X-射线荧光分析散射函数法的原理及其应用Ⅲ.连续背景幂函数法

本文在宽的基体变化范围内对波长为0.081 nm的连续散射X-射线进行了研究,表明质量衰减系数与连续散射强度之间不再遵守传统散射内标法所假定的反比例关系,而是呈一种幂函数关系.理论证明和实验结果一致.提出了用0.081 nm处的散射强度的函数校正基体效应的方法,并用于地质样品中微量锶的测定,结果显示,在较大的基体变动范围内,本法与传统散射内标法相比准确度提高近4倍,克服了传统方法适应基体变化范围小的缺点.     

X—射线荧光分析散射幂函数法的原理及其应用

本文在较宽在基体原子序数变化范围内研究了非相干散射随基体吸收系数的变化规律,发现存在一种幂函数关系,用射内标法所假定的反比关系仅在较窄的轻元素范围内存在,实验证实了这种理论规律的存在。提出了用康普散射幂函数法校正基体吸收效应的新方法。列举了幂函数法在地质样品中的锶的测定实例,证明了该法在宽的基体组成范围内比传统的散射内标法适应性强。     

X-射线荧光分析散射幂函数法的原理及其应用Ⅱ.非相干散射

本文在较宽的基体原子序数变化范围内研究了非相干散射随基体吸收系数的变化规律,发现存在一种幂函数关系,而传统散射内标法所假定的反比关系仅在较窄的轻元素范围内存在.实验证实了这种理论规律的存在.提出了用康普顿散射幂函数法校正基体吸收效应的新方法.列举了幂函数法在地质样品中锶的测定实例,证明该法在宽的基体组成范围内比传统的散射内标法适应性强.     

钢中化学元素的X－射线荧光光谱分析

本文叙述合金钢中１５种元素的Ｘ射线荧光光谱快速定量分析方法。用Ｘ４０软件中的ＰＨ模式进行共存元素间的谱线重叠和基体吸收－增强效应的校正。对于合金中的微量重元素如Ｃｕ，Ｍｏ，Ｎｂ，Ｗ和Ｎｉ以０．０６５ｎｍ处的散射背景为内标局部补偿样品表面结构、仪器波动和基体效应等因素造成的影响。所得分析结果满足生产要求。     

偏振X射线荧光分析尾矿薄层样品的散射校正方法研究

了解尾矿浆中的重金属元素含量能为矿物浮选提供决策依据,不仅可以提高矿物的利用率,还可减少环境污染。X射线荧光光谱法是一种常用的重金属元素分析技术,对于地质类样品的分析,康普顿散射内标法是一种常用的定量方法。但对于薄层沉积样品,其康普顿散射峰强度会受到支撑滤膜的散射影响。由于样品紧密附着在支撑滤膜上,难以直接获得来自样品本身的康普顿散射强度,不利于直接应用康普顿散射峰强度进行定量分析。以尾矿薄层样品为分析对象,研究了不同聚丙烯滤膜厚度对康普顿散射峰强度的影响,并对薄层样品的康普顿散射强度进行了校正。实验结果表明,在0.34～3.06 mm厚度范围内,康普顿散射峰强度随聚丙烯滤膜厚度的增加线性增加,通过建立探测器获得的总康普顿散射强度与滤膜厚度的线性关系,计算出样品的净康普顿散射峰强度。为验证该修正方法的可靠性,利用蒙特卡洛方法模拟研究了无滤膜的尾矿样品和带有不同厚度滤膜的尾矿样品,结果显示经滤膜厚度影响修正后的净康普顿散射峰强度与无滤膜样品康普顿散射峰强度基本一致,相对偏差为0.41%。同时通过实验和模拟计算了0.34 mm厚聚丙烯滤膜时修正后的净康普顿散射峰强度占总康普顿散射峰的比例,分别为91.31%和89.91%,二者基本一致。最后,利用了上述基于滤膜厚度康普顿散射影响的校正方法,建立了基于康普顿散射内标法的定量校准曲线,对两种尾矿浆中的Cu,Zn和Pb元素的定量分析结果显示,未经滤膜厚度修正的康普顿内标校正相比校正前,部分元素定量结果与ICP-OES结果相比,其相对偏差反而增加3.18%～9.00%。而经滤膜厚度修正的康普顿内标方法的定量结果与ICP-OES结果的相对误差在1.14%～11.15%之间,相比于校正之前,相对偏差减少了0.30%～8.97%。     

