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Ralf Riedel 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2002,114(14):2721-2723
Die Übersetzung basiert auf der „Terminology for Compounds in the Si‐Al‐O‐N System“ der Commission on High Temperature Materials and Solid State Chemistry der Inorganic Chemistry Division der International Union of Pure and Applied Chemistry, veröffentlicht in Pure Appl. Chem. 1999 , 71, 1765–1769. Das Original wurde von R. Metselaar, Technische Universiteit Eindhoven (Niederlande) und D. S. Yan, Academia Sinica, Shanghai (China) für die Veröffentlichung vorbereitet. 相似文献
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Wolfgang Schmitt Christopher E. Anson Bernd Pilawa Annie K. Powell 《无机化学与普通化学杂志》2002,628(11):2443-2457
Investigation of the Hydrolytic Build‐up of Iron(III)‐Oxo‐Aggregates The synthesis and structures of five new iron/hpdta complexes [{FeIII4(μ‐O)(μ‐OH)(hpdta)2(H2O)4}2FeII(H2O)4]·21H2O ( 2 ), (pipH2)2[Fe2(hpdta)2]·8H2O ( 4 ), (NH4)4[Fe6(μ‐O)(μ‐OH)5(hpdta)3]·20.5H2O ( 5 ), (pipH2)1.5[Fe4(μ‐O)(μ‐OH)3(hpdta)2]·6H2O ( 7 ), [{Fe6(μ3‐O)2(μ‐OH)2(hpdta)2(H4hpdta)2}2]·py·50H2O ( 9 ) are described and the formation of these is discussed in the context of other previously published hpdta‐complexes (H5hpdta = 2‐Hydroxypropane‐1, 3‐diamine‐N, N, N′, N′‐tetraacetic acid). Terminal water ligands are important for the successive build‐up of higher nuclearity oxy/hydroxy bridged aggregates as well as for the activation of substrates such as DMA and CO2. The formation of the compounds under hydrolytic conditions formally results from condensation reactions. The magnetic behaviour can be quantified analogously up to the hexanuclear aggregate 5 . The iron(III) atoms in 1 ‐ 7 are antiferromagnetically coupled giving rise to S = 0 spin ground states. In the dodecanuclear iron(III) aggregate 9 we observe the encapsulation of inorganic ionic fragments by dimeric{M2hpdta}‐units as we recently reported for AlIII/hpdta‐system. 相似文献
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Alexander Hoffmann Stephan Binder Anton Jesser Roxana Haase Ulrich Flrke Manuel Gnida Marco SalomoneStagni Wolfram Meyer‐Klaucke Benjamin Lebsanft Lara Elena Grünig Simon Schneider Maryam Hashemi Arne Goos Alina Wetzel Michael Rübhausen Sonja Herres‐Pawlis 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(1):305-310
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