发射光谱法测定高纯银中微量金,铂,钯,铑,铱,锑,铅,铋,铁,铜,…

本文研究了贵金属标准溶液除氯离子的有关问题，解决了高纯硝酸银中贵金属等杂质元素的样配制，以硝酸银直接压样于普通电极中直流电弧激发，可测定９９．０－９９．９９％的高纯银，该方法简便、快速、准确。     

锰结核中硅,铝,铁,镁,磷,钾,锰,钛的XRFA

本文叙述了用XRF分析锰结核中Si、Al、Fe、Mg、P、K、Mn和Ti的方法。按照通常锰结核的主次成分制备6个人工合成标准,根据Sherman方程计算了已知成分(二元系统)的相对强度。用L-T方求得了互致元素校正的理论α系数(基本的、混合的、修正的),用DATAFLEX151B计算机以BASIC语言汇了“PRA,APU”计算机程序。然后进行非线性回归分析了锰结核样品得到了满意的结果。     

发射光谱法测定二氧化锆中钙,镁,铝,铁,钛,铪,硅

本文介绍了用碳酸钡作缓冲剂测定二氧化锆中Ｍｇ，Ｆｅ，Ａｌ，Ｃａ，Ｔｉ，Ｈｆ，Ｓｉ杂质元素的发射光谱方法。该方法直接压样于普通电极中，简便，快速。取得了满意的结果。     

ICP-AES同时测定铝合金中Fe,Si,Cu,Mg,Mn,Ni,Zn,Ti,Cr,Sr等杂质元素

本文通过基体干扰和操作条件的试验研究，分别用基体匹配法和干扰系数法校正基体干扰和待测元素间的干扰，建立了以氢氧化钠溶样，ICP－AES同时测定铝合金中铁、锰、铜、锌、镁、钛、硅、镍、铬、锶等杂质元素的方法。方法快速、简便、可靠，回收率93％－102％，适用于进出口铝合金的快速检验。     

FAAS法测定营养素中K,Na,Ca,Mg,Mn,Cu,Zn,Fe等微量元素

本文应用火焰原子吸收法测定了营养素（含美国加营素Ｅｎｓｕｒｅ、中国“茶汤”、豆奶晶和速溶奶粉）中钾、钠等８种微量元素的含量、对于产品质量控制和医用保健食品开发有着重要意义。方法简便快速、灵敏准确，８种微量元素的平均回收率为９８．３８～１０２．６９％；变异系数为１．３８～４．１６％。     

ICP—AES法直接测定锡锭中的As,A1,Bi,Cd,Cu,Fe,Pb,Se,Sb,Zn

以电荷耦合器件为检测器的全谱直读等离子体光谱仪直接测定锡锭中Ａｓ、Ａ１、Ｂｉ、Ｃｄ、Ｃｕ、Ｆｅｄ、Ｐｂ、Ｓｅ、Ｓｂ、Ｚｎ十种杂质元素的含量。该方法简便、快速且具有比化学法更低的检出限,加标回收试验结果不明,回收率为９２％－１０５％,ＲＳＤ均小于１．５％。     

光电直读光谱法测定稀土铝合金中La,Ce,Pr,Nd,Sm ,Si,Fe,Cu

本文报道了稀土铝合金中La,Ce,Pr,Nd,Sm,Si,Fe,Cu的光电直读光谱测定，对光源的激发方式及最佳工作条件进行了选择，应用KH－5高能预火花光源，采用单向全功率放电，先冲洗3秒，然后预燃5秒，曝光10秒。各元素谱线间无干扰，。使用固体试样，样品处理简单。经试验验证该法简便快速，精密度准确度高，含量在0．001％－0．002％之间RSD＜6％，0．02％－0．3％之间RSD＜3％，标准样品的测定值与准确值吻合较好，结果令人满意。     

单道扫描式ICP—AES法测定婴儿乳粉,代乳粉中K,Na,Ca,Mg,P,Fe,Zn,Cu,Mn和Sr

本文采用HNO_3-HClO_4湿法消解样品,用乳化剂OP解决雾化器堵塞问题,利用单道扫描式ICP-AES仪测定婴儿乳粉、代乳粉中十种元素(K、Na、Ca、Mg、F、Fe、Zn、Cu、Mn和Sr)。方法简便快速,回收率在90-105%,相对标准偏差均小于10%,适用于婴儿乳粉、代乳粉中上述元素的测定。     

Influence of the tangential velocity on the compressible Kelvin−Helmholtz instability with nonequilibrium effects

