The three-dimensional photonic crystals coated by gold nanoparticles

We report on the fabrication of metallodielectric photonic crystals by means of interference lithography and subsequent coating by gold nanoparticles. The grating is realized in a SU-8 photoresist using a He-Cd laser of wavelength 442 nm. The use of the wavelength found within the photoresist low absorption band enables fabricating structures that are uniform in depth. Parameters of the photoresist exposure and development for obtaining a porous structure corresponding to an orthorhombic lattice are determined. Coating of photonic crystals by gold nanoparticles is realized by reduction of chloroauric acid by a number of reductants in a water solution. This research shows that the combination of interference lithography and chemical coating by metal is attractive for the fabrication of metallodielectric three-dimensionally periodic microstructures.     

Complex interaction of polarized light with three-dimensional opal-based photonic crystals: Diffraction and transmission studies

Polarization characteristics of light interaction with the photonic crystal of a-SiO₂ synthetic opals were studied under the conditions of low dielectric contrast. We analyzed 3D diffraction patterns of monochromatic light and calculated optical transmission spectra of oriented samples. The diffraction patterns are found to change with the polarization of incident light, indicating a strong polarization dependence of photonic stop bands in synthetic opals. It is shown theoretically there exists a critical angle, θ_c, of the p-polarized light incident on the (h k l) crystal plane, at which the resonance contribution to Bragg diffraction vanishes.     

The superprism effect using large area 2D-periodic photonic crystal slabs

The “superprism effect” is an effect observed in photonic crystal structures whereby the direction of light propagation is extremely sensitive to the wavelength and angle of incidence. To realize the superprism effect, new structures are presented which rely on the sensitivity of the phase velocity in a two-dimensional (2D) photonic crystal slab to observe angular magnification outside the photonic crystal medium. Constant frequency contour calculations for a photonic crystal slab of finite thickness are used to predict the phase velocity superprism effect. Further analysis using 2D finite-difference time-domain simulations indicate that a large area photonic crystal and wide excitation beam are necessary for clear observation of the superprism effect. A fabrication technique is demonstrated to achieve the structure's required nanometer-sized features over centimeter-scale areas.     

Design of photonic bands for opal-based photonic crystals

To make a device from an opal—or otherwise—the photonic bands and the optical properties derived from them are needed. Knowing the effects of different parameters defining the opal geometry and different possible modifications of its structure are needed, too. An accurate definition of the device will be required to obtain a good performance. With this aim, the optics of light with a wavevector in the vicinity of the L point in the Brillouin zone and its coupling to bare opals band structure are presented. An important aspect is the transition from finite to infinite crystal and the study of size effects on the bands. It is possible to substantially alter the photonic band structure of an opal-based system, while maintaining the lattice structure, simply by growing layers of other materials with an appropriate refractive index. Here, it is shown how, by the growth of accurately controlled thin layers of silicon and germanium, and further processing, one can induce the opening of two complete photonic band gaps (PBGs) in an opal structure. Finally, the possibility to fabricate a simple device consisting in a planar waveguide will be shown. By means of a very simple and inexpensive procedure, engineered planar defects acting as microcavities have been realized. These can be viewed as a particular case of a much more general class of heterostructures that can be grown by combining opal vertical deposition and chemical vapour deposition of oxides. A further step is made by applying electron beam lithography to provide lateral definition and facilitate three-dimensional structuring.     

Experimental evidence of photonic band gap extension for disordered 1D photonic crystals based on Si

We have shown theoretically and experimentally the possibility of PBG extension by introducing a silicon wall thickness disorder into the photonic structure. Experiments have been conducted in the infrared spectrum range and calculations have been performed for 1D photonic crystals based on a grooved-silicon structure.     

Realization of compatible stealth material for infrared,laser and radar based on one-dimensional doping-structure photonic crystals

To inhibit the radiant infrared energy between 8 and 14 μm, which is the infrared atmospheric window, and decrease the echo power of detecting laser and radar, to achieve compatible stealth, a doping structural one-dimensional photonic crystal (1-D PC) with Ge, ZnSe and Si was fabricated; and then combine it with radar absorbing material (RAM) to make a compound. After that, the reflection spectra of this compound was tested, and the result shows a high average reflectance (89.5%) in 8–14 μm waveband, and a reflective valley (39.8%) in the wavelength of 10.6 μm, which is the wavelength of CO₂ laser; and the reflectance in radar band shows that at high frequency, especially between 7.8 and 18 GHz, the radar power is strongly absorbed by this material and the reflected energy attenuate over 10 dB within the range from 11.1 GHz to 18.3 GHz, even 24.5 dB to the most in the frequency of 14.6 GHz.     

Comparison of photonic bandgaps of two-dimensional periodic and quasi-periodic photonic crystals with different relative permittivity dielectric

Photonic bandgaps (PBGs) of two-dimensional (2D) triangular-lattice and square-lattice and decagonal quasi-periodic photonic crystals (PCs) have been analyzed, with a given scatterer radius and dielectric relative permittivity changing from 1 to 30 within air-cylinders-in-dielectric and dielectric-cylinders-in-air constructions. The results have shown that 2D quasi-periodic PC is more likely to generate PBG and complete PBG than 2D periodic PC. For the given scatterer radius and two constructions, PBG widths of the two types of 2D PCs vary little, whereas the corresponding center frequencies decrease in smooth “hyperbola-like” curves with dielectric relative permittivity increasing monotonically. The present results will guide the design of PBG-type microstructure photonic devices.     

