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Summary 2,4-Dioxohexahydro-1,3,5-triazin (DHT) reacts with formaldehyde and secondary amines (Mannich reaction) to the corresponding 1,3,5- or 1,5-aminomethyl-DHTs (1a–8a or1b–11b).DHT and formaldehyde give the methylol compounds12a,12b, and12c. Alkylation ofDHT with alkyl halides in presence of base and dimethyl-sulfoxide as the solvent affords the tri-N-alkyl derivatives14–22. 1,5-Dimorpholinomethyl-DHT (1b) can be alkylated in position 3 with alkyl halides. The morpholinomethyl groups in positions 1 and 5 behave as protecting groups and are easily removable. Thus, it is possible to introduce different alkyl substituents into the molecule. The reaction of1b with dihaloalkanes results in a coupling of twoDHT moleculesvia the nitrogen in position 3 (compounds26–29).
Herrn Professor Dr. mult.Friedrich Asinger zum 90. Geburtstag gewidmet 相似文献
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V. V. Bakharev A. A. Ghidaspov A. N. Utenyshev I. A. Litvinov A. B. Dobrynin 《Journal of Structural Chemistry》2006,47(4):786-790
An X-ray diffraction study of 2,4-diamino-6-dinitromethyl-1,3,5-triazine potassium salt is reported. Crystals are monoclinic: a = 7.697(2) Å, b = 11.147(2) Å, c = 12.612(4) Å, β = 117.95(2)°, V = 955.9(4) Å3, space group P21/c; Z = 4, ρcalc = 1.885 g/cm3. The compound crystallizes as a crystalline hydrate with one molecule of water. Anion consists of two planar fragments: dinitromethyl and diamino-1,3,5-triazine, the geometrical parameters of which were analyzed. The coordination of potassium cations and multiple hydrogen bonds leading to the formation of a complex three-dimensional skeleton has been detected. 相似文献
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A new method for the synthesis of 2,4-diazido-6-trinitromethyl-1,3,5-triazine was elaborated. The method makes it possible
to exclude the work with unstable 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 相似文献
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V. V. Korshak T. M. Frunze A. A. Izyneev V. G. Samsonova 《Russian Chemical Bulletin》1972,21(9):2045-2046
Conclusions A study was made of the cyclotrimerization of benzonitrile in chlorosulfonic acid and the optimum conditions were ascertained for the formation of 2,4,6-triphenyl-1,3,5-triazine.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2105, September, 1972. 相似文献
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Mikolaichuk O. V. Protas A. V. Popova E. A. Molchanov O. E. Maistrenko D. N. Ostrovskii V. A. Pavlyukova Yu. N. Sharoyko V. V. Semenov K. N. 《Russian Journal of General Chemistry》2022,92(9):1621-1628
Russian Journal of General Chemistry - New tetrazole-containing derivatives of 2,4-diamino-1,3,5-triazine were synthesized. The cytotoxic activity of the obtained compounds against Huh-7 and HeLa... 相似文献
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M. Becker M. Jansen 《Acta Crystallographica. Section C, Structural Chemistry》1999,55(8):IUC9900094-IUC9900094
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F. Cataldo O. Ursini G. Angelini 《Journal of Radioanalytical and Nuclear Chemistry》2008,277(2):297-302
Triazines are a class of molecules which have been found in meteorites such as Orgueil meteorite. Despite their poor resistance
to UV radiation, these molecules survived millions of years inside a meteorite. The present work is dedicated to the examination
of the radiation resistance of the simplest sym-triazine: 1,3,5-triazine. The crystals of this molecule have been irradiated
with γ-radiation at 50 and 350 kGy and were studied by electronic absorption spectroscopy, liquid chromatography, FT-IR spectroscopy
and differential scanning calorimetry (DSC). All the data suggest the relatively low stability of this molecule to high energy
radiation. The resulting products from radiolysis are formamidine together with triazine dimers and oligomers. Other radiolysis
products are H2, CH4, HCN and other gases. 相似文献
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A mechanism for the nucleophilic substitution of halogen in cyanuric chloride in the presence of tertiary amines is proposed. When carboxylic acids react with cyanuric chloride in the presence of tertiary amines, quaternary acylammonium salts are formed which can be used as acylating agents. 相似文献
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Zbigniew J. Kamiński Stanislaw W. Markowicz Beata Kolesińska Dariusz Martynowski Marek L. Główka 《合成通讯》2013,43(14):2689-2696
Chiral mono-di-and trimenthoxy-1,3,5-triazines ware obtained from natural menthol and cyanuric chloride and applied as enantioselective coupling reagents in the synthesis of dipeptides. 相似文献