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1.
B. P. Tarasov V. N. Fokin A. P. Moravsky Yu. M. Shul'ga 《Russian Chemical Bulletin》1998,47(10):2037-2040
The interaction of crystalline fullerence C60 with highly pure hydrogen, which was evolved from hydrides of intermetallic compounds of rear-earth metals and nickel, was
studied. Crystalline fullerene hydrides containing from 10 to 30 hydrogen atoms per fullerene molecule were synthesized (1.0–2.5
MPa and 300–673 K). Crystalline hydrides release hydrogen at 800 K with retention of the structure of the fullerene molecule.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2093–2096, October, 1998. 相似文献
2.
M. V. Kirov 《Journal of Structural Chemistry》1996,37(1):92-98
A matrix method for conformational optimization of quasi-one-dimensional molecular structures is suggested. The method is
used to determine cyclic and polyhedral configurations of water clusters with the maximal number of stable trans-conformations
of molecular pairs forming hydrogen bonds.
Institute of Earth Cryosphere, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 1, pp. 107–115, January–February, 1996
Translated by L. Smolina 相似文献
3.
The ionic field effect on metal-olefin π-binding is considered for 24 Cu(I) compounds based on X-ray diffraction data. Structural
features due to Cu…(C=C)−H…An and N−H…An bridges in cationic and zwitterionic π-complexes, respectively, are discussed. Parity
of metal-olefin and hydrogen bonds in formation of these structures is shown.
I. Franko Lvov State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 5, pp. 109–119, September–October, 1994.
Translated by A. Arbuznikov 相似文献
4.
T. L. Lebedeva I. I. Vointseva L. M. Gil’man P. V. Petrovskii T. A. Larina 《Russian Chemical Bulletin》1997,46(4):732-738
It was established by Fourier-transform IR and1H NMR spectroscopy that a portion of the units of poly(1,1,2- and 1,2,3-trichlorobuta-1,3-diene) chains rearrange with migration
of the allylic chlorine (1–4%) and allylic hydrogen (3–10%) under the influence of chloroform. Rearrangement with the migration
of hydrogen under the influence of CDCl3, CCl4, and THF was also observed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 763–768, April, 1997. 相似文献
5.
A. P. Zhukovskii L. V. Shurupova M. A. Zhukovskii 《Journal of Structural Chemistry》1995,36(3):426-431
An analysis of band contour in the IR absorption (overtone region) and Raman spectra of water suggests that the high-frequency
components of spectral bands correspond to a single continuous distribution in energy of H-bonds. A local increase in the
probability density function at high frequencies, which leads to an increase in the population of states with weak hydrogen
bonds, is caused by the specific behavior of the angular dependence of the energy of hydrogen bonds between water molecules.
St. Petersburg State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 3, pp. 467–472, May–June, 1995.
Translated by I. Izvekova 相似文献
6.
The geometries and formation enthalpies of reagents, products, and triplet intermediates in the reaction of photoenolization
of o- methylacetophenone and 1- methylanthraquinone are calculated by semiempirical quantum chemical methods. It is shown
that the triplet intermediate is a triplet Σπ- biradical. The geometries and formation enthalpies of the transition state
of the thermal transfer of the hydrogen atom in 9- hydroxy- 1,10- anthraquinone- 1- methide are calculated. The MNDO semiempirical
methods give significantly exaggerated activation enthalpies in the thermal transfer of the hydrogen atom.
Translated fromZhumal Strukturnoi Khimii, Vol. 38, No. 4, pp. 645–654, July–August, 1997. 相似文献
7.
M. V. Kirov 《Journal of Structural Chemistry》1996,37(1):84-91
A topological model of polyhedral water clusters that takes into account the conformational type of hydrogen bond is suggested.
The polyhedral structures are classified according to the number of transand cis-conformations. The structural features of
clusters with the maximal number of more stable trans-conformations are studied.
Institute of Earth Cryosphere, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 1, pp. 98–106, January–February, 1996
Translated by L. Smolina 相似文献
8.
N. N. Karpyshev A. G. Tolstikov O. V. Tolstikova O. D. Yakovleva V. S. Shmakov 《Russian Chemical Bulletin》2000,49(3):569-570
The scalemic form of active alkaloid (−)-dipthocarpamine was synthesized by asymmetric oxidation ofN-isopropyl-N′-(methylthiohexyl)urea with hydrogen peroxide in the presence of vanadium(IV) complexes with chiral Shiff's bases.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 564–565, March, 2000. 相似文献
9.