Novel optical modulator using silicon photonic crystals

We propose a novel compact and integrated optical modulator, which consists of p–i–n silicon photonic crystals with triangular lattice and a line defect waveguide. The device operation is based on a dynamic shift of the photonic band gap (PBG), which induced change in the silicon refractive index by the free carrier injection. We have numerically analyzed and investigated its light modulation performance by using plane wave expansion (PWE) method and finite-difference time-domain method. With small size, rapid response time and high extinct ratio, the designed optical modulator can be used in photonic integrated circuits.     

Coupling reducing k-points for photonic crystal fiber calculations

When describing localized electromagnetic modes in dielectric waveguides by the planewave method, a supercell geometry must necessarily be adopted. We demonstrate in the present work that the convergence of the calculations with respect to supercell size depends strongly on the choice of the transverse Bloch wave vector, k. We describe a method to derive k-points that minimize the coupling between repeated images of the guided modes in real space. Calculations have been done for a quadratic and a triangular photonic crystal fiber structure. With the new coupling reducing (CR) k-points, the convergence of the eigenfrequencies for both the fundamental and second order modes with respect to supercell size is considerably improved. The general approach outlined may also be applied in the case of three-dimensional photonic crystal structures.     

Magneto-optical Faraday effects in dispersive properties for three-dimensional magnetized plasma photonic crystals

The dispersive properties of three-dimensional magnetized plasma photonic crystals composed of homogeneous magnetized plasma spheres immersed in isotropic dielectric host with face-centered-cubic lattices are theoretically studied based on plane wave expansion method, as the magneto-optical Faraday effects of magnetized plasma are considered. The equations for calculating the band structures are theoretically deduced. The photonic band gap and a flatbands region can be obtained. The influences of host dielectric constant, plasma collision frequency, filling factor, external magnetic field and plasma frequency on the dispersive properties are investigated in detail, respectively, and some corresponding physical explanations are also given. The numerical results show that the photonic band gap can be manipulated by the plasma frequency, filling factor, external magnetic field and host dielectric constant, respectively. However, the plasma collision frequency has no effects on photonic band gap. The location of flatbands region cannot be tuned by any parameters except for the plasma frequency and external magnetic field.     

Enhanced-performance relative humidity sensor based on MOF-801 photonic crystals

We proposed an enhanced-performance relative humidity (%RH) nano-sensor based on MOF-801/TiO₂ one-dimensional photonic crystals (1DPC). The maximum reflectance-peak wavelength of it shifted obviously in the range of 20%-90% under varying %RH levels, due to the highly moisture-sensitive MOF-801 film in the 1DPC structure. It was demonstrated that the linear spectrum sensitivity of the MOF-801/TiO₂ %RH 1DPC sensor is exceeding 119 pm/%RH from 20%RH to 90% RH, and the sensitivity of reflection power variations exhibits 1.34 dB/%RH with the resolvable relative humidity variation less than 0.1%RH at 15°C. Meanwhile, the sensor shows a fast optical response time less than 100 ms with exceptional repeatability and reliability, which promises successful measurements of human respiration. Moreover, the sensor performance on the structure of 1DPC is investigated, representing a tradeoff between the sensing sensitivity and response time.     

Properties of defect modes in one-dimensional symmetric defective photonic crystals

We theoretically investigate the properties of defect modes in one-dimensional symmetric defective photonic crystals. We consider three defective photonic crystal structures, air/[(AB)^NsA^α(BA)^Ns]^Np/air, air/[(AB)^NsAB^βA(BA)^Ns]^Np/air, and air/{[(AB)^NsAB^βA(BA)^Ns]B^γ}^Np−1[(AB)^NsAB^βA(BA)^Ns]/air, where A and B are respectively taken to be the high- and low-index dielectric materials. The first has a defect layer of A^α, the second has a composite defect, AB^βA, and the third has a interleaving defect B^γ. The effect of thickness on the defect mode is studied by varying the parameters α, β, and γ, respectively, for the above model structures. It is found that the positions and the number of defect modes can be significantly changed due to the change in the defect thickness. In addition, by increasing the repeated number N_p, we can have multiple defect modes, leading to a possible design of tunable multichannel filter.     

Fabrication of high-quality colloidal photonic crystals with sharp band edges for ultrafast all-optical switching

Application of the pressure controlled isothermal heating vertical deposition method to the fabrication of colloidal photonic crystals is systematically investigated in this paper. The fabricated samples are characterized by scanning electron microscope and transmission spectrum. High-quality samples with large transmissions in the pass bands and the sharp band edges are obtained and the optimum growth condition is determined. For the best sample, the transmission in the pass bands approaches 0.9 while that in the band gap reaches 0.1. More importantly, the maximum differential transmission as high as 0.1/nm is achieved. In addition, it is found that the number of stacking layers does not increase linearly with concentration of PS spheres in a solution, and a gradual saturation occurs when the concentration of PS spheres exceeds 1.5 wt.%. The uniformity of the fabricated samples is examined by transmission measurements on areas with different sizes. Finally, the tolerance of the fabricated samples to baking was studied.     

