Study by brillouin scattering of the C33 constant of thiourea submitted to an electric field

The C₃₃ constant is discontinuous for the lock-in transition at T₁ = 169 K. The variation ΔT₁ of the temperature of transition is a linear function of the applied electric field E and we find $\text{d}\text{T}{}_1\text{d}\text{E}\text{=0.82 deg.cm kV}{}^{\mathrm{?1}}$.Above a mean field E = 10 kV cm^?1 the transition observed for a first heating spreads on several degrees because damages appear in the incommensurate phase and the electric field becomes inhomogeneous.The results obtained at low fields are in very good accordance with the value of $\text{d}\text{T}{}_1\text{d}\text{E}$ calculated from the Clapeyron formula.Taking into account of the incommensurability of the phase above T₁, it can be shown that

$\text{dT}{}_1\text{dE}\text{=}\text{C}\text{2πP}{}_{\mathrm{o}}\text{3}\text{3}\text{?}\text{2}$

The knowledge of the spontaneous polarisation P₀ gives for the Curie constant C = 2.1 × 10³ K in qualitative agreement with the value deduced from measurements of the dielectric constant in the ferroelectric direction.     

Dynamic shielding of a charge in a metal

A discussion of the shielding of a charged particle in a current-carrying conductor is given that is based on the linearized Thomas-Fermi approximation. An expression for the force on a particle of charge q is obtained from which the value of the electric field E_c in the conductor may be found:

$\text{E}{}_{\mathrm{c}}\text{=}\text{lim}\text{q→0}\text{F}{}_{\mathrm{q}}\text{/q}$

It is shown that the force on the particle has the form $\text{F}{}_{\mathrm{q}}\text{= q}\text{E}{}_0\text{× (1 + γ(}\text{q}\text{e}\text{) + …}$ to second order in the charge q, where E₀ is the electric field at large distances from q, e is the charge of the carrier, and γ is a material-dependent constant. The shielding correction has the character of a “wind-force,” and the electric field in the conductor is given by Ec = E₀.     

Dissociation activation barrier and heat of chemisorption: A morse-type analytical approach

The activation barrier ΔE¹_ABfor dissociation AB → A + B on transition-metal surfaces is analyzed within an additive Morse-type approach based on the bond-order conservation. It is shown that $\text{Δ}\text{E}{}^1{}_{\mathrm{AB}}\text{=}\text{D}{}_{\mathrm{AB}}\text{?(}\text{Q}{}_{\mathrm{A}}\text{+}\text{Q}{}_{\mathrm{B}}\text{+}\text{Q}{}_{\mathrm{A}}\text{Q}{}_{\mathrm{B}}\text{/(}\text{Q}{}_{\mathrm{A}}\text{+}\text{Q}{}_{\mathrm{B}}\text{)}$ where D_AB is the gas-phase dissociation energy and Q_A(Q_B) is the heat of atomic chemisorption. Estimates of $\text{Δ}\text{E}{}^1\text{for H}{}_2\text{, N}{}_2\text{, O}{}_2$, and NO are shown to be in reasonable agreement with experiment. The two-dimensional potential diagram of the metal-AB interactions is defined analytically and discussed in some detail.     

Rydberg atoms in crossed electric and magnetic fields. Experimental evidence for the Pauli quantization

The experimental evidence for the Pauli quantization obeyed by the Rydberg spectrum of rubidium, in crossed electric and magnetic fields, is reported. When the external field perturbation associated with Zeeman and linear Stark effects are of the same order but small compared to the Coulomb binding energy, the energy levels of the system are given by $\text{E}{}_{\mathrm{n,k}}\text{= -R/n}{}^2\text{+ ɡK (ω}{}^2{}_{\mathrm{L}}\text{+ ω}{}^2{}_{\mathrm{E}}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, where K is an integer ω_L, ω_E the Larmor and linear Stark frequencies respectively.     

On the calculation of electron density of states in disordered metals

It is demonstrated that in a full nonlocal pseudopotential calculation of the density of states, the results from the standard formula, $\text{N(E) = N(E}{}_{\mathrm{<mtext>FE</mtext>}}\text{)k (}\text{?E}{}_{\mathrm{<mtext>k</mtext>}}\text{?k}\text{)}{}^{\mathrm{?1}}$, do not differ significantly from those using the Green-function method and are reliable for simple liquid metals, despite the fact that there is an uncertainty in treating E_k as a dispersion function.     

