Interaction between edge dislocations and amorphous interphase in carbon nanotubes reinforced metal matrix nanocomposites incorporating interface effect

Dislocations mobility and stability in the carbon nanotubes (CNTs)-reinforced metal matrix nanocomposites (MMNCs) can significantly affect the mechanical properties of the composites. However, current processing techniques often lead to the formation of coated CNT (amorphous interphase exists between the reinforcement and metal matrix), which have large impact upon the image force exerting on dislocations. Even though the importance of the interphase zone formed in metal matrix composites has been demonstrated by many studies for elastic properties, the influence of interphase on the local elastoplastic behavior of CNT-reinforced MMNCs is still an open issue. This paper puts forward a three-phase composite cylinder model with new boundary conditions. In this model, the interaction between edge dislocations and a coated CNT incorporating interface effect is investigated. The explicit expressions for the stress fields and the image force acting on an edge dislocation are proposed. In addition, plastic flow occurring around the coated reinforcement is addressed. The influences of interface condition and the material properties of coated CNT on the glide/climb force are clearly analyzed. The results indicate that the interface effect becomes remarkable when the radius of the coated reinforcement is below 10 nm. In addition, different from the traditional particles, the coated CNT attracts the adjacent edge dislocations, causing pronounced local hardening at the interface between the interphase and the metal matrix under certain conditions. It is concluded that the presence of the interphase can have a profound effect on the local stress field in CNT-reinforced MMNCs. Finally, the condition of the dislocations stability and the equilibrium numbers of dislocations at a given size grain are evaluated for considering the interface effect.     

Rheological characterization of carbon nanotubes/poly(ethylene oxide) composites

Rheological properties of poly(ethylene oxide) nanocomposites embedded with carbon nanotubes (CNTs) were investigated in the present study. It was found that the CNT nanocomposites had a higher effective filler volume fraction than the real filler volume fraction, which yielded a drastic enhancement of shear viscosity. As the CNT loading in the nancomposites increases, non-Newtonian behavior was observed at the low-shear-rate region in the steady shear experiments. Oscillatory dynamic shear experiments showed that more addition of the CNTs led to stronger solidlike and nonterminal behaviors. To identify a dispersion state of the CNTs, field emission scanning electron spectroscopy and transmission electron microscopy were adopted and thermal analysis was also performed by using differential scanning calorimetry. The existence of percolated network structures of the CNTs even at a low CNT loading was verified by rheological properties and electrical conductivities.     

Micromechanics-based thermoelastic model for functionally graded particulate materials with particle interactions

Thermoelastic behavior of functionally graded particulate materials is investigated with a micromechanical approach. Based on a special representative volume element constructed to represent the graded microstructure of a macroscopic material point, the relation between the averaged strains of the particle and matrix phases is derived with pair-wise particle interactions, and a set of governing equations for the thermoelastic behavior of functionally graded materials is presented. The effective coefficient of thermal expansion at a material point is solved through the overall averaged strain of two phases induced by temperature change under the stress-free condition, and is shown to exhibit a weak anisotropy due to the particle interactions within the graded microstructure. When the material gradient is eliminated, the proposed model predicts the effective coefficient of thermal expansion for uniform composites as expected. If the particle interactions are disregarded, the proposed model recovers the Kerner model. The proposed semi-analytical scheme is consistent and general, and can handle any thermal loading variation. As examples, the thermal stress distributions of graded thermal barrier coatings are solved for two types of thermal loading: uniform temperature change and steady-state heat conduction in the gradation direction.     

Local effective thermoelastic properties of graded random structure matrix composites

Summary  We consider a linearly thermoelastic composite medium, which consists of a homogeneous matrix containing a statistically inhomogeneous random set of ellipsoidal uncoated or coated inclusions, where the concentration of the inclusions is a function of the coordinates (functionally graded material). Effective properties, such as compliance and thermal expansion coefficient, as well as first statistical moments of stresses in the components are estimated for the general case of inhomogeneity of the thermoelastic inclusion properties. The micromechanical approach is based on the Green function technique as well as on the generalization of the multiparticle effective field method (MEFM), previously proposed for the research of statistically homogeneous random structure composites. The hypothesis of effective field homogeneity near the inclusions is used; nonlocal effects of overall constitutive relations are not considered. Nonlocal dependences of local effective thermoelastic properties as well as those of conditional averages of the stresses in the components on the concentration of the inclusions are demonstrated. Received 11 November 1999; accepted for publication 4 May 2000     

