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1.
Mijeong Han Huimin Bie David E. Nikles Garry W. Warren 《Journal of polymer science. Part A, Polymer chemistry》2000,38(16):2893-2899
A new diamine monomer was synthesized by the Michael addition of 4,4′‐methylene dianiline with 1,4‐benzoquinone. The monomer was condensed with 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride to give a polyamic acid that was soluble in NMP. The polyamic acid was cast onto iron and thermally imidized to yield the amine–quinone polyimide (AQPI‐2). AQPI‐2 had a thermal decomposition temperature of 540 °C (10% TGA weight loss in N2) and a glass transition at 292 °C, values typical of polyimides. The degradation of the coating on iron after exposure to 0.1 M NaCl electrolyte was followed by electrochemical impedance spectroscopy. Under these conditions a conventional polyimide failed after 3 days exposure, while AQPI‐2 survived more than 24 days exposure. The adhesive bond between the amine–quinone polyimide and the iron surface was so strong that it could not be broken by the electrolyte. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2893–2899, 2000 相似文献
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Mijeong Han David E. Nikles 《Journal of polymer science. Part A, Polymer chemistry》2000,38(18):3284-3292
A series of amine–quinone diol monomers, containing the 2,5‐diamino‐1,4‐benzoquinone group, were synthesized where the alkyl group on the amine was varied from methyl to ethyl to n‐propyl. Polyurethanes were prepared from these monomers by condensation polymerization in N,N‐dimethylformamide solution with toluene diiscyanate and poly(tetrahydrofuran) diol (Mn = 650). These amine–quinone polyurethanes were used as binders in metal particle tape. Samples were exposed to pH 2.0 aqueous buffer and the all amine–quinone polymers were shown to be superior in their ability to protect the iron particle against corrosion, relative to the commercial binders. There was no significant difference in the ability of the three amine–quinone polymers to inhibit corrosion. Clearly the increasing the steric bulk at the nitrogen did not affect their ability to inihibit corrosion. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3284–3292, 2000 相似文献
3.
Chungkyun Kim Hyojeong Kim Kyungrae Park 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2155-2161
Diels–Alder (DA) adducts including 24, 48, and 96 bicyclo end groups on the dendritic periphery were prepared by the reaction of anthracene on the dendrimers (first to fourth generation) and 1,4‐benzoquinone as well as 1,4‐naphtoquinone in boiled toluene. The structural information of DA adducts on the dendritic periphery was received from the hyperfine structural analysis by 1H NMR spectroscopy. The gel permeation chromatography of DA products revealed very low polydispersity values and decreased regular retention time according to increasing generation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2155–2161, 2004 相似文献
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Prof. P. Veeraraghavan Ramachandran Ameya S. Kulkarni Mark A. Pfeil Jacob D. Dennis Jared D. Willits Prof. Stephen D. Heister Prof. Steven F. Son Prof. Timothée L. Pourpoint 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(51):16869-16872
Complexation of amines with borane converts them to hypergols or decreases their ignition delays (IDs) multifold (with white fuming nitric acid as the oxidant). With consistently low IDs, amine–boranes represent a class of compounds that can be promising alternatives to toxic hydrazine and its derivatives as propellants. A structure–hypergolicity relationship study reveals the necessary features for the low ID. 相似文献
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Four new bisdienes were prepared from 2-bromomethyl-1,3-butadiene and N,N-diethyl benzidine; bis[4-(N-ethyl) aminophenyl]-p-diisopropylbenzene, 1,4-diamino-2,3,5,6-tetramethylbenzene and α,α′ bis(4-amino-3,5-dimethyl phenyl)-p-diisopropyl benzene. Polyimides were synthesized by the Diels–Alder reaction of these bisdienes and bis(4-maleimidylphenyl)methane and bis(3-maleimidylphenyl) sulfone. The polymers were soluble in m -cresol, dimethyl sulfoxide and chlorinated hydrocarbon solvents. Moderate thermal stability was observed by thermogravimetric analysis in air and nitrogen. 相似文献
7.
