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含间位取代苯基聚醚酮酮的结晶与晶体结构研究 总被引:1,自引:0,他引:1
通过差示扫描法(DSC)及广角X 射线衍射(WAXD)技术研究了含间位取代苯基聚醚酮酮(PEKmK)的结晶行为与晶体结构.X 射线结果表明,从熔融态及玻璃态结晶时,PEKmK只有一种晶型,其晶胞参数为:a=07672nm,b=06149nm,c=1599nm.DSC结果表明,PEKmK热分析曲线都出现了熔融双峰,低熔融峰(DOWn)热焓占总热焓4~7%,它源于初始结晶形成的同一晶型不同厚度片晶.低熔融峰在250℃以上结晶转化成高熔融峰(I),PEKmK平衡熔点为295℃ 相似文献
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本文报道酸性媒染紫(SVRS)一示波计时电位法测定天然水中不同形态铝。对24个实际水样分别在酸性pH5.2测定了无机单核铝Ali和碱性pH8.8底液中测定总单核铝Ala,有机单核铝Al0-Ala-Alio同时还应用该法测定了酸化水样中总铝AlT,酸溶态铝AlT=AlT-Ala,从而实现了水样中五种形态铝的电化学测定,测定值与Driscoll方法进行了比较对照,结果基本一致。本法特点为:简便快捷,灵敏准确,可以直接测定与铝毒性密切相关的无机单核铝Ali,无需分离步骤,水样用量小,适用于大批量天然水样中Al形态的快速分析。 相似文献
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工业镀层及涂层厚度分析—同位素X射线荧光光谱法 总被引:3,自引:0,他引:3
采用自行研制的同位素X射线荧光分析仪,测定工业镀层和汽车涂层厚度,分析精度(RSD)分别达20%和36%,该法具有快速、简便、无损等优点。 相似文献
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用核磁共振技术,、紫外吸收光谱和硅钼酸反应等方面研究了反应体系中硅酸根离子和铝酸根离子的聚合态,发现反应产物的形成与硅酸根的聚合态有关,单态铝酸根离子民高聚硅酸根离子(聚合度>40)反应生成凝胶;单态铝酸离子与单态或二聚态硅酸根离子反应生成沉淀。本文还研究了相同条件下的水热晶人,在沉淀区、混合区、凝胶区和溶胶区分别晶化得到沸石A、X、Y和P。 相似文献
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砷化镓半导体表面自然氧化层的X射线光电子能谱分析 总被引:1,自引:0,他引:1
用X射线光电子能谱(XPS),测量了Ga3d和As3d光电子峰的结合能值,指认了砷化镓(GaAs)晶片表面的氧化物组成,计算了表面氧化层的厚度,定量分析了表面的化学组成;比较了几种不同的砷化镓晶片表面的差异。结果表明:砷化镓表面的自然氧化层主要由Ga2O3、As2O5、As2O3和单质As组成,表面镓砷比明显偏离理想的化学计量比,而且,氧化层的厚度随镓砷比的增大而增加;溶液处理后,砷化镓表面得到了改善。讨论了可能的机理。 相似文献
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模板法制备高度有序的聚苯胺纳米纤维阵列 总被引:19,自引:0,他引:19
近年来,利用化学或物理方法制备多种材料的纳米有序阵列复合结构已成为学术界的研究热点.用具有纳米孔洞的模板(多孔阳极氧化铝、多孔硅以及聚碳酸脂膜)制备的金属、半导体、碳纳米管等材料的纳米有序阵列复合结构已在润滑、微电极、单电子器件、传感器、垂直磁记录、场致电 相似文献
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The interface reactions between transition metal oxide substrates and ultra thin metal layers of different thickness (<15 nm)
have been investigated by using x-ray photoelectron spectroscopy (XPS). To a different extent oxidation of deposited metal
and reduction of the oxidic substrate is visible for complementary layer systems. For the interface nickel oxide/manganese
an enhanced reaction is found compared to the system manganeseoxide/nickel. Based on the experimental data a model of the
evolving interface is proposed. 相似文献
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X-ray photoelectron spectroscopy(XPS)was used to study two different oxidation treatments on the GaAs(100)surface———the thermal oxidation in the air,and the ultraviolet-light oxidation in the UV-ozone. A series of properties including the oxide composition,chemical states,the surface Ga/As atomic ratio and the thickness of the oxide layer grown on GaAs surface were compared. The results indicate that the oxide composition,the surface Ga / As atomic ratio and the thickness of the oxide layer oxide on GaAs surface are different for different oxidation methods. The oxides on GaAs surface grown by thermal oxidation in the air are composed of Ga2O3,As2O5,As2O3 and elemental As;and the Ga/As atomic ratio is drifted off the stoichiometry far away. The Ga/As atomic ratio of oxide layer on GaAs surface is increases with the thickness of oxide. However,the oxides on GaAs surface grown by UV-ozone are made up of only Ga2O3 and As2O3,As2O5 and elemental As are not detected,the Ga/As atomic ratio is close to unity. The thickness of oxide layer on GaAs can be controlled by the UV exposing time. The mechanism of oxidation of GaAs is also discussed. The UV-light radiation not only causes the oxygen molecular excited forming atomic oxygen,but also induces the valence electrons of the GaAs excited from the valence band,and then the reactivity of Ga and As atom increase,and they can easily react with the excited atomic oxygen at the same reactive velocity. 相似文献
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Effect of CO on surface oxidation of uranium metal 总被引:1,自引:0,他引:1
The surface reactions of uranium metal with carbon monoxide at 25 and 200 °C have been studied by X-ray photoelectron spectroscopy (XPS); respectively. Adsorption of carbon monoxide on the surface layer of uranium metal leads to partial reduction of surface oxide and results in U4f photoelectron peak shifting to the lower binding energy. The content of oxygen in the surface oxide is decreased and O1s/O4f ratio decreases with increasing the exposure of carbon monoxide. The investigation indicates the surface layer of uranium metal has resistance to further oxidation in the atmosphere of carbon monoxide. 相似文献
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Karlsson PM Palmqvist AE Holmberg K 《Langmuir : the ACS journal of surfaces and colloids》2008,24(23):13414-13419