D. T. Sadyrbekov G. A. Atazhanova A. T. Kulyyasov V. A. Raldugin Yu. V. Gatilov M. M. Shakirov T. T. Edil’baeva K. M. Turdybekov S. M. Adekenov 《Chemistry of Natural Compounds》2006,42(1):41-45
The structure of the sesquiterpene ketone buddledin C isolated from Pulicaria prostrata (Gilib.) Aschers., was confirmed by XSA. The stereochemistry of its epoxide, which was formed selectively by treating it
with hydrogen peroxide in alkaline solution, was proposed based on quantum-chemical and molecular-mechanical calculations.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 34–37, January–February, 2006. 相似文献
10.
A. L. Stroyuk A. E. Raevskaya A. V. Korzhak I. E. Kotenko E. M. Glebov V. F. Plyusnin S. Ya. Kuchmii 《Theoretical and Experimental Chemistry》2009,45(1):12-22
A relation was established between the composition of Cd
x
Zn1–x
S nanoparticles and their ability to accumulate excess negative charge during irradiation. The rate of expenditure of the
accumulated charge depends on the composition of the nanoparticles and is determined by their electric capacitance. A correlation
was found between the photocatalytic activity of the Cd
x
Zn1–x
S nanoparticles in the release of hydrogen from solutions of Na2SO3, their composition, and their capacity for photoinduced accumulation of excess charge. It was shown that Ni0 nanoparticles photodeposited on the surface of Cd
x
Zn1–x
S are effective cocatalysts for the release of hydrogen. It was found that ZnII additions in photocatalytic systems based on Cd
x
Zn1–x
S/Ni0 nanostructures have a promoting action on the release of hydrogen from water–ethanol mixtures.
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 45, No. 1, pp. 8–16, January-February, 2009. 相似文献
11.
E. L. Krasnykh 《Journal of Structural Chemistry》2009,50(3):556-560
The vaporization enthalpy of monohydric alcohols with different structures under normal conditions is calculated using a modified
Randič method with an error comparable to the experimental one. The energy of hydrogen bonds in alcohols is determined and
shown to be constant and independent on the alcohol structure.
Original Russian Text Copyright ? 2009 by E. L. Krasnykh
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 577–581, May–June, 2009. 相似文献
12.
V. V. Olijnik 《Journal of Structural Chemistry》1998,39(1):80-87
Structural effects: disordering, twinning, polymorphism, and morphotropism due to substitution of halide atoms are considered
using the results of X-ray diffraction analysis of 18 olefinic π-complexes of Cu(I). These effects are associated with the
heterodesmic character of compounds, in particular, with weak interactions such as lengthened coordination bonds and hydrogen
contacts.
Ukrainian State Wood Technology Institute. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 1, pp. 98–107, January–February, 1998. 相似文献
13.
Lipkowski J. Simonov Yu. A. Lyuboradskii R. Bourosh P. N. Popkov Yu. A. 《Journal of Structural Chemistry》1999,40(5):806-813
Inclusion compounds of solvate water molecules in a crystal matrix are investigated by X-ray diffraction analysis of a macrocyclic
polyamine decaazatricyclo[28.2.2.213.16]tetratriacontane nanohydrate (I). When included in a crystal, water molecules are bonded by water-water (O-H...O) and water—macrocycle
(0-H...N and N-H...O) hydrogen bonds, forming a linear cluster.
Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 5, pp. 993–1001, September–October, 1999. 相似文献
14.
B. A. Trofimov T. A. Skotheim A. G. Mal'kina L. V. Sokolyanskaya G. F. Myachina S. A. Korzhova E. S. Stoyanov I. P. Kovalev 《Russian Chemical Bulletin》2000,49(5):863-869
Polyethylene is exhaustively sulfurized by elemental sulfur at 160–365 °C to release hydrogen sulfide and form black lustrous
powders (sulfur content ≈80%) that possess electric conductivity (10−6–10−8 S cm−1 when doped with I2). Elemental analysis data, IR spectra, X-ray patterns, DSC-TGA. derivatographic data, electric conductivity, and mass spectrometric
characteristics of the polymers synthesized suggest the presence of fused polythienothiophene and polynaphthothienothiophene
blocks in the polymers.
For Part 1, see Ref. 1
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 865–871, May, 2000. 相似文献
15.
A. A. Stolov E. A. Vinokurova D. I. Kamalova T. S. Kozyreva S. A. Petrova A. B. Remizov 《Journal of Structural Chemistry》1998,39(3):388-392
The solvent and polymer matrix effects on the conformation equilibrium in 1,1,2,2-tetrabromoethane (TBE) are investigated
by IR spectroscopy. The free energy differences (ΔG0) of TBE conformations correlate with the dielectric permittivity function of the medium. A pronounced solvent effect on the
absolute integrated intensities of the IR bands arising from the C-H stretching vibrations indicates H-bonding between the
C-H groups of TBE and the solvent. The enthalpies of specific interactions due to hydrogen bonding were estimated using the
intensity rule (1–3 kcal/mole). The absence of correlations between ΔG0 and the solvent basicity parameter leads us to conclude that the trans- and gosh-conformers of TBE form nearly equally strong
hydrogen bonds.
