Photochemical reactions of anthraquinone with hydrocarbons in the presence and absence of oxygen: Trapping of radical intermediates

Radical intermediates formed at 25°C in the presence and absence of oxygen during the photolysis of anthraquinone in aromatic, cyclic and aliphatic hydrocarbon solvents were trapped by 2,6-dichloronitrosobenzene, 2,6-dibromonitrosobenzene and 2,4,6-tribromonitrosobenzene. The resulting nitroxide radicals have been characterized in situ by ESR spectra.

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: 2,6-, 2,6- 2,4,6-— , , 25°C. .

     

Electron microscopic studies of platinum catalysts prepared via decomposition of Al2O3-anchored metal complexes

Reduced alumoplatinum and alumoplatinum-tin catalysts prepared via interaction of an organometallic platinum complex and platinum-tin compounds of various composition with Al₂O₃ mainly contain platinum particles of 10 Å.

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, Al₂O₃, , , 10 Å.

     

Studies of the structure of multicomponent Raney nickel catalysts

Genesis and structure of Raney nickel catalysts modified by Mo, Fe and Ca have been studied by XPS, SIMS and Auger and electron microprobe methods. It has been established that these catalysts are inhomogeneous and their structure can be described by models accounting for the interaction and localization character of metal components, their oxides and hydroxides.

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, - Ni-, Mo, Fe Ca. , , , .

     

A TPR study of SiO2-supported Ru?Ag catalysts

A H₂ chemisorption and TPR study of Ru–Ag/SiO₂ catalysts reveals that after oxidation at 373 K this systems behaves like Ru–Cu/SiO₂. High temperature oxidation, however, does not result in the separation of the metal like in the Ru–Cu case but in the redispersion of Ag on top of the Ru particles.

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H₂ Ru–Ag/SiO₂ , 373 Ru–Cu/SiO₂. , , , Ru–Cu, Ag Ru.

     

Comparison of dynamic mechanical and dielectric thermal analysis on cure studies for composites

Dielectric measurements covering a wide frequency range provide one of the few practical methods for monitoring the cure of thermosets (epoxy, etc.) using relatively non-intrusive sensors. The measurements form the basis of a manufacturing control cycle, in the autoclave, provided the rheological state of the thermoset can be related to the dielectric constant (¹) and loss factor (tan). The present paper concerns further investigations in our laboratory of the correlation between mechanical and dielectric behaviour during cure (1).

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Zusammenfassung Dielektrische Messungen über einem weiten Frequenzbereich stellen die eine Methode dar, um unter Anwendung verhältnismässig nicht-intrusiver Fühler die Aushärtung von Duroplasten /Epoxid usw./ verfolgen zu können. Die Messungen bilden die Grundlage für einen Pertigungsüberwachungskreis des Autoklaven, da der rheologische Zustand des Duroplast mit der Dielektrizitätskonstanten // und dem dielektrischen Verlustfaktor /tan/ in Verbindung gebracht werden kann. Vorliegende Arbeit berichtet über weitere Untersuchungen unseres Laboratoriums über den Zusammenhang zwischen mechanischem und dielektrischen Verhaltens während der Aushärtung.

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120–230°. 2 3590 . . . 150°, . .

     

Adsorption characteristics of some zeolites

Attempts have been made to correlate the Si/Al atom ratio, the degree of crystallinity, crystallite dimensions and the mean diameter of crystalline particles with the relative adsorption affinity index (RAI). Differences in molecular sieving effect and in some diffusional aspects between traditional zeolites and the new shape-selective ZSM are revealed by the adsorption characteristics of cyclohexane, benzene, toluene, neopentane and xylenes.

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Si/Al , , , (RAI). - ZSM , , , .

     

Ethylene hydrogenation in electrochemical cell with solid proton-conducting electrolyte

The effect of electrochemical H⁺ pumping on the hydrogenation rate of ethylene on Ni electrode catalysts in a solid proton-conducting electrolyte cell has been studied.

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Ni — .

     

Adsorption of carbon monoxide on Lewis acid sites of alumina

It has been found that carbon monoxide is adsorbed on Lewis acid sites of a high acid strength. Potential applicability of carbon monoxide as a gaseous base to determine the strength and amount of acid sites is suggested.

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, . CO, , .