共查询到20条相似文献,搜索用时 31 毫秒
1.
Alexander V. Zabula Alexander S. Filatov Marina A. Petrukhina 《Journal of Cluster Science》2010,21(3):361-370
The tetranuclear mixed-valent oxo-cluster [SnIISnIVO(O2CCF3)4]2 (1) has been prepared by reacting SnCl2 with AgO2CCF3 in a sealed ampoule at 90 °C. Alternatively, 1 was obtained by acidolysis of Ph3SnSnPh3 with trifluoroacetic acid in solution. The X-ray diffraction study of 1 revealed the presence of a SnIIOSn2IVOSnII core comprised of the penta-coordinated divalent and six-coordinated tetravalent tin atoms. The 119Sn NMR studies confirmed the stability of the cluster in solution and the presence of two different oxidation states of tin.
An acidolysis of Ph3SnSnPh3 in the presence of [Cu2II(O2CCF3)4] followed by sublimation of the resulting product at 90 °C afforded the first trinuclear mixed metal Sn–Cu cluster [(C6H5)2Sn2IVCuIIO(O2CCF3)6] (2). The X-ray diffraction analysis of 2 revealed the presence of two phenyl groups attached to the six-coordinated tin(IV) atoms and the tetragonal pyramidal environment
of the copper(II) atom. Both complexes have been obtained free of exogenous ligands. 相似文献
2.
G. Yu. Zhigulin G. S. Zabrodina M. A. Katkova S. Yu. Ketkov 《Russian Chemical Bulletin》2018,67(7):1173-1181
The process of solution-phase formation of the CuII–YIII 15-metallacrown-5 complexes bearing the glycinehydroximate ligands has been for the first time investigated by methods of quantum chemistry. The DFT modeling at the B3LYP/DGDZVP (PCM) level was carried out for mono-, bi-, and tri-nuclear copper(II) complexes and also for heteronuclear CuII–YIII derivatives as the metallamacrocycle precursors. The dependence of relative stability of these complexes on the CuII and YIII coordination surroundings and also on the mutual positions of ligands was found. The structural (variations of interatomic distances and valence angles), electronic (changes in the atomic charges and electron density), and thermodynamical (enthalpies and Gibbs free energies) regularities of 15-metallacrown-5 formation were revealed. The key role of YIII cation was established for the process of formation of the polynuclear metallamacrocyclic compound (15-metallacrown-5). 相似文献
3.
B. K. Kasenov Sh. B. Kasenova Zh. I. Sagintaeva A. A. Seisenova M. O. Turtubaeva E. E. Kuanyshbekov K. T. Ermaganbetov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(4):739-743
Temperature dependences of the heat capacity of new zincate-manganites of LaM2IIZnMnO6 (MII = Mg, Ca, Sr, Ba) composition are studied via experimental calorimetry in the interval of 298.15–673 K. It is found that all compounds have λ-shape effects on the curve of dependence Cp° ~ ?(T) with respect to phase transitions of the second kind. Equations for the temperature dependence of the heat capacity are derived with allowance for phase transition temperatures, and thermodynamic functions H°(T) ? H°(298.15), S°(T) and Φxx(T) are calculated on the basis of experimental data on Cp°(T) and the calculated S°(298.15) value. 相似文献
4.
B. K. Kasenov Sh. B. Kasenova Zh. I. Sagintaeva M. O. Turtubaeva K. S. Kakenov G. A. Esenbaeva 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2017,91(3):430-436
The heat capacities of nanosized ferro-chromo-manganites LaM0.5 IIFeCrMnO6.5 (MII–Mg, Ca, Sr, Ba) are measured via dynamic calorimetry in the temperature range of 298.15–673 K using an IT-S-400 instrument. It is established that the C°p~f(T) function of LaM0.5 IIFeCrMnO6.5 (MII–Mg, Ca, Sr, Ba) has λ-type effects, due probably to phase transitions of the second order. Considering the temperatures of the phase transitions, equations of the heat capacity of ferro-chromo-manganites LaM0.5 IIFeCrMnO6.5 (MII–Mg, Ca, Sr, Ba) as a function of temperature are derived on the basis of experimental data. Thermodynamic functions Н°(Т)–Н°(298.15), S°(Т), and Ф хх(Т) are calculated in the temperature range of 298.15–675 K. 相似文献
5.
