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对钠蒸气中的碰撞能量合并过程Na(3PJ)+Na(3PJ′)→Na(nLJ″)+Na(3S1/2)进行了实验研究.在低钠原子密度条件下,用激光将原子分别激发到3P1/2或3P3/2态,测量从nLJ″态发出的荧光强度比和Na(3P3/2)与Na(3P1/2)的密度比,给出了J′=J=1/2或3/2,nLJ″=4D3/2,4D5/2,4F5/2,4F7/2,5S1/2的速率系数对打的比值、当销原子密度足够高时,3P态以统计比率布居,得到了k(nLJ″)(1/2,3/2)对k5S(3/2,3/2)的比值.
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本文从广义协变的运动方程和麦克斯韦方程出发,导出了电子等离子体波各量的解析表达式。指出△ω=2ωp的等离子体波是完全简谐的。完全共振的条件由△ω=2ω(p0)[1+(e2(A2((1)2)+(A2((2)2))/(2m2c4)+(3e2A2(1)A2(2))/(m2c4)]-1/2 给出。
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PRECISE MEASUREMENT OF DENSITY-DEPENDENT SHIFT BY WAVELENGTH MODULATION REFLECTION SPECTROSCOPY
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The density dependence of the line shift of the cesium D2 line is studied with sub-Doppler selective reflection spectroscopy. By use of wavelength modulation and sixth-harmonics detection we observed the coefficient of the pressure-induced shift of the 6S1/2(F=4)→6P3/2(F'=3) hyperfine transition of the cesium D2 line Δδ/ρ=-0.9(5)×10-8cm3. In the limit ρ=0 a frequency shift about -3MHz remains, which may be attributed to long-range atom-surface interactions. The experimental results can be used in measurements of the local field-induced frequency shift at high atomic densities with sufficient accuracy. 相似文献
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利用发展的调制俘获损耗荧光光谱技术实验测量了超冷铯分子0u+(6P3/2)长程态的高灵敏光缔合光谱. 光谱探测范围较国际已有报道扩大了60 cm-1, 观察到25个长程区域新的振动能级. 通过LeRoy-Bernstein公式对振动束缚能数据进行拟合, 获得了超冷铯分子0u+(6P3/2)态的长程系数C3 为16.103±0.010. 构建了超冷铯分子0u+(6P3/2)态长程区域的势能曲线. 相似文献
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通过仿真软件AFORS-HET对a-Si:H(p)/i-a-Si:H/c-Si(n)异质结太阳能电池的光伏特性进行分析及优化,主要对比了a-Si:H(p)层的均匀掺杂和表面掺杂浓度D1=1×1020 cm-3>界面掺杂浓度D2=4×1019 cm-3的梯度掺杂情况时的光伏特性,实现了在梯度掺杂时22.32%的光电转换效率。与均匀梯度掺杂相比,发射层的梯度掺杂除了引入一个附加电场,还优化了能带结构、光谱响应、表面复合速率。结果表明,梯度掺杂可以有效地改善电池的光电转换性能。 相似文献
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本文用固相反应烧结制备出Li2Mo2O6多晶材料。经X射线分析、红外光谱和电子顺磁共振谱(EPR)的研究,确定了它的结构是Li2Mo2O4和MoO2两个晶相组成的烧结体。钼离子以四价状态存在于MoO2晶相结构中。采用交流阻抗谱分析了晶界与温度变化的相关性。测得了样品的ln(σ总T)-1/T 曲线是由两段直线和一段曲线所组成;总电导率化能σ27℃=1.36×10-3(Ω·cm)-1,σ115℃=1.49×10-3(Ω·cm)-1,σ300℃=9.71×10-3(Ω·cm)-1,σ370℃=2.42×10-3(Ω·cm)-1;电导活化能E1=0.043eV,E2=0.235eV,E平均=0.76eV。采用维格纳极化电池法测得电子电导率σe,σe27℃=2.240×10-5(Ω·cm)-1,σe300℃=4.476×10-3(Ω·cm)-1。实验证明,室温下材料为固体电解质,300℃附近为良好的离子与电子混合导体。
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Spectroscopic parameters and molecular constants of HI(X~1Σ~+),DI(X~1Σ~+) and TI(X~1Σ~+) isotope molecules