PC‐Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine–Boranes 下载免费PDF全文
Dr. Heather C. Johnson Prof. Andrew S. Weller 《Angewandte Chemie (International ed. in English)》2015,54(35):10173-10177
{Rh(xantphos)}‐based phosphido dimers form by P? C activation of xantphos (4,5‐bis(diphenylphosphino)‐9,9‐dimethylxanthene) in the presence of amine–boranes. These dimers are active dehydrocoupling catalysts, forming polymeric [H2BNMeH]n from H3B?NMeH2 and dimeric [H2BNMe2]2 from H3B?NMe2H at low catalyst loadings (0.1 mol %). Mechanistic investigations support a dimeric active species, suggesting that bimetallic catalysis may be possible in amine–borane dehydropolymerization. 相似文献
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Craig L. Homrighausen Brent J. Kennedy Erick J. Schutte 《Journal of polymer science. Part A, Polymer chemistry》2005,43(20):4922-4932
This research was focused on the design and execution of new synthetic routes to low‐temperature‐curable poly(silarylene–siloxane)polyimides. The synthesis of individual oligoimide and silarylene–siloxane blocks was followed by hydrosilylation polymerization to produce crosslinked copolymers. The silarylene–siloxane and polyimide blocks were structurally characterized by IR and 1H NMR spectroscopy and size exclusion chromatography. The high‐temperature resistance of the copolymers was evaluated through the measurement of heat distortion temperatures (THD's) via thermomechanical analysis and by the determination of the weight loss at elevated temperatures via thermogravimetric analysis. Glass‐transition temperatures (Tg's) of the silarylene–siloxane segments were measured by differential scanning calorimetry. Hydrosilylation curing was conducted at 60 °C in the presence of chloroplatinic acid (H2PtCl6). The copolymers displayed both high‐temperature resistance and low‐temperature flexibility. We observed Tg of the silarylene–siloxane segment as low as ?77 °C and THD of the polyimide segment as high as 323 °C. The influence of various oligoimide molecular weights on the properties of copolymers containing the same silarylene–siloxane was examined. The effect of various silarylene–siloxane molecular weights on the properties of copolymers containing the same oligoimide was also examined. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4922–4932, 2005 相似文献
10.
Baochau N. Nguyen James C. Shattuck Malcolm P. Stevens 《Journal of polymer science. Part A, Polymer chemistry》2000,38(15):2645-2651
A novel polycyclic dihydroxy diimide monomer was synthesized through the photocycloaddition of N‐methylolmaleimide to benzene and the reaction of maleimide–benzene photoadduct with formaldehyde. The monomer, which evolved formaldehyde at about 165 °C, was subsequently used to prepare low molecular weight polyamineimides and polyurethaneimides. Soluble polyamineimides, prepared with three different aromatic diamine monomers, exhibited initial decomposition temperatures between 277 and 329 °C and glass‐transition temperatures between 180 and 219 °C. An aliphatic polyamineimide prepared from 1,6‐hexanediamine was insoluble and had glass‐transition and initial decomposition temperatures of 225 °C and 294 °C, respectively, with prior loss of formaldehyde from end groups. Polyurethaneimides prepared with two aromatic diisocyanates showed loss of formaldehyde in the approximate range of 160–169 °C followed by loss of CO2 and glass‐transition temperatures of 219 and 233 °C. Attempts to prepare polyamideimides resulted in oligomers with a low nitrogen content. Attempts to prepare polyesterimides were unsuccessful. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2645–2651, 2000 相似文献
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The amine carboxyborane metal complexes, tetrakis - μ - (trimethylamine – boranecarbo - xylato)acetonitrile dicopper(II) and bis-μ- (morpholine–boranecarboxylato)zinc(II) dihydrate demonstrated cytotoxic activity against human Tmolt3, HeLa-S3 and MB-9812 cell growth.Tetrakis-μ-(trimethylamine–boranecarboxylato)-acetonitrile dicopper(II) and bis - μ - (morpholine – boranecarboxylato)zinc (II) dihydrate inhibited L1210 DNA, RNA and protein syntheses, with greatest inhibitory effects on DNA synthesis. The reduction in DNA synthesis correlates well with inhibition of de novopurine synthesis and the key enzymes involved in this pathway, i.e. IMP dehydrogenase and PRPP amido transferase. These compounds were also observed to induce DNA strand scission but did not appear to intercalate between base pairs of DNA, alkylate bases or cause cross-linking of the strands of DNA. Tetrakis-μ-(trimethylamine – boranecarboxylato)acetonitrile dicopper(II) also demonstrated the ability to inhibit L1210 DNA topoisomerase II activity. © 1998 John Wiley & Sons, Ltd. 相似文献
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A new route to synthesize amphiphilic core–shell particles that consist of well‐defined hydrophobic polymer cores and poly(vinylamine) (PVAm) shells has been developed. The PVAm was treated with a small amount of tert‐butyl hydroperoxide to generate free radicals that subsequently initiated both graft‐ and homo‐polymerization of vinyl monomer such as n‐butyl acrylate, methyl methacrylate, and styrene. Stable particles in the range from 100 to 250 nm in diameter with very narrow size distributions (polydispersity index between 1.08 and 1.15) were produced in high yields. TEM images of the particles revealed that they had well‐defined core–shell nanostructures with thick and hairy PVAm shells. The structures of the vinyl monomer and water‐soluble polymer were found to strongly influence the formation of particles and their sizes.
