Synthesis and Crystal Structure of Mixed Mo－W Cubane－type Cluster Compound ［Mo_2W_2S_4（μ－OAc）_2（dtp）_3（dtpH）］·CH_2Cl_2

Ｓｙｎｔｈｅｓｉｓ　ａｎｄ　Ｃｒｙｓｔａｌ　Ｓｔｒｕｃｔｕｒｅ　ｏｆ　Ｍｉｘｅｄ　Ｍｏ－Ｗ　Ｃｕｂａｎｅ－ｔｙｐｅ　Ｃｌｕｓｔｅｒ　Ｃｏｍｐｏｕｎｄ　［Ｍｏ_２Ｗ_２Ｓ_４（μ－ＯＡｃ）_２（ｄｔｐ）_３（ｄｔｐＨ）］·ＣＨ_２Ｃｌ_２ＣｈｅｎＱｉｕ－Ｈｕ?..     

A Novel Cluster［V_2（AgPPh_3）_6S_6O_2］·2CH_2Cl_2 Containinga Cubane－like Array of Six Silver and Two Vanadium Atoms

ＡＮｏｖｅｌＣｌｕｓｔｅｒ［Ｖ_２（ＡｇＰＰｈ_３）_６Ｓ_６Ｏ_２］·２ＣＨ_２Ｃｌ_２ＣｏｎｔａｉｎｉｎｇａＣｕｂａｎｅ－ｌｉｋｅＡｒｒａｙｏｆＳｉｘＳｉｌｖｅｒａｎｄＴｗｏＶａｎａｄｉｕｍＡｔｏｍｓ￥ＺｈｅｎｇＦａ－Ｋｕｎ；ＨｕａｎｇＪｉｎ－Ｓｈｕｎ?..     

Syntheses， Structuresand Reactivity of Incomplete Cubane－like Compound［｛W_3S_4｝｛S_2P（OEt）_2｝_4（H_2O）］and Its Derivates

Ｓｙｎｔｈｅｓｅｓ,ＳｔｒｕｃｔｕｒｅｓａｎｄＲｅａｃｔｉｖｉｔｙｏｆＩｎｃｏｍｐｌｅｔｅＣｕｂａｎｅ－ｌｉｋｅＣｏｍｐｏｕｎｄ［｛Ｗ_３Ｓ_４｝｛Ｓ_２Ｐ（ＯＥｔ）_２｝_４（Ｈ_２Ｏ）］ａｎｄＩｔｓＤｅｒｉｖａｔｅｓ￥ＷｕＸｉｎ－Ｔａｏ;ＷａｎｇＱｕａ...     

Synthesis and Structureof［（C_2H_5）_4N］［Mo_3（μ_3－O）（μ－Cl）_3（μ－CH_3CH_2COO）_3Cl_3］

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ［（Ｃ_２Ｈ_５）_４Ｎ］［Ｍｏ_３（μ_３－Ｏ）（μ－Ｃｌ）_３（μ－ＣＨ_３ＣＨ_２ＣＯＯ）_３Ｃｌ_３］ＺｈｕａｎｇＨｏｎｇ－Ｈｕｉ；ＷｕＤｉｎｇ－Ｍｉｎｇ；ＨｕａｎｇＪｉａｎ－Ｑｕａｎ；ＨｕａｎｇＪｉｎ－Ｌ...     

Synthesis, Crystal Structure and Spectroscopic Properties of an Octanuclear V-S-Cu Cluster {V_2S_6Cu_6}(PPh_3)_6(O)_2·2CH_2Cl_2·CH_3OH with a Metal-sulfur Dodecahedral Cage

1 INTRODUCTION The reactivities of the thiometalates [MOnS4-n]z－ (n=0~2) and their applications in synthetic chemistry are very attractive because they have been shown to act as multi-ligands to a wide variety of metal ions[1]. The chemistry of Mo(W)S clusters derived from thiometalates has been most highly developed[2] for some MoS clusters are closely relevant to biological activities[3,4]. As for thiovanadates, only [VS4]3－ species has been used as ligands to coordinate metal at…     

Study on Infrared Spectra and Chemical Bonding of the Cluster Anion ［Cl_2FeS_2MoS_2Cu（PPh_3）_2］~－

ＳｔｕｄｙｏｎＩｎｆｒａｒｅｄＳｐｅｃｔｒａａｎｄＣｈｅｍｉｃａｌＢｏｎｄｉｎｇｏｆｔｈｅＣｌｕｓｔｅｒＡｎｉｏｎ［Ｃｌ_２ＦｅＳ_２ＭｏＳ_２Ｃｕ（ＰＰｈ_３）_２］~－ＫｏｎｇＸｉａｎ－Ｌｉｎｇ；ＣｈｅｎＺｈｉ－Ｄａ；ＳｈｅｎｇＴｉａｎ－Ｌｕ；ＷｕＸｉ...     