The adsorption of two anionic surfactants, sodium dodecyl sulfate (SDS) and sodium dodecyl phosphate (SDP), at surfaces of aluminum and aluminum oxide has been studied by means of atomic absorption spectrometry (AAS), X-ray photoelectron spectroscopy (XPS), and quartz crystal microbalance with dissipation monitoring (QCM-D). It was shown that more SDP than SDS binds to the surface and that SDP prevents dissolution of aluminum in water whereas SDS does not. This was not obvious, since the adsorption isotherms of the two surfactants to aluminum pigment powder are quite similar, as shown in an earlier work. The decreased aluminum dissolution with SDP compared to SDS was explained by the formation of a more compact protective layer with less permeability on the aluminum surface with SDP than with SDS. This is explained by differences in complexing ability between the surfactants and the aluminum pigment surface. While SDP is expected to form an inner-sphere complex with aluminum, leading to a lower accessibility of aluminum sites to water, SDS is likely to form a weaker outer-sphere complex. 相似文献
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Hauffman T Blajiev O Snauwaert J van Haesendonck C Hubin A Terryn H 《Langmuir : the ACS journal of surfaces and colloids》2008,24(23):13450-13456
The deposition of n-octylphosphonic acid on aluminum oxide was studied. The substrate was pretreated in order to achieve a root-mean-square roughness of <1 nm, a hydroxyl fraction of 30%, and a thickness of approximately 170 nm. It was proven using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) that, rather than a monolayer, an organic multilayer was formed. The growth mechanism was identified as a Stranski-Krastanov one. It was also shown that the use of AFM, probing the surface topography, is essential for a reliable quantification and interpretation of data obtained with XPS. 相似文献
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Changes in the surface chemical state of a nearly equiatomic nickel–titanium (NiTi) alloy caused by immersion in aqueous solutions of HNO3 and H2SO4 as well as subsequent heating in air at 723 K were analyzed using X-ray photoelectron spectroscopy (XPS). An XPS analysis using angle-resolved technique and a mathematical deconvolution technique revealed that a passive layer formed in an ambient atmosphere contained TiO2 as a major state and Ni(OH)2 and NiO as minor states. The Ni(OH)2 on the alloy remained in the region even when heated in air at 723 K. Therefore, the resulting layer became a Ti-oxide layer with Ni segregated region at the surface, which was NiO formed via dehydration of Ni(OH)2. However, immersion in an aqueous solution of HNO3 or H2SO4 enables Ni(OH)2 state to dissolve in the passive layer of a NiTi alloy; thereby, the Ni segregated region rarely appeared in the oxide layer by heating. The Ni segregated region at the surface becomes an obstacle for the inward diffusion of oxygen; thus, the annihilation of such a segregated region results in an increase in the thickness of the oxide layer. 相似文献
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《Surface and interface analysis : SIA》2005,37(1):24-32
Quantitative determination of surface coverage, film thickness and molecular orientation of DNA oligomers covalently attached to aminosilane self‐assembled monolayers has been obtained using complementary infrared and photoelectron studies. Spectral variations between surface immobilized oligomers of the different nucleic acids are reported for the first time. Carbodiimide condensation was used for covalent attachment of phosphorylated oligonucleotides to silanized aluminum substrates. Fourier transform infrared (FTIR) spectroscopy and x‐ray photoelectron spectroscopy (XPS) were used to characterize the surfaces after each modification step. Infrared reflection–absorption spectroscopy of covalently bound DNA provides orientational information. Surface density and layer thickness are extracted from XPS data. The surface density of immobilized DNA, 2–3 (×1013) molecules cm?2, was found to depend on base composition. Comparison of antisymmetric to symmetric phosphate stretching band intensities in reflection–absorption spectra of immobilized DNA and transmission FTIR spectra of DNA in KBr pellet indicates that the sugar–phosphate backbone is predominantly oriented with the sugar–phosphate backbone lying parallel to the surface, in agreement with the 10–20 Å DNA film thickness derived from XPS intensities. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献