Temperature dependence of F-centre hyperfine interactions

We report the temperature dependence of F-centre Isotropic hyperfine energies for the first shells of KCl, KBr, NaCl, LiF and Lid, and the second shell of KCl. In all cases at least 30 ENDOR data points were taken between 1.3° and 300°K, and the Fermi contact energies were found to adhere closely to a curve of the form a(T) = A + B coth (C/T).The effects of pure lattice expansion may be removed with the aid of high pressure ENDOR data. The remaining temperature dependence can be explained in terms of a configuration co-ordinate model, with the F-electron interacting with a single effective mode of lattice vibration.     

Temperature dependence of hyperfine interactions in incommensurate systems

One investigates the influence of thermally excited collective modes in incommensurate systems on the temperature dependence of hyperfine interactions. The observed hyperfine fields are reduced by a temperature-dependent Debye-Waller factor and the hyperfine field amplitude can eventually decrease to zero well below the transition temperature.     

Temperature dependence of the magnetic hyperfine splitting of metastable iron-amalgam

The temperature dependence of the magnetic hyperfine field of a metastable iron-mercury alloy has been measured. The Mössbauer spectrum obtained at 12 K can be fitted with two magnetically split components with hyperfine fields of 39.7 and 36.0 T. With increasing temperature the hyperfine fields decrease much more rapidly than that of α-Fe. The temperature dependence is in accordance with the Bloch law up to 220 K.     

Temperature dependence of the magnetic hyperfine field at cerium impurity in Co

Perturbed gamma-gamma angular correlation (PAC) technique was used to measure the magnetic hyperfine field (B _hf ) at Ce impurity in Co using ¹⁴⁰La→ ¹⁴⁰Ce probe. The radioactive ¹⁴⁰La produced by neutron irradiation of lanthanum metal with thermal neutrons was introduced in Co by arc melting in argon atmosphere. The present measurements cover the temperature range from 4.2– 1300 K. Two pure magnetic interactions were observed at impurity sites, corresponding to a ferromagnetic ordering of Co moments in hcp and fcc phases. The temperature dependence of B _hf for both phases, however, shows a sharp deviation from an expected standard Brillouin-like behavior for the host magnetization. The results are discussed in terms of a simple molecular-field model where the localized moment at impurity ions as well as the conduction electron contributions to the hyperfine field are taken into account.     

Temperature dependence of the magnetic hyperfine interaction for K and Ar in Fe

By means of an integral IMPAD measurement, a temperature dependence of the angular distribution for⁴⁰K ions in magnetically saturated iron has been observed. This temperature dependence has been tentatively attributed to the annealing of defects close to the implanted potassium atoms, associated with an activation energy ofE _a=0.31 (5) eV. A similar temperature dependence has been observed for the system ArFe.Supported by Deutsches Bundesministerium für Forschung und Technologie     

Temperature and magnetic field dependence of superconductivity in nanoscopic metallic grains

We study pairing correlations in ultrasmall superconductor in the nanoscopic limit by means of a toy model where electrons are confined in a single, multiply degenerate energy level. We solve the model exactly to investigate the temperature and magnetic field dependence of number parity effect (dependence of ground state energy on evenness or oddness of the number of electrons). We find a different parity effect parameter to critical temperature ratio (4 rather than 3.5) which turns out to be consistent with exact solution of the BCS gap equation for our model. This suggests the equivalence between the parity effect parameter and the superconducting gap. We also find that magnetic field is suppressed as temperature increases.     

Decoupling experiments for the study of electric and magnetic hyperfine interactions in ferromagnetic compounds

The decoupling experiments involving the time-differential perturbed angular correlation (TDPAC) of the 133–482 keV γ-γ cascade in the presence of an external magnetic field applied along the quantization axis have been performed to measure the electric quadrupole and the magnetic hyperfine interactions experienced by the¹⁸¹Ta nuclei at Hf sites in the pseudobinary compounds HfFe_2-xSi_x, withx=0.1 andx=0.3. The hyperfine magnetic fields measured at 298 K areH _hf=133.1±12.0 kG in the cubic (C15) Laves phase compound HfFe_1.9Si_0.1 andH _hf=76.8±7.0 kG in the hexagonal (C14) Laves phase compound HfFe_1.7Si_0.3. The decoupling technique has also been used to obtain a —ve sign for the hyperfine field experienced by¹⁸¹Ta nuclei at the Ti or Hf sites in the Heusler compound Co₂Ti_0.8Hf_0.2Sn and a+ve sign for the hyperfine field at Zr sites in the cubic (C15) Laves phase compound ZrFe₂.     

Muon hyperfine interactions in magnetic oxides

Muon spin rotation studies on magnetic oxides among which-Fe₂O₃ and Fe₃O₄ have shown that at temperatures below approximately 500 K the muons form a muon-oxygen bond, analogous to a hydrogen bond. Generally, the muon hyperfine interactions in magnetic oxides can be explained in terms of supertransfer (hyperfine) and dipole fields. Supertransfer fields result from covalent bonding effects. For the rare earth (R) orthoferrite series (RFeO₃) comparison is made with Mössbauer results on covalency effects in hyperfine interactions. Suggestions for next stages of experimentation in solid state research in oxides bySR are mentioned.     

Evidence for the angular dependence of the hyperfine interactions in complex magnetic spin structures

A model emphasizing the anisotropy of the local spin polarization has been proposed in order to explain the correlation between the internal fields and magnetic moment distribution in the complex magnetic spin structure region of the Fe_3?xMn_xSi alloys.     

Evaluation of electric hyperfine interactions inAuFe andCrFe

A detailed analysis of room temperature⁵⁷Fe Mössbauer spectra ofAuFe (5 at.% Fe) andCrFe (5, 10 at.% Fe) samples is presented. The deviation from Lorentzian line shape observed in the spectra indicates both thickness effects and structural disorder in these systems. The thickness effect has been taken into account using a new fitting technique that solves the transmission integral numerically rather than relying on the thin absorber approximation. The present results and analyses using both the thin absorber approximation and the full transmission integral methods on these alloy systems are compared with earlier results obtained on these alloy systems using only the thin absorber approximation.     

Magnetic and electric hyperfine interactions in the system EuSm

Magnetic and electric hyperfine interactions in the system EuSm were investigated with the isomeric 11/2^– state in¹⁴⁵Eu by applying the time-differential perturbed angular distribution (TDPAD) method. The temperature dependence of paramagnetism was studied between 90 K and 1000 K by measuring the magnetic hyperfine interaction frequency _L=g_NN¹ (T)B_ext. The paramagnetic correction factor strictly follows the Curie-Weiss relation =1+C/(T-), withC=–50(2) K and =–29(5) K. This is compatible with a hyperfine field ofB _int(0)=–25(1) T, a valence of two for Eu in Sm, and antiferromagnetic order at low temperatures.The temperature dependence of the electric quandrupole coupling constant v_Q, investigated between 100 K and 400 K, can be reproduced by a linear temperature variation v_Q(T)=v_Q(0) (1-AT), with v_Q(0)=16.2(4) MHz andA=7.2(8)·10^–4 K^–1.The paramagnetic relaxation time _rel of the nuclear alignment is proportional to the temperature of the sample, with _rel T^–1=3.7(2) ·10^–9s K^–1.This leads to the Korringa relation _J T=const=5.1(5)·10^–11s K for the relaxation time of the 4f electronic spinJ. Assuming that the relaxation ofJ is mainly caused by exchange interaction between conduction electrons and localized 4f electrons at the Eu site, an exchange integral of |J _eff|=0.10(2) eV can be deduced.