An extended micromechanics method for probing interphase properties in polymer nanocomposites

Inclusions comprised on filler particles and interphase regions commonly form complex morphologies in polymer nanocomposites. Addressing these morphologies as systems of overlapping simple shapes allows for the study of dilute particles, clustered particles, and interacting interphases all in one general modeling framework. To account for the material properties in these overlapping geometries, weighted-mean and additive overlapping conditions are introduced and the corresponding inclusion-wise integral equations are formulated. An extended micromechanics method based on these overlapping conditions for linear elastic and viscoelastic heterogeneous material is then developed. An important feature of the proposed approach is that the effect of both the geometric overlapping (clustered particles) and physical overlapping (interacting interphases) on the effective properties can be distinguished. We apply the extended micromechanics method to a viscoelastic polymer nanocomposite with interphase regions, and estimate the properties and thickness of the interphase region based on experimental data for carbon-black filled styrene butadiene rubbers.     

The effects of the interphase and strain gradients on the elasticity of layer by layer (LBL) polymer/clay nanocomposites

A synergistic stiffening effect observed in the elastic mechanical properties of LBL assembled polymer/clay nanocomposites is studied via two continuum mechanics approaches. The nanostructure of the representative volume element (RVE) includes an effective interphase layer that is assumed to be perfectly bonded to the particle and matrix phases. An inverse method to determine the effective thickness and stiffness of the interphase layer using finite element (FE) simulations and experimental data previously published in Kaushik et al. (2009), is first illustrated. Next, a size-dependent strain gradient Mori–Tanaka (M–T) model (SGMT) is developed by applying strain gradient elasticity to the classical M–T method. Both approaches are applied to LBL-assembled polyurethane–montmorillonite (PU–MTM) clay nanocomposites. Both two-dimensional (2D) and three-dimensional (3D) FE models used in the first approach are shown to be able to accurately predict the stiffness of the PU–MTM specimens with various volume fractions. The SGMT model also accurately predicts the experimentally observed increase in stiffness of the PU–MTM nanocomposite with increasing volume fraction of clay. An analogy between the strain gradient effect and the role of an interphase in accounting for the synergistic elastic stiffening in nanocomposites is provided.     

A concurrent micromechanical model for predicting nonlinear viscoelastic responses of composites reinforced with solid spherical particles

A concurrent micromechanical model for predicting nonlinear viscoelastic responses of particle reinforced polymers is developed. Particles are in the form of solid spheres having micro-scale diameters. The composite microstructures are idealized by periodically distributed cubic particles in a matrix medium. Each particle is assumed to be fully surrounded by polymeric matrix such that contact between particles can be avoided. A representative volume element (RVE) is then defined by a single particle embedded in the cubic matrix. A spatial periodicity boundary condition is imposed to the RVE. One eighth unit-cell model with four particle and polymer subcells is generated due to the three-plane symmetry of the RVE. The solid spherical particle is modeled as a linear elastic material. The polymeric matrix follows nonlinear viscoelastic behaviors of thermorheologically simple materials. The homogenized micromechanical relation is developed in terms of the average strains and stresses in the subcells and traction continuity and displacement compatibility at the subcells’ interfaces are imposed. A stress–strain correction scheme is also formulated to satisfy the linearized micromechanical and the nonlinear constitutive relations. The micromechanical model provides three-dimensional (3D) effective properties of homogeneous composite responses, while recognizing microstructural geometries and in situ material properties of the heterogeneous medium. The micromechanical formulation is designed to be compatible with general displacement based finite element (FE) analyses. Experimental data and analytical micromechanical models available in the literature are used to verify the capability of the above micromechanical model for predicting the overall composite behaviors. The proposed micromodel is also examined in terms of computational efficiency and accuracy.     

