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Xiaomin Ren Miao Guo He Li Chengbin Li Liang Yu Jian Liu Qihua Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(41):14530-14530
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Xiaomin Ren Miao Guo He Li Chengbin Li Liang Yu Jian Liu Qihua Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(41):14625-14630
It is a challenging task to promote the activity and selectivity of a catalyst via precisely engineering the microenvironment, an important factor related with the catalytic performance of natural catalysts. Motivated by the water effect in promoting the catalytic activity explored in this work, a nanoreactor modified with phosphine ligand enabled the efficient hydrogenation of benzoic acid (BA) over Ru nanoparticles (NPs) in organic solvent under mild conditions, which cannot be achieved in unmodified nanoreactors. Both density functional theory (DFT) calculations and catalytic performance tests showed that the phosphine ligands can manipulate the adsorption strength of BA on Ru NPs by tuning the surface properties as well as preferentially interacting with the carboxyl of BA. The insights obtained in the present study provide a novel concept of nanoreactor design by anchoring ligands near catalytically active centers. 相似文献
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Inside Cover: Coordination Assembly of Discoid Nanoparticles (Angew. Chem. Int. Ed. 31/2015) 下载免费PDF全文
Dr. Kenji Hirai Dr. Bongjun Yeom Dr. Shu‐Hao Chang Dr. Hang Chi Dr. John F. Mansfield Dr. Byeongdu Lee Sungsik Lee Prof. Ctirad Uher Prof. Dr. Nicholas A. Kotov 《Angewandte Chemie (International ed. in English)》2015,54(31):8850-8850
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Cover Picture: A Stable Single‐Site Palladium Catalyst for Hydrogenations (Angew. Chem. Int. Ed. 38/2015) 下载免费PDF全文
Gianvito Vilé Davide Albani Dr. Maarten Nachtegaal Zupeng Chen Dr. Dariya Dontsova Prof. Markus Antonietti Prof. Núria López Prof. Javier Pérez‐Ramírez 《Angewandte Chemie (International ed. in English)》2015,54(38):10987-10987