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1.
Synthesis of Hierarchically Porous Sandwich‐Like Carbon Materials for High‐Performance Supercapacitors
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Yiju Li Dr. Chaoji Chen Tingting Gao Dr. Dongming Zhang Dr. Xiaomei Huang Yue Pan Dr. Ke Ye Dr. Kui Cheng Dr. Dianxue Cao Dr. Guiling Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(47):16863-16871
For the first time, hierarchically porous carbon materials with a sandwich‐like structure are synthesized through a facile and efficient tri‐template approach. The hierarchically porous microstructures consist of abundant macropores and numerous micropores embedded into the crosslinked mesoporous walls. As a result, the obtained carbon material with a unique sandwich‐like structure has a relatively high specific surface (1235 m2 g?1), large pore volume (1.30 cm3 g?1), and appropriate pore size distribution. These merits lead to a comparably high specific capacitance of 274.8 F g?1 at 0.2 A g?1 and satisfying rate performance (87.7 % retention from 1 to 20 A g?1). More importantly, the symmetric supercapacitor with two identical as‐prepared carbon samples shows a superior energy density of 18.47 Wh kg?1 at a power density of 179.9 W kg?1. The asymmetric supercapacitor based on as‐obtained carbon sample and its composite with manganese dioxide (MnO2) can reach up to an energy density of 25.93 Wh kg?1 at a power density of 199.9 W kg?1. Therefore, these unique carbon material open a promising prospect for future development and utilization in the field of energy storage. 相似文献
2.
Hui Qiu Hengyang Cheng Jinku Meng Guan Wu Su Chen 《Angewandte Chemie (International ed. in English)》2020,59(20):7934-7943
Chemical architectures with an ordered porous backbone and high charge transfer are significant for fiber‐shaped supercapacitors (FSCs). However, owing to the sluggish ion kinetic diffusion and storage in compacted fibers, achieving high energy density remains a challenge. An innovative magnetothermal microfluidic method is now proposed to design hierarchical carbon polyhedrons/holey graphene (CP/HG) core–shell microfibers. Owing to highly magnetothermal etching and microfluidic reactions, the CP/HG fibers maintain an open inner‐linked ionic pathway, large specific surface area, and moderate nitrogen active site, facilitating more rapid ionic dynamic transportation and accommodation. The CP/HG FSCs show an ultrahigh energy density (335.8 μWh cm?2) and large areal capacitance (2760 mF cm?2). A self‐powered endurance application with the integration of chip‐based FSCs is designed to profoundly drive the durable motions of an electric car and walking robot. 相似文献
3.
Huile Jin Xin Feng Jun Li Matthew Li Yuanzhi Xia Yifei Yuan Chao Yang Bin Dai Zhiqun Lin Jichang Wang Jun Lu Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(8):2419-2423
The design of carbon‐based materials with a high mass density and large porosity has always been a challenging goal, since they fulfill the demands of next‐generation supercapacitors and other electrochemical devices. We report a new class of high‐density heteroatom‐doped porous carbon that can be used as an aqueous‐based supercapacitor material. The material was synthesized by an in situ dehalogenation reaction between a halogenated conjugated diene and nitrogen‐containing nucleophiles. Under the given conditions, pyridinium salts can only continue to perform the dehalogenation if there is residue water remaining from the starting materials. The obtained carbon materials are highly doped by various heteroatoms, leading to high densities, abundant multimodal pores, and an excellent volumetric capacitive performance. Porous carbon tri‐doped with nitrogen, phosphorous, and oxygen exhibits a high packing density (2.13 g cm?3) and an exceptional volumetric energy density (36.8 Wh L?1) in alkaline electrolytes, making it competitive to even some Ni‐MH cells. 相似文献
4.