回火金属玻璃小角X射线散射强度的背底校正

提出校正回火金属玻璃（非晶合金）小角ｘ射线散射强度的背底误差的方法：将淬火态非晶合金的小角Ｘ射线散射强度作为在相同的实验条件下得到的回火非晶合金小角Ｘ射线散射强度的背底而予以扣除。并将这样扣除背底和用通常方法扣除背底得到的结果相比较，由前者得到的散射强度遵从Ｐｏｒｏｄ律，并进而得到Ｐｏｒｏｄ常数Ｋ_p＝４．６×１０^-2（ｎｍ^-3），积分不变量Q_s＝１．６３（ｎｍ^-2），比内表面Ｓ_p＝８４ｍ²／ｃｍ³，Ｐｏｒｏｄ半径Ｒ_p＝４．４ｎｍ用通常方法扣除背底后的散射强度不满足Ｐｏｒｏｄ规律。 关键词：     

纳米Ge颗粒镶嵌薄膜的Raman散射光谱研究

研究了镶嵌在ＳｉＯ_２介质中的不同尺寸（４—１６ｎｍ）纳米Ｇｅ颗粒的Ｒａｍａｎ散射谱特征，与大块标准Ｇｅ晶体的散射峰相比，观察到了理论预期的纳米半导体粒子的Ｒａｍａｎ散射峰的宽化和红移现象．采用声子限域模型较好地解释了实验结果．探讨了ＳｉＯ_２介质基体作用于镶嵌Ｇｅ粒子的压应力以及纳米Ｇｅ粒子的表面界面效应对Ｒａｍａｎ散射光谱的峰形、峰位变化所产生的影响 关键词：     

X射线荧光光谱中散射效应对荧光强度的贡献研究

采用理论计算和实验测定的方法研究了在纯元素样品、BaB二元样品及熔融片样品中三种散射效应对荧光强度的贡献(包括相干散射X射线激发的荧光强度、非相干散射X射线激发的荧光强度以及其他方向的一次荧光X射线被散射进探测方向的强度)大小及其变化规律。研究结果表明,三种散射效应对荧光强度的贡献大小与所研究元素原子特征谱线的能量及样品的基体有关,元素原子的特征谱线能量越高,散射效应对荧光强度的贡献越大;轻基体样品中散射效应对荧光的贡献比重基体样品大。实验证明,将散射效应包括在基本参数法的理论计算中可以有效地提高理论计算的准确度。     

非晶PET纤维的分子链段取向分布的研究

用对称透射法,收集在室温下不同拉伸比的非晶聚酯（ＰＥＴ）纤维之二有Ｘ射线散射（ＷＡＸＳ）强度函数Ｉ（κ,α）,采用自编ＭＰＳ９６型全谱分峰程序,将不同方位角α测得的ＷＡＸＳ强度曲线上的４个非晶重叠峰进行分解,获得分子链间原子 射引起的２个峰为：ＫＡ＝０．１４１ｎｍ＾－１,ＫＢ＝０．１７２ｎｍ＾－１;分子链内原子 射引起的２个峰为;ＫＣ＝０．３１１ｎｍ＾－１,ＫＤ＝０．５５５ｎｍ＾－１,详细分析了     

铌酸钾锂晶全及其宽带二次谐波产生

报道了利用引上提拉法生长晨线性光学晶体铌酸钾锂,并且其实现了对准连续可调谐钛宝激光倍频。在波长为８９０－９５２ｎｍ范围内,通过室温下非监界相位匹配,得到４４５－４７６ｎｍ的二次谐波。抽运光强为１４４－２６９ｎＷ,二次谐波强度为０．５８－１．７３ｍＷ,倍频效率可达０．６５％。     

All-fiber Raman supercontinuum generator

The results on an all-fiber supercontinuum generator that exhibits a continuous wide spectrum in the range 1060–1640 nm predominantly owing to the cascade stimulated Raman scattering in a single-mode quartz fiber at a relatively high power of the combined femtosecond-picosecond pumping with a central wavelength of 1080 nm are presented for the first time. The mean power of the supercontinuum is 2.1 W.     

