Pulsed ESR on the organic ion radical salt: 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-[TCNQ]2

We present firstT _1e ^?1 andT _2e ^?1 measurements on the organic ion radical salt 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂ as function of temperature and of orientation. The electronic spin diffusion constant could be determined directly by the electron spin echo field gradient technique:D (300 K)=0.03±0.02 cm²/sec. Pulsed ESR experiments have — in comparison to conventional cw-ESR — the advantage to monitor viaT _1e ^?1 andT _2e ^?1 the spectral density of dynamical processes at different frequencies. This is shown in a general manner on 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂. Between 300 and 60 K,T _1e ^?1 andT _2e ^?1 are close in amplitude and have a similar temperature dependence. At 60 K their degeneracy is lifted, yielding a quantitative value for the effective spin exchange between localized spinsτ _ex ^?1 sec^?1 and via the absolute value of the relaxation an average distance of the localized centers of about 12 Å. The dynamical data as evaluated above cannot be correlated with the conductivity, clearly indicating that the conduction electrons are a minority, not being monitored by the ESR-experiments.     

Dephasing in the semiclassical limit is system-dependent

Dephasing in open quantum chaotic systems has been investigated in the limit of large system sizes to the Fermi wavelength ratio, L/λ_F 〉 1. The weak localization correction g ^wl to the conductance for a quantum dot coupled to (i) an external closed dot and (ii) a dephasing voltage probe is calculated in the semiclassical approximation. In addition to the universal algebraic suppression g ^wl ∝ (1 + τ_D/τ_?)^?1 with the dwell time τ_D through the cavity and the dephasing rate τ _? ^?1 , we find an exponential suppression of weak localization by a factor of ∝ exp[? $\tilde \tau $ /τ_?], where $\tilde \tau $ is the system-dependent parameter. In the dephasing probe model, $\tilde \tau $ coincides with the Ehrenfest time, $\tilde \tau $ ∝ ln[L/λ_F], for both perfectly and partially transparent dot-lead couplings. In contrast, when dephasing occurs due to the coupling to an external dot, $\tilde \tau $ ∝ ln[L/ξ] depends on the correlation length ξ of the coupling potential instead of λ_F.     

Form factor π0 → γ* + γ* at different photon virtualities

The π⁰ γγ vertex for virtual photons of squared masses q ₁ ² and q ₂ ² plays a vital rôle in several physical processes; for example for q ₁ ² < 0, q ₂ ² < 0, in the two-photon physics reaction e ⁺ e ^? → e ⁺ e ^?π⁰, and for q ₁ ² > 0, q ₂ ² > 0, in the annihilation process e ⁺ e ^? → π⁰ l ⁺l^?. It is also of interest because of its link to the axial anomaly. We suggest a new approach to this problem. We have obtained a closed analytic expression for the vertex in the limit in which at least one of ¦q ₁ ² ¦ and ¦q ₂ ² ¦ is large for arbitrary fixed values of the ratio q ₁ ² /q ₂ ² . We compare our results with those obtained previously by Brodsky and Lepage. It should be straightforward to test our predictions experimentally.     

Hyperfeinstruktur und Lebensdauer des 82 P 3/2-Terms von Rubidium

The hyperfine structure splitting of the 8² P _3/2 state of Rb⁸⁵ and Rb⁸⁷ has been investigated with optical double resonance. The following interaction constants have been obtained:A _8p ⁸⁵ =1.99(2) MHz,B _8p ⁸⁵ =1.98(12) MHzA _8p ⁸⁷ =6.75(3) MHz,B _8p ⁸⁷ =0.96(6) MHz. The lifetime of the 8² P _3/2 state is: τ=4.0(8) · 10^?7 sec.     

Interpretation of multifrequency transient EPR spectra of the P 700 + A0Q K − state in photosystem I complexes with a sequential correlated radical pair model: Wild type versus A0 mutants

Transient electron paramagnetic resonance (TR-EPR) spectra of the electron-hole pair state P ₇₀₀ ⁺ A₀Q _K ^? in photosystem I are numerically calculated. Parameter variation concerns mainly the exchange integralJ of the precursor spin pair state P ₇₀₀ ⁺ A ₀ ^? Q_K and its lifetime τ. A prominent emissive feature in the high-field region (P ₇₀₀ ⁺ part) of the EPR spectrum turns out to be diminished with increasing lifetime τ of the precursor pair state in the case of positive exchange couplingJ>0 (ferromagnetic type). Correspondingly, the emissive feature becomes more pronounced with increasing lifetime τ in the case of negative exchange couplingJ<0 (antiferromagnetic type). These results can be used to interpret the changes in the pattern observed in TR-EPR spectra comparing wild-type and specific A₀ mutants. The central ligating amino acid residue to the A₀ chlorophyll cofactor is mutated from native methionine (M) to leucine (L) in either the PsaA or the PsaB branch. Changes are observed only for the A-side mutant: M688L(PsaA). They are consistent with the following parameters in the precursor pair P ₇₀₀ ⁺ A ₀ ^? :J≈0.5÷1.0 mT and τ=1.5÷2 ns (as compared to τ～0.05 ns in the wild type).     