Dr. Zaifang Li Guoqiang Ma Ru Ge Fei Qin Xinyun Dong Wei Meng Tiefeng Liu Jinhui Tong Fangyuan Jiang Yifeng Zhou Ke Li Xue Min Prof. Dr. Kaifu Huo Prof. Dr. Yinhua Zhou 《Angewandte Chemie (International ed. in English)》2016,55(3):979-982
Thick, uniform, easily processed, highly conductive polymer films are desirable as electrodes for solar cells as well as polymer capacitors. Here, a novel scalable strategy is developed to prepare highly conductive thick poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (HCT‐PEDOT:PSS) films with layered structure that display a conductivity of 1400 S cm?1 and a low sheet resistance of 0.59 ohm sq?1. Organic solar cells with laminated HCT‐PEDOT:PSS exhibit a performance comparable to the reference devices with vacuum‐deposited Ag top electrodes. More importantly, the HCT‐PEDOT:PSS film delivers a specific capacitance of 120 F g?1 at a current density of 0.4 A g?1. All‐solid‐state flexible symmetric supercapacitors with the HCT‐PEDOT:PSS films display a high volumetric energy density of 6.80 mWh cm?3 at a power density of 100 mW cm?3 and 3.15 mWh cm?3 at a very high power density of 16160 mW cm?3 that outperforms previous reported solid‐state supercapacitors based on PEDOT materials. 相似文献
5.
Three‐Dimensional Nitrogen‐Doped Hierarchical Porous Carbon as an Electrode for High‐Performance Supercapacitors
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Jing Tang Dr. Tao Wang Dr. Rahul R. Salunkhe Prof. Saad M. Alshehri Dr. Victor Malgras Prof. Yusuke Yamauchi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(48):17293-17298
A facile and sustainable procedure for the synthesis of nitrogen‐doped hierarchical porous carbons with a three‐dimensional interconnected framework (NHPC‐3D) was developed. The strategy, based on a colloidal crystal‐templating method, utilizes nitrogenous dopamine as the precursor due to its unique properties, including self‐polymerization under mild alkaline conditions, coating onto various surfaces, a high carbonization yield, and well‐preserved nitrogen doping after heat treatment. The obtained NHPC‐3D possesses a high surface area of 1056 m2 g?1, a large pore volume of 2.56 cm3 g?1, and a high nitrogen content of 8.2 wt %. The NHPC‐3D is implemented as the electrode material of a supercapacitor and exhibits a specific capacitance as high as 252 F g?1 at a current density of 2 A g?1. The device also shows a high capacitance retention of 75.7 % at a higher current density of 20 A g?1 in aqueous electrolyte due to a sufficient surface area for charge accommodation, reversible pseudocapacitance, and minimized ion‐transport resistance, as a result of the advantageous interconnected hierarchical porous texture. These results showcase NHPC‐3D as a promising candidate for electrode materials in supercapacitors. 相似文献
6.
Guiyin Xu Bing Ding Ping Nie Laifa Shen Jie Wang Prof. Xiaogang Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(37):12306-12312
Porous nitrogen‐doped carbon nanotubes (PNCNTs) with a high specific surface area (1765 m2 g?1) and a large pore volume (1.28 cm3 g?1) have been synthesized from a tubular polypyrrole (T‐PPY). The inner diameter and wall thickness of the PNCNTs are about 55 nm and 22 nm, respectively. This material shows extremely promising properties for both supercapacitors and for encapsulating sulfur as a superior cathode material for high‐performance lithium–sulfur (Li‐S) batteries. At a current density of 0.5 A g?1, PNCNT presents a high specific capacitance of 210 F g?1, as well as excellent cycling stability at a current density of 2 A g?1. When the S/PNCNT composite was tested as the cathode material for Li‐S batteries, the initial discharge capacity was 1341 mAh g?1 at a current rate of 1 C and, even after 50 cycles at the same rate, the high reversible capacity was retained at 933 mAh g?1. The promising electrochemical energy‐storage performance of the PNCNTs can be attributed to their excellent conductivity, large surface area, nitrogen doping, and unique pore‐size distribution. 相似文献
7.