Vibration of thermally postbuckled carbon nanotube-reinforced composite beams resting on elastic foundations

This paper investigates the small- and large-amplitude vibrations of thermally postbuckled carbon nanotube-reinforced composite (CNTRC) beams resting on elastic foundations. For the CNTRC beams, uniformly distributed (UD) and functionally graded (FG) reinforcements are considered where the temperature-dependent material properties of CNRTC beams are assumed to be graded in the thickness direction and estimated through a micromechanical model. The motion equations are derived based on a higher order shear deformation beam theory with including the beam-foundation interaction. The initial deflection caused by thermal postbuckling is also included. The numerical illustrations concern small- and large-amplitude vibration characteristics of thermally postbuckled CNTRC beams under uniform temperature field. The effects of carbon nanotube (CNT) volume fraction and distribution patterns as well as foundation stiffness on the vibration characteristics of CNTRC beams are examined in detail.     

Micromechanics-based modelling of stiffness and yield stress for silica/polymer nanocomposites

Establishing structure–property relationships for nanoparticle/polymer composites is a fundamental task for a reliable design of such new systems. A micromechanical analytical model is proposed in the present work, in order to address the problem of stiffness and yield stress prediction in the case of nanocomposites consisting of silica nanoparticles embedded in a polymer matrix. It takes into account an interphase corresponding to a perturbed region of the polymer matrix around the nanoparticles. Its modulus is continuously graded from that of the silica nanoparticle to that of the polymer matrix. Considering the thickness of the third phase as a characteristic length scale, the influence of particle size on the overall nanocomposite behaviour is examined. The key role of the interphase on both the overall stiffness and yield stress is studied and the model output is compared to experimental data of various silica spherical nanoparticle/polymer composites extracted from the literature. The model is also used to examine the influence of interphase features on the overall nanocomposite behaviour. A finite element analysis is then achieved and the numerical results are validated using the analytical predictions. Local stress and strain distributions are analysed in order to understand the phenomena occurring at the nano-scale.     

Influence of elastic foundations and carbon nanotube reinforcement on the hydrostatic buckling pressure of truncated conical shells

In this study, the effects of elastic foundations(EFs) and carbon nanotube(CNT) reinforcement on the hydrostatic buckling pressure(HBP) of truncated conical shells(TCSs) are investigated. The first order shear deformation theory(FOSDT) is generalized to the buckling problem of TCSs reinforced with CNTs resting on the EFs for the first time. The material properties of composite TCSs reinforced with CNTs are graded linearly according to the thickness coordinate. The Winkler elastic foundation(W-EF) and Pasternak elastic foundation(P-EF) are considered as the EF. The basic relations and equations of TCSs reinforced with CNTs on the EFs are obtained in the framework of the FOSDT and solved using the Galerkin method. One of the innovations in this study is to obtain a closed-form solution for the HBP of TCSs reinforced with CNTs on the EFs. Finally, the effects of the EFs and various types CNT reinforcements on the HBP are investigated simultaneously. The obtained results are compared with the results in the literature, and the accuracy of results is confirmed.     

Multiscale micromechanical modeling of the constitutive response of carbon nanotube-reinforced structural adhesives

Appropriate formulations are developed to allow for the atomistic-based continuum modeling of nano-reinforced structural adhesives on the basis of a nanoscale representative volume element that accounts for the nonlinear behavior of its constituents; namely, the reinforcing carbon nanotube, the surrounding adhesive and their interface. The newly developed representative volume element is then used with analytical and computational micromechanical modeling techniques to investigate the homogeneous dispersion of the reinforcing element into the adhesive upon both the linear and nonlinear properties. Unlike our earlier work where the focus was on developing linear micromechanical models for the effective elastic properties of nanocomposites, the present approach extends these models by describing the development of a nonlinear hybrid Monte Carlo Finite Element model that allows for the prediction of the full constitutive response of the bulk composite under large deformations. The results indicate a substantial improvement in both the Young’s modulus and tensile strength of the nano-reinforced adhesives for the range of CNT concentrations considered.     