Synthesis and Crystal Structure of［Lu（NO_3）_3（H_2O）_2（CH_3CN）］（Benzo－15－C－5）·CH_3CN

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｌｕ（ＮＯ_３）_３（Ｈ_２Ｏ）_２（ＣＨ_３ＣＮ）］（Ｂｅｎｚｏ－１５－Ｃ－５）·ＣＨ_３ＣＮＷａｎｇＲｕｉ－Ｙａｏ；ＪｉｎＺｈｏｎｇ－Ｓｈｅｎｇ；ＮｉＪｉａ－Ｚｕａｎ（Ｌａｂｏｒａｔｏｒｙｏ...     

Synthesis and Crystal Structure of Dinuclear Copper Cluster Compound ［Cu（dtp）PPh_3］_2

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＤｉｎｕｃｌｅａｒＣｏｐｐｅｒＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄ［Ｃｕ（ｄｔｐ）ＰＰｈ_３］_２ＣｈｅｎＱｉｕ－Ｈｕａ；ＬｕＳｈａｏ－Ｆａｎｇ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ（ＳｔａｔｅｋｅｙＬａｂ...     

Synthesis,Structure and Reaction of a New Bitungsten Compound:(Et_4N)_2W_2S_4 (tdt)_2

1INTRODUCTION'TheclusterscontainingMo--SorW--Shavebeenstudiedextensivelyfortheirimportantapplicationsinmanyfieldsll~43.Alongwith.thedevelopmentofrationaldesignedsynthesissuchasthe"UnitConstruction"utilizingwell-definedactivecom-poundsasbuildingblocks,binuclearsulfidecompoundsusedtodesignnewclustershavebeenpaidattentiontots'6itandalotofcompoundscontainingiM,S.O.--.J' (M=MoorW)coreshavebeenprepared['i.Inthispaper,thefirstexamplpofbitung-stencompoundwithtdtZ--ligands(Et.N),W,S.(tdt),,…     

Synthesis and Crystal Structure of μ_4－alkyne Cluster Complex（μ_4－η~2－C_2Ph_2）Co_4（CO）_8（μ－CO）_2

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆμ_４－ａｌｋｙｎｅＣｌｕｓｔｅｒＣｏｍｐｌｅｘ（μ_４－η~２－Ｃ_２Ｐｈ_２）Ｃｏ_４（ＣＯ）_８（μ－ＣＯ）_２ＳｏｎｇＬｉ－Ｃｈｅｎｇ;ＳｈｅｎＪｉｎ－Ｙｕ;ＨｕＱｉｎｇ－Ｍｅｉ;Ｈｕａｎｇ...     

Structural Studies of [V_2S_6O_2(CuPPh_3)_4(CuMeCN)_2]·2CH_2Cl_2·2PrOH

ＳｔｒｕｃｔｕｒａｌＳｔｕｄｉｅｓｏｆ［Ｖ_２Ｓ_６Ｏ_２（ＣｕＰＰｈ_３）_４（ＣｕＭｅＣＮ）_２］·２ＣＨ_２Ｃｌ_２·２ＰｒＯＨＺＨＡＮＧＨａｎ－Ｈｕｉ；ＹＵＸｉｕ－Ｆｅｎ；ＹＡＮＧＲｏｎｇ－Ｓｈｅｎｇ；ＺＨＥＮＧＦａ－Ｋｕｎ；ＨＵＡＮＧＬｉａｏ－Ｙｕ...     

Studies on the V－Cu－S Heterometallic Cluster Compounds（2）．Crystal Structure of［VS_4（CuPPh_3）_5Br_2］·0．5CH_2Cl_2

ＳｔｕｄｉｅｓｏｎｔｈｅＶ－Ｃｕ－ＳＨｅｔｅｒｏｍｅｔａｌｌｉｃＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓ（２）．ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［ＶＳ_４（ＣｕＰＰｈ_３）_５Ｂｒ_２］·０．５ＣＨ_２Ｃｌ_２ＺｈｅｎｇＦａ－Ｋｕｎ；ＹｕＸｉｕ－Ｆｅｎ（Ｓｔａ...     