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《Journal of polymer science. Part A, Polymer chemistry》2018,56(10):1058-1066
Two novel bio‐based diamines are synthesized through introduction of renewable 2,5‐furandicarboxylic acid (2,5‐FDCA), and the corresponding aromatic polyimides (PIs) are then prepared by these diamines with commercially available aromatic dianhydrides via two‐step polycondensation. The partially bio‐based PIs possess high glass transition temperatures (Tgs) in the range from 266 to 364 °C, high thermal stability of 5% weight loss temperatures (T5%s) over 420 °C in nitrogen and outstanding mechanical properties with tensile strengths of 79–138 MPa, tensile moduli of 2.5–5.4 GPa, and elongations at break of 3.0–12.3%. Some colorless PI films (PI‐1‐b and PI‐1‐c) with the transmittances at 450 nm over 85% are prepared. The overall properties of 2,5‐FDCA‐based PIs are comparable with petroleum‐based PI derived from isophthalic acid, displaying the potential for development of innovative bio‐based materials. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 1058–1066 相似文献
14.
Jingling Yan Taihang Li Zhen Wang Lianxun Gao Mengxian Ding 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4933-4940
3,3′‐Dichloro‐N,N′‐biphthalimide (3,3′‐DCBPI), 3,4′‐dichloro‐N,N′‐biphthalimide (3,4′‐DCBPI), and 4,4′‐dichloro‐N,N′‐biphthalimide (4,4′‐DCBPI) were synthesized from 3‐ or 4‐chlorophthalic anhydrides and hydrazine in glacial acetic acid. The yield of 3,3′‐DCBPI (90%) was much higher than that of 4,4′‐DCBPI (33%) because of the better stability of the intermediate, 3‐chloro‐N‐aminophthalimide, and 3,3′‐DCBPI. A series of hydrazine‐based polyimides were prepared from isomeric DCBPIs and 4,4′‐thiobisbenzenethiol (TBBT) in N,N‐dimethylacetamide in the presence of tributylamine. Inherent viscosity of these polymers was in the range of 0.51–0.69 dL/g in 1‐methyl‐2‐pyrrolidinone (NMP) at 30 °C. These polyimides were soluble in 1,1,2,2‐terachloroethane, NMP, and phenols. The 5% weight‐loss temperatures (T5%s) of the polymers were near 450 °C in N2. Their glass‐transition temperatures (Tgs) determined by dynamic mechanical thermal analysis and differential scanning calorimetry increased according to the order of polyimides based on 4,4′‐DCBPI, 3,4′‐DCBPI, and 3,3′‐DCBPI. The hydrolytic stability of these polymers was measured under acid, basic, and neutral conditions and the results indicated that the order was 3,3′‐DCBPI/TBBT > 3,4′‐DCBPI/TBBT > 4,4′‐DCBPI/TBBT. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4933–4940, 2007 相似文献
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Choonkeun Lee Saimani Sundar Jinuk Kwon Haksoo Han 《Journal of polymer science. Part A, Polymer chemistry》2004,42(14):3612-3620
A series of six‐membered sulfonated polyimides were synthesized using 1,4,5,8‐naphthalenetetracarboxylic dianhydride, 4,4′‐diaminobiphenyl 2,2′‐disulfonic acid as the sulfonated diamine, and various nonsulfonated diamine monomers having different bridging groups. These bulky bridging groups have the capacity to increase hydrolytic stability and proton conductivity. Polyimides with bulky bridging groups showed increased solubility but exhibited lower thermal stability. The ion exchange capacity and water uptake reduced with increase in the bulkiness of the bridging group. This was attributed to the increase in the molecular weight of the repeating unit and hence effectively reduced the sulfonic acid content. In low temperatures, the conductivity was lower than Nafion®115 and, with increase in temperature, the conductivity rapidly increased and exhibited better conductivity than Nafion®115. Polyimides with bulky bridging groups 4‐amino phenyl sulfone, and 2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane showed higher conductivity than other polyimides and Nafion®115 despite low ion exchange capacity. The hydrolytic stability of the polyimides with bulky bridging groups was higher than the polyimides with less bulky atoms because of the imparted flexibility. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3612–3620, 2004 相似文献
16.
