重氢原子进入钛晶格中引起“过热”现象的量热实验

氘原子进入钛晶格后产生电解“过热”现象。对“过热”热量的准确测量是判定电解过程中是否有“过热”的重要依据。采用我们研究的大功率开放量热设备［２］，用重水进行电解实验。出现了“过热”，“过热”功率为１６－６９瓦，±０３瓦，分别为输入电功率的３０％－３２％。     

量子效应对液体水结构的影响

利用高灵敏的拉曼光谱系统地研究了由量子效应引起的轻水和重水的结构差异. 测量了5～85 oC的轻水和重水的拉曼光谱,明显地观察到两种水的拉曼光谱谱形的差别. 使用全局拟合方法分析了所有谱图的谱形,结果显示在同一个温度下重水的局部结构要比轻水的结构有序,并且他们结构上的差异随着温度的升高而减少. 另外计算了水结构差异的指标|温度漂移,从低温到高温时这个指标从28 oC减小到18 oC. 这些结构差异表明量子效应在室温范围内也非常重要. 我们还利用Vant't Hoff关系式分析了水分子相互作用能. 这些结构上的细节可以帮助建立更加可靠的水模型.     

光泵重水气体产生THz激光的半经典理论分析

从半经典密度矩阵理论出发，采用三能级系统模型对光泵重水气体产生太赫兹激光进行了理论分析，求解得到了脉冲光泵重水气体分子产生太赫兹激光过程中激光信号增益系数G_s和抽运光信号被吸收系数G_p的表达式，通过迭代法对太赫兹激光信号的输出光强进行了数值计算，理论计算得到的频谱特性曲线完全符合受激Raman辐射的频谱特性，即频谱宽度较大、输出光强随抽运失谐量的改变而变化明显等特征.在脉冲激光抽运受激Raman辐射过程中，工作介质D₂O气体分子的偶极矩由于受到抽运脉冲光场的扰动发生变化，在频谱特性曲线中表现为受激辐射THz信号的谱线发生了分裂.理论计算结果与已报道的实验结果能较好地相符.     

纯物质亚稳态机理的研究及液体过热亚稳态极限的预测

在通常条件下，物质到达该条件下的平衡相变点却没有发生相变，仍然保持相变点以前的形态，这种形态称之为物质的亚稳态。亚稳态分为过冷态和过热态，如图1所示，液体在某压力下在L点应开始蒸发为气体，液体却处于过热亚稳态，曲线CL和CO间的相区为过热区，点O是T2温度下液体过减压的极限点，也是P=Pnor=0.101325MPa下液体的过热极限点，液体状态达到O点必产爆炸式的气化，CO线就是过热极限曲线，也称旋节线。在定容条件下，液体达到过热极限时，产生爆炸式气化，在极短的时间内会产生很大压力。工程上由于过热液失稳引起的蒸汽爆炸带…     

重水分子伸缩振动谱的非线性量子理论计算

用非线性量子理论中的离散自陷方程对蒸汽态和液态重水分子在高激发态下的伸缩振动能谱进行了计算。从中发现重水分子的振动能谱分布具有许多有趣的特点。计算所得到的结果对研究重水在高压状态下的特性具有重要的应用价值。     

变温电源法分离氢同位素技术

核电站反应堆中用作中子慢化剂的重水（D2O)会通过核反应生成DTO。随着堆运行时间的增加，在重水中的DTO浓度也逐步增加，需要将重水进行处理，以除去重水中所含的氚。本项研究中，建立了一套变温气相色谱法分离氢同位素的演示实验系统。     

抽运光强度对光学抽运重水气体产生THz激光的影响分析

利用半经典理论，对脉冲光学抽运重水气体产生THz激光信号过程进行分析，对其中抽运光强度与输出THz信号光之间的关系进行了数值计算和求解，结果表明，THz信号出射光强度跟抽运源入射光强度之间不满足简单的线性关系，而是呈现高阶的非线性关系.在工作介质腔长、气压和工作温度一定的条件下，存在最佳抽运光强度，在一定的抽运光强范围内，THz信号出射光强度与抽运源入射光强度的关系呈现近似线性的增长关系，抽运光能量和信号光能量之间的转换效率相对较高，当抽运光强超过一定值时，由于瓶颈效应的发生会导致THz输出信号的逐步减弱，并产生一定的频率调谐范围.     