Study on the Magnetic Properties of MoFe_3S_4 Single Cubane－like Clusters Containing R_2dtc Ligands

ＳｔｕｄｙｏｎｔｈｅＭａｇｎｅｔｉｃＰｒｏｐｅｒｔｉｅｓｏｆＭｏＦｅ_３Ｓ_４ＳｉｎｇｌｅＣｕｂａｎｅ－ｌｉｋｅＣｌｕｓｔｅｒｓＣｏｎｔａｉｎｉｎｇＲ_２ｄｔｃＬｉｇａｎｄｓＬＩＵＱｉｕ－Ｔｉａｎ；ＤＥＮＧＹｕ－Ｈｅｎｇ；ＣＨＥＮＣｈａｎｇ－Ｎｅｎｇ（?..     

Synthesis, Crystal Structure and Luminescence Property of [Ag_2(dppm)_2(NMP)_2](SbF_6)_2·4H_2O·3CH_2Cl_2

1 INTRODUCTION cited state by the intense spin-obital coupling of Ag?, and the energy gap between triplet excited state and The study of photoluminescent properties of d10 singlet ground state is very small, which causes lu- metal complexes has been receiving current atten- minescence quenching of Ag? complex[15, 16 ] . tion. A number of polynuclear complexes of Au, Ag, In this paper, we report the synthesis and struc- and Cu containing bridging phosphine ligands have tural characterizat…     

EPR Study of a New Crystal of the Binuclear Copper（Ⅱ） Cluster Compound－〔Cu_2（α－C_（10）H_7CH_2CO_2）_4－（DMF）_2〕·（DMF）_2·H_2O

ＥＰＲＳｔｕｄｙｏｆａＮｅｗＣｒｙｓｔａｌｏｆｔｈｅＢｉｎｕｃｌｅａｒＣｏｐｐｅｒ（Ⅱ）ＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄ－〔Ｃｕ_２（α－Ｃ_（１０）Ｈ_７ＣＨ_２ＣＯ_２）_４－（ＤＭＦ）_２〕·（ＤＭＦ）_２·Ｈ_２Ｏ￥ＳｕｎＱｉｏｎｇ－Ｌｉ；ＨｕａｎｇＸ?..     

Synthesis and Structural Characterization of the Complex 〔Et_4N〕_2〔Ni_2(C_2S_4)(C_3S_5)_2〕

１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｏｕｎｄｓｗｉｔｈｄｍｉｔ（ｄｍｉｔ＝１,３ ｄｉｔｈｉｏｌｅ ２ ｔｈｉｏｎｅ ４,５ ｄｉｔｈｉｏｌａｔｅ）ｈａｓａｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌ...     

Synthesis and Structural Characterization of a Hetcrobimctallic Molybdenum-Copper-Sulfur Compound [Et_4N]_2 CMoCu_3S_4 (S_2CNEt_2)_3]

<正> The title compound crystallizes in orthogonal space group P212121with α= 12. 848 (5), b =13. 227 (3), c = 29. 519(8) A ,Z = 4 , V= 5016. 5 A3 and Dc = 1. 483g/cm3. 4940 independent reflcctiions were collected on a CAD4 diffractometer with MoKa radiation in the range of 1°<0<25°,of which 3559 reflections having intensities I >3σ(I) were used for structure determination. The structure was solved by direct methods and refined by the least-squares method to final discrepancy factors R=0. 071 and Rw - 0. 075. The anion of the title compound can be described as a slightly distorted MoS42-tetrahedron coordinated by three [CuS2CNEt2] units ,with the four metal atoms lying approximately in a plane.     

Synthesis,Structure and Electrochemistry of Triruthenium Cluster Complex [Ru_3(μ_3- O)(μ-CH_3CO_2)_6(py)_2(PPh_2py)](PF_6)·CH_2Cl_2

1 INTRODUCTION The transition metal cluster complexes exhi- biting multistep redox processes have attracted more and more attention because of their potential applications in the areas of photonic and electronic devices[1～4]. The oxo-centered carboxyla…     

Synthesis and Structure of Ru (pap)_2Cl_2 · 4EtOH

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆＲｕ（ｐａｐ）_２Ｃｌ_２·４ＥｔＯＨ￥ＺｈａｏＷｅｉ－Ｊｕｎ；ＺｈａｎｇＳｈｕ－Ｊｉ；ＤｅｎｇＹｉ；ＺｈａｎｇＺｈｅｎｇ－Ｚｈｉ；ＭａＹａｎ－Ｆｅｎｇ；ＨｕａｎｇＷｅｉ－Ｐｉｎｇ；ＷａｎｇＨｏｎｇ－Ｇｅｎ...