The first example of the formation of hydrogen-deficient radical cations of the type [M + H](.2+) is demonstrated to occur through a one-electron-transfer mechanism upon low-energy collision-induced dissociation (CID) of gas-phase triply charged [Cu(II)(terpy)(M + H)](.3+) complex ions (where M is an angiotensin III or enkephalin derivative; terpy = 2,2':6',2'-terpyridine). The collision-induced dissociation of doubly charged [M + H](.2+) radical cations generates similar product ions to those prepared through hot electron capture dissociation (HECD). Isomeric isoleucine and leucine residues were distinguished by observing the mass differences between [z(n) + H](.+) and w(n)(+) ions (having the same residue number, n) of the Xle residues. The product ion spectrum of [z(n) + H](.+) reveals that the w(n)(+) ions are formed possibly from consecutive fragmentations of [z(n) + H](.+) ions. Although only the first few [M + H](.2+) species have been observed using this approach, these hydrogen-deficient radical cations produce fragment ions that have more structure-informative patterns and are very different from those formed during the low-energy tandem mass spectrometry of protonated peptides. 相似文献
6.
2-Pivaloylamino-6-acetonyl-isoxanthopterin (1,
) has been reacted with
under suitable conditions for synthesizing the new compound
] (2). It has been characterized by elemental analysis, electrospray ionization mass spectrometry, magnetic susceptibility measurement,
different spectroscopic techniques, and cyclic voltammetry. Molecular mechanics (MM2) method provided with its optimized geometry
(having lowest steric energy), consistent with the above data; the optimized bond lengths and bond angles data tally with
the literature X-ray structural data. Reactivity of (2) towards phenylalanine in the presence of
in methanol has been followed both kinetically and stoichiometrically; a reasonable amount of tyrosine could be recovered
from the reaction medium. The negative
value (−274.0 J mol−1
indicates an associative pathway for this process. (2) is also able to react with bromobenzene as indicated by time-dependent absorption spectra as well as product identification.
Efficacy of the pterin ligand residue
of (2) in rendering the latter reactive towards the above-mentioned organic compounds, has been discussed on the basis of experimental
evidence. 相似文献
7.
Yanluo Lu Lan Yang Min Wei Yaning Xie Tao Liu 《Journal of Solid State Electrochemistry》2007,11(9):1157-1162
Supramolecular pillared oxides were prepared through the intercalation of M2+ cations into a MnO2 host matrix by the method of ion exchange between the precursor δ-K
x
MnO2 and the corresponding guest. The materials M-MnO2 crystallize in the hexagonal system, the same structure as the precursor, with a larger interlamellar spacing. In the case
of ZrO-MnO2, extended X-ray absorption fine structure (EXAFS) determination indicates that the Zr atom locates between the MnO2 layers forming a stable structure. Compared with the precursor, the cycling property of M-MnO2 was improved distinctly, while the capacity decreased to some degree due to the strong interaction between pillars and the
host matrix. Among these pillared materials, ZrO-MnO2 has an advanced reversible capacity of 161.5 mAh·g−1 and improved cycling behavior compared with the precursor. 相似文献
8.
T. V. Magdesieva O. M. Nikitin A. V. Yakimansky M. Ya. Goikhman I. V. Podeshvo 《Russian Chemical Bulletin》2010,59(2):342-347
A method for electrosynthesis of heteropolynuclear biquinoline-containing CuI and PdII complexes using sacrificial Cu and Pd anodes was developed. The sequence of anode dissolution (first Pd and then Cu) was
important for the synthesis of the complex. The opposite sequence of dissolution resulted in oxidation of the initially formed
CuI ions to CuII. The obtained CuI and PdII complexes with polymer ligands had high catalytic activity in the reaction of aryl halides with phenylacetylene giving rise
to a C(sp2)-C(sp) bond. The yield of arylphenylacetylene in the presence of 0.1 mol.% of Pd catalyst in relation to the starting halide
was 50–90% depending on the nature of the aryl halide. 相似文献
9.
P. B. Fabrichnyi M. V. Korolenko V. E. Tkachenko M. Danot C. Payen 《Russian Journal of Inorganic Chemistry》2007,52(8):1262-1268
The hyperfine structure of the low-temperature Mössbauer spectra of dopant 119Sn4+ ions (0.4 at. %) in a fine crystalline MnO sample, characterized by X-ray diffraction and magnetic measurements, has been studied. The 119Sn spectra show that tin is distributed over positions with an inhomogeneous cationic environment. The appearance of such positions is explained by the local compensation for the excess charge of Sn4+ by manganese vacancies V Mn and segregation of defects resulting in precipitation of MnSnO3 clusters. The non-uniform distribution of Sn4+ and the related dependence of the number of broken magnetic bonds on the local tin concentration are responsible for the fluctuation of the T N values, which is “perceived” by 119Sn in different MnO crystallites. The 119Sn spectra exclude the possibility that tin enters into the composition of superpara-magnetic particles. 相似文献
10.