Investigation of surface topology of printed nanoparticle layers using wide‐angle low‐Q scattering

A new small‐angle scattering technique in reflection geometry is described which enables a topological study of rough surfaces. This is achieved by using long‐wavelength soft X‐rays which are scattered at wide angles but in the low‐Q range normally associated with small‐angle scattering. The use of nanometre‐wavelength radiation restricts the penetration to a thin surface layer which follows the topology of the surface, while moving the scattered beam to wider angles preventing shadowing by the surface features. The technique is, however, only applicable to rough surfaces for which there is no specular reflection, so that only the scattered beam was detected by the detector. As an example, a study of the surfaces of rough layers of silicon produced by the deposition of nanoparticles by blade‐coating is presented. The surfaces of the blade‐coated layers have rough features of the order of several micrometers. Using 2 nm and 13 nm X‐rays scattered at angular ranges of 5°≤θ≤ 51° and 5°≤θ≤ 45°, respectively, a combined range of scattering vector of 0.00842 Å^?1≤Q≤ 0.4883 Å^?1 was obtained. Comparison with previous transmission SAXS and USAXS studies of the same materials indicates that the new method does probe the surface topology rather than the internal microstructure.     

Static laser light scattering (SLLS) investigations of the scattering parameters of a synthetic polymer

A laser light scattering system was built to study the scattering parameters of some materials in solution form. The light source used was an argon-ion laser at wavelength 488 nm (all lines). The investigated material was a synthetic polymer which has a wide range of applications in the field of teeth medicine applications. This is polymethyl-methacrylate (PMMA) which is used for the formation of artificial clamps. The PMMA was solved in both acetone and methyl-ethyl-ketone (MEK). The acetone solvent is chosen for its high specific refractive index increment dn/dc at the same wavelength 488 nm as the argon laser source. The angular distribution of the scattered laser light intensities of PMMA dissolved in acetone was measured at different scattering angles from 30 to 150° for each concentration. The angular distributions have a symmetrical behavior about the scattering angle π/2; by using the scattered intensities the Zimm plot was formed. The weight average molecular weight (WAMW) was determined, the two other scattering parameters like as radius of gyration, h, and the second verial coefficient, A₂ were determined.     

利用康普顿后向散射产生X光源的研究

 利用高能电子对电磁波的康普顿后向散射可以获得波长短、方向性好的X光辐射,这种具有亮度高、发散角小、光子能量可调等特点的辐射,有很好的应用前景。由于电子对电磁场的散射截面很小,要获得较高强度的辐射,不仅要求很强的电磁场作为散射场,而且要求电子束的亮度高;利用光阴极RF腔注入器及30MeV射频加速器产生的30MeV电子束同Nd:YAG激光光腔中的强光场作用,可以获得较高强度的康普顿后向散射,其波长为0.07~0.14nm,发光本领可以达到2.5×10¹¹光子/s。     

Experimental determination of scattering matrices of dust particles at visible wavelengths: The IAA light scattering apparatus

We present a new apparatus for measuring the complete scattering matrix as a function of the scattering angle of dust irregular particles. The design is based on the well-known apparatus located in Amsterdam, The Netherlands. In this improved version we have extended the scattering angle ranging from 3° to 177°. Moreover, the measurements are performed with a tunable argon–krypton laser that emit at a wavelength (λ) of 483, 488, 520, 568, or 647 nm. The apparatus has been developed at the Instituto de Astrofísica de Andalucía (IAA), Granada, Spain. To measure the scattering matrix elements we use a number of different optical components such as polarizers, a quarter-wave plate, and an electro-optic modulator. These components are used to manipulate the polarization state of light. By using eight different combinations for the orientation angles of the optical components, all scattering matrix elements are obtained as functions of the scattering angle. The accuracy of the instrument is tested by comparing the measured scattering matrices of water droplets at 488, 520, and 647 nm with Lorenz–Mie calculations for a distribution of homogeneous water droplets.     