The147Sm(n,α)144Nd Reaction on 2 keV neutrons

Through (p,2n) in-beam γ and e^? measurements the excitation of the 235 μs 9⁺ isomer in¹⁴⁶Eu has been determined to be 666.3 keV. High spin members of the πd ₅ ^2/?1 νf_7/2 and πg ₇ ^2/?1 νf_7/2 particle hole multiplets populated in the isomeric decay were located.     

Resonant dislocation motion in NaCl crystals in the EPR scheme in the Earth’s magnetic field with pulsed pumping

Resonant dislocation motions in NaCl(Ca) crystals under the simultaneous action of the Earth’s magnetic field B _Earth (～66 μT) and a pulsed pump field $\tilde B$ of sufficient amplitude $\tilde B_m $ and certain duration τ have been detected and studied. The measured dislocation path peaks l(τ) have a maximum at τ = τ _r ≈ 0.53 μs. The resonance criterion has been found to be the ordinary EPR condition in which the g-factor is close to 2 and the optimum inverse pulse duration τ _r ^?1 is used instead of the harmonic pump field frequency ν _r . The largest peak l(τ) height is reached at mutually orthogonal dislocation (L) and magnetic field (B _Earth and $\tilde B$ ) orientations. Pulsed field rotation to the position $\tilde B$ ‖ B _Earth significantly decreases but does not “kill” the effect. For dislocations parallel to the Earth’s field (L ‖ B _Earth), the resonance almost disappears even at $\tilde B$ ⊥ B _Earth. In the optimum geometry of experiments, as the pump field amplitude $\tilde B_m $ decreases from 17.6 to 10 μT, the path peak height l _r = l(τ _r ) decreases only by 7.5%, remaining at the level of l _r ～ 10² μm, and at a $\tilde B_m $ further fall-off to 4 μT, it rapidly decreases to background values. In this case, the relative density of mobile dislocations similarly decreases from ～90 to 40%. Possible physical mechanisms of the observed effect have been discussed.     

Hadronic contributions to (g−2) of the leptons and to the effective fine structure constant α(M Z 2 )

The new experiment planned at Brookhaven to measure the anomalous magnetic moment of the muona _μ≡(g _μ?2)/2 will improve the present accuracy of 7 ppm by about a factor of 20. This requires a careful reconsideration of the theoretical uncertainties of theg?2 predictions, which are dominated by the error of the contribution from the light quarks to the photon vacuum polarization. This issue is cruicial also for the precise determination of the running fine structure constant at theZ-peak as LEP/SLC experiments continue to increase their precision. In this paper we present an updated analysis of the hadronic vacuum polarization using all presently availablee ⁺e^? data. This seems to be justified because previous work on the subject was based to some extent on preliminary or incomplete experimental data. Contributions from different energy ranges are presented separately forg?2 of the muon and the τ-lepton and for α(M _Z ² ). We obtain the resultsa _μ ^had* =(725±16)×10^?10 anda _τ ^had* =(351±10)×10^?8, where the asterisk indicates the dressed (renormalization group improved) value. For the effective fine structure constant atM _Z=91.1888 GeV we obtainΔα _had ⁽⁵⁾ =0.0280±0.0007 and α(M _Z ² )^?1=128.896±0.090. Further improvement in the accuracy of theoretical predictions which depend on the hadronic vacuum polarization requires more precise measurements ofe ⁺e^? cross-sections at energies below about 12 GeV in future experiments.     

Anomalous magnetic moment of theW-bosons and non-standardZ 0 W + W − coupling in polarizede − e + collisions

We study quantitatively the reactions \(e^ + e^ - \to W^ + e\bar \nu _e \) ,e _R ^? e ⁺ and the rare decay \(Z^0 \to W^ \pm l^ \mp \mathop {\nu _e }\limits^{( - )} \) forl=e, μ and τ, as a test for anomalous γW ⁺ W ^? andZ ⁰ W ⁺ W ^? structure. If κ denotes the anomalous magnetic moment of theW-boson and ω its anomalous coupling to theZ ⁰, values of |ω|>2.5 and |κ|>1.5 can be ruled out at LEP and SLC rather easily. This will put constraints on composite model building.     

