强流脉冲电子束辐照诱发纯钼表面的损伤效应及结构缺陷

利用强流脉冲电子束（HCPEB）装置对纯钼表面进行辐照处理,并利用X射线衍射仪,扫描电子显微镜（SEM）、透射电子显微镜（TEM）详细分析了辐照表面的微观结构和损伤效应. 1次HCPEB辐照后,纯钼表层积聚了极大的残余应力,多次辐照后表面未融化区域出现大量绝热剪切带,且局部区域发生开裂. 微观结构分析显示,辐照后材料表面形成发散状的位错组态和大量空位簇缺陷;绝热剪切带内部是尺寸为1 μm 左右等轴状的再结晶晶粒. 剪切带造成的材料表面局部软化以及间隙原子偏聚于晶界是材料发生开裂的主要原因. 另外,表面熔化区域可形成尺寸为20 nm左右的纳米晶. 关键词： 强流脉冲电子束 纯钼 绝热剪切带 空位簇缺陷     

Strain localization and its connection with the deformed state of the material

The detection of the passage of a shear band over an undeformed material poses a new question about the causal connection between the strain and the formation of shear bands. The collapse of a thick-walled tube is considered from the standpoint of the spall mechanism, according to which localized strain bands under pulsed loading are the result of interference of unloading waves; the negative stresses in the extension zone in this case do not exceed the strength of the material. It is found that radial cracks and their continuations in the form of shear bands appear at the unloading stage after the strained state of the material has already formed as a result of collapse. In other words, damageability is superimposed on the deformed material, and both these processes are independent and accompany each other.     

Non-linear oscillatory rheological properties of a generic continuum foam model: Comparison with experiments and shear-banding predictions

The occurrence of shear bands in a complex fluid is generally understood as resulting from a structural evolution of the material under shear, which leads (from a theoretical perspective) to a non-monotonic stationary flow curve related to the coexistence of different states of the material under shear. In this paper we present a scenario for shear-banding in a particular class of complex fluids, namely foams and concentrated emulsions, which differs from other scenarios in two important ways. First, the appearance of shear bands is shown to be possible both without any intrinsic physical evolution of the material (e.g. via a parameter coupled to the flow such as concentration or entanglements) and without any finite critical shear rate below which the flow does not remain stationary and homogeneous. Secondly, the appearance of shear bands depends on the initial conditions, i.e. the preparation of the material. In other words, it is history dependent. This behaviour relies on the tensorial character of the underlying model (2D or 3D) and is triggered by an initially inhomogeneous strain distribution in the material. The shear rate displays a discontinuity at the band boundary whose amplitude is history dependent and thus depends on the sample preparation.     

The mechanisms of plastic strain accommodation during the high strain rate collapse of corrugated Ni–Al laminate cylinders

The Thick-Walled Cylinder method was used on corrugated Ni–Al reactive laminates to examine how their mesostructures accommodate large strain, high strain rate plastic deformation and to examine the potential for intermetallic reaction initiation due to mechanical stimuli. Three main mesoscale mechanisms of large plastic strain accommodation were observed in addition to the bulk distributed uniform plastic flow: (a) the extrusion of wedge-shaped regions into the interior of the cylinder along planes of easy slip provided by angled layers, (b) the development of trans-layer shear bands in the layers with orientation close to radial and (c) the cooperative buckling of neighbouring layers perpendicular to the radius. These mesoscale mechanisms acted to block the development of periodic patterns of multiple, uniformly distributed, shear bands that have been observed in all previously examined solid homogeneous materials and granular materials. The high-strain plastic flow within the shear bands resulted in the dramatic elongation and fragmentation of Ni and Al layers. The quenched reaction between Al and Ni was observed inside these trans-layer shear bands and in a number of the interfacial extruded wedge-shaped regions. The reaction initiated in these spots did not ignite the bulk of the material, demonstrating that these mesostructured Ni-Al laminates are able to withstand high-strain, high-strain rate deformation without reaction. Numerical simulations of the explosively collapsed samples were performed using the digitized geometry of corrugated laminates and predictions of the final, deformed mesostructures agree with the observed deformation patterns.     

Structural, elastic, vibrational and electronic properties of amorphous Al2O3 from ab initio calculations

First-principles molecular dynamics calculations of the structural, elastic, vibrational and electronic properties of amorphous Al(2)O(3), in a system consisting of a supercell of 80 atoms, are reported. A detailed analysis of the interatomic correlations allows us to conclude that the short-range order is mainly composed of AlO(4) tetrahedra, but, in contrast with previous results, also an important number of AlO(6) octahedra and AlO(5) units are present. The vibrational density of states presents two frequency bands, related to bond-bending and bond-stretching modes. It also shows other recognizable features present in similar amorphous oxides. We also present the calculation of elastic properties (bulk modulus and shear modulus). The calculated electronic structure of the material, including total and partial electronic density of states, charge distribution, electron localization function and the ionicity for each species, gives evidence of correlation between the ionicity and the coordination for each Al atom.     

