Inelastic atom-surface scattering: A comparison of classical and quantum treatments

The validity of the classical approximation is investigated for the calculation of the energy transfer and sticking coefficient of particles scattered by harmonic solids. If in zeroth order the static approximation for the force between particle and solid is valid, the energy transfer can be calculated classically, if the WKB approximation for the matrix element of the force holds. This is the case except at low impact energies. The characteristic energy below which quantum effects become important depends strongly on the long range behavior of the force.For the sticking coefficient one has to distinguish quantum effects of particle and solid. Quantum effects for the particle can again be neglected if the WKB approximation for the matrix elements is valid. The solid, however, can be treated classically only, if the number of excited phonons is large compared to unity. This requires energy transfers large compared to the Debye energy of the solid.Extract from doctoral thesis of R.S. submitted to Fakultät für Physik, Techn. Univ. München, 1979. Work supported in part by DFG, Sonderforschungsbereich 128     

Nonstandard analysis in classical physics and quantum formal scattering

After a rigorous introduction to hyperreal numbers, we give in terms of non standard analysis, (1) a Lagrangian statement of classical physics, and (2) a statement of formal quantum scattering.     

Characterization of classical Gaussian processes using quantum probes

We address the use of a single qubit as a quantum probe to characterize the properties of classical noise. In particular, we focus on the characterization of classical noise arising from the interaction with a stochastic field described by Gaussian processes. The tools of quantum estimation theory allow us to find the optimal state preparation for the probe, the optimal interaction time with the external noise, and the optimal measurement to effectively extract information on the noise parameter. We also perform a set of simulated experiments to assess the performances of maximum likelihood estimator, showing that the asymptotic regime, where the estimator is unbiased and efficient, is approximately achieved already after few thousands repeated measurements on the probe system.     

Comparison between the classical and quantum theories of incoherent scattering

Acta physica Academiae Scientiarum Hungaricae - The incoherent scattering of light by a volume of gas can be treated by classical methods in a straightforward manner. Certain difficulties are...     

Minimum length from quantum mechanics and classical general relativity

We derive fundamental limits on measurements of position, arising from quantum mechanics and classical general relativity. First, we show that any primitive probe or target used in an experiment must be larger than the Planck length lP. This suggests a Planck-size minimum ball of uncertainty in any measurement. Next, we study interferometers (such as LIGO) whose precision is much finer than the size of any individual components and hence are not obviously limited by the minimum ball. Nevertheless, we deduce a fundamental limit on their accuracy of order lP. Our results imply a device independent limit on possible position measurements.     

On the definition and evolution of states in relativistic classical and quantum mechanics

Some of the problems associated with the construction of a manifestly covariant relativistic quantum theory are discussed. A resolution of this problem is given in terms of the off mass shell classical and quantum mechanics of Stueckelberg, Horwitz and Piron. This theory contains many questions of interpretation, reaching deeply into the notions of time, localizability and causality. A proper generalization of the Maxwell theory of electromagnetic interaction, required for the well-posed formulation of dynamical problems of systems with electromagnetic interaction is discussed, and some of the significance of recently found (classical) relativistic chaotic behavior is pointed out. Many results of a technical nature have been achieved in this framework; in this paper, some of these are reviewed, but I shall concentrate on a discussion of the basic ideas and foundations of the theory.On sabbatical leave from School of Physics and Astronomy, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, Israel.     

Efficient classical simulation of continuous variable quantum information processes

We obtain sufficient conditions for the efficient simulation of a continuous variable quantum algorithm or process on a classical computer. The resulting theorem is an extension of the Gottesman-Knill theorem to continuous variable quantum information. For a collection of harmonic oscillators, any quantum process that begins with unentangled Gaussian states, performs only transformations generated by Hamiltonians that are quadratic in the canonical operators, and involves only measurements of canonical operators (including finite losses) and suitable operations conditioned on these measurements can be simulated efficiently on a classical computer.     

Deriving a kinetic uncertainty relation for piecewise deterministic processes: from classical to quantum

From the perspective of Markovian piecewise deterministic processes (PDPs), we investigate the derivation of a kinetic uncertainty relation (KUR), which was originally proposed in Markovian open quantum systems. First, stationary distributions of classical PDPs are explicitly constructed. Then, a tilting method is used to derive a rate functional of large deviations. Finally, based on an improved approximation scheme, we recover the KUR. These classical results are directly extended to the open quantum systems. We use a driven two-level quantum system to exemplify the quantum results.     

The logic of quantum mechanics derived from classical general relativity

For the first time it is shown that the logic of quantum mechanics can be derived from classical physics. An orthomodular lattice of propositions characteristic of quantum logic, is constructed for manifolds in Einstein’s theory of general relativity. A particle is modelled by a topologically non-trivial 4-manifold with closed timelike curves—a 4-geon, rather than as an evolving 3-manifold. It is then possible for both the state preparationand measurement apparatus to constrain the results of experiments. It is shown that propositions about the results of measurements can satisfy a non-distributive logic rather than the Boolean logic of classical systems. Reasonable assumptions about the role of the measurement apparatus leads to an orthomodular lattice of propositions characteristic of quantum logic.     

