How flow changes polymer depletion in a slit

A theoretical model is developed for predicting dynamic polymer depletion under the influence of fluid flow. The results are established by combining the two-fluid model and the self-consistent field theory. We consider a uniform fluid flow across a slit containing a solution with polymer chains. The two parallel and infinitely long walls are permeable to solvent only and the polymers do not adsorb to these walls. For a weak flow and a narrow slit, an analytic expression is derived to describe the steady-state polymer concentration profiles in a $ \Theta$ -solvent. In both $ \Theta$ - and good-solvents, we compute the time evolution of the concentration profiles for various flow rates characterized by the Peclet number. The model reveals the interplay of depletion, solvent condition, slit width, and the relative strength of the fluid flow.      

Standard Model Gauge Couplings from Gauge-Dilatation Symmetry Breaking

It is well known that the self-energy of the gauge bosons is quadratically divergent in the Standard Model when a simple cutoff is imposed. We demonstrate phenomenologically that the quadratic divergences in fact unify. The unification occurs at a surprisingly low scale, \(\Lambda _\mathrm {u}\approx 4\times 10^7\)  GeV. Suppose now that there is a spontaneously broken rotational symmetry between the space-time coordinates and gauge theoretical phases. The symmetry-breaking pattern is such that the gauge bosons arise as the massless Goldstone bosons, whereas the dilatonic mode acts as the massive (Higgs) boson, whose vacuum expectation value determines the gauge couplings. In this case, the quadratic divergences or the tadpoles of the gauge boson self-energy should indeed unify because these divergences need to be cancelled by a universal dilatonic contribution, assuming dynamical symmetry breaking. If there is dynamical symmetry breaking, we are in principle able to calculate the value of the gauge couplings as well as the scale hierarchy \(\Lambda _\mathrm {cut}/\Lambda _\mathrm {u}\) . We perform this calculation by adopting a naive quartic symmetry-breaking potential which unfortunately violates local gauge invariance. Using tadpole-cancellation and dilatonic self-energy conditions, the value of \(\Lambda _\mathrm {cut}\) is then found to be approximately \(4\times 10^{18}\)  GeV in the Feynman gauge and \(5\times 10^{15}\)  GeV in the Landau gauge. The cancellation of an anomaly in the dilaton self-energy requires that the number of fermionic generations equals three. The symmetry-breaking needs to be driven by some other mass-generating mechanism such as electroweak symmetry breaking. Our estimation for \(\Lambda _\mathrm {u}\) is of the correct order if \(\Lambda _\mathrm {cut}\approx 5\times 10^{15}\)  GeV.     

Motions of vortex patches

An evolution equation describing the motion of vortrex patches is established. The existence of steady solutions of this equation is proved. These solutions arem-fold symmetric regions of constant vorticity ω₀ and are uniformly rotating with angular velocity Ω in the range $$\tilde \Omega _{m - 1}< \tilde \Omega \leqslant \tilde \Omega _m (\tilde \Omega = \Omega /\omega _0 ,m \geqslant 2)$$ where \(\tilde \Omega _m = (m - 1)/2m\) . We call this class, ofm-fold symmetric rotating regionsD, the class of them-waves of Kelvin. Any may be regarded as a simply connected region which is a stationary configuration of the Euler equations in two dimensions. If then any magnification, rotation or reflection is also in with the same angular velocity Ω ofD. The angular velocity \(\Omega _m = \tilde \Omega _m \omega _0 \) corresponds only to the circle solution, which is a trivial member of every class ,m?2. The class corresponds to the rotating ellipses of Kirchoff. Other properties of the class are established.     

Particle-quadrupole and particle-octupole coupled states in 145Sm

In the present paper we present part of the results obtained in the study of above-yrast states in ¹⁴⁵Sm using the ¹⁴²Nd(α,Xnγ) reaction. γ-γ, angular distribution, polarization, and excitation function measurements were performed. All multiplet members of the and the multiplets have been observed. The unperturbed energies for the multiplet have been estimated using the extensive information existing on one neutron transfer reactions. The results are compared with the ¹⁴³Nd case. The similarity is remarkable.     