Abstract The title compound, labeled with 13C in the ethyl groups was synthesized from K13CN and low-molecular-weight components. The synthetic relay compound was 31(32)[13C]-xanthobilirubinic acid methyl ester in a synthetic route that leads to a label in the ethyl β-substituent of a dipyrrinone
model for bilirubin. This labeled dipyrrinone was oxidatively coupled to the dimethyl ester of mesobiliverdin-XIIIα, thereby
providing a route to a 13C-labeled mesobiliverdin and mesobilirubin, with one carbon of each ethyl being 98% 13C-enriched.
Graphical Abstract
相似文献
11.
N. Yoshida A. A. Tsaturyan T. Akitsu Y. Tsunoda I. N. Shcherbakov 《Russian Chemical Bulletin》2017,66(11):2057-2065
The synthesis of novel CuII complexes with a Schiff base obtained by condensation of salicylaldehyde and an l-aspartic acid ester are described. The physicochemical properties of the complexes were compared with those of related CuII complexes obtained earlier. All the complexes studied were characterized by elemental analysis as well as by IR, UV-Vis, and EPR spectroscopies. The activity of the complexes and their hybrid systems (HS) with TiO2 in visible-light-driven photocatalysis in organic solvents was investigated. After irradiation with visible light, the complexes and corresponding HS reduce Cr6+ to Cr3+ more efficiently than bare TiO2. To determine the molecular orbital compositions and energies and to explain the electronic spectra and redox properties of the systems studied, density functional calculations of the optimized structures of representative model complexes were performed. 相似文献
12.
As part of a mass spectrometric investigation of the binding properties of sulfonamide anion receptors, an atmospheric pressure
chemical ionization mass spectrometric (APCI-MS) method involving direct infusion followed by thermal desorption was employed
for identification of anionic supramolecular complexes in dichloromethane (CH2Cl2). Specifically, the dansylamide derivative of tris(2-aminoethyl)amine (tren) (1), the chiral 1,3-benzenesulfonamide derivatives of (1R,2S)-(+)-cis-1-amino-2-indanol (2), and (R)-(+)-bornylamine, (3), were shown to bind halide and nitrate ions in the presence of (n−Bu)4N+X− (X− = Cl−, NO3−, Br−, I−). Solutions of receptors and anions in CH2Cl2 were combined to form the anionic supramolecular complexes, which were subsequently introduced into the mass spectrometer
via direct infusion followed by thermal desorption. The anionic supramolecular complexes [M+X]−, (M=1–3, X−=Cl−, NO3−, Br−, I−) were observed in negative mode APCI-MS along with the deprotonated receptors [M−H]−. Full ionization energy of the APCI corona pin (4.5 kV) was necessary for obtaining mass spectra with the best signal-to-noise
ratios. 相似文献
13.
Boukraa Yamina 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(13):2642-2645
A study on the extraction of copper(II), cobalt(II), and nickel(II) from solutions containing ions of both metals with N-salicylideneaniline(SAN) in chloroform has been realized. Distribution of the metal ions in wide range of pH has been studied. Extraction of copper(II) was always favored over that of cobalt(II). Extraction of copper(II) from binary metal solution is selective and it can be quantitatively separated from cobalt(II). The equilibrium constant of the extraction of cobalt and nickel from an aqueous solution containing both metals using SAN were evaluated. The separation factors for cobalt and nickel were expressed as a function of the distribution of nickel and cobalt. From these results, salicylideneaniline is an adequate extractant for extractive separation of such mixtures. 相似文献
14.
Potential energy curves of NgH+ cations (Ng = Kr, Xe, Rn) were obtained by using four-component relativistic CCSD(T) coupled cluster calculations. Dissociation
energies, equilibrium bond lengths, electronic properties, such as dipole moments and electric field gradients at the nuclei,
and the related spectroscopic parameters of the electronic ground state have been determined. The results obtained for KrH+ and XeH+ are in good agreement with available experimental data, while those for RnH+ have been determined for the first time at this level of theory. 相似文献
15.
Makoto Takezaki Hiroyuki Aoki Michiko Kodama Toshihiro Tominaga 《Journal of Thermal Analysis and Calorimetry》2010,101(3):1149-1153
The solubility of hexadecyltrimethylammonium tetrachloroaurate (CTA·AuCl4) in water was measured at different temperatures of 288.2, 293.2, 298.2, 303.2, and 308.2 K. The enthalpy change associated
with the formation of the CTA·AuCl4 precipitate was estimated on the basis of the van’t Hoff equation and was found to be −42.5 ± 2.8 kJ mol−1 at 298.2 K. The calorimetric enthalpy change for the CTA·AuCl4 precipitate formation was directly determined by isothermal titration calorimetry performed at 298.2 K and was found to agree
well with that estimated from the van’t Hoff equation. 相似文献
16.