Kelvin−Helmholtz (KH) instability is a fundamental fluid instability that widely exists in nature and engineering. To better understand the dynamic process of the KH instability, the influence of the tangential velocity on the compressible KH instability is investigated by using the discrete Boltzmann method based on the nonequilibrium statistical physics. Both hydrodynamic and thermodynamic nonequilibrium (TNE) effects are probed and analyzed. It is found that, on the whole, the global density gradients, the TNE strength and area firstly increase and decrease afterwards. Both the global density gradient and heat flux intensity in the vertical direction are almost constant in the initial stage before a vortex forms. Moreover, with the increase of the tangential velocity, the KH instability evolves faster, hence the global density gradients, the TNE strength and area increase in the initial stage and achieve their peak earlier, and their maxima are higher for a larger tangential velocity. Physically, there are several competitive mechanisms in the evolution of the KH instability. (i) The physical gradients increase and the TNE effects are strengthened as the interface is elongated. The local physical gradients decrease and the local TNE intensity is weakened on account of the dissipation and/or diffusion. (ii) The global heat flux intensity is promoted when the physical gradients increase. As the contact area expands, the heat exchange is enhanced and the global heat flux intensity increases. (iii) The global TNE intensity reduces with the decreasing of physical gradients and increase with the increasing of TNE area. (iv) The nonequilibrium area increases as the fluid interface is elongated and is widened because of the dissipation and/or diffusion.     

Discrete ellipsoidal statistical BGK model and Burnett equations

A new discrete Boltzmann model, the discrete ellipsoidal statistical Bhatnagar–Gross–Krook (ESBGK) model, is proposed to simulate nonequilibrium compressible flows. Compared with the original discrete BGK model, the discrete ES-BGK has a flexible Prandtl number. For the discrete ES-BGK model in the Burnett level, two kinds of discrete velocity model are introduced and the relations between nonequilibrium quantities and the viscous stress and heat flux in the Burnett level are established. The model is verified via four benchmark tests. In addition, a new idea is introduced to recover the actual distribution function through the macroscopic quantities and their space derivatives. The recovery scheme works not only for discrete Boltzmann simulation but also for hydrodynamic ones, for example, those based on the Navier–Stokes or the Burnett equations.     

Effect of melting heat transfer and thermal radiation on Casson fluid flow in porous medium over moving surface with magnetohydrodynamics

In this study, the effects of variable fluid properties on heat transfer in MHD Casson fluid melts over a moving surface in a porous medium in the presence of the radiation are examined. The relevant similarity transformations are used to reduce the governing equations into a system of highly nonlinear ordinary differential equations and those are then solved numerically using the Runge–Kutta–Fehlbergmethod. The effects of different controlling parameters, namely, the Casson parameter,melting and radiation parameters, Prandtl number,magnetic field, porosity, viscosity and the thermal conductivity parameters on flow and heat transfer are investigated. The numerical results for the dimensionless velocity and temperature as well as friction factor and reducedNusselt number are presented graphically and discussed. It is found that the rate of heat transfer increases as the Casson parameter increases.     

Variable Fluid Property Effect on Heat Transfer and Frictional Flow Characteristics of Water Flowing through Microchannel

The effects of temperature-dependent viscosity and thermal conductivity on heat transfer and frictional flow characteristics of water flowing through a microchannel are numerically investigated in this work. The hydrodynamically and thermally developing flow with no-slip, notemperature jump, and constant wall heat flux boundary condition is numerically studied using 2D continuum-based conservation equations. A significant deviation in Nusselt number from conventional theory is observed due to flattening of axial velocity profile due to temperaturedependent viscosity variation. The Nusselt number shows a significant deviation from conventional theory due to flattening of the radial temperature profile due to temperature-dependent thermal conductivity variation. It is noted that the deviation in Nusselt number from conventional theory is maximum for combined temperature-dependent viscosity and thermal conductivity variations. The effects of temperature-dependent viscosity and thermal conductivity on the Fanning friction factor are also investigated. Additionally, the effects of variable fluid properties on Poiseuille number, Prandtl number, and Peclet number are also investigated.     

Numerical study of magneto-convective heat and mass transfer from inclined surface with Soret diffusion and heat generation effects: A model for ocean magnetic energy generator fluid dynamics

A mathematical model is developed for steady state magnetohydrodynamic (MHD) heat and mass transfer flow along an inclined surface in an ocean MHD energy generator device with heat generation and thermo-diffusive (Soret) effects. The governing equations are transformed into nonlinear ordinary differential equations with appropriate similarity variables. The emerging two-point boundary value problem is shown to depend on six dimensionless thermophysical parameters - magnetic parameter, Grashof number, Prandtl number, modified Prandtl number, heat source parameter and Soret number in addition to plate inclination. Numerical solutions are obtained for the nonlinear coupled ordinary differential equations for momentum, energy and salinity (species) conservation, numerically, using the Nachtsheim–Swigert shooting iteration technique in conjunction with the Runge–Kutta sixth order iteration scheme. Validation is achieved with Nakamura's implicit finite difference method. Further verification is obtained via the semi-numerical Homotopy analysis method (HAM). With an increase in magnetic parameter, skin friction is depressed whereas it generally increases with heat source parameter. Salinity magnitudes are significantly reduced with increasing heat source parameter. Temperature gradient is decreased with Prandtl number and salinity gradient (mass transfer rate) is also reduced with modified Prandtl number. Furthermore, the flow is decelerated with increasing plate inclinations and temperature also depressed with increasing thermal Grashof number.     

