–Mehl–Avrami (JMA) theory and a modified Avrami (MA) analysis. An Avrami exponent
close to 1.5 was found at the early stage of the transformation suggesting a pure growth mechanism from pre-existing nucleation
sites. Nevertheless, it was observed a decrease of the Avrami exponent to 0.5 at higher transformed fraction demonstrating
a dimension loss in the growth mechanism due to the existence of the high misfit strain at the interface β/ω. 相似文献
5.
A. P. Filippov A. S. Kovalenko V. G. Il’in 《Theoretical and Experimental Chemistry》1998,34(3):165-171
Phosphomolybdic acid forms compounds with surfactant cations in acid aqueous media (pH 1.0–2.5) to give compounds A3[PMo12O40] or Etn3[PMo12O40]2·nEtnCl2 (n=0−3) with various nanoperiodicity depending on the surfactant and synthesis conditions.
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, Kiev 252039,
Ukraine. Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 34, No. 3, 184–190, May–June, 1998. 相似文献
6.
Bin Tu Qingqi Chen Fang Yan Jinshi Ma Karl Grubmayr Heinz Falk 《Monatshefte für Chemie / Chemical Monthly》2001,19(8):693-705
ω-Chloroalkyl biliverdins, prepared in three steps from 8-unsubstituted dipyrrinones in 70–80% overall yields, were reduced
by sodium borohydride to provide the corresponding ω-chloroalkyl bilirubins in high yields. Upon treatment of the ω-chloroalkyl
biliverdins with sodium hydroxide in ethanol, C12-N22 bridged biliverdins were obtained in high yields. 相似文献
7.
Z. Janout S. Pospíšil M. Vobecký 《Journal of Radioanalytical and Nuclear Chemistry》1980,56(1-2):71-81
A Doppler broadening is described of the 4438 keV spectral gamma-line observed by means of a Ge(Li) detector during the deexcitation
of nuclei of12C in an inelastic scattering12C(n, n′γ)12C using an241Am−Be source as well as during the reaction9Be(α, nγ)12C taking place in the Am−Be source. The FWHM of the spectral line is equal to (90±4) keV in the latter reaction and (64±8)
keV in the former process. Experimental values agree well with theoretical ones.
Presented at the Instrumental Activation Analysis Conference, IAA 79, June 4–8, 1979, Klučenice, Czechoslovakia. 相似文献
8.
Bin Tu Qingqi Chen Fang Yan Jinshi Ma Karl Grubmayr Heinz Falk 《Monatshefte für Chemie / Chemical Monthly》2001,132(6):693-705
Summary. ω-Chloroalkyl biliverdins, prepared in three steps from 8-unsubstituted dipyrrinones in 70–80% overall yields, were reduced
by sodium borohydride to provide the corresponding ω-chloroalkyl bilirubins in high yields. Upon treatment of the ω-chloroalkyl
biliverdins with sodium hydroxide in ethanol, C12-N22 bridged biliverdins were obtained in high yields.
Received December 13, 2000. Accepted January 15, 2001 相似文献
9.
Li Wang Shuguang Jian Peng Nan Jimei Liu Yang Zhong 《Chemistry of Natural Compounds》2005,41(5):491-493
The chemical constituents of leaf oils of Elephantopus scaber L. from 12 locations in Southern China, including three provinces and Hong Kong, were investigated using GC/MS. A total of
24 compounds were detected, of which 20 were identified by their mass spectra fragmentation patterns. The major compounds
include hexadecanoic acid (8.19–39.22%), octadecadienoic acid (trace - 29.22%), five alkane homologues, i.e., n-tetradecane
(1.19–5.26%), n-pentadecane (3.22–12.05%), n-hexadecane (2.38–16.26%), n-heptadecane (2.48–15.32%), and n-octadecane (1.39–9.59%),
as well as tetramethylhexadecenol (2.06–4.31%). Hierarchical cluster analysis classified the leaf oils into two groups. Two
main chemotypes of leaf oils in E. scaber were thus identified, one rich in hexadecanoic acid and octadecadienoic acid, and the other rich in the five alkane homologues.
