共查询到20条相似文献,搜索用时 15 毫秒
1.
《高分子科学》2009,27(1)
Apart from long-known and applied nanostructures like carbon black for tyres or pigments for coatings nanotechnoiogy has created highly sophisticated structures used for nano/molecular electronics,diagnostics,drug delivery,UV-absorbers etc.Often the main question to be solved analytically is the local determination of tiny amounts of chemicals resulting in an ever increasing need for highly sensitive as well as locally resolved techniques.Applications of techniques like mass spectroscopy,transmission electron microscopy as well as ultracentrifugation to problems arising from nanotechnology in the chemical industry will be described. 相似文献
2.
Apart from long-known and applied nanostructures like carbon black for tyres or pigments for coatings nanotechnology has created highly sophisticated structures used for nano/molecular electronics,diagnostics,drug delivery, UV-absorbers etc.Often the main question to be solved analytically is the local determination of tiny amounts of chemicals resulting in an ever increasing need for highly sensitive as well as locally resolved techniques.Applications of techniques like mass spectroscopy,transmission el... 相似文献
3.
Nanozymes with intrinsic enzyme‐like properties have attracted significant interest owing to their capability to address the limitations of traditional enzymes such as fragility, high cost and difficult mass production. However, the currently reported nanozymes are generally less active than natural enzymes. In recent years, with the rapid development of nanoscience and nanotechnology, single‐atom nanozymes (SAzymes) with well‐defined electronic and geometric structures have shown a promise to serve as direct surrogates of traditional enzymes by mimicking the highly evolved catalytic center of natural enzymes. In this review, we will introduce the enzymatic characteristics and recent advances of SAzymes, and summarize their significant applications from in vitro detection to in vivo monitoring and therapy. 相似文献
4.
Michael Groß 《Chemie in Unserer Zeit》2013,47(6):368-374
Diatoms are a highly unusual group of organisms. They acquired their photosynthesis apparatus later than the plants, but had such extraordinary success in the last 200 million years that they made large contributions to the Earth's geochemical cycles and climate regulation. Current ideas to sequester carbon dioxide by fertilising ocean water with iron also targets diatoms, which are the fastest to respond to nutrient availability. Their intricately structured, lace‐like silica shells are of interest to nanotechnology. However, as they are far from the beaten tracks of biochemical research and not represented by any of the classic model organisms, their morphogenesis is still poorly understood and cannot be replicated in vitro. 相似文献
5.
Dr. Rajesh Seenivasan Charles Kolodziej Prof. Chandran Karunakaran Prof. Clemens Burda 《Chemical record (New York, N.Y.)》2017,17(9):886-901
Over the past several decades, nanotechnology has contributed to the progress of biomedicine, biomarker discovery, and the development of highly sensitive electroanalytical / electrochemical biosensors for in vitro and in vivo monitoring, and quantification of oxidative and nitrosative stress markers like reactive oxygen species (ROS) and reactive nitrogen species (RNS). A major source of ROS and RNS is oxidative stress in cells, which can cause many human diseases, including cancer. Therefore, the detection of local concentrations of ROS (e. g. superoxide anion radical; O2•−) and RNS (e. g. nitric oxide radical; NO• and its metabolites) released from biological systems is increasingly important and needs a sophisticated detection strategy to monitor ROS and RNS in vitro and in vivo. In this review, we discuss the nanomaterials‐based ROS and RNS biosensors utilizing electrochemical techniques with emphasis on their biomedical applications. 相似文献
6.
In recent decades, nanotechnology has been empowered as a new and developing interdisciplinary region of science and innovation that coordinates material science and biology. Nanoscience and nanotechnology open up new streets of examination that are helpful in synthesizing novel nanomaterials with remarkable applications. Among different metal nanomaterials, silver nanoparticles (AgNPs) attracted the attention of researchers due to their versatile antibacterial characteristics and biological properties. Biogenically synthesizing AgNPs from plants and microorganisms seems to be a highly promising alternative for developing a technology that is both environmentally benign and fast. Plants and microorganisms' ability to synthesize AgNPs has mostly remained untapped, and the lack of investigation is due to the vast variety of plants and microorganisms. This review aims to describe the current progress in various synthetic techniques for AgNPs and their potential for antibacterial applications. It discusses biogenic synthetic approaches, the role of various metabolites in the growth processes of AgNPs with antibacterial implications, bactericidal mechanisms, and the influence of operational parameters on AgNPs synthesis. Furthermore, the present status, critical challenges, and future outlook of AgNPs will be explored, which will definitely affect their present and future scenarios. We believe that by focusing readers' attention on nature-inspired, biogenically synthesized AgNPs and their bactericidal applications, this review will enable them to formulate a new perspective. 相似文献
7.