Wanwan Li Fengxian Gao Xiaoqian Wang Dr. Ning Zhang Prof. Dr. Mingming Ma 《Angewandte Chemie (International ed. in English)》2016,55(32):9196-9201
We report a supramolecular strategy to prepare conductive hydrogels with outstanding mechanical and electrochemical properties, which are utilized for flexible solid‐state supercapacitors (SCs) with high performance. The supramolecular assembly of polyaniline and polyvinyl alcohol through dynamic boronate bond yields the polyaniline–polyvinyl alcohol hydrogel (PPH), which shows remarkable tensile strength (5.3 MPa) and electrochemical capacitance (928 F g?1). The flexible solid‐state supercapacitor based on PPH provides a large capacitance (306 mF cm?2 and 153 F g?1) and a high energy density of 13.6 Wh kg?1, superior to other flexible supercapacitors. The robustness of the PPH‐based supercapacitor is demonstrated by the 100 % capacitance retention after 1000 mechanical folding cycles, and the 90 % capacitance retention after 1000 galvanostatic charge–discharge cycles. The high activity and robustness enable the PPH‐based supercapacitor as a promising power device for flexible electronics. 相似文献
8.
Biomass‐Derived Porous Carbon with Micropores and Small Mesopores for High‐Performance Lithium–Sulfur Batteries
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Kai Yang Prof. Qiuming Gao Yanli Tan Weiqian Tian Weiwei Qian Lihua Zhu Chunxiao Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(10):3239-3244
Biomass‐derived porous carbon BPC‐700, incorporating micropores and small mesopores, was prepared through pyrolysis of banana peel followed by activation with KOH. A high specific BET surface area (2741 m2 g?1), large specific pore volume (1.23 cm3 g?1), and well‐controlled pore size distribution (0.6–5.0 nm) were obtained and up to 65 wt % sulfur content could be loaded into the pores of the BPC‐700 sample. When the resultant C/S composite, BPC‐700‐S65, was used as the cathode of a Li–S battery, a large initial discharge capacity (ca. 1200 mAh g?1) was obtained, indicating a good sulfur utilization rate. An excellent discharge capacity (590 mAh g?1) was also achieved for BPC‐700‐S65 at the high current rate of 4 C (12.72 mA cm?2), showing its extremely high rate capability. A reversible capacity of about 570 mAh g?1 was achieved for BPC‐700‐S65 after 500 cycles at 1 C (3.18 mA cm?2), indicating an outstanding cycling stability. 相似文献
9.
Conductive Microporous Covalent Triazine‐Based Framework for High‐Performance Electrochemical Capacitive Energy Storage
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Yajuan Li Shuanghao Zheng Xue Liu Pan Li Dr. Lei Sun Ruixia Yang Sen Wang Prof. Dr. Zhong‐Shuai Wu Prof. Dr. Xinhe Bao Prof. Dr. Wei‐Qiao Deng 《Angewandte Chemie (International ed. in English)》2018,57(27):7992-7996
Nitrogen‐enriched porous nanocarbon, graphene, and conductive polymers attract increasing attention for application in supercapacitors. However, electrode materials with a large specific surface area (SSA) and a high nitrogen doping concentration, which is needed for excellent supercapacitors, has not been achieved thus far. Herein, we developed a class of tetracyanoquinodimethane‐derived conductive microporous covalent triazine‐based frameworks (TCNQ‐CTFs) with both high nitrogen content (>8 %) and large SSA (>3600 m2 g?1). These CTFs exhibited excellent specific capacitances with the highest value exceeding 380 F g?1, considerable energy density of 42.8 Wh kg?1, and remarkable cycling stability without any capacitance degradation after 10 000 cycles. This class of CTFs should hold a great potential as high‐performance electrode material for electrochemical energy‐storage systems. 相似文献
10.
Hao Tian Jieqiong Qin Dan Hou Qian Li Chen Li Zhong‐Shuai Wu Yiyong Mai 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(30):10279-10284
Free‐standing 2D porous nanomaterials have attracted considerable interest as ideal candidates of 2D film electrodes for planar energy storage devices. Nevertheless, the construction of well‐defined mesopore arrays parallel to the lateral surface, which facilitate fast in‐plane ionic diffusion, is a challenge. Now, a universal interface self‐assembly strategy is used for patterning 2D porous polymers, for example, polypyrrole, polyaniline, and polydopamine, with cylindrical mesopores on graphene nanosheets. The resultant 2D sandwich‐structured nanohybrids are employed as the interdigital microelectrodes for the assembly of planar micro‐supercapacitors (MSCs), which deliver outstanding volumetric capacitance of 102 F cm?3 and energy density of 2.3 mWh cm?3, outperforming most reported MSCs. The MSCs display remarkable flexibility and superior integration for boosting output voltage and capacitance. 相似文献
11.
