Development of an external cavity quantum cascade laser spectrometer at 7.5 μm for gas detection

We report the development of an external cavity quantum cascade laser spectrometer at 7.5 μm. The quantum cascade laser and its anti-reflection coating were specially developed for this application. We provide details of the external cavity design and data processing. A continuous wave emission is demonstrated from 1,293 up to 1,350 cm^?1. A preliminary test of the spectrometer was realized by measurements on acetone and phosphoryl chloride.     

High peak power 16 μm InP-related quantum cascade laser

In this paper ～16 μm-emitting multimode InP-related quantum cascade lasers are presented with the maximum operating temperature 373 K, peak and average optical power equal to 720 mW and 4.8 mW at 303 K, respectively, and the characteristic temperature (T₀) 272 K. Two types of the lasers were fabricated and characterized: the lasers with a SiO₂ layer left untouched in the area of the metal-free window on top of the ridge, and the lasers with the SiO₂ layer removed from the metal-free window area. Dual-wavelength operation was obtained, at λ ～ 15.6 μm (641 cm^?1) and at λ ～ 16.6 μm (602 cm^?1) for lasers with SiO₂ removed, while within the emission spectrum of the lasers with SiO₂ left untouched only the former lasing peak was present. The parameters of these devices like threshold current, optical power and emission wavelength are compared. Lasers without the SiO₂ layer showed ～15% lower threshold current than these ones with the SiO₂ layer. The optical powers for lasers without SiO₂ layer were almost twice higher than for the lasers with the SiO₂ layer on the top of the ridge.     

Photoacoustic gas sensing with a commercial external cavity-quantum cascade laser at 10.5 μm

We report the implementation of a commercial external cavity-quantum cascade laser emitting at 10.5 μm in a photoacoustic spectrometer. This spectrometer enables measurements on broad spectral range up to 60 cm⁻¹ which means that spectra of complex molecules can be recorded as well as a whole absorption band of a small molecule. The wide tuning range of the source of this photoacoustic spectrometer demonstrates the possibility to detect small and complex molecules such as carbon dioxide and butane.     

A narrow-line-width external cavity quantum dot laser for high-resolution spectroscopy in the near-infrared and yellow spectral ranges

We demonstrate a diode laser system which is suitable for high-resolution spectroscopy in the 1.2 μm and yellow spectral ranges. It is based on a two-facet quantum dot chip in a Littrow-type external cavity configuration. The laser is tunable in the range 1125–1280 nm, with an output power of more than 200 mW, and exhibits a free-running line width of 200 kHz. Amplitude and frequency noise were characterized, including the dependence of the frequency noise on the cavity length. Frequency stabilization to a high-finesse reference cavity is demonstrated, whereby the line width was reduced to approx. 30 kHz. Using a femtosecond frequency comb, the residual frequency instability was determined and found to be below 300 Hz on the time scales 1–300 s. Yellow light (>3 mW) at 578 nm was generated by frequency doubling in an enhancement cavity containing a PPLN crystal. The source has potential application for precision spectroscopy of ultra-cold Yb atoms and cold molecular hydrogen ions.     

Modes competition in a birefringence cavity laser with optical feedback

The modes competition characteristics in birefringence cavity laser are studied in different regions of the gain curve. The mode's intensity modulation depth with modes competition is much deeper than that without modes competition. When the average intensities of the two modes are comparable, the intensity modulation depth of either mode reaches its maximum. Modes competition can do more contribution to the mode's modulation depth than the percentage of light reflected back into the laser cavity does. These characteristics can be used to improve the sensitivity of an optical feedback system. A modes competition factor is introduced to either mode's intensity expression which describes the laser intensity more precisely.     

New method for isotopic ratio measurements of atmospheric carbon dioxide using a 4.3 μm pulsed quantum cascade laser

We present a new approach to the measurement of stable isotopic ratios of carbon dioxide using a near-room-temperature pulsed quantum cascade laser and a spectral ratio method based upon dual multiple pass absorption cells. The spectral ratio method improves precision and accuracy by reducing sensitivity to variations in the laser tuning rate, power and line width. The laser is scanned across three spectral lines (near 2310 cm^-1) quantifying three CO₂ isotopologues: ¹²C¹⁶O₂, ¹³C¹⁶O₂ and ¹²C¹⁶O¹⁸O. Isotopic ratios are determined simultaneously with a precision of 0.2δ for each ratio with a one-second measurement. Signal averaging for 400 s improves the precision to better than 0.03δ for both isotopic ratios (¹³ R and ¹⁸ R). Long-term accuracy of 0.2 to 0.3δ is demonstrated with replicate measurements of the same sample over a one-month period. The fast time response of this instrument is suitable for eddy flux measurements. PACS 07.57.Ty; 42.62.Fi; 92.70.Cp; 91.67.Rx     