Stuck in traffic: Patterns of powder adhesion

The adhesion of fine particles to surfaces is important for applications ranging from drug delivery to fouling of solar cells. In this letter, we show that powder adhesion can occur in unexpected patterns, concentrating particular grain types in some locations and clearing them from others, and we propose a straightforward traffic model that appears to reproduce many of the behaviors seen. The model predicts different patterns depending on inter-particle cohesion, and we find in both experiment and model that adhesion occurs in three distinct stages.      

Is the CNMSSM more credible than the CMSSM?

“Post-sphaleron baryogenesis”, a fresh and profound mechanism of baryogenesis accounts for the matter–antimatter asymmetry of our present universe in a framework of Pati–Salam symmetry. We attempt here to embed this mechanism in a non-SUSY SO(10) grand unified theory by reviving a novel symmetry breaking chain with Pati–Salam symmetry as an intermediate symmetry breaking step and as well to address post-sphaleron baryogenesis and neutron–antineutron oscillation in a rational manner. The Pati–Salam symmetry based on the gauge group \(\mathrm{SU}(2)_L \times \mathrm{SU}(2)_{R} \times \mathrm{SU}(4)_C\) is realized in our model at \(10^{5}\) – \(10^{6}\)  GeV and the mixing time for the neutron–antineutron oscillation process having \(\Delta B=2\) is found to be \(\tau _{n-\bar{n}} \simeq 10^{8}\) – \(10^{10}\)  s with the model parameters, which is within the reach of forthcoming experiments. Other novel features of the model include low scale right-handed \(W^{\pm }_R\) , \(Z_R\) gauge bosons, explanation for neutrino oscillation data via the gauged inverse (or extended) seesaw mechanism and most importantly TeV scale color sextet scalar particles responsible for an observable \(n\) – \(\bar{n}\) oscillation which may be accessible to LHC. We also look after gauge coupling unification and an estimation of the proton lifetime with and without the addition of color sextet scalars.     

An efficient and facile synthesis of 3-amino-5-chromenyl-butenolides from 3-formyl chromone, dialkyl acetylenedicarboxylate, and primary amines

A three-component reaction of 3-formyl chromones, dialkyl acetylenedicarboxylate, and isocyanides in the presence of $\text{ POCl}_{3}$ was used as a highly efficient and practical approach for the synthesis of 3-amino-5-chromenyl-butenolides. High yields and high bond forming efficiency, and simple operations are the advantages of this method. Graphical abstract      

Mesoscopic models for DNA stretching under force: New results and comparison with experiments

We investigate the dynamical behavior of simple networks, namely loops with an additional internal regulating connection. Continuous dynamics for mRNA and protein concentrations is compared to a Boolean model for gene activity. Using a generalized method and within a single framework, we study different continuous models and different types of regulatory functions, and establish conditions under which the system can display stable oscillations or stable fixed points. These conditions depend only on general features such as the degree of cooperativity of the regulating interactions and the logical structure of the interactions. There are no simple rules for deciding when Boolean and continuous dynamics agree with each other, but we identify several relevant criteria.      