A theory of plasticity for carbon nanotube reinforced composites

Carbon nanotubes (CNTs) possess exceptional mechanical properties, and when introduced into a metal matrix, it could significantly improve the elastic stiffness and plastic strength of the nanocomposite. But current processing techniques often lead to an agglomerated state for the CNTs, and the pristine CNT surface may not be able to fully transfer the load at the interface. These two conditions could have a significant impact on its strengthening capability. In this article we develop a two-scale micromechanical model to analyze the effect of CNT agglomeration and interface condition on the plastic strength of CNT/metal composites. The large scale involves the CNT-free matrix and the clustered CNT/matrix inclusions, and the small scale addresses the property of these clustered inclusions, each containing the randomly oriented, transversely isotropic CNTs and the matrix. In this development the concept of secant moduli and a field fluctuation technique have been adopted. The outcome is an explicit set of formulae that allows one to calculate the overall stress-strain relations of the CNT nanocomposite. It is shown that CNTs are indeed a very effective strengthening agent, but CNT agglomeration and imperfect interface condition can seriously reduce the effective stiffness and elastoplastic strength. The developed theory has also been applied to examine the size (diameter) effect of CNTs on the elastic and elastoplastic response of the composites, and it was found that, with a perfect interface contact, decreasing the CNT radius would enhance the overall stiffness and plastic strength, but with an imperfect interface the size effect is reversed. A comparison of the theory with some experiments on the CNT/Cu nanocomposite serves to verify the applicability of the theory, and it also points to the urgent need of eliminating all CNT agglomeration and improving the interface condition if the full potential of CNT reinforcement is to be realized.     

A combined viscoelastic–viscoplastic behavior of particle reinforced composites

This study formulates a micromechanical model for predicting effective viscoelastic–viscoplastic responses of composites. The studied composites consist of solid spherical particle reinforcements dispersed in a homogeneous matrix. The particle constituent is assumed linear elastic, while the matrix exhibits combined viscoelastic–viscoplastic responses. The Schapery integral model is used for the 3D isotropic non-linear viscoelastic responses. Two viscoplastic models are considered: the Perzyna model, having a rate-independent yield surface and an overstress function, and the Valanis endochronic model based on an irreversible thermodynamics without a yield surface. The Valanis model is suitable for materials when viscoplastic responses occur at early loadings (small stress levels). A unit-cell model with four particle and polymer sub-cells is generated to obtain homogenized responses of the particle-reinforced composites. Available micromechanical models and experimental data in the literature are used to verify the proposed micromechanical model in predicting effective time-dependent and inelastic responses of composites. Field variables in the homogenized composites are compared to the ones in heterogeneous composites. The heterogeneous composites, having detailed particle geometries, are modeled using finite element (FE) method.     

Three-dimensional theory of stability of a carbon nanotube in a matrix

The three-dimensional theory of stability of a carbon nanotube (CNT) in a polymer matrix is presented. The results are obtained on the basis of the three-dimensional linearized theory of stability of deformable bodies. Flexural and helical (torsional) buckling modes are considered. It is proved that the helical (torsional) buckling modes occur in a single CNT (the interaction of neighboring CNTs is neglected) and do not occur in nanocomposites (the interaction of neighboring CNTs is taken into account) __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 1, pp. 23–37, January 2006.     

功能梯度界面相对周期分布纤维增强复合材料反平面剪切的影响

基于复变函数理论和边界配点法,探索了功能梯度界面相在周期均匀分布纤维增强复合材料反平面剪切问题中所起的作用.由于纤维在复合材料基体中的周期分布是均匀的,将其简化成含一功能梯度界面相夹杂的方形单胞.采用分层均匀化方法,将功能梯度界面相离散成K层界面层.当K足够大时,每个界面层可视为匀质材料,同时计算得到的复合材料宏观性能...     

Three-dimensional thermoelastic analysis of finite length laminated cylindrical panels with functionally graded layers

Based on the 3D thermoelasticity theory, the thermoelastic analysis of laminated cylindrical panels with finite length and functionally graded (FG) layers subjected to three-dimensional (3D) thermal loading are presented. The material properties are assumed to be temperature-dependent and graded in the thickness direction. The variations of the field variables across the panel thickness are accurately modeled by using a layerwise differential quadrature (DQ) approach. After validating the approach, as an important application, two common types of FG sandwich cylindrical panels, namely, the sandwich panels with FG face sheets and homogeneous core and the sandwich panels with homogeneous face sheets and FG core are analyzed. The effect of micromechanical modeling of the material properties on the thermoelastic behavior of the panels is studied by comparing the results obtained using the rule of mixture and Mori–Tanaka scheme. The comparison studies reveal that the difference between the results of the two micromechanical models is very small and can be neglected. Then, the effects of different geometrical parameters, material graded index and also the temperature dependence of the material properties on the thermoelastic behavior of the FG sandwich cylindrical panels are carried out.     

