共查询到20条相似文献,搜索用时 250 毫秒
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"Their book is a most useful resource for approaching a large literature that even a specialist needs help to assimilate. It covers many widely separated areas - synthetic chemistry to theoretical physics, fundamental science to applications." 相似文献
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In this paper, the ion transfer process of bromocresol purple(BCP) across the liquid/liquid interface has been described. The effects of the supporting eletrolyte in two phases and solvent on the transfer behavior of bromocresol purple have been investigated in detail and the relationship between the ion transfer and concentration of electrolytes in the organic phase is explained in terms of the dissociation of TBA~+ anti TPB~- in the organic phase. The proposed transfer mechanism for BCP has been proved to be reasonable by UV-spectroscopy of the products of the electrolysis in aqueous phase. The standard potential differences △_0~wφ~0 and standard Gibbs energies △_0~WG~0 of BCP transfer from water to some organic solvents are calculated. The dissociation constants of BCP obtained are in agreement with the literature values. 相似文献
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热致型光敏液晶高分子在液晶场中光交联反应的研究 总被引:1,自引:0,他引:1
研究了具有肉桂酸酯侧链基的热致型液晶高分子的光交联行为.结果表明,在20min紫外光照射的条件下,形成液晶相的液晶高分子膜的光交联凝胶百分率要明显高于尚未形成液晶相的同种高分子膜.对形成液晶相的高分子膜,在环境温度低于液晶各向同性温度T时,温度对光交联凝胶百分率的影响甚微.这表明,由于液晶高分子中致介单元的聚集和有序排列形成的微区结构也影响了大分子链侧基肉桂酸酯的聚集状态.从而使其光化学性质发生变化. 相似文献
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Stig E. Friberg Chang Sup Wohn Yuh-Jye Uang Frances E. Lockwood 《Journal of Dispersion Science and Technology》2013,34(5-6):429-440
Solubilization in non-aqeuous lyotropic liquid crystals was investigated by determination of the stability region of a lamellar liquid crystal in systems of triethanolamine (TEA), dodecylbenzenesulfonic acid (DBSA) and a series of solvents. The solubilization maximum was moved towards higher OBSA/TEA ratios for polar solvents and the reverse for non-polar ones. The solvents caused the maximum increase of interlayer spacing when added. 相似文献
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Advances have been made in understanding the interactions of composition, molecular weight, liquid crystallinity,orientation, and three-dimensional crystallinity on the properties of injection-molded and melt-spun liquid crystalline polyesters (LCP's). Two classes of potentially low-cost LCP's were compared:(1) semiflexible LCP's prepared from 1,6-hexanediol and the dimethyl ester of either trans-4, 4'stilbenedicarboxylic acid or 4.4 ' biphenyldicarboxylic acid and (2) all-aromatic LCP's prepared from terephthalic acid, 2, 6-naphthalenedicarboxylic acid, the diacetate of hydroquinone, and the acetate of p-hydroxybenzoic acid. The effects of composition on the plastic properties of the 4-component all-aromatic LCP's were determined with the aid of a 3 x 3 factorial statistically designed experiment, the generation of equations with a computer program, and the plotting of three-dimensional figures and contour diagrams. The effects of absolute molecular weight (M_w) on the tensile strengths of the semiflexible LCP's and one of the all-aromatic LCP's having an excellent balance of plastic properties were also compared, and it was observed that the semiflexible LCP's required M_w's about 4 times higher than the all-aromatic LCP to attain a given strength. Persistence lengths and molecular modeling were used to explain these differences. 相似文献
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The equation of the potential-current curve for the ion transfer across the liquid/liquid interface during the linear current scanning has been derived theoretically. A method to calculate the kinetics parameters for the ion transfer by the way of linear current scanning is presented. The transfer of TPAs~+ ions, which is a typical basic electrolyte ion usually used in liquld/liquid interface electrochemistry, was practically investigated at the water/nitrobenzene interface. 相似文献
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This paper offers some new evidence on the polymorphism of solid state of liquid crystalline aromatic copolyesters which were prepared in our laboratory. The effects of different treatment conditions(quenching and annealing) on solid structure have been examined mainly by DSC and X-ray diffraction. The discussion focuses on the supercooled mesophase and low temperature solid-solid transition, the shifting of double melting peaks of annealed samples and the changing of their ΔH data depending on the treatment temperature, time and thermal scanning rate. 相似文献
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端羟基液体聚丁二烯的流变性质 总被引:1,自引:0,他引:1
本文研究了端羟基液体聚丁二烯(丁羟)的流变性质,它是剪切速率、温度和分子量的函数。测量是在HAAKE RV2锥板式粘度计上进行的,温度15—70℃,剪切速度0—2,275s-1。 当丁羟本体粘度小于1Pa•s,剪切速率低于650s-1时,其流动行为基本为牛顿型,在其它条件下则为非牛顿型。当丁羟分子量在1,000—5,600范围内,其本体粘度与温度关系符合经验公式:logηa=A+B/T。我们也确立了本体粘度与数均分子量的关系,在20℃时ηa=2.09×10-8Mn2•52,在25℃时为ηa=1.14×10-8Mn2•55。 相似文献
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渗透气化法分离液体混合物 总被引:2,自引:1,他引:1
渗透气化法是一种用来分离液体混合物的膜分离方法。本综述简要地讨论了渗透气化法的机理。本法用于乙醇-水混合物的分离,对于从生物源生产乙醇具有重要意义。乙醇-水混合物的分离膜可以分成二类:亲水性膜和亲乙醇膜。使用若干物理方法可改进渗透气化过程。最后,作者认为渗透气化膜的发展趋势是从均质膜,不对称膜向复合膜过渡。 相似文献
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合成了一种联苯型液晶环氧化合物(LCE),和一系列含有不同长度柔性亚甲基联苯介晶单元的环氧树脂固化促进剂(LCECAn,n=2,4,6)。利用傅立叶变换红外光谱(FTIR)和核磁共振(1HNMR)对化合物的结构进行了表征。此外,利用DSC考察了加入LCECAn的LCE/DDM固化体系的反应活性。结果表明,LCECAn能促进LCE/DDM固化体系的固化反应,分别加入10%LCECA2、10%LCECA4和10%LCECA6后,LCE/DDM体系的固化峰顶温度由150℃分别降低到136℃、139℃和137℃。 相似文献
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Abstract— Chlorophyll derivatives can be oriented in a liquid crystal matrix. The temperature and angular dependence of the absorption spectra are studied with polarized light. From these results we can deduce the orientation of the molecules of dye in the liquid crystal. The deconvolution of the Soret band also allows us to assign to the different components their related transition moments. 相似文献
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《中国化学快报》1991,(8)
A series of "liquid crystal polymers with two-dimensional mesogeuic units" were synthesized by the polycondensations of the monomer 2, 5-dihydroxybenzylidene-4-phenetidine with a diacid chloride selected from a series of α, ω-bis(4-chloroformylphenyloxy)carbonylalkues. This is the first series of polymers reported under the newly proposed concept "liquid crystal polymers with two dimensional mesogenic units". 相似文献