3D photonic crystals based on macroporous silicon: Towards a large complete photonic bandgap

Recently, a new three-dimensional photonic crystal consisting of two interpenetrating hexagonal pore sets was introduced. Here, we investigate the influence of possible experimental errors including shift, tilt and rotation of one pore set on the size of the bandgap theoretically and determine fabrication tolerances. A structure is fabricated in silicon using photo-electrochemical etching and subsequent focused ion beam milling. The change of the cross-section of the milled pores with pore depth is investigated and reflection measurements along different directions are performed indicating the low frequency edge of the photonic bandgap.     

Fabrication of near infrared metallodielectric photonic crystal using metal-coated dielectric spheres

A metallodielectric photonic crystal with photonic band gaps in near infrared regime has been constructed using layer-by-layer stacking of two-dimensional micro-size metal-coated dielectric spheres array. In transmission spectra two photonic band gaps are observed at 1.38 μm and 2.46 μm, which are in agreement with theoretical calculations. Experimental results show that the photonic band gaps can be realized with about ten layers. The structure with metallic microspheres provides us a novel way for fabrication of near infrared metallic photonic crystals.     

Band gap studies of 2D photonic crystals with hybrid scatterers

Two-dimensional (2D) photonic crystals (PCs) of a square lattice with dielectric hybrid rods in air are proposed; these PCs consist of a square rod at the center of the unit cell and additional circular rods with their outermost edges against the middle of each side of the lattice unit cell. The band gap structures of PCs can be tailored and optimized by rotating the square rods and adding circular rods to the lattice unit cell. The variation of bands near the complete photonic band gap boundaries, due to some specific modes, is sensitive to certain structural parameters of the system. The results can be understood by analyzing the spatial energy distribution of the electromagnetic fields. Based on such a field analysis, a novel interpretative model is proposed. The PC can be fabricated easily and operated in the microwave region and, hence, should be suitable for applications in new microwave devices.     

Branching features of photonic bandgaps in Fibonacci dielectric heterostructures

We propose branching features of photonic band gaps in one-dimension Fibonacci dielectric heterostructures with arbitrary generation orders and thicknesses based on the gap map diagram, which is determined by the band edge formalism to avoid numerical instability. We find that the gap map diagram can be divided by the half-wave lines into several regions, each of which has similar gap pattern. The branching rules including the existence condition and the frequency range of each major gap as well as the number of all minor gaps in each region for systems with arbitrary thicknesses and generations are proposed. The number of major gaps in each region for the Fibonacci systems equals two rather than one for traditional binary layers. Moreover, the conditions of maximum gapwidth for the Fibonacci systems are not near the quarter wavelength, although the ones for traditional binary layers are at the quarter wavelength.     

Investigation of thermal influence on the bandgap properties of liquid-crystal photonic crystal fibers

We have analyzed the thermal influence on the bandgap properties of liquid-crystal photonic crystal fibers. The bandgap parameters which affect the transmission conditions have been investigated. It is observed that the photonic bandgap can be thermally tuned, i.e. the red or blue shift of the bandgap results from the temperature dependence of the refractive index of the liquid crystal. For the planar alignment of liquid-crystal filled cladding, the ordinary refractive index plays a major role in determining the bandgap properties; the extraordinary refractive index comes into influence while the ordinary refractive index is relatively constant of temperature. The analyses agree well with the experiments results.     

Superprism properties in 2D polymer photonic crystals at high normal frequencies

The superprism effects of higher bands, i.e., for normal frequencies of higher than one, in two-dimensional (2D) polymer photonic crystals (PCs) are investigated. It is shown that in a polymer PC of triangular symmetry with filling factor of about 31%, the gradual transition of the hexagonal into triangular equi-frequency dispersion contours leads to a strong superprism in the 6th band at a normal frequency of 1.2. This dispersion is more prominent than those observed in the lower bands in 2D PCs. Also, this requires a lattice constant longer than the concerned wavelength. Furthermore, in a 2D polymer PC with a filling factor of about 83% a strong discontinuous superprism effect occurs at normal frequencies higher than one, which is due to an abrupt transition between two modes with the refraction angles of opposite signs. The effect can be exploited for switching applications as demonstrated in the paper.     

a-Si:H based two-dimensional photonic crystals

We describe the fabrication processes of silicon-based two-dimensional photonic crystals (2D-PCs) with a photonic band gap in the near-IR range. The procedures involve electron beam lithography followed by an anisotropic etching step of hydrogenated amorphous silicon thin films deposited by plasma enhanced chemical vapor deposition. Micrometric and submicrometric arrays of cylindrical holes are transferred using a poly-methylmethacrylate resist layer as a mask. A careful comparison between standard parallel plate reactive ion etching and inductively coupled plasma etching techniques is performed, aimed at obtaining periodic structures with high aspect ratio and good profile sharpness.