Wen Lu Junling Shen Peng Zhang Yijun Zhong Yong Hu Xiong Wen Lou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(43):15587-15593
Hierarchical hollow structures for electrode materials of supercapacitors could enlarge the surface area, accelerate the transport of ions and electrons, and accommodate volume expansion during cycling. Besides, construction of heterostructures would enhance the internal electric fields to regulate the electronic structures. All these features of hierarchical hollow heterostructures are beneficial for promoting the electrochemical properties and stability of electrode materials for high‐performance supercapacitors. Herein, CoO/Co‐Cu‐S hierarchical tubular heterostructures (HTHSs) composed of nanoneedles are prepared by an efficient multi‐step approach. The optimized sample exhibits a high specific capacity of 320 mAh g?1 (2300 F g?1) at 2.0 A g?1 and outstanding cycling stability with 96.5 % of the initial capacity retained after 5000 cycles at 10 A g?1. Moreover, an all‐solid‐state hybrid supercapacitor (HSC) constructed with the CoO/Co‐Cu‐S and actived carbon shows a stable and high energy density of 90.7 Wh kg?1 at a power density of 800 W kg?1. 相似文献
12.
Realizing both High Energy and High Power Densities by Twisting Three Carbon‐Nanotube‐Based Hybrid Fibers
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Ye Zhang Yang Zhao Dr. Xunliang Cheng Dr. Wei Weng Jing Ren Xin Fang Yishu Jiang Peining Chen Zhitao Zhang Prof. Yonggang Wang Prof. Huisheng Peng 《Angewandte Chemie (International ed. in English)》2015,54(38):11177-11182
Energy storage devices, such as lithium‐ion batteries and supercapacitors, are required for the modern electronics. However, the intrinsic characteristics of low power densities in batteries and low energy densities in supercapacitors have limited their applications. How to simultaneously realize high energy and power densities in one device remains a challenge. Herein a fiber‐shaped hybrid energy‐storage device (FESD) formed by twisting three carbon nanotube hybrid fibers demonstrates both high energy and power densities. For the FESD, the energy density (50 mWh cm?3 or 90 Wh kg?1) many times higher than for other forms of supercapacitors and approximately 3 times that of thin‐film batteries; the power density (1 W cm?3 or 5970 W kg?1) is approximately 140 times of thin‐film lithium‐ion battery. The FESD is flexible, weaveable and wearable, which offers promising advantages in the modern electronics. 相似文献
13.
Kinetically Controlled Assembly of Nitrogen‐Doped Invaginated Carbon Nanospheres with Tunable Mesopores
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Yang Liu Dr. Hongwei Zhang Owen Noonan Chun Xu Dr. Yuting Niu Yannan Yang Prof. Liang Zhou Dr. Xiaodan Huang Prof. Chengzhong Yu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(42):14962-14967
Mesoporous hollow carbon nanospheres (MHCS) have been extensively studied owning to their unique structural features and diverse potential applications. A surfactant‐free self‐assembly approach between resorcinol/formaldehyde and silicon alkoxide has emerged as an important strategy to prepare MHCS. Extending such a strategy to other substituted phenols to produce heterogeneous‐atom‐doped MHCS remains a challenge due to the very different polymerization kinetics of various resins. Herein, we report an ethylenediamine‐assisted strategy to control the cooperative self‐assembly between a 3‐aminophenol/formaldehyde resin and silica templates. Nitrogen‐doped mesoporous invaginated carbon nanospheres (N‐MICS) with an N content of 6.18 at %, high specific surface areas (up to 1118 m2 g?1), large pore volumes (2.47 cm3 g?1), and tunable mesopores (3.7–11.1 nm) have been prepared. When used as electrical double‐layer supercapacitors, N‐MICS show a high capacitance of 261 F g?1, an outstanding cycling stability (≈94 % capacitance retention after 10 000 cycles), and a good rate performance. 相似文献
14.
