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1.
Mariusz Majchrzak Monika Ludwiczak Malgorzata Bayda Bronislaw Marciniak Bogdan Marciniec 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):127-137
The novel trans‐stereo‐regular silylene–thiophene derivatives ( 4 , 5 ) with perfect consecutive silylene–arylene–silylene–vinylene linkage were synthesized via silylative coupling polycondensation of 2,5‐bis(vinyldimethylsilyl)thiophene ( 2 ) or 5,5′‐bis(vinyldimethylsilyl)‐2,2′‐bithiophene ( 3 ) catalyzed by ruthenium‐hydride complex [RuHCl(CO)(PCy3)2] ( 1 ). Their spectroscopic, absorption, and luminescence properties were characterized and compared with those of model compounds containing thiophene or bithiophene chromophores. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 127–137, 2008 相似文献
2.
Torsten W. Bünnagel Benjamin S. Nehls Frank Galbrecht Kristina Schottler Christof J. Kudla Markus Volk João Pina João S. Seixas de Melo Hugh D. Burrows Ullrich SCherf 《Journal of polymer science. Part A, Polymer chemistry》2008,46(22):7342-7353
A series of step‐ladder copolymers based on thiophene–phenylene–thiophene SL1 ‐ SL3 and thiophene–naphthylene–thiophene SL4 repeat units with varying lengths of the oligothiophene segment has been designed and synthesized via a microwave‐assisted Stille‐type cross‐coupling reaction followed by a polymer‐analogous cyclization reaction. The optical properties of the step‐ladder copolymers have been investigated in detail, in particular at low temperature and in the solid‐state. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7342–7353, 2008 相似文献
3.
Hong‐Yu Wang Jun‐Hua Wan Hong‐Ji Jiang Gui‐An Wen Jia‐Chun Feng Zhi‐Jian Zhang Bo Peng Wei Huang Wei Wei 《Journal of polymer science. Part A, Polymer chemistry》2007,45(6):1066-1073
The cross‐shaped p–n diblock oligomers based on oligothiophenes (OTs) and 1,3,4‐oxadiazole (OXD) were synthesized and investigated regarding optical properties, electrochemistry, quantum chemical calculations, and intramolecular energy transfer. Since only one emission peak is observed in PL spectra of the oligomers, it is evidenced that effective energy transfer from the OXD to OTs branch. The electrochemical experiments show that almost complete spatial separation of HOMO and LUMO with the thiophene number increasing. The theoretical calculations were carried out regarding which conformer is the lowest in energy, the torsion angle between thiophene/oxadiazole and the central benzene ring, and electron densities distributions of the oligomers. Based on all data, a model for intramolecular energy‐transfer process has been put forward to explain the optical properties. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1066–1073, 2007 相似文献
4.
Muhammad Zareef Rashid Iqbal Najim A. Al‐Masoudi Javid H. Zaidi Muhammad Arfan 《Heteroatom Chemistry》2007,18(4):425-431
New benzenesulfonamides, most of which are chiral, incorporating 1,3,4‐oxadiazole, and selected amino acid entities have been synthesized, using the microwave irradiation method. Most of the synthesized compounds were tested against HIV activity. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:425–431, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20316 相似文献
5.
Exploring novel poly(thiophene‐3‐yl‐amine) through facile self acid assisted‐polycondensation
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Kang Jiang Xi Cheng Xinyi Cai Shozo Yanagida Jiangbin Xia 《Journal of polymer science. Part A, Polymer chemistry》2017,55(24):4003-4012
Aromatic moieties of benzene and pyridine as side chains for poly(thiophene‐3‐yl‐amine) are rationally designed and synthesized by facile self acid‐assisted polycondensation (SAAP). Nitrogen atom is the key atom to form ammonium cation which guarantees SAAP success while other aromatic moieties are chosen carefully to attach on N atom to functionalize poly(thiophene‐3‐yl‐amine) matrix. Our results indicate that thiophene‐3‐yl‐amine is an excellent platform to construct plenty of functionalized monomers candidates for SAAP. Our study would push SAAP or AAP scope forward and pave the way to explore much more polythiophene derivatives. Furthermore, DFT calculation is carried out to deep understand AAP mechanism. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 4003–4012 相似文献
6.