A self-seeded fiber laser incorporated with a fiber Bragg grating external cavity semiconductor laser

A self-seeded fiber laser incorporated with a fiber Bragg grating external cavity semiconductor laser (FBG-ECL) and a Mach-Zehnder interferometer (MZI) were reported in this paper. The MZI provided a Q-switching with response time in the order of micro-seconds. The FBG-ECL provided narrow pulses as seeds to shorten the Q-switched pulses. Experimentally, pulse width of 0.8 μs was measured, which was one fifth of the pulse width without self-seeding.     

Ozone detection by differential absorption spectroscopy at ambient pressure with a 9.6 μm pulsed quantum-cascade laser

We report direct absorption spectroscopic detection of ozone at ambient pressure with a pulsed, DFB quantum-cascade laser (QCL) tuned within 1044–1050 cm^-1 by temperature scanning. Wavelength calibration curves were derived from FTIR and CO₂ spectra and interpreted with respect to the heat transfer from the heterostructure to the sink. The laser linewidth (0.13 cm^-1 FWHM) was found to decrease with temperature, probably as a result of operation at constant current. Spurious spectral features due to baseline inaccuracies were successfully filtered out from the QCL O₃ spectra using differential absorption. Reference O₃ concentrations were obtained by applying the same method to UV spectra, simultaneously measured with a differential optical absorption spectrometer (DOAS). Column densities retrieved from QCL spectra are in fairly good agreement (±20%) with the DOAS values above 28 ppmm. The estimated QCL lowest detectable, absolute and differential absorptions, (7×10^-3 and 2×10^-3, respectively), entail effective detection limits of 14 and 25 ppmm, respectively. Ongoing improvements in the acquisition system should allow the achievement of detection limits at the level of commercial open-path DOAS systems (2 ppmm) in the near future. Our results demonstrate the applicability of the differential absorption method to QCL spectroscopy at ambient pressure, and encourage its use for open path detection. PACS 42.62.Fi; 82.80.Gk; 92.60.Sz     

Fourier transform spectroscopy around 3 μm with a broad difference frequency comb

We characterize a new mid-infrared frequency comb generator based on difference frequency generation around 3.1 μm. High power per comb mode (>10^?7 W/mode) is obtained over a broad spectral span (>750 nm, >790 cm^?1). The source is used for direct absorption spectroscopy with a Michelson-based Fourier transform interferometer.     

Mid-infrared quantum cascade detectors for applications in spectroscopy and pyrometry

In this paper, we give an overview of quantum cascade detector technology for the near- and mid-infrared wavelength range. Thanks to their photovoltaic operating principle, the most advanced quantum cascade detectors offer great opportunities in terms of high detection speed, reliable room temperature operation, and excellent Johnson noise limited detectivity. Besides some important features dealing with their fabrication and their general characteristics, we will also briefly present some possibilities for performance improvement. Elementary theoretical considerations adopted from photoconductive detectors confirm that optimization of such devices always involves various trade-offs.     

High efficiency lasing of a dye-doped polymer laser with 1.06 μm pumping

For the first time, tunable lasing from a dye laser with an active polymer medium has been obtained using 1.06 μm pumping. The conversion efficiency of 43% and the tunable range of Δλ=63 nm have been reached with the use of polymethine dye in a polyurethane matrix. Received: 20 April 2001 / Revised version: 16 July 2001 / Published online: 19 September 2001     

Diode-pumped vertical external cavity surface emitting laser at 1 μm

We demonstrated a diode-pumped vertical external cavity surface emitting laser with simple plane-concave cavity. When the pump power at a wavelength of 811.6 nm is 1.5 W, the maximum output power is 40.4 mW at the wavelength of 1005.8 nm. The optical-optical conversion efficiency is 2.7%. .     

Design and optimization of a GaAs-based sub-7-μm quantum cascade laser based on multivalley Monte Carlo simulation

We present the design and optimization of a deep-well GaAs-based quantum cascade laser (QCL) emitting at 6.7 μm, the shortest wavelength in GaAs-based QCLs, using a multivalley Monte Carlo simulation. Simulation results provide direct insights into optimizing the layer sequence design. The optimized structure exhibits sufficient gain for lasing at both 77 and 300 K. The calculated threshold-current densities are 5 kA/cm² at 77 K and 14 kA/cm² at 300 K.     