Stark mixing spectroscopy in cesium

We present a new technique for selectively populating excited states which are inaccessible by dipole excitation from the ground state. The method uses a static electric field to introduce a component of a dipole-allowed state into the state of interest. We have applied the method to cesium to measure lifetimes and a Stark mixing coefficient. The results are $\text{τ(6}{}^2\text{D}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)=64(2) ns}$, $\text{τ(7}{}^2\text{D}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)=92.5(15) ns}$, and <6²D_{$\text{5}\text{2}$}|;ez |7²P_{$\text{3}\text{2}$}>/(E_7P?E_6D)=0.7(3)×10^?3 where is in kV/cm. 141     

Holtzmark electric field distribution in a two-dimensional electron fluid

The Holtzmark distribution for the thermal electric field at a neutral point in a two-dimensional and uncorrelated electron fluid is given by $\text{β(1 + β}{}^2\text{)}{}^{\mathrm{<mtext>?3</mtext><mtext>2</mtext>}}$, with $\text{β =}\text{E}\text{E}{}_0$, and E₀ = πnZ_pe in terms of the density n and perturber Z_pe.     

Activation energy of field emission flicker noise power due to adsorbed potassium on tungsten

The temperature dependence of the field emission flicker noise spectral density functions has been investigated for potassium adsorbed on tungsten (112) planes by a probe hole technique. By integration of the spectral density functions $\text{W(?) = B}{}_{\mathrm{i}}\text{?}{}^{\mathrm{?ge}}\text{i}$ the noise power $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ for different frequency intervals Δ? is obtained. From the exponential temperature dependence of $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ noise power “activation energies” q_Δ? are determined. Plots of these energies versus coverage show a similar “oscillating” behaviour as recently found for $\text{W(?}{}_{\mathrm{j}}\text{)}$ or which indicates phase transitions of the adsorbed potassium submonolayers. The noise activation energies are discussed in terms of existing models and a comparison is made between the experimental q values and surface diffusion energies E_d as determined by conventional methods.     

Influence of self-fields on the Vlasov equilibrium and stability properties of relativistic electron beam-plasma systems

The influence of self-fields on the equilibrium and stability properties of relativistic beam-plasma systems is studied within the framework of the Vlasov-Maxwell equations. The analysis is carried out in linear geometry, where the relativistic electron beam propagates through a background plasma (assumed nonrelativistic) along a uniform guide field $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$, It is assumed that $\text{ν}\text{γ}{}_0\text{? 1}$ for the beam electrons (ν is Budker's parameter, and γ₀mc² is the electron energy), but no a priori assumption is made that the beam density is small (or large) in comparison with the plasma density, or that conditions of charge neutrality or current neutrality prevail in equilibrium. It is shown that the equilibrium self-electric and self-magnetic fields, $\text{E}{}_{\mathrm{r}}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{r}}$ and $\text{B}{}_{\mathrm{\theta }}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{\theta }}$, can have a large effect on equilibrium and stability behavior. Equilibrium properties are calculated for beam (j = b) and plasma (j = e, i) distribution functions of the form f_b⁰(H, P_θ, P_z) = F(H ? ω_rbP_θ) × δ(P_z ? P₀)(j = b), and $\text{f}{}_{\mathrm{j}}{}^0\text{(H, P}{}_{\mathrm{\theta }}\text{, P}{}_{\mathrm{z}}\text{) = f}{}_{\mathrm{j}}{}^0\text{(H ? ω}{}_{\mathrm{rj}}\text{P}{}_{\mathrm{\theta }}\text{? V}{}_{\mathrm{j}}\text{P}{}_{\mathrm{z}}\text{?}\text{m}{}_{\mathrm{i}}\text{V}{}_{\mathrm{j}}{}^2\text{2}\text{)}$ (j = e, i), where H is the energy, P_θ is the canonical angular momentum, P_z is the axial canonical momentum, and ω_rj (the angular velocity of mean rotation for j = b, e, i), V_j (the mean axial velocity for j = e, i), and P₀ are constants. The linearized Vlasov-Maxwell equations are then used to investigate stability properties in circumstances where the equilibrium densities of the various components (j = b, e, i) are approximately constant. The corresponding electrostatic dispersion relation and ordinary-mode electromagnetic dispersion relation are derived (including self-field effects) for body-wave perturbations localized to the beam interior (r <R_b). These dispersion relations are analyzed in the limit of a cold beam and cold plasma background, to illustrate the basic effect that lack of charge neutrality and/or current neutrality can have on the two-stream and filamentation instabilities. It is shown that relative rotation (induced by self-fields) between the various components (j = b, e, i) can (a) result in modified two-stream instability for propagation nearly perpendicular to $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$, and (b) significantly extend the band of unstable k_z-values for axial two-stream instability. Moreover, in circumstances where the beam-plasma system is charge-neutralized but not current-neutralized, it is shown that the azimuthal self-magnetic field $\text{B}{}_{\mathrm{\theta }}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{\theta }}$ has a stabilizing influence on the filamentation instability for ordinary-mode propagation perpendicular to $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$.     