Direct computation of scattering matrices for general quantum graphs

We present a direct and simple method for the computation of the total scattering matrix of an arbitrary finite noncompact connected quantum graph given its metric structure and local scattering data at each vertex. The method is inspired by the formalism of Reflection–Transmission algebras and quantum field theory on graphs though the results hold independently of this formalism. It yields a simple and direct algebraic derivation of the formula for the total scattering and has a number of advantages compared to existing recursive methods. The case of loops (or tadpoles) is easily incorporated in our method. This provides an extension of recent similar results obtained in a completely different way in the context of abstract graph theory. It also allows us to discuss briefly the inverse scattering problem in the presence of loops using an explicit example to show that the solution is not unique in general. On top of being conceptually very easy, the computational advantage of the method is illustrated on two examples of “three-dimensional” graphs (tetrahedron and cube) for which other methods are rather heavy or even impractical.     

Time-dependent quantum mechanical approach to reactive scattering and related processes

The time-dependent quantum mechanical approach has emerged as a powerful and a practical computational tool for studying a variety of gas-phase chemical problems in recent years. In this report, we discuss the various developments that have made this possible with special emphasis on methodology and application to reactive scattering, photo-excitation processes and gas-surface interaction.     

Nonequilibrium charge susceptibility and dynamical conductance: identification of scattering processes in quantum transport

We calculate the nonequilibrium charge transport properties of nanoscale junctions in the steady state and extend the concept of charge susceptibility to the nonequilibrium conditions. We show that the nonequilibrium charge susceptibility is related to the nonlinear dynamical conductance. In spectroscopic terms, both contain the same features versus applied bias when charge fluctuation occurs in the corresponding electronic resonances. However, we show that, while the conductance exhibits features at biases corresponding to inelastic scattering with no charge fluctuations, the nonequilibrium charge susceptibility does not. We suggest that measuring both the nonequilibrium conductance and charge susceptibility in the same experiment will permit us to differentiate between different scattering processes in quantum transport.     

Effect of spontaneous Raman scattering on quantum channel wavelength-multiplexed with classical channel

We quantitatively estimate the effect of spontaneous Raman scattering on a quantum channel wavelength-multiplexed with a classical channel. Based on an experiment that measured the generation power of spontaneous Raman scattering in a fiber, the performance of wavelength-multiplexed quantum key distribution (QKD) systems using the differential-phase-shift protocol is evaluated for various system conditions.     

On some aspects of the definition of scattering states in quantum field theory

The problem of extending quantum-mechanical formal scattering theory to a more general class of models that also includes quantum field theories is discussed, with the aim of clarifying certain aspects of the definition of scattering states. As the strong limit is not suitable for the definition of scattering states in quantum field theory, some other limiting procedure is needed. Two possibilities are considered, the abelian limit and adiabatic switching. Formulas for the scattering states based on both methods are discussed, and it is found that generally there are significant differences between the two approaches. As an illustration of the applications and the features of these formulas, S-matrix elements and energy corrections in two quantum field theoretical models are calculated using (generalized) old-fashioned perturbation theory. The two methods are found to give equivalent results.     

Roles of classical dynamics and quantum dynamics on activated processes occurring in liquids

This paper reviews the reactive flux correlation function approach to studying the classical dynamics of activated processes in liquids. The possibilities and consequences of nonadiabatic electronic transitions in affecting this dynamics is also considered. We emphasize the feasibility of quantitative trajectory studies and the fact that these studies have yet to be fully exploited in the development of approximate theories of activated processes.     

Zwitters: Particles between quantum and classical

We describe both quantum particles and classical particles in terms of a classical statistical ensemble, with a probability distribution in phase space. By use of a wave function in phase space both can be treated in the same quantum formalism. Quantum particles are characterized by a specific choice of observables and time evolution of the probability density. Then interference and tunneling are found within classical statistics. Zwitters are (effective) one-particle states for which the time evolution interpolates between quantum and classical particles. Experimental bounds on a small parameter can test quantum mechanics.     

Tomographic quantum cryptography: equivalence of quantum and classical key distillation

The security of a cryptographic key that is generated by communication through a noisy quantum channel relies on the ability to distill a shorter secure key sequence from a longer insecure one. For an important class of protocols, which exploit tomographically complete measurements on entangled pairs of any dimension, we show that the noise threshold for classical advantage distillation is identical with the threshold for quantum entanglement distillation. As a consequence, the two distillation procedures are equivalent: neither offers a security advantage over the other.     

Classical limit of scattering in quantum mechanics—A general approach

The classical and quantum physics seem to divide nature into two domains macroscopic and microscopic. It is also certain that they accurately predict experimental results in their respective regions. However, the reduction theory, namely, the general derivation of classical results from the quantum mechanics is still a far cry. The outcome of some recent investigations suggests that there possibly does not exist any universal method for obtaining classical results from quantum mechanics. In the present work we intend to investigate the problem phenomenonwise and address specifically the phenomenon of scattering. We suggest a general approach to obtain the classical limit formula from the phase shiftδ _l, in the limiting value of a suitable parameter on whichδ _l depends. The classical result has been derived for three different potential fields in which the phase shifts are exactly known. Unlike the current wisdom that the classical limit can be reached only in the high energy regime it is found that the classical limit parameter in addition to other factors depends on the details of the potential fields. In the last section we have discussed the implications of the results obtained.