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The potential energy curve (PEC) of HI(X1Σ+) molecule is studied using the complete active space self-consistent field method followed by the highly accurate valence internally contracted multireference configuration interaction approach at the correlation-consistent basis sets, aug-cc-pV6Z for H and aug-cc-pV5Z-pp for I atom. Using the PEC of HI(X1Σ+), the spectroscopic parameters of three isotopes, HI(X1Σ+), DI(X1Σ+) and TI(X1Σ+), are determined in the present work. For the HI(X1Σ+), the values of D0, De, Re, ωe, ωeχe, αe and Be are 3.1551 eV, 3.2958 eV, 0.16183 nm, 2290.60 cm-1, 40.0703 cm-1, 0.1699 cm-1 and 6.4373 cm-1, respectively; for the DI (X1Σ+), the values of D0, De, Re, ωe, ωeχe, αe and Be are 3.1965 eV, 3.2967 eV, 0.16183 nm, 1626.8 cm-1, 20.8581 cm-1, 0.0611 cm-1 and 3.2468 cm-1, respectively; for the TI (X1Σ+), the values of D0, De, Re, ωe, ωeχe, αe and Be are of 3.2144 eV, 3.2967 eV, 0.16183 nm, 1334.43 cm-1, 14.0765 cm-1, 0.0338 cm-1 and 2.1850 cm-1, respectively. These results accord well with the available experimental results. With the PEC of HI(X1Σ+) molecule obtained at present, a total of 19 vibrational states are predicted for the HI, 26 for the DI, and 32 for the TI, when the rotational quantum number J is equal to zero (J = 0). For each vibrational state, vibrational level G(?), inertial rotation constant B? and centrifugal distortion constant D? are determined when J = 0 for the first time, which are in excellent agreement with the experimental results. 相似文献
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采用自助熔剂缓冷法成功地生长出了Nd1.85Ce0. 15CuO4-δ单晶,其零场下零电阻温度约为21K. 在0—0.5T范围内分别测量了磁场平行和垂直样品表面的电阻转变曲线以及0.5T不同角度下的电阻转变曲线. 结果显示磁场平行和垂直样品表面时的转变温度Tp随磁场的变化均服从H=H0(1-Tp(h)/Tp(0))2关系. 0.5T
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1.85Ce0.15CuO4-δ单晶')" href="#">Nd1.85Ce0.15CuO4-δ单晶
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对多晶Y3Fe3Fe5-xMnxO12(x=0.05和0.09),得到300K下的中子衍射曲线。发现当x=0.05时,Mn3+离子占据16a和24d位置的几率分别为0.72和0.28;当x=0.09时,Mn3+离子全部占据16a位置;还得到两种组分16a和24d位置各自的磁矩值。在外磁场(800—10KOe)下测量Y3Fe5-xMnxO12(x=0—0.11)的磁化曲线,温度范围是1.5—300K。得到饱和磁矩值;并利用趋近饱和定律确定1.5K下的磁晶各向异性常数k1值,发现|k1|值随含锰量增加而减小。
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Variation of dielectronic satellite intensity factors with n for dielectronic recombination processes in selected lithium—like ions
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Satellite intensity factors F*2(s→f) have been calculated for the 1s22s+εl→(1s23l′nl″)*→1s22sml''+hν dielectronic recombination processes of lithium-like V, Cu, Se, Ag and Ba ions. The relevant atomic parameters have been calculated explicitly for all intermediate resonance states |s〉≡|1s23l′nl″SLJ〉 with n=3-9 in the intermediate coupling scheme. The 1/n3 scaling, which has often been used in extrapolating F*(s→f) for n≥4, is tested against these values of F*2(s→f). 相似文献