Justin E. Cochran Elizabeth Amir Kulandaivelu Sivanandan Sung‐Yu Ku Jung Hwa Seo Brian A. Collins John R. Tumbleston Michael F. Toney Harald Ade Craig J. Hawker Michael L. Chabinyc 《Journal of Polymer Science.Polymer Physics》2013,51(1):48-56
An alkylated semiconducting polymer comprising alternating bithiophene‐[all]‐S,S‐dioxide and aromatic monothiophene units in the polymer backbone was synthesized with the intent of modifying the energy gap and lowest unoccupied molecular orbital for use as a stable n‐type semiconductor. Films spun from this semiconducting polymer were characterized utilizing X‐ray scattering, near edge X‐ray absorption fine structure spectroscopy, ultraviolet photoelectron spectroscopy, and thin‐film field effect transistors to determine how oxidation of the thiophene ring systems impacts the structural and electronic properties of the polymer. The thiophene‐S,S‐dioxide polymers have lower optical and electrical band gaps than corresponding thiophene polymers. X‐ray scattering results indicate that the polymers are well ordered with the π–π stacking distances increased by 0.4 Å relative to analogous thiophene polymers. The electrical stability of these polymers is poor in transistors with a drop in the field effect mobility by approximately one order of magnitude upon addition of just 5% of the thiophene‐S,S‐dioxide unit in a copolymer with thiophene. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013 相似文献
7.
A series of 4‐aryl‐5‐phenylimino‐3‐S‐(hepta‐O‐acetyl lactosyl)‐1,2,4‐thiadiazolines have been synthesized by the interaction of S‐(hepta‐O‐acetyl lactosyl)‐1‐arylisothiocarbamides and S‐chloro‐N‐phenyl isothiocarbamoyl chloride. The title compounds were characterized on the basis of elemental analysis and IR, NMR, mass spectral studies. The title compounds exhibited comparable antimicrobial activities against pathogens such as E. coli, S. aureus, P. vulgaris, S. typhi, A. niger, and Candida guilliermondii. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:390–392, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20310 相似文献
8.
Palas Baran Pati Soumyajit Das Sanjio S. Zade 《Journal of polymer science. Part A, Polymer chemistry》2012,50(19):3996-4003
Four D–A–D type co‐oligomers have been synthesized by Stille condensation between monostannyl derivatives of furan/thiophene/selenophene/3,4‐ethylenedioxythiophene (EDOT) and 4,7‐dibromo‐benzo[1,2,5]oxadiazole. All these co‐oligomers were successfully electrochemically polymerized in dichloromethane and characterized by spectroelectrochemistry. All four polymers possess narrow optical band gap. Spectroelectrochemical studies of polymer films on indium tin oxide revealed that the replacement of donor EDOT with furan/thiophene/selenophene has affected the low‐energy charge‐carrier (bipolaron) formation significantly. Kinetic studies based on chronoamperometry show that the polymer P5 (EDOT‐capped benzo[1,2,5]oxadiazole system) possess better electrochromic property with high transmittance (66%) in visible region than the other copolymers. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
9.
Reaction of ethyl 2‐diazo‐4,5,6,7‐tetrahydrobenzo[b]thiophene‐3‐carboxylate 1 with 3‐iminobutyronitrile 2 gave the hydrazone derivative 3 . The reactivity of the latter product toward a variety of chemical reagents as well as the biological activity of the newly synthesized products were studied. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:403–412, 2000 相似文献
10.
A series of new thermoplastic polyesters based on 3,4‐ethylenedioxythiophene (EDOT) with flexible aliphatic spacers have been synthesized and characterized for the first time. The thermal properties of these polyesters based on EDOT are comparable to those of conventional polyesters based on the 1,4‐phenyl unit, indicating that EDOT is a viable replacement for the phenyl units. The glass‐transition and melting‐transition temperatures decrease monotonically with an increase in the spacer length. Theoretical calculations have revealed that the core angle for EDOT is comparable to that of unsubstituted thiophene and hence should be compatible with the formation of the mesophase. This has been confirmed experimentally by the synthesis of a main‐chain, thermotropic, liquid‐crystalline polyester based on EDOT that exhibits fluid birefringence. In fact, this is the first report in which a main‐chain, liquid‐crystalline polymer based on 3,4‐disubstituted thiophene has been successfully designed and synthesized. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3479–3486, 2006 相似文献
11.