Choonkeun Lee Saimani Sundar Jinuk Kwon Haksoo Han 《Journal of polymer science. Part A, Polymer chemistry》2004,42(14):3621-3630
A series of sulfonated polyimides with increasing alkyl substituents in the o‐position to diamine were synthesized from 4,4′‐methylene dianiline, 4,4′‐diamine‐3,3′‐dimethyl‐diphenylmethane, and 4,4′‐diamine‐3,5,3′,5′‐tetraethyl‐diphenylmethane using 1,4,5,8‐naphthalenetetracarboxylic dianhydride and perylenetetracarboxylic dianhydride by chemical imidization method. 4,4′‐Diaminobiphenyl 2,2′‐disulfonic acid was used as sulfonated diamine. The variation in the membrane properties with increase in substitution was analyzed. Solubility increased with substitution whereas the thermal stability decreased with increase in substitution. Ion exchange capacity and water uptake reduced with increase in substitution because of the low sulfonic acid content at a particular weight due to the increased molecular weight of the repeating unit. The conductivity of the substituted diamines was higher than the unsubstituted diamines at higher temperature regardless of low ion exchange capacity and water uptake. The increase in conductivity with increase in temperature was more rapid in polyimides than in Nafion®115. Hydrolytic stability of the polyimides with substitution is more than the unsubstituted diamines. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3621–3630, 2004 相似文献
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Chia Wei Chang Ching Hsuan Lin Po Wen Cheng Hann Jang Hwang Shenghong A. Dai 《Journal of polymer science. Part A, Polymer chemistry》2009,47(10):2486-2499
Two novel phosphorus‐functionalized aromatic diamines, 1,1‐bis(4‐aminophenyl)‐1‐(6‐oxido‐6H‐dibenz <c,e> <1,2> oxaphosphorin‐6‐yl)ethane ( 1 ) and bis(4‐aminophenyl)‐(6‐oxido‐6H‐dibenz <c,e> <1,2> oxaphosphorin‐6‐yl)phenylmethane ( 2 ), were prepared from 9,10‐dihydro‐oxa‐10‐phosphaphenanthrene‐10‐oxide, 4‐aminoacetophenone, or 4‐aminobenzophenone in excess aniline using p‐toluenesulfonic acid monohydrate as catalyst by an efficient, one‐pot procedure. The effect of electron withdrawing/donating groups on the stabilization of the resulting carbocation seems critical for the success of the process and was discussed in detail. Based on diamines ( 1–2 ), a series of new polyimides, (5a–5d) and (6a–6d) , were prepared, respectively. Polyimides (5a–5d) are flexible and creasable. In contrast, polyimides (6a–6d) are brittle because of the structure rigidity, according to the analysis based on the NMR temperature‐dependent spectra of ( 2 ). Polyimides 5 displaying high Tg (318–392 °C), high moduli (3.39–4.49 GPa), low coefficient of thermal expansion (42–50 ppm/°C), and moderate thermal stability (Td 5 wt % at 426–439 °C), are excellent high‐Tg and flame‐retardant materials. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2486–2499, 2009 相似文献
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Hung‐ju Yen Shiue‐ming Guo Jui‐ming Yeh Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2011,49(16):3637-3646
Two series of polyimides I – II with methyl‐substituted triphenylamine units were prepared from the diamines, 4,4′‐diamino‐2″,4″,6″‐trimethyltriphenylamine (Me3TPA‐diamine; 1 ) and 4,4′‐diamino‐4″‐methyltriphenylamine (MeTPA‐diamine; 2 ), and two commercially available tetracarboxylic dianhydrides via a conventional two‐step chemical imidization. All the polymers were readily soluble in many polar solvents and showed useful levels of thermal stability associated with high glass transition temperatures (266–340 °C) and high char yields (higher than 49% at 800 °C in nitrogen). The polymer films showed reversible electrochemistry/electrochromism accompanied by a color change from neutral pale yellow to green oxidized form with good coloration efficiency, switching time, and stability. The CO2 permeability coefficients (PCO2) and permeability selectivity (PCO2/PCH4) for these polyimide membranes were in the range of 34.1–229.2 barrer and 21.3–28.9, respectively. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
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Yi‐Chun Kung Wen‐Fu Lee Sheng‐Huei Hsiao Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2011,49(10):2210-2221
A series of novel polyimides based on N,N‐di(4‐aminophenyl)‐1‐aminopyrene and aromatic or alicyclic tetracarboxylic dianhydrides were synthesized. The polymers exhibited good solubility in many polar organic solvents and could afford robust films via solution casting. The polyimides derived from aromatic dianhydrides exhibited high thermal stability and high glass‐transition temperatures (333–364 °C). Cyclic voltammetry studies of the polymer films showed that these polyimides are both p and n dopable and have multicolored electrochromic states. For the polyimides derived from alicyclic dianhydrides, they revealed a strong blue‐light emission with high fluorescence quantum yields (?PL > 45%) and a marked solvatochromic behavior. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献