__________
Published in Kimiya Prirodnikh Soedinenii No. 5, pp. 403–404, September–October, 2005. 相似文献
10.
I. V. Shmygol’ S. V. Snegir V. A. Pokrovskii 《Theoretical and Experimental Chemistry》2007,43(4):272-277
A comparative analysis of the laser desorption/ionization of vitamin B12 by matrix-assisted laser desorption/ionization (MALDI) and desorption/ionization on porous silicon (DIOS) was carried out.
The mass spectra obtained were interpreted and the pathways for ion formation and decomposition were established. The MALDI
fragmentation of the positive vitamin B12 ions is more extensive than the DIOS fragmentation. The most extensive fragmentation was found using the MALDI method for
negative vitamin B12 ions, which are lacking when using the DIOS method.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 4, pp. 251–256, July–August, 2007. 相似文献
11.
The temperature dependence of the ratios of the rate constants k(C5H10)/k(C6H12) and k(C6H12)/k(C6D12) for the reaction of the cycloalkanes C5H10, C6H12, and C6D12 with OH+ cations in the system (NH4)2S2O8 (0.1 mol/kg)-H2SO4 (94.4 mass %) in the 6–50 °C range has been studied. The activation energies found E(C6H12) − E(C5H10) = − 5.3 ± 0.3 and E(C6D12) − E(C6H12) = 7.9 ± 0.7 (kJ/mol) permits the comparison of OH+ to a group of reagents (NO+2, Pd2+, HSO+3) which interact with the C-H bond via an electrophilic substitution mechanism.
Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 44, No. 6, pp. 354–358, November–December, 2008. 相似文献
12.
A. A. Semioshkin P. V. Petrovskii D. Gabel B. Brellochs V. I. Bregadze 《Russian Chemical Bulletin》1998,47(5):950-955
The sodium salt of [B12H12]2− dianion reacts with carboxylic acid halides to give a mixture of B-acylated product [B12H11COR]2− and an unstable intermediate, the latter undergoing hydrolysis to form [B12H11OH]2−. The ratio of the products formed depends on the nature of the radical R. The reaction mechanism was studied by NMR spectroscopy.
A number of novel [B12H11COR]2− compounds were synthesized; their structures were confirmed by NMR and IR spectral data.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 980–985, May, 1998. 相似文献
13.
An efficient one-step synthesis of the diacetate of the tetracyclic triterpenoid onoceranediol (4) by radical cleavage of the readily available 12-hydroperoxy-8α,12-epoxy-11-bishomodrimane is described. Drim-9(11)-en-8α-yl
acetate (7) is formed in this reaction as a byproduct. Onoceranediol diacetate 4 is converted into onoceranediol on treatment with LiAlH4, and acetate 7 is transformed into drim-9(11)-en-8α-ol on saponification.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2571–2573, November, 2005. 相似文献
14.
Jie Shu 《Journal of Solid State Electrochemistry》2009,13(10):1535-1539
Electrochemical behavior and stability of spinel Li4Ti5O12 are investigated in a broad voltage window (0.0–5.0 V vs. Li/Li+). The voltage profile of the Li4Ti5O12 electrode shows a plateau region at 1.55 V and two sloped regions below 1.55 V when the electrode is cycled between 0.0 and
2.0 V. It is found that Li4Ti5O12 maintains high lithium storage characteristic with the increase of the current density. Moreover, Li4Ti5O12 shows excellent rate performance in 0.0–2.0 V and good cyclic performances in 0.0–4.0 and 1.0–5.0 V. Besides, the crystal
structure is kept when it is cycled between 0.0 and 5.0 V. 相似文献
15.
V. L. Lobachev Ya. V. Matvienko E. S. Rudakov 《Theoretical and Experimental Chemistry》2008,44(2):109-115
The c-C6H12/c-C6D12 kinetic isotope effect (KIE), the k6/k5 rate constant ratio (c-C6H12/c-C5H10), and the temperature dependence of these ratios in the gas-phase reactions of cycloalkanes with peroxynitrous acid and OH
radicals are identical. The same result was obtained for the reactions in aqueous solution. These data are in accord with
the conclusion that OH· radicals formed in the homolysis of the HO-ONO bond are the active species in the reactions of HOONO with hydrocarbons in
aqueous solution and in the gas phase.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 44, No. 2, pp. 105–110, March–April, 2008. 相似文献
16.
