How flow changes polymer depletion in a slit

A theoretical model is developed for predicting dynamic polymer depletion under the influence of fluid flow. The results are established by combining the two-fluid model and the self-consistent field theory. We consider a uniform fluid flow across a slit containing a solution with polymer chains. The two parallel and infinitely long walls are permeable to solvent only and the polymers do not adsorb to these walls. For a weak flow and a narrow slit, an analytic expression is derived to describe the steady-state polymer concentration profiles in a $ \Theta$ -solvent. In both $ \Theta$ - and good-solvents, we compute the time evolution of the concentration profiles for various flow rates characterized by the Peclet number. The model reveals the interplay of depletion, solvent condition, slit width, and the relative strength of the fluid flow.      

Structure and dynamics of a polymer melt at an attractive surface

We study the structural and dynamic properties of a polymer melt in the vicinity of an adhesive solid substrate by means of Molecular Dynamics simulation at various degrees of surface adhesion. The properties of the individual polymer chains are examined as a function of the distance to the interface and found to agree favorably with theoretical predictions. Thus, the adsorbed amount at the adhesive surface is found to scale with the macromolecule length as $\Gamma \propto \sqrt N$ , regardless of the adsorption strength. For chains within the range of adsorption we analyze in detail the probability size distributions of the various building blocks: loops, tails and trains, and find that loops and tails sizes follow power laws while train lengths decay exponentially thus confirming some recent theoretical results. The chain dynamics as well as the monomer mobility are also investigated and found to depend significantly on the proximity of a given layer to the solid adhesive surface with onset of vitrification for sufficiently strong adsorption.      

Mesoscopic models for DNA stretching under force: New results and comparison with experiments

We investigate the dynamical behavior of simple networks, namely loops with an additional internal regulating connection. Continuous dynamics for mRNA and protein concentrations is compared to a Boolean model for gene activity. Using a generalized method and within a single framework, we study different continuous models and different types of regulatory functions, and establish conditions under which the system can display stable oscillations or stable fixed points. These conditions depend only on general features such as the degree of cooperativity of the regulating interactions and the logical structure of the interactions. There are no simple rules for deciding when Boolean and continuous dynamics agree with each other, but we identify several relevant criteria.      

Motions of vortex patches

An evolution equation describing the motion of vortrex patches is established. The existence of steady solutions of this equation is proved. These solutions arem-fold symmetric regions of constant vorticity ω₀ and are uniformly rotating with angular velocity Ω in the range $$\tilde \Omega _{m - 1}< \tilde \Omega \leqslant \tilde \Omega _m (\tilde \Omega = \Omega /\omega _0 ,m \geqslant 2)$$ where \(\tilde \Omega _m = (m - 1)/2m\) . We call this class, ofm-fold symmetric rotating regionsD, the class of them-waves of Kelvin. Any may be regarded as a simply connected region which is a stationary configuration of the Euler equations in two dimensions. If then any magnification, rotation or reflection is also in with the same angular velocity Ω ofD. The angular velocity \(\Omega _m = \tilde \Omega _m \omega _0 \) corresponds only to the circle solution, which is a trivial member of every class ,m?2. The class corresponds to the rotating ellipses of Kirchoff. Other properties of the class are established.     

Reverse buoyancy in a vibrated granular bed: Computer simulations

We have performed molecular dynamics simulations of an intruder in a vibrated granular bed including interstitial fluid effects to account for the phenomenon of reverse buoyancy. We show that our model is able to reproduce the overall behaviour observed by previous experimental works and is the first finite-elements simulation to show the sinking of intruders lighter than the granular bed. To further advance our comprehension of this phenomenon, we studied the motion of the intruders in a single vibration cycle with respect to the bottom of the granular column, finding a substantial qualitative difference for heavy and light intruders and we compare these results with experiments using fine-sized glass beads. We show that, though heavy intruders seem unaffected by the force due to the fluid, the effect on light intruders is remarkable.      

Active chiral fluids

Active processes in biological systems often exhibit chiral asymmetries. Examples are the chirality of cytoskeletal filaments which interact with motor proteins, the chirality of the beat of cilia and flagella as well as the helical trajectories of many biological microswimmers. Here, we derive constitutive material equations for active fluids which account for the effects of active chiral processes. We identify active contributions to the antisymmetric part of the stress as well as active angular momentum fluxes. We discuss four types of elementary chiral motors and their effects on a surrounding fluid. We show that large-scale chiral flows can result from the collective behavior of such motors even in cases where isolated motors do not create a hydrodynamic far field.      

Dynamics of Purcell’s three-link microswimmer with a passive elastic tail

One of the few possible mechanisms for self-propulsion at low Reynolds number is undulations of a passive elastic tail, as proposed in the classical work of Purcell (1977). This effect is studied here by investigating a variant of Purcell??s three-link swimmer model where the front joint angle is periodically actuated while the rear joint is driven by a passive torsional spring. The dynamic equations of motion are formulated and explicit expressions for the leading-order solution are derived by using perturbation expansion. The dependence of the motion on the actuation amplitude and frequency is analyzed, and optimization with respect to the swimmer??s geometry is conducted.      