Mechanism by which a single water molecule affects primary charge separation kinetics in a bacterial photosynthetic reaction center of Rhodobacter sphaeroides

Using quantum-chemical methods, we have studied the role played by water molecules W-A and W-B that are bound by hydrogen bonds to accessory bacteriochlorophyll molecules B _A and B _B in the process of primary charge separation in the reaction center of Rhodobacter Sphaeroides. We have found that the occurrence of a rotational mode of the W-A molecule at 32 cm^?1 and/or its harmonics in stimulated emission of an electron donor P* and the dynamics of population of the states P⁺B _A ^? and P⁺H _A ^? may be related to the structural heterogeneity of the reaction center and the existence of a conformation in which the W-A molecule is predominantly involved in one hydrogen bond (with BA). Based on the calculated redox potentials B _A and P, it has been shown that the appearance of the W-A molecule in the reaction center reduces the energy of the P⁺B _A ^? state by ??600 cm^?1. This is somewhat smaller than the influence of the amino-acid residue Tyr^M210 (??870 cm^?1) and correlates well with a substantial decrease in the electron transfer rate in mutant forms of reaction centers GM203L (which do not contain W-A molecules) and YM210F (in which Tyr^M210 is replaced with Phe). The data obtained allow us to suggest that rotation of the water molecule with a fixed position of its H atom that is involved in a hydrogen bond with the keto carbonyl group of B _A is initiated due to the charge separation between the halves of special pair P and the formation of the state P _A ⁺ P _B ^? . The large effect of this rotation on the kinetics of population of the states P⁺B _A ^? and P⁺H _A ^? after the excitation of P is quite consistent with its influence on the energy of the state P⁺B _A ^? .     

EPR of a fullerene-molecule-derived paramagnetic center as a mesoscopic conducting object

Discussion of theg-factor value of fullerene is based on the model of itinerant electrons restricted to the surface of the fullerene molecule C₆₀. The Ag shift, i.e., the difference between the experimentalg-factor and theg-factor of free electron Δg = g ? 2.0023 for C ₆₀ ^?1 is negative as for a very small metallic conducting particle.g-factor value is proportional to the interaction between itinerant electrons in the conduction band, thus the Δg is negative for C ₆₀ ^?1 and C ₆₀ ^?3 having less than half filled conduction band, while Δg is positive for C ₆₀ ⁺ where the conduction band is almost filled.     

Search for CP violation in Z0 → τ + τ − and an upper limit on the weak dipole moment of the τ lepton

An improved test of invariance in the reaction e⁺e^? τ ⁺ τ ^? on the Z0 peak is performed using the data sample recorded between 1991 and 1995 with the OPAL detector at LEP. Optimal observables, requiring the reconstruction of the τ flight direction and spin, have been used for different final state topologies. From the non-observation of violation we derive 95% confidence level upper limits on the real and imaginary parts of the weak dipole moment of the τ lepton of |Re(d _τ ^w (m _Z ² | < 5.6 × 10^?18 e cm and |Im(d _τ ^w (m _Z ² ))| < 1.5 × 10^?17 e cm, respectively.     

Study of B s 0 → µ+µ− and B d 0 → µ+µ− decays in flavor-changing Z′ models

Recently, the first evidence for the decay B _s ⁰ → μ ⁺ μ ^? has been announced by the LHCb Collaboration and the measured branching ratio B( _s ⁰ → μ ⁺) = (3.2 _?1.2 ^+1.5 ) × 10^?9 is in good agreement with the standard model (SM) expectation. It has also reported an upper limit for B(B _d ⁰ → μ ⁺ μ ^?) < 9.4 × 10^?10 at 95% confidence level. In this paper, we study the B _s ⁰ → μ ⁺ μ ^? and B _d ⁰ → μ ⁺ μ ^? rare decays in flavor-changing Z′ model. Our estimated branching ratios are enhanced from their SM values and provide signals for new physics.     

Spin effects in two-body hadronic decays of the B c mesons

Spin effects in the weak two-body hadronic decays of the B _c and B _c ^* mesons into J/ψ and ρ(π) mesons are considered within the model of hard one-gluon exchange between quarks at high momentum transfers. It is shown that the polarization of the J/ψ meson in the decays of the B _c ^* meson differs substantially from that in the decays of the B _c ^* meson. The decay widths of the B _c ^* meson differ significantly from the widths of the B _c ^* meson.     