Erjun Zhou Zhan'ao Tan Youjun He Chunhe Yang Yongfang Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(4):629-638
Two alternating poly[3‐(hex‐1‐enyl)thiophene‐co‐thiophene]s, Pa (with 77% trans‐isomer and 23% cis‐isomer) and Pb (with 100% trans‐isomer), were synthesized by the coupling of 2,5‐dibromo‐3‐hex‐1‐enyl‐thiophene to 2,5‐bis(tributylstannyl)thiophene via a Stille reaction and compared with poly(3‐hexylthiophene‐co‐thiophene) ( P1 ) to study the effect of changing the carbon(α)–carbon(β) single bond into a carbon–carbon double bond on the properties of the polymers. From P1 to Pb and to Pa , the ultraviolet–visible absorption peaks of the polymers were slightly redshifted, and their electrochemical bandgaps decreased by 0.05–0.1 eV. X‐ray diffraction analysis indicated that Pa had a better lamellar structure than Pb . The hole mobilities of the three polymers, determined with the space‐charge‐limited current model, were 5.23 × 10?6 ( P1 ), 2.34 × 10?4 ( Pb ), and 7.02 × 10?4 cm2/V s ( Pa ). The power conversion efficiencies (PCEs) of polymer solar cells based on the three polymers were 0.87 ( P1 ), 1.16 ( Pb ), and 1.70% ( Pa ). The increase in the hole mobility and PCE revealed the important effect of changing the carbon(α)–carbon(β) single bond into a carbon–carbon double bond on the properties of polythiophene derivatives containing 3‐alkylthiophene. The strategy used in this work enlarges the thinking to obtain novel, efficient donor polymers for optoelectronic applications. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 629–638, 2007 相似文献
12.
A new p‐phenylene–vinylene–thiophene‐based siloxane block copolymer has been synthesized. The copolymer consists of alternating rigid and flexible blocks. The rigid blocks are composed of phenylene–vinylene–thiophene‐based units, and the flexible blocks are derived from 1,3‐dialkyldisiloxane units. The former component acts as the chromophore, and allows fine tuning of band gap for blue‐light emission, while the latter imparts good solubility of the copolymer in organic solvents, and thus, should enhance processibility of the resulting copolymer. The thermal properties of the copolymer have been characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The photoluminescence (PL) of the copolymer in solution and in cast film has been studied. The effects of concentration on the PL intensity of the new copolymer in polymer blends with poly(methyl methacrylate) (PMMA) and poly(vinyl carbazole) (PVK) have also been described. Efficient energy transfer from PVK to the new block copolymer in the blended film was observed. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1450–1456, 2000 相似文献
13.
Antonio Roviello Annamaria Buono Antonio Carella Giuseppina Roviello Antonio Cassinese Mario Barra Mariano Biasucci 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1758-1770
An easy synthetic procedure for soluble poly[3‐(4‐alcoxyphenyl)thiophene]s is reported. The polymers present a high regioregularity degree as determined by both UV–vis spectra and 1H and 13C NMR analysis. Furthermore, X‐ray powder diffraction analysis performed on films of the polymers suggests a π‐stacked packing structure of the macromolecules. Electrical characterization was performed on one of the synthesized polythiophenes on both undoped and doped (with FeCl3 or iodine) films. The conductivity and charge‐carrier mobility were assessed by current–voltage and field effect measurements. Well‐structured polymer films were obtained simply via spin coating from chloroform solutions and without the need of further processing, unlike other regioregular polythiophenes reported in the literature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1758–1770, 2007 相似文献
14.
Alaa A. Hassan Nasr K. Mohamed Lamiaa E. Abd El‐Haleem Stefan Bräse Martin Nieger 《Journal of heterocyclic chemistry》2015,52(5):1368-1372
A series of (Z)‐methyl‐2‐[(Z)‐3‐substituted‐4‐oxo‐2‐(2‐picolinoyl‐/thiophene‐2‐carbonyl)‐hydrazonothiazolidin‐5‐ylidene]acetates were synthesized by condensation N‐substituted‐(2‐picolinoyl‐, thiophene‐2‐carbonyl)hydrazinecarbothioamides with dimethylacetylenedicarboxylate. The structure of thiazolidin‐4‐one derivatives has been confirmed unambiguously by single crystal X‐ray crystallography. 相似文献
15.
A new method for linear polymerization of maleimides via the Diels–Alder reaction has been developed. This method involves use of a new cross‐linking agent, benzene‐3,4‐dimethylenesuccinimide, which can be generated in situ from its thiophene precursor, benzene‐2,5‐dihydrothiophene‐3,4‐dicarboximide‐S,S‐dioxide. This new cross‐linking agent is reasonably reactive, readily prepared, and stable at room temperature. A controlled molecular weight oligomer has been synthesized and applied to the polymerization to yield a highly thermal stable polyimide. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:648–652, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20249 相似文献
16.