On the occurrence of polygon-shaped patterns in vibrated cylindrical granular beds

We report experimental observations of polygon-shaped patterns formed in a vertically vibrated bed of circular cross-section. A phase map is determined, showing that the polygon pattern is established for ?? = A(2??f)²/g ? 10 . The sensitivity of the polygon structure to bed parameters was tested by studying beds of different particle sizes and fill levels. It was hypothesized that the polygon pattern observed in cylindrical beds is the corresponding pattern to the formation of arches in square-shaped beds. The close relationship between these two patterns was demonstrated by two observations: i) the radii of the arches of a corresponding square bed and the inner radius of the cylindrical bed were found to be very similar and ii) the boundary lengths of the two patterns were in good agreement.      

Particle-quadrupole and particle-octupole coupled states in 145Sm

In the present paper we present part of the results obtained in the study of above-yrast states in ¹⁴⁵Sm using the ¹⁴²Nd(α,Xnγ) reaction. γ-γ, angular distribution, polarization, and excitation function measurements were performed. All multiplet members of the and the multiplets have been observed. The unperturbed energies for the multiplet have been estimated using the extensive information existing on one neutron transfer reactions. The results are compared with the ¹⁴³Nd case. The similarity is remarkable.     

Universality of the Local Regime for the Block Band Matrices with a Finite Number of Blocks

We consider the block band matrices, i.e. the Hermitian matrices $H_N$ , $N=|\Lambda |W$ with elements $H_{jk,\alpha \beta }$ , where $j,k \in \Lambda =[1,m]^d\cap \mathbb {Z}^d$ (they parameterize the lattice sites) and $\alpha , \beta = 1,\ldots , W$ (they parameterize the orbitals on each site). The entries $H_{jk,\alpha \beta }$ are random Gaussian variables with mean zero such that $\langle H_{j_1k_1,\alpha _1\beta _1}H_{j_2k_2,\alpha _2\beta _2}\rangle =\delta _{j_1k_2}\delta _{j_2k_1} \delta _{\alpha _1\beta _2}\delta _{\beta _1\alpha _2} J_{j_1k_1},$ where $J=1/W+\alpha \Delta /W$ , $\alpha < 1/4d$ . This matrices are the special case of Wegner’s $W$ -orbital models. Assuming that the number of sites $|\Lambda |$ is finite, we prove universality of the local eigenvalue statistics of $H_N$ for the energies $|\lambda _0|< \sqrt{2}$ .     

An efficient and facile synthesis of 3-amino-5-chromenyl-butenolides from 3-formyl chromone, dialkyl acetylenedicarboxylate, and primary amines

A three-component reaction of 3-formyl chromones, dialkyl acetylenedicarboxylate, and isocyanides in the presence of $\text{ POCl}_{3}$ was used as a highly efficient and practical approach for the synthesis of 3-amino-5-chromenyl-butenolides. High yields and high bond forming efficiency, and simple operations are the advantages of this method. Graphical abstract      

Spherical top-hat collapse of a viscous unified dark fluid

In this paper, we test the spherical collapse of a viscous unified dark fluid (VUDF) which has constant adiabatic sound speed and show the nonlinear collapse for VUDF, baryons, and dark matter, which are important in forming the large-scale structure of our Universe. By varying the values of the model parameters $\alpha $ and $\zeta _{0}$ , we discuss their effects on the nonlinear collapse of the VUDF model, and we compare its result to the $\Lambda $ CDM model. The results of the analysis show that, within the spherical top-hat collapse framework, larger values of $\alpha $ and smaller values of $\zeta _{0}$ make the structure formation earlier and faster, and the other collapse curves are almost distinguished with the curve of $\Lambda $ CDM model if the bulk viscosity coefficient $\zeta _{0}$ is less than $10^{-3}$ .     

Influence of assortativity and degree-preserving rewiring on the spectra of networks

Newman’s measure for (dis)assortativity, the linear degree correlation coefficient $\rho _{D}$ , is reformulated in terms of the total number N _k of walks in the graph with k hops. This reformulation allows us to derive a new formula from which a degree-preserving rewiring algorithm is deduced, that, in each rewiring step, either increases or decreases $\rho _{D}$ conform our desired objective. Spectral metrics (eigenvalues of graph-related matrices), especially, the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and the algebraic connectivity $\mu _{N-1}$ (second-smallest eigenvalue of the Laplacian) are powerful characterizers of dynamic processes on networks such as virus spreading and synchronization processes. We present various lower bounds for the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and we show, apart from some classes of graphs such as regular graphs or bipartite graphs, that the lower bounds for $\lambda _{1}$ increase with $\rho _{D}$ . A new upper bound for the algebraic connectivity $\mu _{N-1}$ decreases with $\rho _{D}$ . Applying the degree-preserving rewiring algorithm to various real-world networks illustrates that (a) assortative degree-preserving rewiring increases $\lambda _{1}$ , but decreases $\mu _{N-1}$ , even leading to disconnectivity of the networks in many disjoint clusters and that (b) disassortative degree-preserving rewiring decreases $\lambda _{1}$ , but increases the algebraic connectivity, at least in the initial rewirings.     