F. Bousmina L. Zayani D. Ben Hassen-Chehimi N. Kbir-Ariguib M. Trabelsi-Ayedi 《Monatshefte für Chemie / Chemical Monthly》2003,134(5):763-768
Summary. The diagram of the ternary system Mg2+/Cl−, SO4
2−–H2O was established at 15°C by means of analytical and conductimetric measurements. Three compounds were found in this diagram,
which are MgSO4·6H2O, MgSO4·7H2O, and MgCl2·6H2O. The solubility field of MgSO4·7H2O is important whereas those of MgSO4·6H2O and MgCl2·6H2O are small. The compositions (mass-%) of the two invariant points determined by the two methods are: MgSO4:MgCl2=2.73:33.80 and MgSO4: MgCl2=3.38:28.91. Both the measured and the calculated isotherm at 15°C have been used for modelling of the diagram Mg2+/Cl−, SO4
2−–H2O between 0 and 35°C. The polythermal invariant point was approximately located between 15 and 10°C.
Corresponding author. E-mail: ariguib@planet.tn
Received October 16, 2002; accepted (revised) December 3, 2002
Published online April 24, 2003
RID="a"
ID="a" Dedicated to Prof. Dr. Heinz Gamsj?ger on the occasion of his 70th birthday 相似文献
17.
Patrícia Severino Samantha C. Pinho Eliana B. Souto Maria H. A. Santana 《Journal of Thermal Analysis and Calorimetry》2012,108(1):101-108
This study focuses on the physicochemical characterization of lipid materials useful for the production of the so-called solid lipid nanoparticles (SLN) and nanostructured lipid carriers (NLC). The chosen lipids were Dynasan®114 (glyceril trimyristate) and Dynasan®118 (glyceril tristearate) as solid lipids (SL), melting temperature above 80 °C, and Miglyol®812 (caprylic/capric triglyceride) and Miglyol®840 (propylene glycol dicaprylate/dicaprate) as liquid lipids (LL), crystallizing below ?15 °C. Raw lipids (pure or SL:LL mixtures) were analyzed by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD), and Polarized Light Microscopy (PLM), before and after tempering at 80 °C for 1 h. The selected SL:LL combination was 70% (Dynasan®114 and 118) and 30% (Miglyol®812 and 840) for the production of SLN and NLC by high-pressure homogenization (HPH), respectively. Particles with a mean size of 200 nm (polydispersity index <0.329) and zeta potential of ?15 mV were obtained, and their long-term stability was confirmed for 3 months of storage at 7 °C. 相似文献
18.
Silvia Dulanská Boris Remenec L’ubomír Mátel Igor Antalík 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(1):97-101
Two separation techniques for plutonium determination using AnaLig® Pu02 molecular recognition technology product (MRT) and extraction chromatography TRU® resin were tested. The methods performance was investigated by analysis of National Physical Laboratory (NPL-Alpha-Beta High, ABH 2003, 2005) intercomparison test samples. The results obtained for both procedures were compared in terms of activities and recoveries. Data analysis showed good agreement with the reference values. The AnaLig® Pu02 separation method for 239,240Pu, 238Pu determination was successfully validated with the same performance as the TRU® resin method. 相似文献
19.
N. V. Aksenov H. Bruchertseifer G. Ya. Starodub G. K. Vostokin E. E. Tereshatov G. A. Bozhikov S. V. Shishkin S. N. Dmitriev 《Journal of Radioanalytical and Nuclear Chemistry》2009,279(1):341-343
A rapid method for the preparation of 87Y/87mSr radionuclide generator from a rubidium chloride target irradiated with 35 MeV α-particles is described. A simple two-step
procedure is used to obtain a carrier-free 87mSr isotope with a high enough radiochemical yield and high purity in the final aqueous fraction. 相似文献
20.
E. M. Bond S. Glover D. J. Vieira R. S. Rundberg G. Belier V. Meot D. Hynek Y. Jansen J. Becker R. Macri 《Journal of Radioanalytical and Nuclear Chemistry》2008,276(2):549-554
This paper describes the preparation of samples for an experiment to measure the cross-section for 235U(n,n′)235mU in a fast fission spectrum of neutrons provided by a fast pulsed reactor/critical assembly. Samples of 235mU have been prepared for the calibration of the internal conversion electron detector that is used for the 235mU measurement. Two methods are described for the preparation of 235mU. The first method used a U-Pu chemical separation based on anion-exchange chromatography and the second method used an alpha
recoil collection method. Thin, uniform samples of 235mU+235U were prepared for the experiment using electrodeposition. 相似文献