Rational Design of Ni Nanoparticles on N‐Rich Ultrathin Carbon Nanosheets for High‐Performance Supercapacitor Materials: Embedded‐ Versus Anchored‐Type Dispersion
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Mei Yang Yiren Zhong Dr. Liwei Su Prof. Jinping Wei Prof. Zhen Zhou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(17):5046-5053
Highly dispersed Ni nanoparticles (NPs) and abundant functional N‐species were integrated into ultrathin carbon nanosheets by using a facile and economical sol–gel route. Embedded‐ and anchored‐type configurations were achieved for the dispersion of Ni NPs in/on N‐rich carbon nanosheets. The anchored‐type composite exhibited outstanding pseudocapacitance of 2200 F g?1 at 5 A g?1 with unusual rate capability and extraordinary cyclic stability over 20 000 cycles with little capacitance decay. Aqueous asymmetric supercapacitors fabricated with this composite cathode demonstrated a high energy density of 51.3 Wh kg?1 at a relatively large power density of 421.6 W kg?1, along with outstanding cyclic stability. This approach opens an attractive direction for enhancing the electrochemical performances of metal‐based supercapacitors and can be generalized to design high‐performance energy‐storage devices. 相似文献
15.
Self‐Assembling Synthesis of Free‐standing Nanoporous Graphene–Transition‐Metal Oxide Flexible Electrodes for High‐Performance Lithium‐Ion Batteries and Supercapacitors
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The synthesis of nanoporous graphene by a convenient carbon nanofiber assisted self‐assembly approach is reported. Porous structures with large pore volumes, high surface areas, and well‐controlled pore sizes were achieved by employing spherical silica as hard templates with different diameters. Through a general wet‐immersion method, transition‐metal oxide (Fe3O4, Co3O4, NiO) nanocrystals can be easily loaded into nanoporous graphene papers to form three‐dimensional flexible nanoarchitectures. When directly applied as electrodes in lithium‐ion batteries and supercapacitors, the materials exhibited superior electrochemical performances, including an ultra‐high specific capacity, an extended long cycle life, and a high rate capability. In particular, nanoporous Fe3O4–graphene composites can deliver a reversible specific capacity of 1427.5 mAh g?1 at a high current density of 1000 mA g?1 as anode materials in lithium‐ion batteries. Furthermore, nanoporous Co3O4–graphene composites achieved a high supercapacitance of 424.2 F g?1. This work demonstrated that the as‐developed freestanding nanoporous graphene papers could have significant potential for energy storage and conversion applications. 相似文献
16.
Min Du Dian Song Aoming Huang Ruixuan Chen Danqing Jin Kun Rui Chao Zhang Jixin Zhu Wei Huang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(16):5361-5365
Cost‐effective metal‐based nanostructured hybrids have been widely dedicated to potential energy storage and conversion applications. Herein, we develop a facile methodology for the synthesis of precise carbon‐confined hybrid nanostructures by stereoselective assembly accompanied by catalytic pyrolysis. Polyacrylonitrile fiber films favors not only metal‐polymer coordination, but also oriented assembly to ensure the well‐defined nanostructure of the carbon hybrids. During chemical vapor deposition (CVD), cobalt‐nanoparticle‐catalyzed growth of carbon‐nanotube branches driven by organic molecules (e.g. melamine) delivers hierarchical carbon hybrids. The resulting carbon hybrids exhibit outstanding electrochemical performance for metal‐ion batteries, for example, a high specific capacity of 680 mAh g?1 after 320 cycles (Li‐storage) and 220 mAh g?1 after 500 cycles (Na‐storage) without decay. 相似文献
17.
Carbon‐based supercapacitors are a kind of supercapacitors with very promising applications because of their low cost, good stability and adjustable properties. Simple and rapid syntheses of carbon materials with a high surface area and narrow pore size distribution are of great significance to practical applications of carbon‐based supercapacitors. Here we report a new strategy to synthesize sub‐nanometer porous carbon films (Snp‐CF) via a condensation reaction under mild conditions. Carbon films exhibit a narrow pore size distribution (6.6 Å) and high surface area (508 m2 g?1) after annealing at 700 °C. Snp‐CF‐700 displays a good specific capacity and excellent cycle performance (130 F g?1 after 5000 cycles, 118 % of initial 110 F g?1). 相似文献
18.