Hydrodynamic and Thermodynamic Nonequilibrium Effects around Shock Waves: Based on a Discrete Boltzmann Method

A shock wave that is characterized by sharp physical gradients always draws the medium out of equilibrium. In this work, both hydrodynamic and thermodynamic nonequilibrium effects around the shock wave are investigated using a discrete Boltzmann model. Via Chapman–Enskog analysis, the local equilibrium and nonequilibrium velocity distribution functions in one-, two-, and three-dimensional velocity space are recovered across the shock wave. Besides, the absolute and relative deviation degrees are defined in order to describe the departure of the fluid system from the equilibrium state. The local and global nonequilibrium effects, nonorganized energy, and nonorganized energy flux are also investigated. Moreover, the impacts of the relaxation frequency, Mach number, thermal conductivity, viscosity, and the specific heat ratio on the nonequilibrium behaviours around shock waves are studied. This work is helpful for a deeper understanding of the fine structures of shock wave and nonequilibrium statistical mechanics.     

Variable fluid properties and variable heat flux effects on the flow and heat transfer in a non-Newtonian Maxwell fluid over an unsteady stretching sheet with slip velocity

The effects of variable fluid properties and variable heat flux on the flow and heat transfer of a non-Newtonian Maxwell fluid over an unsteady stretching sheet in the presence of slip velocity have been studied. The governing differential equations are transformed into a set of coupled non-linear ordinary differential equations and then solved with a numerical technique using appropriate boundary conditions for various physical parameters. The numerical solution for the governing non-linear boundary value problem is based on applying the fourth-order Runge-Kutta method coupled with the shooting technique over the entire range of physical parameters. The effects of various parameters like the viscosity parameter, thermal conductivity parameter, unsteadiness parameter, slip velocity parameter, the Deborah number, and the Prandtl number on the flow and temperature profiles as well as on the local skin-friction coefficient and the local Nusselt number are presented and discussed. Comparison of numerical results is made with the earlier published results under limiting cases.     

低温下粗糙表面接触间隙气体热导的研究

对低温非真空环境下粗糙接触界面间隙中介质气体的传热进行了理论分析．依据克努森数的大小,建立了不同传热区域的间隙气体热导理论模型．并对影响接触界面间隙热导的克努森数、普朗特数、热导率、适应系数、压力等参数进行了分析,为实际情况下接触界面的传热提供了理论基础．而且通过实验证明了在界面接触压力较小的情况下,即使对于硬度较小导热性能好的接触固体,间隙气体的导热量仍大于通过实际接触点的导热量．     

Effect of heat generation on transient flow of micropolar fluid in a porous vertical channel

The present work is performed to study the effect of heat generation on fully developed flow and heat transfer of micropolar fluid between two parallel vertical plates. The rigid plates are assumed to exchange heat with an external fluid by convection. The governing equations are solved by using Crank–Nicolson implicit finite difference method. The effects of governing parameters such as transient, heat generation, micropolar parameter, Prandtl number, Biot number, and Reynolds number on the velocity and temperature profiles are discussed. It is found that the presence of heat generation enhances the velocity and temperature of the micropolar fluid at the middle of the channel.     

Nonequilibrium and morphological characterizations of Kelvin–Helmholtz instability in compressible flows

We investigate the effects of viscosity and heat conduction on the onset and growth of Kelvin–Helmholtz instability (KHI) via an efficient discrete Boltzmann model. Technically, two effective approaches are presented to quantitatively analyze and understand the configurations and kinetic processes. One is to determine the thickness of mixing layers through tracking the distributions and evolutions of the thermodynamic nonequilibrium (TNE) measures; the other is to evaluate the growth rate of KHI from the slopes of morphological functionals. Physically, it is found that the time histories of width of mixing layer, TNE intensity, and boundary length show high correlation and attain their maxima simultaneously. The viscosity effects are twofold, stabilize the KHI, and enhance both the local and global TNE intensities. Contrary to the monotonically inhibiting effects of viscosity, the heat conduction effects firstly refrain then enhance the evolution afterwards. The physical reasons are analyzed and presented.