Free vibration analysis of elastically supported functionally graded annular plates subjected to thermal environment

Free vibration analysis of functionally graded (FG) thin-to-moderately thick annular plates subjected to thermal environment and supported on two-parameter elastic foundation is investigated. The material properties are assumed to be temperature-dependent and graded in the thickness direction. The equations of motion and the related boundary conditions, which include the effects of initial thermal stresses, are derived using the Hamilton’s principle based on the first order shear deformation theory (FSDT). The initial thermal stresses are obtained by solving the thermoelastic equilibrium equations. Differential quadrature method (DQM) as an efficient and accurate numerical tool is adopted to solve the thermoelastic equilibrium equations and the equations of motion. The formulations are validated by comparing the results in the limit cases with the available solutions in the literature for isotropic and FG circular and annular plates. The effects of the temperature rise, elastic foundation coefficients, the material graded index and different geometrical parameters on the frequency parameters of the FG annular plates are investigated. The new results can be used as benchmark solutions for future researches.     

A new method for characterizing the interphase regions of carbon nanotube composites

The elastic properties of a carbon nanotube (CNT) reinforced composite are affected by many factors such as the CNT–matrix interphase. As such, mechanical analysis without sufficient consideration of these factors can give rise to incorrect predictions. Using single-walled carbon nanotube (SWCNT) reinforced Polyvinylchloride (PVC) as an example, this paper presents a new technique to characterize interphase regions. The representative volume element (RVE) of the SWCNT–PVC system is modeled as an assemblage of three phases, the equivalent solid fiber (ESF) mimicking the SWCNT under the van der Waals (vdW) forces, the dense interphase PVC of appropriate thickness and density, and the bulk PVC matrix. Two methods are proposed to extract the elastic properties of the ESF from the atomistic RVE and the CNT-cluster. Using atomistic simulations, the thickness and the average density of interphase matrix are determined and the elastic properties of amorphous interphase matrix are characterized as a function of density. The method is examined in a continuum-based three-phase model developed with the aid of molecular mechanics (MM) and the finite element (FE) method. The predictions of the continuum-based model show a good agreement with the atomistic results verifies that the interphase properties of amorphous matrix in CNT-composites could be approximated as a function of density. The results show that ignoring either the vdW interaction region or the interphase matrix layer can bring about misleading results, and that the effect of internal walls of multi-walled carbon nanotubes (MWCNTs) on the density and thickness of the dense interphase is negligible.     

A micromechanical model for predicting thermal properties and thermo-viscoelastic responses of functionally graded materials

This study introduces a micromechanical model for predicting effective thermo-viscoelastic behaviors of a functionally graded material (FGM). The studied FGM consists of two constituents with varying compositions through the thickness. The microstructure of the FGM is idealized as solid spherical particles spatially distributed in a homogeneous matrix. The mechanical properties of each constituent can vary with temperature and time, while the thermal properties are allowed to change with temperature. The FGM model includes a transition zone where the inclusion and matrix constituents are not well defined. At the transition zone, an interchange between the two constituents as inclusion and matrix takes place such that the maximum inclusion volume contents before and after the transition zone are less than 50%. A micromechanical model is used to determine through-thickness effective thermal conductivity, coefficient of thermal expansion, and time-dependent compliance/stiffness of the FGM. The material properties at the transition zone are assumed to vary linearly between the two properties at the bounds of the transition zone. The micromechanical model is designed to be compatible with finite element (FE) scheme and used to analyze heat conduction and thermo-viscoelastic responses of FGMs. Available experimental data and analytical solutions in the literature are used to verify the thermo-mechanical properties of FGMs. The effects of time and temperature dependent constituent properties on the overall temperature, stress, and displacement fields in the FGM are also examined.