质谱法精密测定重水中的氢同位素丰度

介绍了用高分辨气体质谱计精密测定重水中氢同位素丰度的分析方法．实验自制了一套重水分解系统,以金属铀作还原剂,在一定的温度下还原重水为氘气．采用低温活性碳作为吸收剂,将样品分解、制备成气体试样,用高分辨气体质谱计测定重水中氢同位素丰度．该方法测定高浓度（〉99％）重水的氘丰度,测量结果的相对标准偏差不大于0．02％。     

光纤通信中有色散影响的受激喇曼散射信道特性研究

提出了在波分复用光纤通信系统中，考虑光纤色散“走离”时受激喇曼散射(SRS)信道的新模型,给出了计算中距离步长的选取公式。根据该模型，数值计算了各信道在随机数字序列调制下和在受激喇曼散射(SRS)非线性效应作用下经过有色散“走离”的波分复用光纤系统的传输功率。得出光纤色散会降低SRS效应引起的输出功率波动的结论,画出了在SRS效应作用下输出功率标准差随色散系数变化的曲线，并对产生该现象的机理进行了定性分析。该模型适合于任意光纤色散、任意输入功率和任意信道数目。     

拉曼光谱研究苯-重水间氢同位素分馏效应

应用金刚石压腔结合拉曼光谱技术研究了封闭体系内氢同位素在苯和重水之间的分馏效应。物相间达到同位素交换平衡是测定稳定同位素分馏系数的前提。与高温高压条件下水抑制正烷烃、环烷烃等烷烃的氢同位素分馏不同,苯的特殊结构可促使其在实验条件下与重水发生氢同位素分馏。通过逐步升高体系温度、增大苯和重水的接触面积、300 ℃下恒温足够长时间等实验手段促使苯和液态重水间达到氢同位素交换平衡,测得300 ℃条件下苯和重水之间的氢同位素分馏系数为0.909 9。证明了原位拉曼技术测定不同液相间氢同位素分馏系数的可行性,同时扩展了金刚石压腔结合拉曼光谱技术测定不同物相间稳定同位素分馏系数的应用范围。     

The crystal change and "excess heat" produced by long time electrolysis of heavy water with titanium cathode

According to the theory given in the paper[1], the long time electrolysis experiment with titanium cathode in heavy water (D2O) were done for many times by using the open-loop multi-parameters electrolysis calorimetry system, which is established by us. The specialty is that the cathode is titanium rod and the anode is platinum wire. The early experiment result[3] is still repeated in our recent experiment. The obvious "excess heat" phenomenon can take place only when the electrolysis last more than ten days and amount of "excess heat" increased with the electrolysis time. The "excess heat" can also be obtained from the "boiling to dry" experiment. In the recent experiment, we obtain the results that the amount of "excess heat" is about 3.6 times the input energy, the "excess heat" power is 76.5 W, and the "excess heat" power density is 121.7 W/cm3. After the electrolysis, the crystal structure of the Ti cathode was measured with x-ray diffraction apparatus. We found that the crystal structure of Ti cathode was changed to face-centered cubic structure of TiD2 from its hexagonal structure. This result is in agreement with the Gou's theory mentioned in reference[1].     

Quantum Differences between Heavy and Light Water

The structures of heavy and light water at ambient conditions are investigated with the combined techniques of x-ray diffraction, neutron diffraction, and computer simulation. It is found that heavy water is a more structured liquid than light water. We find the OH bond length in H2O is approximately 3% longer than the OD bond length in D2O. This is a much larger change than current predictions. Corresponding to this, the hydrogen bond in light water is approximately 4% shorter than in heavy water, while the intermolecular HH distance is approximately 2% longer.     

基于铟锡氧化物/Ti复合电极的高亮度碳纳米管场致发射冷阴极

通过制作亲碳性铟锡氧化物(ITO)/Ti复合电极,改善移植型碳纳米管(CNT)冷阴极的导电电极与CNT膜层之间附着性能,从而消除CNT与电极间的界面势垒和非欧姆接触对CNT阴极场发射均匀性和稳定性的影响.采用磁控溅射技术和丝网印刷工艺制作了ITO/Ti基CNT阴极.用X射线衍射仪和场致发射扫描电子显微镜表征CNT阴极结构,结果显示热处理后的ITO/Ti基CNT阴极中可能有TiC相生成,从而使得导电电极与CNT形成有中间物的强作用体系.该体系降低甚至消除电极与CNT之间的界面势垒,增加了CNT与电极间形成欧姆接触的概率.用四探针技术分析电阻率,结果表明ITO/Ti复合电极具有电阻并联效果,CNT阴极导电性能提高.场致发射特性测试表明ITO/Ti基CNT阴极的场致发射电流达到384μA/cm2,较普通ITO基CNT阴极的场致发射电流有显著提高,能够激发测试阳极发出均匀、稳定的高亮度荧光.制作ITO/Ti复合电极是实现场致发射稳定、均匀的低功耗CNT阴极的有效途径.     

Experimental study on Ti N coated racetrack-type ceramic pipe

Ti N film was coated on the internal surface of a racetrack-type ceramic pipe by three different methods:radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of Ti N film under different coating methods were compared. The highest deposition rate was 156 nm/h, which was obtained by magnetron sputtering coating. Based on AFM, SEM and XPS test results, the properties of Ti N film, such as film roughness and surface morphology, were analyzed. Furthermore, the deposition rates were studied with two different cathode types, Ti wires and Ti plate. According to the SEM test results, the deposition rate of Ti N/Ti film was about 800 nm/h with Ti plate cathode by DC magnetron sputtering. Using Ti plate cathode rather than Ti wire cathode can greatly improve the film deposition rate.     

