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Keisuke Nishikawa Kengo Morita Subaru Hashimoto Akihiro Hoshino Takumi Ikeuchi Momochika Kumagai Yoshiki Morimoto 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(30):10274-10278
Biomimetic epoxide‐opening cascades of polyepoxides enable the efficient and rapid construction of polyether frameworks. Herein, we show that the epoxide‐opening cascade cyclization that affords tetrahydrofuran products in acidic aqueous media produces tetrahydropyran (THP) in neutral water. THP formation proceeded by simply heating polyepoxides in neutral water and followed a different cyclization mode from those observed so far. The novel cascade cyclization in H2O was applied to the synthesis of a new nerolidol‐type sesquiterpenoid, resulting in revision of the proposed structure and determination of the absolute configuration. 相似文献
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Cover Picture: The Chemical Basis of Fungal Bioluminescence (Angew. Chem. Int. Ed. 28/2015) 下载免费PDF全文
Dr. Konstantin V. Purtov Dr. Valentin N. Petushkov Dr. Mikhail S. Baranov Dr. Konstantin S. Mineev Dr. Natalja S. Rodionova Zinaida M. Kaskova Aleksandra S. Tsarkova Dr. Alexei I. Petunin Dr. Vladimir S. Bondar Dr. Emma K. Rodicheva Dr. Svetlana E. Medvedeva Prof. Yuichi Oba Yumiko Oba Prof. Alexander S. Arseniev Prof. Sergey Lukyanov Prof. Josef I. Gitelson Dr. Ilia V. Yampolsky 《Angewandte Chemie (International ed. in English)》2015,54(28):8001-8001
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Dr. Qing Xiao Wei‐Wu Ren Zhi‐Xing Chen Tian‐Wen Sun Yong Li Qin‐Da Ye Jian‐Xian Gong Fan‐Ke Meng Lin You Yi‐Fan Liu Ming‐Zhe Zhao Ling‐Min Xu Zhen‐Hua Shan Ying Shi Prof. Dr. Ye‐Feng Tang Prof. Dr. Jia‐Hua Chen Prof. Dr. Zhen Yang 《Angewandte Chemie (International ed. in English)》2011,50(32):7195-7195
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