Femtosecond pulse generation using stimulated Raman scattering in integrated silicon optical waveguide device

To generate ultrafast femtosecond optical pulses, we propose a model of an integrated device consisting of a Mach-Zehnder interferometer (MZI) with two symmetric 3 dB directional couplers and a straight waveguide based on the single-mode silicon-on-insulator (SOI) optical waveguide. The principle of pulse generation in the presented device is based on the strong stimulated Raman scattering (SRS) in silicon; the center wavelength of the pulse generated is tunable by changing the center wavelength of the co-propagating pump pulse. Numerical results show that, when a continuous wave (CW) with a weak power at 1670 nm wavelength and a pump pulse with a high peak power at 1550 nm wavelength are co-propagating, a narrow femtosecond pulse with a pulse width (full width at half maximum, FWHM) of ∼60 fs (FWHM of the pump pulse is 166.5 fs) can be achieved in the device proposed. In addition, when the waveguide length, pump peak power, and pump-pulse width are fixed, the properties of generated femtosecond pulse depend strongly on the incident chirp of the pump pulse and the CW power.     

实际加工表面红外激光散射特性的实验研究

为了研究激光在实际加工表面的散射特性,利用分辨率为10 nW的激光功率计PM100D,波长为1550 nm的激光器和精密转台,自行设计并搭建了半球空间中目标表面散射特性的测量系统. 以典型的刨床加工的若干标准粗糙度比较样块为被测目标,在1550 nm红外激光以不同方位照射下,测量了微观具有V形槽结构的不同粗糙度的样块表面的散射功率分布. 实验结果转换成双向反射分布函数后,对比分析了入射光方位、入射角和表面粗糙度对此类典型表面散射特性的影响,并分析了特殊散射场形成的原因. 结果表明,表面纹理、入射角以及粗糙度均对目标表面的散射特性有规律性影响,这一结果对于具有规律性加工纹理表面的散射特性的研究和建模有一定的参考价值,对激光技术在实际加工表面的应用研究提供了一定的基础. 关键词： 散射特性 双向反射分布函数 红外激光 实际加工表面     

Raman scattering and luminescence of yttria nanopowders and ceramics

We have studied Raman scattering in yttria nanopowders and ceramics that was excited by radiation at wavelengths of 514.5 and 632.8 nm. We show that, in undoped nanopowders and cubic phase of doped yttria ceramics, only the Raman scattering by phonons is observed, with no other Raman scattering centers having been revealed. In nanopowders of the monoclinic phase, we have observed an additional Raman line with a Raman shift of 1093 ± 4 cm^?1. If all the objects under investigation are excited by the radiation at a wavelength of 514.5 nm, their spectra exhibit four series of photoluminescence lines, two of which (at λ = 521–523 and 538–564 nm) are emitted by Er³⁺ ions, “impurity” dopants, while the other two lines (at λ = 607–635 and 644–684 nm) are emitted by intrinsic centers. Under excitation by the radiation at a wavelength of 632.8 nm, only a series of bands at λ = 644–684 nm is emitted. In addition to these photoluminescence bands, neodymium-doped ceramics show photoluminescence bands of Nd³⁺ ions. We have shown that intrinsic luminescence centers, which occur in all the examined specimens, are capable of acting as acceptors with respect to neodymium ions excited to the upper laser level.     

Multiple scattering effect in the Young-like interference pattern of an optical wave scattered by a double cylinder

The plane-polarized laser wave with a wavelength of 441.6 nm collides with two close parallel cylinders, called a double cylinder, each of a diameter about 100 or 200 nm at normal incidence. The measured angular distribution of the scattered light intensity, called a Young-like interference pattern, is compared with the rigorous theoretical calculation over a wide range of scattering angles. We have experimentally confirmed the multiple scattering effect of the wave between cylinders in an exact way.