Yun Zheng Lihua Lin Xiangju Ye Fangsong Guo Prof. Xinchen Wang 《Angewandte Chemie (International ed. in English)》2014,53(44):11926-11930
Graphitic carbon nitride can be imprinted with a twisted hexagonal rod‐like morphology by a nanocasting technique using chiral silicon dioxides as templates. The helical nanoarchitectures promote charge separation and mass transfer of carbon nitride semiconductors, enabling it to act as a more efficient photocatalyst for water splitting and CO2 reduction than the pristine carbon nitride polymer. This is to our knowledge a unique example of chiral graphitic carbon nitride that features both left‐ and right‐handed helical nanostructures and exhibits unique optical activity to circularly polarized light at the semiconductor absorption edge as well as photoredox activity for solar‐to‐chemical conversion. Such helical nanostructured polymeric semiconductors are envisaged to hold great promise for a range of applications that rely on such semiconductor properties as well as chirality for photocatalysis, asymmetric catalysis, chiral recognition, nanotechnology, and chemical sensing. 相似文献
8.
Protein fibrils are a crucial subject of study in various research fields and disciplines. Amyloid fibrils are highly ordered fibrillar structures assembled from either peptides or unfolded proteins, which have a great importance in biology, medicine and recently have started to find an important role in many nanotechnology applications. Understanding the mechanisms of fibrillation, the structural features, and the physical and mechanical properties of these fibrils is an essential step to both unraveling their biological role and also their successful applications in nanotechnology and material science. Atomic force microscopy (AFM) is one of the most widely used single-molecule techniques to study the properties of amyloid fibrils. In this review we will discuss how the application of AFM during last few years has allowed moving considerably forward in the research of amyloid fibrils. We will review how AFM has rapidly evolved from a purely microscopic technique, providing important information about fibril structure and fibrillation processes, to a tool capable to probe also intrinsic properties of amyloid fibrils such as their strength and Young's moduli. 相似文献
9.
Dr. Alessandra Zanut Dr. Francesco Palomba Matilde Rossi Scota Sara Rebeccani Prof. Massimo Marcaccio Dr. Damiano Genovese Prof. Enrico Rampazzo Prof. Giovanni Valenti Prof. Francesco Paolucci Prof. Luca Prodi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(49):22042-22047
The combination of highly sensitive techniques such as electrochemiluminescence (ECL) with nanotechnology sparked new analytical applications, in particular for immunoassay-based detection systems. In this context, nanomaterials, particularly dye-doped silica nanoparticles (DDSNPs) are of high interest, since they can offer several advantages in terms of sensitivity and performance. In this work we synthesized two sets of monodispersed and biotinylated [Ru(bpy)3]2+-doped silica nanoparticles, named bio-Triton@RuNP and bio-Igepal@RuNP, obtained following the reverse microemulsion method using two different types of nonionic surfactants. Controlling the synthetic procedures, we were able to obtain nanoparticles (NPs) offering highly intense signal, using tri-n-propylamine (TPrA) as coreactant, with bio-Triton@RuNps being more efficient than bio-Igepal@RuNP. 相似文献
10.
Editor-in-Chief 《Journal of Thermal Analysis and Calorimetry》2006,86(1):165-166
The
Guest Editors of this Special Chapter and the Conference Organisers are looking
forward to meeting you at the
31st
International Conference on Vacuum Microbalance Techniques
IVMTC31,
Izmir Institute of Technology Izmir, Turkey 12–14 September, 2007
SCOPE OF THE CONFERENCE
The subject matter of the Conference
covers all aspects of mass and force determination, in particular under vacuum
or controlled atmosphere. It includes theoretical and experimental work like
thermogravimetry, sorptometry and measurement of chemisorption, physisorption,
surface reactions, magnetic properties, surface tension, etc. Reports on progress
in instrumentation should deal with microbalance and related techniques including
supplementary equipment and corresponding coupling techniques.