Naturalness and Theoretical Constraints on the Higgs Boson Mass

Arbitrary regularization dependent parameters in Quantum Field Theory are usually fixed on symmetry or phenomenology grounds. We verify that the quadratically divergent behavior responsible for the lack of naturalness in the Standard Model (SM) is intrinsically arbitrary and regularization dependent. While quadratic divergences are welcome for instance in effective models of low energy QCD, they pose a problem in the SM treated as an effective theory in the Higgs sector. Being the very existence of quadratic divergences a matter of debate, a plausible scenario is to search for a symmetry requirement that could fix the arbitrary coefficient of the leading quadratic behavior to the Higgs boson mass to zero. We show that this is possible employing consistency of scale symmetry breaking by quantum corrections. Besides eliminating a fine-tuning problem and restoring validity of perturbation theory, this requirement allows to construct bounds for the Higgs boson mass in terms of $\delta m^{2}/m^{2}_{H}$ (where m _H is the renormalized Higgs mass and δm ² is the 1-loop Higgs mass correction). Whereas $\delta m^{2}/m^{2}_{H}<1$ (perturbative regime) in this scenario allows the Higgs boson mass around the current accepted value, the inclusion of the quadratic divergence demands $\delta m^{2}/m^{2}_{H}$ arbitrarily large to reach that experimental value.     

On a symmetry topological classification of edge states in crystalline spin-Hall insulators with the time reversal invariance

Symmetry analysis reveals all types of singularities of the edge states in two-dimensional systems with a boundary (2D → 1D systems), which are invariant under time reversal. Symmetry reasons also provide the matching condition for material functions parameterizing the Hamiltonian at various points of the Brillouin zone. The unified parameterization of the Hamiltonian makes it possible to construct the mapping of trajectories closed in the quasimomentum k in the Brillouin zone into the SU(2) topological group. There are only two equivalence classes of Hamiltonians, which are given by the elements of the first fundamental group . The first type of surface states corresponds to a normal insulator and the second type corresponds to a topological spin-Hall insulator. Comparison with the classification based on the Pfaffian method is performed.     

New constraints on the 3-3-1 model with right-handed neutrinos

In the framework of a 3-3-1 model with right-handed neutrinos and three scalar triplets we consider different spontaneous symmetry breaking patterns seeking for a non-linear realization of accidental symmetries of the model, which will produce physical Nambu–Goldstone (NG) bosons in the neutral scalar spectrum. We make a detailed study of the safety of the model concerning the NG boson emission in energy-loss processes which could affect the standard evolution of astrophysical objects. We consider the model with a \(\mathbb {Z}_2\) symmetry, conventionally used in the literature, finding that in all of the symmetry breaking patterns the model is excluded. Additionally, looking for solutions for that problem, we introduce soft \(\mathbb {Z}_2\)-breaking terms in the scalar potential in order to remove the extra accidental symmetries and at the same time maintain the model as simple as possible. We find that there is only one soft \(\mathbb {Z}_2\)-breaking term that enables us to get rid of the problematic NG bosons.     

Instabilities in wormlike micelle systems

Shear-banding is ubiquitous in complex fluids. It is related to the organization of the flow into macroscopic bands bearing different viscosities and local shear rates and stacked along the velocity gradient direction. This flow-induced transition towards a heterogeneous flow state has been reported in a variety of systems, including wormlike micellar solutions, telechelic polymers, emulsions, clay suspensions, colloidal gels, star polymers, granular materials, or foams. In the past twenty years, shear-banding flows have been probed by various techniques, such as rheometry, velocimetry and flow birefringence. In wormlike micelle solutions, many of the data collected exhibit unexplained spatio-temporal fluctuations. Different candidates have been identified, the main ones being wall slip, interfacial instability between bands or bulk instability of one of the bands. In this review, we present experimental evidence for a purely elastic instability of the high shear rate band as the main origin for fluctuating shear-banding flows.      

Heavy baryons in the relativistic quark model

In the framework of the relativistic quasipotential quark model the mass spectrum of baryons with two heavy quarks is calculated. The quasipotentials for interactions of two quarks and of a quark with a scalar and axial vector diquark are evaluated. The bound state masses of baryons with are computed.     

