共查询到19条相似文献,搜索用时 93 毫秒
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设计合成了3种8-羟基喹啉衍生物配体:(E)-2-[2-(2-硝基苯基)乙烯基]-8-羟基喹啉(4a),(E)-2-[2-(3-硝基苯基)乙烯基]-8-羟基喹啉(4b),(E)-2-[2-(4-硝基苯基)乙烯基]-8-羟基喹啉(4c)及其相应的锌配合物5a~5c,产物经1H NMR,IR,MS和元素分析技术进行了结构表征.通过紫外滴定模拟了金属锌与配体的配位过程,分别测定了它们固态和溶液状态下的荧光性质:光谱显示化合物5a~5c固体荧光光谱的λmax分别是596,625,592 nm,在DMF溶液中的λmax分别是562,536,618 nm.荧光光谱显示硝基位置的改变可以调控8-羟基喹啉锌配合物的发光性质. 相似文献
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以芳胺和正丁醛为原料,对甲基苯磺酸(TsOH)为促进剂,采用"一锅法"合成了3-乙基-2-丙基喹啉衍生物,系统地考察了原料比例、溶剂以及芳胺上取代基对反应的影响,比较了不同的质子酸促进剂对喹啉衍生物产率以及选择性的影响,并对产物进行了核磁共振表征.实验结果表明当用对甲基苯磺酸(TsOH)为促进剂时,3乙基-2-丙基喹啉收率可达到59%,同时生成40%N-丁基苯胺;磷钼酸、浓硫酸也可以选择性地得到喹啉衍生物,但收率较低,分别只有28%和24%.同时,考察了苯胺环上取代基对喹啉收率的影响,当苯环上有供电子基时,有利于喹啉的生成,而吸电子基则不利于喹啉的生成.并推测了反应机理. 相似文献
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N-(1-异喹啉)硫代亚胺碳酸乙酯荧光光谱的pH效应研究 总被引:1,自引:0,他引:1
本文合成了一种新的1位取代的异喹啉衍生物的脲类似物, 发现该化合物的荧光性质随溶液酸碱度的变化十分敏感. 详细研究该化合物的荧光光谱与溶液pH的相关性, 将有助于了解和阐明异喹啉衍生物的脲类似物的激发态光物理行为, 为进一步研究其它异喹啉衍生物的脲类似物及其配合物的光学性质提供理论依据. 相似文献
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A gold-catalyzed three-component coupling reaction (A3 reaction) was developed as an efficient approach for the synthesis of challenging 2,4-disubstituted quinoline derivatives. Compared to previously reported Cu/Au bi-catalyst system, this protocol enables achieving A3 reaction only in the presence of triazole-gold catalyst. Notably, 4-alkyl substituted or 2-alkyl substituted quinoline derivatives were obtained with good yields, which highlighted the unique advantage of this new strategy. 相似文献
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It is shown that it is possible to use heterocyclic ketones to synthesize condensed pyrimidine derivatives in the case of 1-(p-toluenesulfo)-1,2,3,4-tetrahydroquinol-4-one, which on reaction with benzylidenebisurea gives 2-hydroxy-4-phenyl-6-(p-toluenesulfo)-3, 4, 5, 6-tetrahydropyrimido [5,4-c] quinoline, and the latter, after dehydrogenation via the 2-hydroxy, 2-chloro derivatives, was converted to 4-phenylpyrimido [5, 4-c] quinoline, a new heterocyclic system.For Part IV see [13]. 相似文献
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《化学:亚洲杂志》2017,12(14):1719-1723
A facile construction of quinoline‐2‐carboxylate esters through an aerobic oxidation of alkyl 4‐anilinocrotonates is described. In the presence of dioxygen, sp3 C−H bonds in 4‐anilinocrotonates can easily be oxidized by using a catalytic amount of a radical cation salt, providing a radical intermediate. After further oxidation and domino cyclization, the desired quinoline derivatives were afforded in high yields. This reaction provides a new way to construct the pharmaceutically relevant quinoline skeleton, avoiding harsh reaction conditions and tedious starting material synthesis. 相似文献