Surface Morphology of Deformed Amorphous-Nanocrystalline Materials and the Formation of Nanocrystals

The formation of nanocrystals under deformation in Al-, Fe-, and Co-based amorphous alloys are studied using X-ray diffraction and transmission and scanning microscopy methods. It is shown that the presence of shear bands in deformed amorphous alloys is an insufficient condition for nanocrystal formation. The presence of a large number of intersecting shear bands and an increase in the material temperature in the shear-band region in the case of intense plastic deformation contributes to nanocrystal formation.     

Turbulence and dissipative structures in shock-loaded copper

Shock-loading tests of polycrystalline copper M3 under conditions of uniaxial deformation at impact velocities of 100 to 700 m/s were performed. It was established that a threshold deformation rate exists above which dissipative structures in the dynamically deformed material arise in the form of local regions of cellular type, with a size of 15–25 μm, separated by shear plastic bands. The basic size of cellular structure domains is on the nanometer scale. The microhardness of the material within the cellular structures is somewhat higher than in the bands of plastic deformation that separate these structures. At threshold deformation rates and above it, the defect of the mass velocity, the difference between the impactor velocity for symmetrical collision and the free surface velocity at the plateau of the compression pulse, increases sharply as does the spall strength of the material.     

Slip, yield, and bands in colloidal crystals under oscillatory shear

We study dense colloidal crystals under oscillatory shear using a confocal microscope. At large strains the crystals yield and the suspensions form shear bands. The pure harmonic response exhibited by the suspension rules out the applicability of nonlinear rheology models typically used to describe shear banding in other types of complex fluids. Instead, we show that a model based on the coexistence of linearly responding phases of the colloidal suspension accounts for the observed flows. These results highlight a new use of oscillatory measurements in distinguishing the contribution of linear and nonlinear local rheology to a globally nonlinear material response.     

Hot spots in an athermal system

We study experimentally the dynamical heterogeneities occurring at slow shear, in a model amorphous glassy material, i.e., a 3D granular packing. The deformation field is resolved spatially by using a diffusive wave spectroscopy technique. The heterogeneities show up as localized regions of strong deformations spanning a mesoscopic size of about 10 grains and called the "hot spots." The spatial clustering of hot spots is linked to the subsequent emergence of shear bands. Quantitatively, their appearance is associated with the macroscopic plastic deformation, and their rate of occurrence gives a physical meaning to the concept of "fluidity," recently used to describe the local and nonlocal rheology of soft glassy materials.     

Deformation band evolution in [110] Al single crystals strained in tension

Several types of deformation bands form during uniaxial extension of Al single crystals for which the tensile axis is initially parallel to [110]. The objectives of the present work are to analyse crystal orientation evolution in the deformation bands and adjoining regions, and to integrate the experimental observations with a crystal mechanics model. The most prominent deformation bands contain secondary slip traces and exhibit crystal rotations consistent with unpredicted slip on a secondary slip system. These special bands of secondary slip (SBSS) become more closely aligned with the tensile axis as extension increases. The evolution of SBSS inclination with extension indicates that SBSS form initially as kink bands and that SBSS boundaries are immobile. SBSS grow during straining by expansion of the volume of material in which secondary slip operates. Deformed matrix (DM) bands are zones between SBSS; primary slip predominates in DM bands. Small intra-DM bands result from spatial variation of the shear amplitudes for the two primary slip systems. The evolution of intra-DM band inclination with extension indicates that intra-DM bands form initially as kink bands and that the band boundaries are mobile, at least to some extent.     

Shear localization in a model glass

Using molecular dynamics simulations, we show that a simple model of a glassy material exhibits the shear localization phenomenon observed in many complex fluids. At low shear rates, the system separates into a fluidized shear band and an unsheared part. The two bands are characterized by a very different dynamics probed by a local intermediate scattering function. Furthermore, a stick-slip motion is observed at very small shear rates. Our results, which open the possibility of exploring complex rheological behavior using simulations, are compared to recent experiments on various soft glasses.     

Microalloying and the mechanical properties of amorphous solids

The mechanical properties of amorphous solids like metallic glasses can be dramatically changed by adding small concentrations (as low as 0.1%) of foreign elements. The glass-forming-ability, the ductility, the yield stress and the elastic moduli can all be greatly effected. This paper presents theoretical considerations with the aim of explaining the magnitude of these changes in light of the small concentrations involved. The theory is built around the experimental evidence that the microalloying elements organise around them a neighbourhood that differs from both the crystalline and the glassy phases of the material in the absence of the additional elements. These regions act as isotropic defects that in unstressed systems modify the shear moduli. When strained, these defects interact with the incipient plastic responses which are quadrupolar in nature. It will be shown that this interaction interferes with the creation of system-spanning shear bands and increases the yield strain. We offer experimentally testable estimates of the lengths of nano-shear bands in the presence of the additional elements.     