The Grüneisen parameter γ of KBr,RbCl and Bi through high pressure phase transitions

High pressure values for the adiabatic pressure derivative of temperature $\text{(}\text{?T}\text{?P}\text{)}{}_{\mathrm{s}}$ have been obtained by measuring the temperature change caused by a small rapid increase in pressure. Values for KBr and RbCl in phases B1 and B2 and for Bi in phases I, II and III are given for T = 295 K. The Grüneisen parameter γ is given by $\text{γ =}\text{B}{}_{\mathrm{s}}\text{(}\text{?T}\text{?P}\text{)}{}_{\mathrm{s}}\text{T}$ where B_s is the adiabatic bulk modulus. Ultrasonic and statk compressibility data are used to estimate the pressure and phase dependence of B_s. Dramatic increases in both γ and (?T/?P)_s are observed as the pressure increases through a phase transition. Values for the logarithmic derivate $\text{q ≡ (? ln}\text{γ}\text{?}\text{ln V}{}_{\mathrm{T}}$ are given.     

A simplified Fokker-Planck operator for unlike-particle collisions

The linearized Fokker-Planck operator reads $\text{C}{}^1{}_{\mathrm{jk}}\text{= C(f}{}_{\mathrm{1j}}\text{, f}{}_{\mathrm{0k}}\text{)}$. The first term is rather simple, but the second one is very complicated. A much simpler - though exact - form of C(f_0j, f_1k) is proposed, for a special class of f_1k occuring in diffusion theory.     

The E-B band system of diatomic iodine

Sequential pump and probe pulses are used to excite state-selected E ← B ← X transitions in I₂ vapor, and the E ← B bands recorded by polarization-labeling spectroscopy at relatively high dispersion. Molecular constants and Dunham expansion coefficients Y_n,0 (n = 0–7), Y_n,1 (n = 0–3), and Y_n,2 (n = 0, 1) for the E state are obtained in the range 0 ≤ v_E ≤ 96, based on a global least-squares fit of 1050 assigned rotational transitions. Definite evidence is cited to show that the EO_g⁺ ion-pair state correlates diabatically with the ground state $\text{I}{}^{\mathrm{?}}\text{(}{}^1\text{S}{}_0\text{) + I}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_2\text{)}$ of the separated ions.     

Nodal expansions for strongly coupled classical plasmas

The canonical equilibrium properties of classical Coulomb systems are investigated in 2 + ? dimensions for any value of the plasma parameter $\text{Λ}{}_{\mathrm{?}}\text{=}\text{e}{}^2\text{k}{}_{\mathrm{B}}\text{Tλ}{}^{\mathrm{?}}{}_{\mathrm{D}}$, through the nodal expansion of the two-particle correlation function g₂(r), wh ere e is the electronic charge, k_B the Boltzmann constant, T the absolute temperature and λ_D the Debye length. We first consider the one-component plasma (OCP) model. An attention is especially paid on the higher order bridge (non-convolution type) graphs. The long-ranged resummations of the convolution-like geometric series which build up the hypernetted chain (HNC) approximation are considered at length. The short-range resummations are also performed in view of their specific interest for evaluating the enhancement rates of nuclear reactions in Astrophysics and Fusion Physics. Next, we shall extend the classical nodal expansions to high-temperature OCP models in which the short distance interactions have to be corrected for the ? ≠ 0 diffract ion effects. A second generalization concerns the high-temperature two-component plasma(TCP) model of point charges of opposite signs at high temperatures. In both cases, the bare Coulomb interaction is modified by a temperature-dependent effective interaction which allows for an entirely classical treatment of the small quantum corrections. Finally, the equilibrium properties of the TCP are used to work out the density corrections to the hydrodynamic (Bohm) diffusion transverse to an arbitrarily strong and static magnetic field.     