SCIENTIFIC
PROGRAMME
The scientific programme will include plenary lectures
and contributed lectures (20 min) as well as poster presentations which deal
with.
• History and advances in microweighing • New
techniques to measure mass and weight in vacuum and controlled environments
• Gravimetric measuement of highly porous materials; catalysts, polymers,
advanced materials, nanotechnology • Adsorption rates and equilibria
• Industrial applications of microbalance and microforce sensors including
oscillators and load cells • The coupling techniques: to DSC, TMA, DTA,
DTG, MS, IR, etc. • Vacuum apparatus, microelectronics and related equipment.
EXHIBITION
An exhibition of balances, thermoanalytical apparatus
and complementary techniques will take place during this conference.
IMPORTANT DATES
Pre-registration: November 10, 2006; Notifications
acceptance: December 13, 2006; Deadline for registration: June 16, 2007; Deadline
for paper submission for publication: September 14, 2007
THE VENUE
IZMIR
Izmir ‘The pearl of the Aegean’
is the third most populous city of Turkey and the country’s largest
port after Istanbul. It is located on the Aegean Sea near the Gulf of Izmir.
The former Smyrna is one of the oldest cities of the Mediterranean basin,
established in the 3rd millennium B.C. Impressive
civil work of Greek architecture, synagogues, early Christian and Islamic
buildings are preserved in the town and in the near surrounding. Modern Izmir
also incorporates world-famous ancient cities like Ephesus, Pergamon and Sardis.
IZMIR INSTITUTE OF TECHNOLOGY
was established in 1992 as
the third University in Izmir. There are 115 teaching staff, 403 research
assistants, and about 2000 students in the University. The University has
Faculties of Science, Engineering and Architecture. The 31st International
Vacuum Microbalance Techniques Conference will be held during September 2007
in the Department of Chemical Engineering. The Department has three professors,
three associate professors, and 9 assistant professors. The main research
areas of the department are interdisciplinary such as materials science, environmental
science, biotechnology and energy. Facilities of the Department include FTIR
and UV spectrometers, volumetric and gravimetric gas adsorption systems, magnetic
suspension balance, thermal analyzers, rheometers, polymer processing equipment. 相似文献
11.
《Arabian Journal of Chemistry》2022,15(4):103715
Oral administration represents the most suitable mean among different means of administering drugs because it ensures high compliance by patients. Nevertheless, the lacking aqueoussolubility, as well as, inadequate metabolic/enzymatic stability of medicines are leading obstacles to successful drug administration by oral route. Among different systems, drug administration systems based on nanotechnology have the potential to surmount the problems associated with oral drug administration. Drug delivery systems based on nanotechnology offer an alternative to deliver antihypertensive agents with enhanced therapeutic effect and bioavailability. In this study, meta-analysis was utilized in combining data relating to oral bioavailability (area under plasma concentration time curve, AUC) enhancement through nanotechnology from multiple studies. Twenty-one studies of the total 37articles included in this study were from the kingdom of Saudi Arabia and were included in a specific meta-analysis. From the analysis conducted, the overall enhancement power of the nanotechnology based formulations on drug bioavailability was found to be 7.94% (95 %CI [5.809, 10.064]). Haven utilized comprehensive and recent data of the confirmed the enhancement of bioavailability using nanotechnology which for this study was grouped into five: solid lipid nanoparticles; polymer based nanoparticles; SNEEDS/Nanoemulsion; liposomes/proliposomes and; nanostructured lipid carriers. Furthermore, the meta-analysis, provided evidence of insignificant differences between APG Bio-SNEDDS and its free drug suspension (Apeginin, APG), though with relative bioavailabiilty of 1.91. Notwithstanding most of the treatment showed a substantial relative bioavailability. 相似文献
12.