Influence of injected plasma on oscillations of cathode luminosityin triggered vacuum breakdown

The authors report experiments performed with a triggered vacuum gap in order to investigate how plasma injected into the gap affects the frequency of oscillations in cathode luminosity during vacuum breakdown. The density of injected plasma is varied by changing the parameters of the triggering gap. Light from the main gap is recorded using an ultrafast streak camera. In all cases, streak photographs show oscillations in cathode light with a constant pulse repetition rate of about 5 ns/pulse. The injected plasma does not affect the repetition rate of cathode light pulses. Additional testing of the streak camera indicates that light pulses in a streak trace can be created very easily by electromagnetic interference. It is concluded that cathode light pulses are most likely an artifact associated with the improperly shielded streak camera     

Investigations of the Cathode Spot Dynamics in a Vacuum Arc Coating Process

Influence of cathode materials (Ti, Al, Cu, TiN), ambient gases (Ar, N₂, p = 0.1-1 Pa) and the arc current itself on the motion and the velocity of cathode spots in an arc coating process have been investigated with the help of a new high speed framing camera. It was found, that the cathode material causes different spot currents but in general the spot arrangement and the motion on the surface are similar. Surface contaminations due to ambient gases affect this dynamics in several ways. Insulating layers like AIN can drastically increase the instantaneous spot velocity, for example from <5 m/s on Al up to 170 m/s on AIN contaminated areas. TiN layers with a high conductivity increase the spot mobility at first. But at nearly completely contaminated surfaces (simulated by a TiN cathode), the mobility is strongly decreased. The values change from an average velocity of 6.3 m/s with a diffusion constant of 54 cm²/s (Ti, 0.01 Pa) to 2 m/s and 6.4 cm²/s at TiN. The course of the instantaneous spot velocity during the spot splitting phase was investigated too. The instantaneous spot velocity of each of the two new spots originated from the starting spot is relatively high (30–40 m/s) within the first 50 μs. The cathode material and the ambient gases are of slight influence in this phase. The movement is directed. In the further development the instantaneous spot velocity is decreasing to values under 5–10 m/s. The motion is now more and more random. Additionally it could be proved, that the lower stability limit for a stable discharge is strongly connected with the spot current, which depends on discharge conditions.     

超二代微光像增强器多碱光电阴极膜厚测量研究

介绍了多碱光电阴极的光学性能和光谱反射率特性,测量了多碱阴极的光谱反射率曲线.该曲线与普通光学膜层光谱反射率曲线相比,形状较不规则,原因是多碱阴极膜层存在光吸收.光谱反射率曲线上的干涉峰是入射光在玻璃与阴极膜层界面反射和在阴极膜层与真空的界面反射的两束光发生干涉的结果.根据干涉的原理,如果阴极膜层所反射的两束光的光程差为二分之一波长的偶倍数时,光谱反射将出现干涉加强峰;如果阴极膜层所反射的两束光的光程差为二分之一波长的奇倍数时,光谱反射将出现干涉减弱峰.根据超二代像增强器光谱反射干涉峰对应的波长,可以计算出其阴极膜层的厚度约为191 nm,比二代像增强器阴极膜层的厚度增加了38％.多碱阴极膜层厚度是影响多碱阴极灵敏度的一个关键参量,仅仅靠人眼观察阴极膜层颜色的方法不准确.实践证明,利用光谱反射的方法来计算阴极膜层厚度的方法简单有效.如果在多碱阴极的制作过程中进行光谱反射率的监控,那么将可以精确控制阴极膜层的厚度,对多碱阴极的研究将会更加深入,多碱阴极的灵敏度也将会得到进一步的提升.     

Determination of the specific ion erosion of the vacuum arc cathode by measuring the total ion current from the discharge plasma

The specific ion erosion γ_i of cathodes made of C, Mg, Al, Ti, Co, Cu, Y, Mo, Cd, Sm, Ta, W, Pt, Pb, and Bi is determined by measuring the total ion current from the vacuum arc plasma. It is demonstrated that the ratio of the total ion current to the discharge current, α_i in a vacuum arc varies from 5 to 19%, depending on the cathode material. It is found experimentally that the ion current fraction α_i is inversely proportional to the atomic bond energy of the cathode material. It is shown that an increase in the total ion current extracted from the discharge plasma when applying an external magnetic field to the cathode region of the discharge is related solely to the appearance of ions with higher charge numbers in the plasma, while the magnitude of the specific ion erosion γ_i remains unchanged.     

Nonequilibrium lighting plasmas

The science of a variety of devices employing nonequilibrium lightning plasmas is reviewed. The devices include the fluorescent lamp, the low-pressure sodium lamp, the neon sign, ultraviolet lamps, glow indicators, and a variety of devices used by spectroscopists, such as the hollow cathode light source. The plasma conditions in representative commercial devices are described. Recent research on the electron gas, the role of heavy particles, spatial and temporal inhomogeneities, and new electrodeless excitation schemes is reviewed. Areas of future activity are expected to be in new applications of high-frequency electronics to commercial devices, new laser-based cidiagnostics of plasma conditions, and more sophisticated models requiring more reliable and extensive rate coefficient data