The influence of shear bands on final structure and magnetic properties of 3% Si non-oriented silicon steel

The presence of shear bands in the deformed material before final annealing is very important for Goss and Cube textures formation in silicon steel [S.C. Paolinelli, M.A. Cunha, J. Magn. Magn. Mater. 255 (2003) pp. 379. [1]; J.T. Park, J.A. Szpunar, Acta Mater., 51 (2003) 3037. [2]]. The increase of the hot-band grain size can increase the number of shear bands, which favor the nucleation of these orientations. In this work, the effect of the hot band grain size variation, promoted by varying the hot rolling finishing temperature, on final structure and magnetic properties was investigated for 3% Si alloy. It was found that the increase of the hot-band grain size increases the occurrence of shear bands and promotes an increase of η fiber fraction and a reduction of γ fiber fraction, improving the magnetic induction. On the other hand, the final grain size is reduced when the hot-band grain size is larger than 190 μm, deteriorating the core loss values in spite of the texture benefits. The reduction of final grain size was explained by the increase of the number of nuclei at the beginning of the recrystallization caused by the increase of shear bands in the deformed material.     

Stress-induced phase transitions in diamond

A phase transformation in diamond into an intermediate carbon phase (ICP) was revealed in regions of maximal shear stress of diamond anvils. The transition was stimulated by additional stresses supplied to the compressed anvils with torque by a rotation of the anvil around the anvil's axis; maximal shear stress approached 55 GPa during the rotation. Creation of an ICP is considered as a mechanism of the stress-induced stability loss of the diamond structure. The characteristic Raman bands of ICP near 250, 500, 650–850 and 1050–1390 cm^?1 were observed in the failure regions.     

Special misorientations in localized deformation regions in Fe-3%Si alloy single crystals

Extended regions located at an angle of 20° to the rolling plane are observed inside deformation bands in a (110)[001] Fe-3%Si alloy single crystal at a high strain (～60%). These regions were interpreted earlier as shear bands. The lattice orientation in these bands is close to (110)[001], and their habit plane is parallel to the {112} planes of the deformed {111}〈112〉 matrix. The misorientations between the bands and the matrix group around special misorientations Σ9, Σ19a, Σ27a, and Σ33a, which are characterized by close angles of rotation about axis 〈110〉. During primary recrystallization, the (110)[001] grains growing from the bands retain segments of the corresponding special boundaries with the deformed matrix.     

Bifurcations to diversify geometrical patterns of shear bands on granular material

The mechanism to diversify geometrical patterns on granular material was elucidated using a group-theoretic image analysis of patterned shear bands, with associated numerical bifurcation analysis. Pattern formation of granular materials took the course of the evolution of a diamondlike diffuse bifurcation breaking uniformity, followed by further bifurcation, mode jumping, and the formation and disappearance of shear bands through localization. A chaotic explosive increase of possible postbifurcation states was emphasized as a mechanism to diversify geometrical patterns.     

Lattice reorientation in the shear bands of {112}〈131〉 crystallites in an Fe-3%Si alloy

Subregions (0.1 μm) with the {110}〈113〉 orientation form in shear bands in grains with the {112}〈131〉 orientation in a deformed (? ≈ 50%) polycrystalline Fe-3%Si alloy sample. The relationship between the matrix and the subregions in the shear bands is described by a special misorientation close to Σ5. It is assumed that the subregions that have a {110}〈hhl〉 orientation and special misorientation Σ5 with the surrounding matrix and form in the shear bands of crystallites with orientations other than {111}〈112〉 can serve as anomalous growth nuclei during heat treatment because of a high density of special Σ5 boundaries.     

Sheared solid materials

We present a time-dependent Ginzburg-Landau model of nonlinear elasticity in solid materials. We assume that the elastic energy density is a periodic function of the shear and tetragonal strains owing to the underlying lattice structure. With this new ingredient, solving the equations yields formation of dislocation dipoles or slips. In plastic flow high-density dislocations emerge at large strains to accumulate and grow into shear bands where the strains are localized. In addition to the elastic displacement, we also introduce the local free volumem. For very smallm the defect structures are metastable and long-lived where the dislocations are pinned by the Peierls potential barrier. However, if the shear modulus decreases with increasingm, accumulation ofm around dislocation cores eventually breaks the Peierls potential leading to slow relaxations in the stress and the free energy (aging). As another application of our scheme, we also study dislocation formation in two-phase alloys (coherency loss) under shear strains, where dislocations glide preferentially in the softer regions and are trapped at the interfaces.     

Shock compression of [001] single crystal silicon

Silicon is ubiquitous in our advanced technological society, yet our current understanding of change to its mechanical response at extreme pressures and strain-rates is far from complete. This is due to its brittleness, making recovery experiments difficult. High-power, short-duration, laser-driven, shock compression and recovery experiments on [001] silicon (using impedance-matched momentum traps) unveiled remarkable structural changes observed by transmission electron microscopy. As laser energy increases, corresponding to an increase in peak shock pressure, the following plastic responses are are observed: surface cleavage along {111} planes, dislocations and stacking faults; bands of amorphized material initially forming on crystallographic orientations consistent with dislocation slip; and coarse regions of amorphized material. Molecular dynamics simulations approach equivalent length and time scales to laser experiments and reveal the evolution of shock-induced partial dislocations and their crucial role in the preliminary stages of amorphization. Application of coupled hydrostatic and shear stresses produce amorphization below the hydrostatically determined critical melting pressure under dynamic shock compression.