Synthesis of 7‐chloro‐9‐trifluoromethyl‐/7‐fluorophenothiazines is reported by Smiles rearrangement of 5‐chloro‐3‐trifluoromethyl‐/5‐fluoro‐2‐formamido‐2′‐nitrodiphenyl sulfides. The later were obtained by the formylation of 2‐amino‐5‐chloro‐7‐trifluoromethyl‐/5‐fluoro‐2′‐nitrodiphenyl sulfides, which were prepared by the condensation of 2‐amino‐5‐fluoro‐/5‐chloro‐3‐trifluoromethyl benzenethiols with o‐halonitrobenzenes. 1‐Nitrophenothiazines have also been synthesized by the condensation of 2‐aminobenzenethiols with o‐halonitrobenzenes, involving Smiles rearrangement in situ. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:81–86, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20235 相似文献
17.
《Journal of polymer science. Part A, Polymer chemistry》2018,56(13):1457-1467
Conjugated copolymers based on benzodithiophene (BDT) derivatives and thiophene‐quinoxaline‐thiophene (TQT) segments represent an efficient class of light harvesting materials for organic photovoltaic (OPV) applications. Commonly, BDT‐TQT copolymers are synthesized by Stille cross‐coupling polymerization. In this study, alkoxy and thienyl functionalized alternating BDT‐alt‐TQT copolymers are synthesized by direct arylation polymerization (DArP), using Ozawa conditions. An extensive optimization of the reaction conditions such as the catalytic system, solvent, temperature, base, and the concentration of the catalyst is accomplished. The optical and electrochemical properties of the copolymers obtained by DArP are compared to the reference polymers synthesized by Stille cross‐coupling polymerization. Finally, the optimized BDT‐alt‐TQT copolymers are incorporated into organic solar cells as electron donors. The solar cells of the DArP copolymers exhibit power conversion efficiencies up to 80% (rel.) of their Stille cross coupling analogues. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 1457–1467 相似文献
18.
Systematic NMR characterization of 4‐thio‐5‐furan‐pyrimidine nucleosides or 4‐thio‐5‐thiophene‐pyrimidine nucleosides (ribonucleosides and 2′‐deoxynucleosides) was performed. All proton and carbon signals of 4‐thio‐5‐thiophene‐ribouridine and related analogues were unambiguously assigned. The orientations of the base (4‐thiouridine or its deoxy analogue) relative to the ring (furan or thiophene) are explored by a NMR approach and further supported by X‐ray crystallographic studies. The procedures presented here would be applicable to other modified nucleosides and nucleotides. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
19.
The reaction of 2,3,4‐tri‐O‐acetyl‐β‐D‐xylopyranosyl isothiocyanate ( 1 ) and 2‐amino‐4‐arylthiazoles ( 2 ) gave xylosylthioureas 3 . These thiourea derivatives reacted with alkyl/aryl amine in the presence of HgCl2 to give a new series of N‐alkyl/aryl‐N″‐(4‐arylthiazol‐2‐yl)‐N″‐xylosyl guanidines 4 . Some of the synthesized guanidines were screened for their biological activity. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:688–694, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20379 相似文献
20.
Jae‐Wan Jang Hyojung Cha Yun‐Hi Kim Soon‐Ki Kwon Chan Eon Park 《Journal of polymer science. Part A, Polymer chemistry》2013,51(22):4742-4751
Two novel polymeric semiconductor materials based on naphtho[2,1‐b:3,4‐b']dithiophene (NDT), PNDT‐TTT and PNDT‐TET , were designed and synthesized. These synthesized polymers were tested in bulk heterojunction solar cells as blends with the acceptor [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM). PNDT‐TTT contained tri‐thiophene units, and PNDT‐TET contained bi‐thiophene units coupled by ethylenic linkages. Comparison to the properties of PNDT‐T , which contained single thiophene units, these polymers exhibit red‐shifted absorption spectra as a result of the enhanced conjugation lengths. These effects resulted in high short circuit currents (JSC) in the organic solar cells. The PNDT‐TET ‐ and PNDT‐TTT ‐based devices exhibited considerably better photovoltaic performances, with power conversion efficiencies of 3.5 and 3.3%, respectively, compared to the PNDT‐T ‐based device (1.3%). © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4742–4751 相似文献