Franz Pertlik 《Monatshefte für Chemie / Chemical Monthly》2001,132(12):1509-1513
Summary. Single crystals of K2Ag12Te7 (a = 11.460(2), c = 4.660(1) ?; V = 530.01 ?3; space group: P63/m; Z = 1) were synthesized under hydrothermal conditions at 250°C in concentrated aqueous KOH solution from elementary silver
and tellurium. The crystal structure is characterized by trigonal prismatic KTe6 polyhedra, connected via two common faces to KTe3 rods parallel to [001]. These rods are combined by two crystallographically independent Ag atoms, each coordinated to four
Te and three Ag atoms (Ag–Te and Ag–Ag < 3.1 ?) to a framework of the formula (K2Ag12Te6)2 + and with channels parallel to the sixfold axis. These channels are statistically occupied by one further Te atom per unit
cell, distributed over two independent positions.
Received May 17, 2001. Accepted (revised) July 3, 2001 相似文献
17.
A method for preparative production of 3β,20S-dihydroxydammar-24-en-12-one 3,20-di-O-β-D-glucopyranoside (1), a glycoside from Panax japonicus, chikusetsusaponin-LT8 was developed. Chemical transformation of betulafolientriol, a component of Betula leaves extract, produced the 12-keto-20S-protopanaxadiol (3β,20S-dihydroxydammar-24-en-12-one) (2), exhaustive glycosylation of which by 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosylbromide (3) under Koenigs—Knorr reaction conditions with subsequent removal of protecting groups formed 3β,20S-dihydroxydammar-24-en-12-one
3,20-di-O-β-D-glucopyranoside (1). The principal glycosylation product was 3β,20S-dihydroxydammar-24-en-12-one 3-O-β-D-glucopyranoside if equimolar amounts of (2) and (3) were used.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 44–48, January–February, 2006. 相似文献
18.
The succinic acid 12α-deoxoartemisinyl ester 4′-O-demethyl-4-β-(4″-nitroanilino)-4-desoxypodophyllotoxin was synthesized for the first time.
Published in Khimiya Prirodnykh Soedinenii, No. 5, pp. 442–443, September–October, 2007. 相似文献
19.
A fluorimetric method for the determination of vitamin B12 has been developed. The fluorescence emission was measured at λex/λem275/305 nm in phosphate buffer solution (pH 7.0), and the experimental variables and possible interference were studied. The
linear calibration range was 1.000 ng/mL to 100.0 ng/mL with a correlation coefficient of 0.9994 and a detection limit of
0.1 ng/mL. The method is rapid, simple and highly sensitive. It was used to determine vitamin B12 in pharmaceutical preparations. The recovery was 96%–98% and the relative standard deviation was in the range of 1.8%–2.7%.
The results agreed with those obtained by spectrophotometry.
Received: 17 July 2000 / Revised: 4 September 2000 / Accepted: 7 September 2000 相似文献
20.
S. Yamaguchi 《Colloid and polymer science》1998,276(12):1151-1158
The change of three-phase behavior of a water/hexaethylene-glycol dodecyl ether (C12EO6)/propanol/heptane system was studied with increasing temperature (30.0–48.9 °C). A cone-like three-phase body consisting
of aqueous (W), surfactant (Dp), and oil (O) phases is formed in the composition tetrahedron at lower temperatures. The body is expanded with increasing
temperature, and touches the water–C12EO6–heptane triangle (the base) at 44.8 °C. At about 45.6 °C the loci of the Dp and O phases meet and cut off at a critical double end point and the three-phase body separates into two bodies: one has
a chiral shape and the other is unclosed. The unclosed body is transformed with the change of shape of the tie triangle on
the base as temperature increases and leaves from the base at 48.9 °C. A closed-loop miscibility gap between middle surfactant
(D′
p) and O phases or a cone-like three-phase body is formed inside the composition tetrahedron at higher temperatures. The roles
of C12EO6 and propanol are also discussed.
Received: 14 April 1998 Accepted: 15 July 1998 相似文献