Angular correlations and the tau-neutrino mass

Effects of a nonzero mass for the tau neutrinov _τ as well as a right-handed charged-current contribution to the τ?v _τ coupling are discussed. Angular correlations of the decay products of τ⁺τ^? ine ⁺ e ^? annihilation are calculated as functions of \(m_{v_\tau } \) and the relative amount of right-handed τ?v _τ coupling.     

Absorptionsspektren des Er3+-Ions in Scandiumvanadat und Scandiumphosphat bei verschiedenen Dotierungen

The optical absorption spectra of trivalent erbium in ScVO₄ single crystals and ScPO₄ powders with doping ratios between (500∶1) and (10∶1) have been obtained between 15,000 and 27,000 cm^?1. From the positions of the Stark components of (Sc, Er)VO₄ (100∶1) the five crystal field parametersB ₀ ² ,B ₀ ⁴ ,B ₀ ⁶ ,B ₄ ⁴ andB ₄ ⁶ have been determined. Moreover the paramagnetic resonance of (Sc, Er)VO₄ single crystals with doping ratios mentioned above have been examined. With these experimental results informations have been obtained about the doping with metal-ions of an essentially different ionic radius.     

Q^2 \to A\sqrt s Scaling law fore + e −→hadrons andpp collisions at high energy

It has been conjectured recently that multiparticle production in low momentum transfer hadronic collisions is due to gluon bremsstrahlung off highly virtual (mass \(\mu ^2 \sim \sqrt s \) ) quarks. The model gives a new scaling law: \(Q^2 \to A\sqrt s \) , for comparinge ⁺ e ^?→hadrons andpp non-diffractive inelastic data. The scaling law is tested for average multiplicities, plateau height and 〈p ₂ ^⊥ 〉. Fore ⁺ e ^? annihilation a parametrization of data based on perturbative QCD approach is used.     

Conserved-vector-current hypothesis and the\bar v_e e^ - \to \pi ^ - \pi ^0 process

Based on the conserved-vector-current (CVC) hypothesis and a four-ρ-resonance unitary and analytic VMD model of the pion electromagnetic form factor, theσ _tot(E _v ^lab ) and dσdE _π ^lab of the weak \(\bar v_e e^ - \to \pi ^ - \pi ^0\) process are predicted theoretically for the first time. Their experimental approval could verify the CVC hypothesis for all energies above the two-pion threshold. Since, unlike the electromagnetic e⁺e^?→π⁺π^? process, there is no isoscalar vector-meson contribution to the weak \(\bar v_e e^ - \to \pi ^ - \pi ^0\) reaction, accurate measurements of theσ _tot(E _v ^lab ) that moreover is strengthened with energyE _v ^lab linearly could solve now a widely discussed problem of the mass specification of the first excited state of theρ(770) meson. As a by-product, an equality \(\sigma _{tot} (\bar v_e e^ - \to \pi ^ - \pi ^0 ) = \sigma _{tot} (e^ + e^ - \to \pi ^ - \pi ^0 )\) is predicted for \(\sqrt s \approx 70 GeV\) .     

Inclusive production ofK s 0 , K s 0 K s 0 andK *±(892) in\bar pp interactions at 3.0, 3.5, 4.0 and 4.5 GeV/c

InclusiveK _s ⁰ andK _s ⁰ K _s ⁰ production in \(\bar pp\) interactions at 3.0, 3.5, 4.0 and 4.5 GeV/c are studied. Cross sections ofK _s ⁰ , K _s ⁰ K _s ⁰ andK ^*±(892) are presented for each incident momentum. The production ofK _s ⁰ andK ^*±(892) through annihilation process is investigated. It is found that the annihilation process is dominant but decreases with incident momentum. The annihilation process is compared withe ⁺ e ^? interactions. Remarkable similarity between them is found in the \({{x_0 = 2E(K_s^0 )} \mathord{\left/ {\vphantom {{x_0 = 2E(K_s^0 )} {\sqrt s }}} \right. \kern-0em} {\sqrt s }}\) distribution. Events with two detectedK _s ⁰ 's are analyzed. The result shows theK _s ⁰ K _s ⁰ pairs are produced in the central region of c.m. system and there is a clearS ^* signal in theK _s ⁰ K _s ⁰ effective mass distribution.