Dynamics of Purcell’s three-link microswimmer with a passive elastic tail

One of the few possible mechanisms for self-propulsion at low Reynolds number is undulations of a passive elastic tail, as proposed in the classical work of Purcell (1977). This effect is studied here by investigating a variant of Purcell??s three-link swimmer model where the front joint angle is periodically actuated while the rear joint is driven by a passive torsional spring. The dynamic equations of motion are formulated and explicit expressions for the leading-order solution are derived by using perturbation expansion. The dependence of the motion on the actuation amplitude and frequency is analyzed, and optimization with respect to the swimmer??s geometry is conducted.      

Decoherence induced by magnetic impurities in a quantum hall system

Scattering by magnetic impurities is known to destroy coherence of electron motion in metals and semiconductors. We investigate the decoherence introduced in a single act of electron scattering by a magnetic impurity in a quantum Hall system. For this, we introduce a fictitious nonunitary scattering matrix for electrons that reproduces the exactly calculated scattering probabilities. The strength of decoherence is identified by the deviation of eigenvalues of the product from unity. Using the fictitious scattering matrix, we estimate the width of the metallic region at the quantum Hall effect inter-plateau transition and its dependence on the exchange coupling strength and the degree of polarization of magnetic impurities.     

Electro-Production of Light Lambda Hypernuclei

Through the study of light hypernuclei, we can learn about hyperon nucleon interaction. The hypernuclear spectroscopy with electron beams is one of most powerful methods to study detailed structure of light hypernuclei thanks to its high energy resolution. With a decade of efforts at Jefferson Lab, the spectroscopy of Λ hypernuclei with an electron beam is now established. Observation of ${_{\Lambda}^{7}}$ He which gave the last missing binding energy of the A = 7, T = 1 iso-triplet hypernuclei provides an important experimental input for the charge symmetry breaking (CSB) effect of the ΛN interaction. Further study about A = 4 hypernuclear iso-doublet, ${_{\Lambda}^{4}}$ H and ${_{\Lambda}^{4}}$ He, is necessary and such experiments are now planned.     

Charge density excitations in bilayer graphene in high magnetic field

The charge-density excitations in bilayer graphene at the filling-factor ν 1 at small momenta are considered in the frame of the Hartree-Fock approximation. The presence of small asymmetry of graphene layers is included. The dependence of the magnetoplasmon energy on the bilayer ground state is shown. The energy splitting proportional to $ \sqrt H $ for the symmetric case with half-filled zero-energy levels is found both for bilayer and monolayer graphene.     

Cyclic Azacyanines: Experimental and Computational Studies on Spectroscopic Properties and Unique Reactivity

The absorption and fluorescence properties of cyclic azacyanine (CAC) derivatives were examined in several solvents. The presence of electron donating or withdrawing groups on the CAC impacts spectroscopic properties. The general solvent relaxation displayed by azacyanine derivatives is in accordance with Lippert-Mataga’s prediction but exception is noted in the case of protic solvent due to specific hydrogen bonding interactions. Fluorescence lifetime decay studies indicate a relaxation time in the nanosecond timescale with mono exponential decay. Donating substituents markedly increase the excited state lifetime, whereas withdrawing groups marginally decrease the excited state lifetime. Quantum chemical computations were used to explore the origins of the reactivity and spectroscopic properties of CACs; results are consistent with a model in which regioselectivity results from differences in mechanistic steps occurring after initial attack by hydroxide on the CAC.      

Reverse buoyancy in a vibrated granular bed: Computer simulations

We have performed molecular dynamics simulations of an intruder in a vibrated granular bed including interstitial fluid effects to account for the phenomenon of reverse buoyancy. We show that our model is able to reproduce the overall behaviour observed by previous experimental works and is the first finite-elements simulation to show the sinking of intruders lighter than the granular bed. To further advance our comprehension of this phenomenon, we studied the motion of the intruders in a single vibration cycle with respect to the bottom of the granular column, finding a substantial qualitative difference for heavy and light intruders and we compare these results with experiments using fine-sized glass beads. We show that, though heavy intruders seem unaffected by the force due to the fluid, the effect on light intruders is remarkable.