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将2-甲基-8-羟基喹啉与四苯乙烯或三苯乙烯基团结合,合成了两种新型喹啉衍生物(4-Br-TPE-8HQ及TriPE-8HQ),并对其进行了光物理性能研究。结果发现,连接有四苯乙烯的喹啉衍生物能够体现聚集诱导发光(AIE)特性,而连接三苯乙烯的喹啉衍生物却显示温和的聚集诱导猝灭(ACQ)效应,实现了通过功能基团来调节目标分子聚集诱导效应的目的。研究发现,不同体系下分子的整体平面性有所不同,其中三苯乙烯修饰的衍生物在溶液中的荧光寿命(0.55 ns)高于固体荧光寿命(0.43 ns);循环伏安法证明两者具有良好的电化学稳定性,计算得到的4-Br-TPE-8HQ和TriPE-8HQ的LUMO能级分别为-2.40 eV和-2.43 eV,表明为两个化合物注入电子是可行的。 相似文献
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由异色满酮-4(1)与邻氨基苯甲醛或邻氨基胡椒醛进行Friedlender缩合反应得到异色满并喹啉衍生物异色满并[4,3-b]喹啉(2)和9,10-亚甲二氧基异色满并[4,3-b]喹啉(3). 相似文献
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Synthesis and Structure Characterization of 1,5‐Benzothiazepine Derivatives Bearing Quinoline Moiety 下载免费PDF全文
A series of 1,5‐benzothiazepine derivatives bearing quinoline moiety were obtained by 1,5‐benzothiazepine containing 2‐phensulfanyl‐quinoline ( 4a , 4b , 4c ) with equimolar amounts of benzohydroximinoyl chlorides 5 in CH2Cl2 at room temperature. Structures of new compounds were confirmed by elemental analysis, IR, 1H‐NMR, MS, and X‐ray diffraction analysis. 相似文献
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Hemanth Kumar P. Jyothish Kumar L. Pavithrra G. Rajasekaran R. Vijayakumar V. Karan Rohith Sarveswari S. 《Research on Chemical Intermediates》2020,46(3):1869-1880
Research on Chemical Intermediates - A series of new pyrrolidine-appended phenoxy-substituted quinoline derivatives were synthesized using 2-chloro-3-formyl quinoline. Initially, the second... 相似文献
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Divyesh C.Mungra Harshad G.Kathrotiya Niraj K.Ladani Manish P.Patel Ranjan G.Patel 《中国化学快报》2012,23(12):1367-1370
A series of some new tetrazolo[1,5-a]quinoline based tetrasubstituted imidazole derivatives 6a-1 have been synthesized by a reaction of tetrazolo[1,5-a]quinoline-4-carbaldehyde 3a-d,benzil 4,aromatic amine 5a-c and ammonium acetate in the presence of iodine through one-pot multi-component reaction(MCR) approach.All the derivatives were screened for antimicrobial and antituberculosis activities and results worth further investigations. 相似文献
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Christophe Biot Jean Dessolin Isabelle Ricard 《Journal of organometallic chemistry》2004,689(25):4678-4682
Starting from triazacyclononane, easily accessible ferrocenic quinoline derivatives were synthesized. Their antiplasmodial properties were investigated against chloroquine sensitive (HB3) and chloroquine-resistant (Dd2) Plasmodium falciparum. One of them, 7-chloro-4-[4-(7-chloro-4-quinolyl)-7-ferrocenylmethyl-1,4,7- triazacyclononan-1-yl]quinoline (4) showed potent antimalarial activity in vitro against the chloroquine-resistant strain Dd2 and therefore revealed to be the most promising lead from the present work for new organometallic antimalarial agents. 相似文献