Chaohai Wang Jeonghun Kim Jing Tang Jongbeom Na Yong‐Mook Kang Minjun Kim Hyunsoo Lim Yoshio Bando Jiansheng Li Yusuke Yamauchi 《Angewandte Chemie (International ed. in English)》2020,59(5):2066-2070
Carbon aerogels (CAs) with 3D interconnected networks hold promise for application in areas such as pollutant treatment, energy storage, and electrocatalysis. In spite of this, it remains challenging to synthesize high‐performance CAs on a large scale in a simple and sustainable manner. We report an eco‐friendly method for the scalable synthesis of ultralight and superporous CAs by using cheap and widely available agarose (AG) biomass as the carbon precursor. Zeolitic imidazolate framework‐8 (ZIF‐8) with high porosity is introduced into the AG aerogels to increase the specific surface area and enable heteroatom doping. After pyrolysis under inert atmosphere, the ZIF‐8/AG‐derived nitrogen‐doped CAs show a highly interconnected porous mazelike structure with a low density of 24 mg cm?3, a high specific surface area of 516 m2 g?1, and a large pore volume of 0.58 cm?3 g?1. The resulting CAs exhibit significant potential for application in the adsorption of organic pollutants. 相似文献
19.
Design of Advanced MnO/N‐Gr 3D Walls through Polymer Cross‐Linking for High‐Performance Supercapacitor
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Ngoc Quang Tran Dr. Bong Kyun Kang Sintayehu Nibret Tiruneh Prof. Dae Ho Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(5):1652-1657
Three‐dimensional, vertically aligned MnO/nitrogen‐doped graphene (3D MnO/N‐Gr) walls were prepared through facile solution‐phase synthesis followed by thermal treatment. Polyvinylpyrrolidone (PVP) was strategically added to generate cross‐links to simultaneously form 3D wall structures and to incorporate nitrogen atoms into the graphene network. The unique wall features of the as‐prepared 3D MnO/N‐Gr hybirdes provide a large surface area (91.516 m2 g?1) and allow for rapid diffusion of the ion electrolyte, resulting in a high specific capacitance of 378 F g?1 at 0.25 A g?1 and an excellent charge/discharge stability (93.7 % capacity retention after 8000 cycles) in aqueous 1 m Na2SO4 solution as electrolyte. Moreover, the symmetric supercapacitors that were rationally designed by using 3D MnO/N‐Gr hybrids exhibit outstanding electrochemical performance in an organic electrolyte with an energy density of 90.6 Wh kg?1 and a power density of 437.5 W kg?1. 相似文献
20.
Man Jiang Jingli Zhang Lingbao Xing Jin Zhou Hongyou Cui Weijiang Si Shuping Zhuo 《中国化学》2016,34(11):1093-1102
Porous carbons (PC) were prepared from a waste biomass named chestnut shell via a two‐step method involving carbonization and KOH activation. The morphology, pore structure and surface chemical properties were investigated by scanning electron microscopy (SEM), N2 sorption, Raman spectroscopy, X‐ray diffraction (XRD) and X‐ray photoelectron spectroscopy (XPS). The carbons have been evaluated as the electrode materials for supercapacitors by a two‐electrode system in 6 mol/L KOH electrolyte. Benefiting from the porous texture, high surface area and high oxygen content, the PCs derived from chestnut shell have exhibited high specific capacitance of 198.2 (PC‐1), 217.2 (PC‐2) and 238.2 F·g?1 (PC‐3) at a current density of 0.1 A·g?1, good rate capability of 55.7%, 56.6% and 54.9% in a range of 0.1–20 A·g?1 and high energy density of 5.6, 6.1 and 6.7 Wh·kg?1, respectively. This is believed to be due to electric double layer capacitance induced by the abundant micropores and extra pseudo‐capacitance generated by oxygen‐containing groups. At a power density of 9000 Wh·kg?1, the energy density is 3.1, 3.5 and 3.7 Wh·kg?1 for PC‐1, PC‐2 and PC‐3, respectively, demonstrating the potential of the carbons derived from chestnut shells in energy storage devices. 相似文献