Charge density excitations in bilayer graphene in high magnetic field

The charge-density excitations in bilayer graphene at the filling-factor ν 1 at small momenta are considered in the frame of the Hartree-Fock approximation. The presence of small asymmetry of graphene layers is included. The dependence of the magnetoplasmon energy on the bilayer ground state is shown. The energy splitting proportional to $ \sqrt H $ for the symmetric case with half-filled zero-energy levels is found both for bilayer and monolayer graphene.     

Semiclassical strings in supergravity PFT

In this paper, we introduce the bulk viscosity in the formalism of modified gravity theory in which the gravitational action contains a general function \(f(R,T)\) , where \(R\) and \(T\) denote the curvature scalar and the trace of the energy–momentum tensor, respectively, within the framework of a flat Friedmann–Robertson–Walker model. As an equation of state for a prefect fluid, we take \(p=(\gamma -1)\rho \) , where \(0 \le \gamma \le 2\) and a viscous term as a bulk viscosity due to the isotropic model, of the form \(\zeta =\zeta _{0}+\zeta _{1}H\) , where \(\zeta _{0}\) and \(\zeta _{1}\) are constants, and \(H\) is the Hubble parameter. The exact non-singular solutions to the corresponding field equations are obtained with non-viscous and viscous fluids, respectively, by assuming a simplest particular model of the form of \(f(R,T) = R+2f(T)\) , where \(f(T)=\alpha T\) ( \(\alpha \) is a constant). A big-rip singularity is also observed for \(\gamma <0\) at a finite value of cosmic time under certain constraints. We study all possible scenarios with the possible positive and negative ranges of \(\alpha \) to analyze the expansion history of the universe. It is observed that the universe accelerates or exhibits a transition from a decelerated phase to an accelerated phase under certain constraints of \(\zeta _0\) and \(\zeta _1\) . We compare the viscous models with the non-viscous one through the graph plotted between the scale factor and cosmic time and find that the bulk viscosity plays a major role in the expansion of the universe. A similar graph is plotted for the deceleration parameter with non-viscous and viscous fluids and we find a transition from decelerated to accelerated phase with some form of bulk viscosity.     

On a symmetry topological classification of edge states in crystalline spin-Hall insulators with the time reversal invariance

Symmetry analysis reveals all types of singularities of the edge states in two-dimensional systems with a boundary (2D → 1D systems), which are invariant under time reversal. Symmetry reasons also provide the matching condition for material functions parameterizing the Hamiltonian at various points of the Brillouin zone. The unified parameterization of the Hamiltonian makes it possible to construct the mapping of trajectories closed in the quasimomentum k in the Brillouin zone into the SU(2) topological group. There are only two equivalence classes of Hamiltonians, which are given by the elements of the first fundamental group . The first type of surface states corresponds to a normal insulator and the second type corresponds to a topological spin-Hall insulator. Comparison with the classification based on the Pfaffian method is performed.     

N,N,N^{\prime },N^{\prime }-Tetrabromobenzene-1,3-disulfonamide and poly(N-bromo-N-ethylbenzene-1,3-disulfonamide) as new and efficient catalysts for the synthesis of highly substituted 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives

Various mono and bis-1,6-dihydropyrazine-2,3-dicarbonitrile derivatives were efficiently synthesized by reacting 2,3-diaminomaleonitrile (DAMN), isocyanides and ketones in the presence of a catalytic amount of $N,N{,}N^{\prime }{,}N^{\prime }$ -tetrabromobenzene-1,3-disulfonamide [TBBDA] and poly( $N$ -bromo- $N$ -ethylbenzene-1,3-disulfonamide) [PBBS] in EtOH/H $_{2}$ O at ambient temperature. Graphic abstract $N,N,N^{\prime },N^{\prime }$ -Tetrabromobenzene-1,3-disulfonamide and poly( $N$ -bromo- $N$ -ethylbenzene-1,3-disulfonamide) as new and efficient catalysts for the synthesis of highly substituted 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives.      

Self-regulation in self-propelled nematic fluids

Monte Carlo simulation of the rupture of multiple receptor-ligand bonds between two PMN cells suspended in a Newtonian fluid is performed. In the presence of a hydrodynamic drag force acting on two PMN cells the interplay of multiple receptor-ligand bonds between these cells leads to a bimodal distribution of the bond rupture force at certain loading rates. Specifically, it is found that the interplay of multiple bonds between two PMN cells in the presence of hydrodynamic drag force acting on these cells modifies the bond energy landscape in such a way as to lead to a bimodal distribution of the bond rupture force where a low force peak switches to a high force peak as the loading rate is increased progressively, characteristics of two-state systems.