Experimental study of actively mode-locked semiconductor laser with grating external cavity

In this paper,complete mode-locking optical pulses have been obtained froman actively mode-locked GaAs/GaAlAs semiconductor laser with grating external cavity.Theshortest optical pulse is 7.3 ps measured by second harmonic generation(SHG)autocorrelator.The repetition rate is 995.12 MHz and the central wavelength is 798.4 nm.The effect ofmodulation frequency,modulation current,and bias current on the optical pulses width areinvestigated.     

A trace methane gas sensor using mid-infrared quantum cascaded laser at 7.5 μm

Presented is a compact instrument developed for in situ high-stable and sensitive continuous measurement of trace gases in air, with results shown for ambient methane (CH₄) concentration. This instrument takes advantage of recent technology in thermoelectrically cooled pulsed Fabry–Perot (FP) quantum cascaded (QC) laser driving in a pulse mode operating at 7.5 μm to monitor a well-isolated spectral line near the ν4 fundamental band of CH₄. A high-quality liquid nitrogen cooled mercury cadmium telluride mid-infrared detector with time discriminating electronics is used along with a total reflection coated gold ellipsoid mirror offering 20 cm single pass optical absorption in an open-path cell to achieve stability of 5.2 × 10^?3 under experimental condition of 200 ppm measured ambient CH₄. The instrument operates continuously, and integrated software for laser control using direct absorption provides quantitative trace gas measurements without calibration. One may substitute a QC laser operating at a different wavelength to measure other gases. The instrument can be applied to field measurements of gases of environmental concern.     

Tunable diode laser spectroscopy of benzene near 1684 nm with a low-temperature VCSEL

We describe the application of a long-wavelength vertical-cavity surface-emitting laser (VCSEL) with extended tuning range to the detection of benzene vapor at atmospheric pressure. A benzene absorption feature centered at 1684.24 nm was accessed by reducing the heat sink temperature of a VCSEL designed for room-temperature operation to −55°C. This allowed us to increase the injection current and thus to extend a single-scan tuning interval up to 46.4 cm⁻¹ or 13.2 nm around a central wavelength of 1687.4 nm. Five absorption lines of methane in the 5903–5950 cm⁻¹ range could be acquired within single laser scans at a repetition rate of 500 Hz. A benzene absorption feature between 5926 and 5948 cm⁻¹ was recorded for concentration measurements at atmospheric pressure using a single-pass 1.2 m absorption cell. A 50 ppmv mixture of CH₄ in N₂ was introduced into the cell along with benzene vapor to calibrate benzene concentration measurements. Benzene mixing ratios down to ∼90 ppmv were measured using a direct absorption technique. The minimum detectable absorbance and detection limit of benzene were estimated to be ∼10⁻⁴ and 30 ppmv, respectively. Using the wavelength modulation technique, we measured a second harmonic sensor response to benzene vapor absorption in air at atmospheric pressure as a function of modulation index. We conclude that a low-temperature monolithic VCSEL operating near 1684 nm can be employed in compact benzene sensors with a detection limit in the sub-ppm range.     

Discharge instability induced by external laser preionization of a XeF discharge laser

External-laser-induced preionization of excimer lasers was investigated. A discharge XeF laser was preionized by two different UV lasers [a KrF laser (λ=249 nm) and an ArF laser (λ=193 nm)], and the improvements in performance of the XeF laser were compared. The XeF laser beam profiles were measured by an intensified CCD (ICCD) camera with temporal resolution of 10 ns. Striated XeF laser profiles were obtained with 249 nm laser preionization, whereas there was no striation in the profiles for 193 nm laser preionization. These striations originated from discharge in the XeF laser induced by laser preionization. The influence of excited rare-gas atoms on the discharge instability was examined.     

CH4/air/SO2 premixed flame spectroscopy with a 7.5-μm diode laser

As sulfur dioxide (SO₂) is often involved in combustion processes, we present here SO₂-concentration measurements in the post-flame region of a CH₄/air/SO₂ premixed flame. SO₂ concentrations were deduced from high-resolution absorption spectra recorded with a mid-infrared tunable diode-laser (TDL) source operating at liquid nitrogen temperature. Single-mode, continuous frequency tuning around 1384.5 cm^-1 (or 7.5 μm) is achieved by a fine TDL temperature ramp. These experiments lead us to develop in situ combustion-pollutant measurements with compact apparatus. We show that this non-intrusive method is efficient for detection and allows the retrieval of SO₂ concentration and temperature. Received: 19 February 2001 / Revised version: 18 April 2001 / Published online: 7 June 2001