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Akinobu Matsuzawa Akihiro Nojiri Naoya Kumagai Masakatsu Shibasaki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(17):5036-5042
Solvent‐dependent, self‐discrimination of diamides is described. Mixing a solution of (R)‐ 1 a and (S)‐ 1 a , which are valine‐derived, bis(2‐hydroxyphenyl)diamide‐bearing, multiple hydrogen‐bonding modules, in dichloromethane immediately led to the formation of a thick suspension comprising a 1:1 heterochiral aggregate of 1 a . The solubility of heterochiral 1 a was substantially lower in halogenated solvents than in ethyl acetate. A perusal of racemic crystal structures obtained from chloroform and ethyl acetate revealed a significant difference in the crystal‐packing pattern, which is likely to be the basis for the pronounced difference in solubility. Specific self‐discrimination of 1 a in an ensemble of eight structurally related molecules showcased the specific aggregation through the hydrogen‐bonding network of the bis(2‐hydroxyphenyl)diamide framework. The low solubility of heterochiral 1 a in halogenated solvent was exploited to achieve high stereoselectivity in a catalytic asymmetric reaction by using a low enantiomeric excess sample of 1 a . 相似文献
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Inside Back Cover: Octadecanuclear Gear Wheels by Self‐Assembly of Self‐Assembled “Double Saddle”‐Type Coordination Entities: Molecular “Rangoli” (Chem. Eur. J. 4/2015) 下载免费PDF全文
Hareesha Dasary Dr. Rajamony Jagan Prof. Dr. Dillip Kumar Chand 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(4):1819-1819
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Inside Back Cover: Solvatochromism,Reversible Chromism and Self‐Assembly Effects of Heteroatom‐Assisted Aggregation‐Induced Enhanced Emission (AIEE) Compounds (Chem. Eur. J. 40/2015) 下载免费PDF全文
Caixia Niu Ying You Liu Zhao Prof. Dacheng He Na Na Prof. Jin Ouyang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(40):14231-14231
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Back Cover: Ultrasound‐Driven Secondary Self‐Assembly of Amphiphilic β‐Cyclodextrin Dimers (Chem. Eur. J. 13/2015) 下载免费PDF全文
Hai‐tao Zhang Prof. Dr. Xiao‐dong Fan Prof. Dr. Wei Tian Rong‐tian Suo Zhen Yang Yang Bai Wan‐bin Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5256-5256
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Back Cover: Spontaneous Stepwise Self‐Assembly of a Polyoxometalate–Organic Hybrid into Catalytically Active One‐Dimensional Anisotropic Structures (Chem. Eur. J. 31/2014) 下载免费PDF全文
Dr. Panchao Yin Aruuhan Bayaguud Peng Cheng Fadi Haso Lang Hu Joy Wang Prof. Dr. Dmitri Vezenov Dr. Randall E. Winans Dr. Jian Hao Dr. Tao Li Prof. Dr. Yongge Wei Prof. Dr. Tianbo Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(31):9816-9816
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Inside Cover: Exploiting Aromatic Interactions for β‐Peptide Foldamer Helix Stabilization: A Significant Design Element (Chem. Eur. J. 16/2014) 下载免费PDF全文
Dr. István M. Mándity Dr. Antonella Monsignori Dr. Lívia Fülöp Prof. Dr. Enikö Forró Prof. Dr. Ferenc Fülöp 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(16):4494-4494
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Inside Cover: Stoichiometrically Controlled Revocable Self‐Assembled “Spiro” versus Quadruple‐Stranded “Double‐Decker” Type Coordination Cages (Chem. Eur. J. 41/2014) 下载免费PDF全文
Sreenivasulu Bandi Dr. Amlan K. Pal Prof. Dr. Garry S. Hanan Prof. Dr. Dillip Kumar Chand 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(41):13038-13038
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Inside Cover: Torands Revisited: Metal Sequestration and Self‐Assembly of Cyclo‐2,9‐tris‐1,10‐phenanthroline Hexaaza Macrocycles (Chem. Eur. J. 23/2015) 下载免费PDF全文
Dr. Matthias Georg Schwab Dr. Masayoshi Takase Dr. Alexey Mavrinsky Dr. Wojciech Pisula Prof. Dr. Xinliang Feng Dr. José A. Gámez Prof. Dr. Walter Thiel Dr. Kunal S. Mali Prof. Dr. Steven de Feyter Prof. Dr. Klaus Müllen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(23):8302-8302
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