Thirty years of capillary electrophoresis in food analysis laboratories: potential applications 总被引:1,自引:0,他引:1
CE has generated considerable interest in the research community since instruments were introduced by different trading companies in the 1990s. Nowadays, CE is popular due to its simplicity, speed, highly efficient separations and minimal solvent and reagent consumption; it can also be included as a useful technique in the nanotechnology field and it covers a wide range of specific applications in different fields (chemical, pharmaceutical, genetic, clinical, food and environmental). CE has been very well evaluated in research laboratories for several years, and different new approaches to improve sensitivity (one of the main drawbacks of CE) and robustness have been proposed. However, this technique is still not well accepted in routine laboratories for food analysis. Researching in data bases, it is easy to find several electrophoretic methods to determine different groups of analytes and sometimes they are compared in terms of sensitivity, selectivity, precision and applicability with other separation techniques. Although these papers frequently prove the potential of this methodology in spiked samples, it is not common to find a discussion of the well-known complexity of the matrices to extract analytes from the sample and/or to study the interferences in the target analytes. Summarizing, the majority of CE scientific papers focus primarily on the effects upon the separation of the analytes while ignoring their behavior if these analytes are presented in real samples. 相似文献
13.
Irfan Ijaz Ezaz Gilani Ammara Nazir Aysha Bukhari 《Green Chemistry Letters and Reviews》2020,13(3):223-245
ABSTRACT Nanotechnology is an emerging field of science. The base of nanotechnology is nanoparticles. The size of nanoparticles ranges from 1 to 100?nm. The nanoparticles are classified into different classes such as inorganic nanoparticles, organic nanoparticles, ceramic nanoparticles and carbon base nanoparticles. The inorganic nanoparticles are further classified into metal nanoparticles and metal oxide nanoparticles.similarly carbon base nanoparticles classified into Fullerene, Carbon nanotubes, Graphene, Carbon nanofiber and carbon black Nanoparticles are also classified on the basis of dimension such as one dimension nanoparticles, two-dimension nanoparticles and three-dimension nanoparticles. The nanoparticles are synthesized by using two approaches like top-down approach and bottom-up approach. In this review chemical, physical and green synthesis of nanoparticles is reported. The synthesized nanoparticles are synthesized using different qualitative and quantitative techniques. The Qualitative techniques include Fourier Transform Infrared Spectroscopy (FT-IR), UV-Vis spectrophotometry, Scanning electron microscope (SEM), X.ray diffraction (XRD) and Atomic Force Microscopy (AFM). The Quantitative techniques include Transmission Electron Microscopy (TEM), Annular Dark-Field Imaging (HAADF) and Intracranial pressure (ICP). The nanoparticles have different application which is reported in this review. 相似文献
14.
Bode P 《Analytical and bioanalytical chemistry》2004,379(2):181-187
The choices of universities and national research institutions in supporting scientific research are increasingly justified on the basis of, amongst others, the relevance that has to be reflected by external, preferably sustainable funding of the research programs. Many traditional fields of application such as environmental sciences do not offer a promising outlook in this respect. As a consequence, university research reactors face closure because of reallocations of university funds to more contemporary sciences such as molecular biology and nanotechnology. Therefore, laboratories operating nuclear analytical techniques (NAA, (TR)XRF, and PIXE) need to use their creativity in finding ways for participation in, for example, nanotechnology, cancer research, or genomics. This requires an open mind in terms of the opportunities, strengths, and weaknesses of the techniques, and a departure of technique-oriented research towards problem-oriented research in which other nuclear techniques can be used. The unique features of radiotracers, nuclear imaging, and nuclear beam techniques are discussed in view of the new areas mentioned above. Some examples of opportunities for nuclear analytical techniques in the above-mentioned fields are given. 相似文献
15.
FAN Chunhai 《高等学校化学研究》2020,36(2):0-0
To celebrate the 35th anniversary of Chemical Research in Chinese Universities,we herein organize this themed issue on DNA nanotechnology.Active researchers in the field of DNA nanotechnology are invited to contribute to this issue. 相似文献
16.