Kazan State University. Kazan State Technological University. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 478–483, May–June, 1998.
This work was supported by RFFR grant No. 96-03-32171a. 相似文献
16.
Correlations between the internuclear distances r(M-X), the bond energies E(M-X), and the valence force constants fr for di- and trihalides of Group II–V elements are established. Some missing values are estimated.
Ivanovo State Chemical Technological Academy. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 5, pp. 859–875, September–October, 1996.
Translated by L. Smolina
Ivanovo State Chemical Technological Academy. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 5, pp. 859–875, September–October, 1996. 相似文献
17.
N. A. Ustynyuk M. G. Peterleitner O. V. Gusev L. I. Denisovich 《Russian Chemical Bulletin》1993,42(10):1727-1730
The electrochemical behavior of rhodium sandwich complexes containing η4-pentamethylcyclopentadiene or tetramethylfulvene fragments has been studied by cyclic voltammetry. The complexes undergo
one-electron oxidation to give unstable 17-electron radical cations which are converted into rhodocenium salts as a result
of elimination or uptake of hydrogen or C-C bond cleavage.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1802–1805, October, 1993. 相似文献
18.
V. M. Pinchuk A. N. Nazarov V. S. Lysenko V. M. Kovalev 《Journal of Structural Chemistry》1996,37(1):18-23
SCF-MO-LCAO calculations in the MINDO/3 approximation were used to determine some mechanisms of interactions between atomic
hydrogen and silicon lattice vacancies and between interstitial silicon atoms and hydrogen-charged lattice vacancies. In a
completely hydrogen-charged vacancy, hydrogen atoms are localized on the Si−Si bond of the second coordination sphere with
respect to the vacancy, so that the crystal lattice is ordered around the vacancy. The capture of atomic hydrogen in any charge
state by a vacancy significantly decreases the potential barriers of the annihilation of the Frenkel pairs. After an interstitial
atom has been captured by a hydrogen-charged vacancy, it is energetically profitable for the hydrogen atom to transfer to
a neighboring vacancy. The interaction mechanisms revealed are consistent with the model of the accelerated annealing of lattice
vacancy defects by high-frequency plasma treatment. In addition, the calculation results suggest that materials with hydrogen-charged
silicon should be more stable to ionizing radiation than materials with hydrogen-free silicon, since the probability that
the interstitial silicon involved in the Frenkel pair will be recaptured by the lattice point is rather high.
Kiev Polytechnical Institute. Translated fromZhurnal Strukturmoi Khimii, Vol. 37, No. 1, pp. 22–28, January–Feburary, 1996.
Translated by I. Izvekova 相似文献
19.
B. P. Tarasov V. N. Fokin A. P. Moravskii Yu. M. Shul’ga 《Russian Chemical Bulletin》1997,46(4):649-652
Fullerene hydrides containing 24–26 H atoms per fullerene molecule were obtained by hydrogenation of solid-phase mixtures
of fullerenes with either intermetallic compounds LaNi5, LaNi4.65Mn0.35, CeCo3 or V and Pd metals with gaseous hydrogen at 1.0–2.5 MPa and 573–673 K. These fullerene hydrides decompose at 800 K with evolution
of H2. Upon subsequent heating to 1000 K, vanadium reacts with fullerene to yield a cubic phase of vanadium carbide. The intermetallic
compounds react with fullerene with the formation of a metallic phase of the 3d-metal and destruction of fullerene. Palladium
does not react with fullerene.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 679–683, April, 1997. 相似文献
20.
A. S. Burlov A. É. Mistryukov A. D. Garnovskii V. S. Sergienko 《Journal of Structural Chemistry》1996,37(3):474-479
The structure of a new Schiff base, o-tosylaminobenzaldehyde, which has a bulky aliphatic substituent at the azomethine N
atom, was determined by X-ray diffraction analysis. The structure contains an intramolecular hydrogen bond N-H...N, flattening
the azomethine molecule and closing the six-membered quasiaromatic H-ring.
Scientific Research Institute of Physical and Organic Chemistry, Rostov State University. N. S. Kurnakov Institute of General
and Inorganic Chemistry, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 3, pp. 544–549, May–June, 1996. 相似文献