Sensitivity of nonequilibrium systems

Simple mechanisms through which nonequilibrium structures can be influenced by external fields are discussed. It is shown that a very weak gravitational or electric field can have a large influence on selection or creation of structures. In the absence of cooperativity, the influence of a weak field, to the leading order, is characterized by the ratio (E_int/kT), where E_int is the energy of interaction; however, when there is far-from-equilibrium cooperativity, it is shown that the influence of the field is characterized by $\text{(E}{}_{\mathrm{int}}\text{kT)}{}^{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}$.     

The giant Gamow-Teller resonance states

The mean energy of the giant Gamow-Teller resonance state (GTS) is studied, which is defined by the non-energy-weighted and the linearly energy-weighted sum of the strengths for Σ^A_i = 1^τi?σⁱ? Using Bohr and Mottelson's hamiltonian with the ξl· σ force, the difference between the mean energies of GTS and the isobaric analog state (IAS) is expressed as$\text{E}{}_{\mathrm{GTS}}\text{?E}{}_{\mathrm{IAS}}\text{,≈ 2〈π¦Σ}{}^{\mathrm{A}}{}_{\mathrm{i}}\text{=1ξ}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{· σ}{}_{\mathrm{i}}\text{¦π〉/ (3T}{}_0\text{-4(k}{}_{\mathrm{\tau }}\text{?k}{}_{\mathrm{\sigma \tau }}\text{) T}{}_0$. The observed energy systematics is well explained by k_τ?k_{στ≈ 4/A MeV}. The relationship between the mean energies and the excitation energies of the collective states in the random phase approximation for charge-exchange excitations is discussed in a simple model. From the excitation energy systematics of GTS, the values of k_στ and the Migdal parameter g′ are estimated to be about $\text{k}{}_{\mathrm{\sigma \tau }}\text{=}\text{(16–24)}\text{A}\text{MeV and}\text{g′ = 0.49–0.72}$, respectively.     

Modelling of kink nucleation and propagation along steps of finite length

A discrete model for kink nucleation and propagation along steps of finite length is developed. The step velocities were calculated as a function of the step length, the first order rate constants, k_s and k_K, for kink nucleation and propagation respectively, and a kink interaction parameter. The two limiting kinetic regimes of short and long steps as well as the intermediate transitional regime were considered. For very short steps, S² ? $\text{k}{}_{\mathrm{<mtext>K</mtext>}}\text{k}{}_{\mathrm{<mtext>s</mtext>}}$, the velocity varied directly with the number of sites S. Steps which met the criterion S² ? $\text{k}{}_{\mathrm{<mtext>K</mtext>}}\text{k}{}_{\mathrm{<mtext>s</mtext>}}$, were shown to have velocities on the order (2k_Kk_s)^{$\text{1}\text{2}$}, independent of step length. Step velocities were constant over large ranges of the kink interaction parameter. The steps were shown to be “sharp” for zero or attractive kink interaction, but with sufficiently large kink repulsion very diffuse steps could be formed. The density of kinks and numbers of kinks nucleated along an atom row were also calculated.     

Two-magnon Raman scattering in the two-dimensional antiferromagnet K2FeF4

Two-magnon Raman scattering in the planar quadratic antiferromagnet K₂FeF₄ is investigated. The temperature dependence of the energy shift is in good agreement with second-order Green-function theory, as is the linewidth at low temperature. Numerical results, including renormalization, are the Heisenberg exchange $\text{J}\text{k}{}_{\mathrm{B}}\text{= ?14.5 ± 0.7}\text{K}$ and the anisotropy $\text{Δ(T = 0) = gμ}{}_{\mathrm{B}}\text{H}{}_{\mathrm{A}}\text{4|J|S = 0.18 ± 0.05}$, but with $\text{J[1 + Δ(T = 0)]}\text{k}{}_{\mathrm{B}}\text{= ?17.06 ± 0.10}\text{K}$.