Udo Feldkamp 《Journal of computational chemistry》2010,31(3):660-663
The design of nucleic acid sequences for a highly specific and efficient hybridization is a crucial step in DNA computing and DNA‐based nanotechnology applications. The CANADA package contains software tools for designing DNA sequences that meet these and other requirements, as well as for analyzing and handling sequences. CANADA is freely available, including a detailed manual and example input files, at http://ls11‐www.cs.uni‐dortmund.de/molcomp/downloads . © 2009 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
17.
Soeun Gim Giulio Fittolani Dr. Yoshiharu Nishiyama Prof. Peter H. Seeberger Dr. Yu Ogawa Dr. Martina Delbianco 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(50):22766-22772
Hierarchical carbohydrate architectures serve multiple roles in nature. Hardly any correlations between the carbohydrate chemical structures and the material properties are available due to the lack of standards and suitable analytic techniques. Therefore, designer carbohydrate materials remain highly unexplored, as compared to peptides and nucleic acids. A synthetic D -glucose disaccharide, DD , was chosen as a model to explore carbohydrate materials. Microcrystal electron diffraction (MicroED), optimized for oligosaccharides, revealed that DD assembled into highly crystalline left-handed helical fibers. The supramolecular architecture was correlated to the local crystal organization, allowing for the design of the enantiomeric right-handed fibers, based on the L -glucose disaccharide, LL , or flat lamellae, based on the racemic mixture. Tunable morphologies and mechanical properties suggest the potential of carbohydrate materials for nanotechnology applications. 相似文献
18.
Design of the nanostructures based on membrane proteins (the key functional elements of biomembranes) and colloid nanoparticles is a fascinating field at the interface of biochemistry and colloids, nanotechnology and biomedicine. The review discusses the main achievements in the field of ultrathin films prepared from bacterial reaction center proteins and light-harvesting complexes, as well as these complexes tagged with quantum dots. The principles of preparation of these thin films and their structure and properties at different interfaces are described; as well as their characteristics estimated using a combination of the modern interfacial techniques (absorption and fluorescence spectroscopy, atomic force and Brewster angle microscopy, etc.) are discussed. Further approaches to develop the nanostructures based on the membrane proteins and quantum dots are suggested. These supramolecular nanostructures are promising prototypes of the materials for photovoltaic, optoelectronic and biosensing applications. 相似文献
19.
《Spectrochimica Acta Part B: Atomic Spectroscopy》2005,60(1):13-26
This paper reviews a range of instrumental microanalytical techniques for their potential in following the development of nanotechnology. Needs for development in secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), Auger emission spectrometry (AES) laser mass spectrometry, X-ray photon spectroscopy are discussed as well as synchrotron-based methods for analysis. Objectives for development in all these areas for the coming 5 years are defined. Developments of instrumentation in three European synchrotron installations are given as examples of ongoing development in this field. 相似文献
20.
Scattering techniques represent non-invasive experimental approaches and powerful tools for the investigation of structure and conformation of biomaterial systems in a wide range of distances, ranging from the nanometric to micrometric scale. More specifically, small-angle X-rays and neutron scattering and light scattering techniques represent well-established experimental techniques for the investigation of the structural properties of biomaterials and, through the use of suitable models, they allow to study and mimic various biological systems under physiologically relevant conditions. They provide the ensemble averaged (and then statistically relevant) information under in situ and operando conditions, and represent useful tools complementary to the various traditional imaging techniques that, on the contrary, reveal more local structural information. Together with the classical structure characterization approaches, we introduce the basic concepts that make it possible to examine inter-particles interactions, and to study the growth processes and conformational changes in nanostructures, which have become increasingly relevant for an accurate understanding and prediction of various mechanisms in the fields of biotechnology and nanotechnology. The upgrade of the various scattering techniques, such as the contrast variation or time resolved experiments, offers unique opportunities to study the nano- and mesoscopic structure and their evolution with time in a way not accessible by other techniques. For this reason, highly performant instruments are installed at most of the facility research centers worldwide. These new insights allow to largely ameliorate the control of (chemico-physical and biologic) processes of complex (bio-)materials at the molecular length scales, and open a full potential for the development and engineering of a variety of nano-scale biomaterials for advanced applications. 相似文献