Ultrasonic measurement and characterization of a low concentration system of solid particles in liquid,in high shear flow

The objective of this paper is ultrasonic measurement and characterization of solid particles in liquid (20–40 μm glass beads in water) in high shear flow (1.5–2 m/s). Ultrasonic time dependent signals as well as frequency spectra are analyzed, for simultaneous determination of average particle concentration and average flow speed. As a result, the distribution of sound energy in such concentrated systems at given flow speeds is measured. Influence of flow turbulence is demonstrated in measurements. Also, characteristic behaviors of liquid–particle mixtures like particle clustering and influence of gas bubbles have been investigated. Experimental results are complemented with a discussion of factors that influence measurement uncertainty.     

The effects of acoustic flow and mechanical flow on the sonochemical efficiency in a rectangular sonochemical reactor

Visualization of cavitation behavior in a rectangular sonochemical reactor at 490 kHz was carried out by a laser sheet technique and the distribution of liquid flow was measured by a laser Doppler velocimeter. The pattern of liquid flow and distribution of acoustic pressure of the rectangular sonochemical reactor were investigated as a function of the input power from 10 to 50 W. The liquid moved upward above the transducer at every power. As increasing the input power, the random flow out side the cylindrical part above the transducer changed into the convective one and the region of the visualized standing wave which was formed in the cylindrical part changed with the input power. The position showing the sonochemical luminescence exists inside or near the region where the standing wave was visualized. Introduction of a stirrer resulted in disturbance of liquid flow and expanded the position showing the sonochemical luminescence, but the luminescence intensity was weakened. The sonochemical efficiency was enhanced by about twice by introduction of the stirrer. From these results, we discussed the effects of liquid flow on sonochemical efficiency with and without a stirrer.     

Direct energy flow measurement in magneto-sensitive vibration isolator systems

The effectiveness of highly nonlinear, frequency, amplitude and magnetic field dependent magneto-sensitive natural rubber components applied in a vibration isolation system is experimentally investigated by measuring the energy flow into the foundation. The energy flow, including both force and velocity of the foundation, is a suitable measure of the effectiveness of a real vibration isolation system where the foundation is not perfectly rigid. The vibration isolation system in this study consists of a solid aluminium mass supported on four magneto-sensitive rubber components and is excited by an electro-dynamic shaker while applying various excitation signals, amplitudes and positions in the frequency range of 20–200 Hz and using magneto-sensitive components at zero-field and at magnetic saturation. The energy flow through the magneto-sensitive rubber isolators is directly measured by inserting a force transducer below each isolator and an accelerometer on the foundation close to each isolator. This investigation provides novel practical insights into the potential of using magneto-sensitive material isolators in noise and vibration control, including their advantages compared to traditional vibration isolators. Finally, nonlinear features of magneto-sensitive components are experimentally verified.     

Development of composite plate for compact silencer design

A compact flow-through plate silencer is constructed for low frequency noise control using new reinforced composite plates. The concept comes from the previous theoretical study [L. Huang, Journal of the Acoustical Society of America 119 (2006) 2628–2638] which concerns a clamped supported plate enclosed by rigid cavities. When the grazing incident sound wave comes and induces the plate into the vibration, it will radiate sound and reflect sound. Such sound reflection causes a desirable noise reduction from low to medium frequency with wide broadband. The structural property of the very light plate with high bending stiffness is very crucial element in such plate silencer. In this study, an approach to fabricate new reinforced composite panel with light weight and high flexibility to increase the bending stiffness is developed in order to realize the function of this plate silencer practically. The plate silencer can be constructed in more compact size compared with the previous two-plate silencer with two rectangular cavities and the performance with the stopband of the range from 229 to 618 Hz, in which the transmission loss is higher than 10 dB over the whole frequency band without flow or with flow at the speed of 15 m/s, can be achieved. The experimental data also proves that the non-uniform clamped plates with thinner ends perform very well. To implement the use of such silencer practically in controlling noise at different dominant frequency ranges, a design chart has been established for searching the optimal bending stiffness and corresponding stopband at different geometries.     

Langevin simulations of rod-shaped object alignment by surface flow

Nano or micro-scale rod shaped objects suspended in a liquid flowing on a flat solid surface might be aligned or orientated by the nature of the liquid, type of flow and planar channel geometry containing the flow. Orientation might enhance or inhibit certain chemical reactions between the objects, the underlying surface, other chemicals or with the walls of the vessels holding the flowing suspension. The probability density function describing the orientations of the objects satisfies a Fokker–Planck equation whose solution is obtained with Langevin simulation for different surface flow parameters. The methods developed in the present work enable us to evaluate the orientation probability density function for a range of the Peclet number α covering several orders of magnitude, 10^? 4 ≤ α ≤ 10⁸. The experimental detection of orientation control is obtained optically from the measurement of dichroism and birefringence of the suspension. We describe different methods providing experimental proof of the onset of alignment control.     

Fine structure of far infrared spectrum of ethanol in the lowest OH-torsional vibrational trans-state (e0) of ethanol

In this report the spectroscopic results for far infrared Fourier transform spectrum corresponding to the b-type transitions within the lowest lying trans-substrate (e₀) have been presented. The calculated matrix elements connecting various K-levels suggest that ΔK = 1 transitions within the trans- subs-state should be quite strong but the transitions between the trans state to the gauche states would quite week (practically non-existent). This was also concluded by previous studies using microwave and millimeter wave regions (Pearson et al., 1982; Millar, 1995). The assignments were confirmed by direct observations at the spectrum and the agreement between the observed and calculated spectrum using precise energy levels reported by Pearson et al. (1982). All the strong ^RR and some ^RQ branch lines starting from K = 10 ← 9 through K = 24 ← 23 have been identified. State dependent expansion parameters for all the 15 sub-bands have been presented. These parameters can reproduce the experimental wave numbers within experimental uncertainty. An atlas for about 450 transition lines corresponding to transitions within the e₀ torsional–vibrational species has been prepared. To our knowledge this is the first time the high resolution far infra-red spectral region study for ethanol have been performed.     

High-resolution transmission measurements of CO2 at high temperatures for industrial applications

High-resolution transmission spectra of CO₂ in the 2.7, 4.3 and 15 μm regions at temperatures up to 1773 K and at approximately atmospheric pressure (1.00±0.01 atm) are measured and compared with line-by-line calculations based on the HITEMP-1995, HITEMP-2010, CDSD-HITEMP and CDSD-4000 databases. The spectra have been recorded in a high-temperature flow gas cell and using a Fourier transform infrared (FTIR) spectrometer at a nominal resolution of 0.125 cm^?1. The volume fractions of CO₂ in the measurements were 1, 10 and 100%. The measurements have been validated by comparison with medium-resolution data obtained by Bharadwaj and Modest [6]. The deviations between the experimental spectra and the calculations at 1773 K and the vibrational energy exchange and thermal dissociation of CO₂ at high temperatures are discussed.     

Investigation of acoustic cavitation energy in a large-scale sonoreactor

Acoustic cavitation energy distributions were investigated for various frequencies such as 35, 72, 110 and 170 kHz in a large-scale sonoreactor. The energy analyses were conducted in three-dimensions and the highest and most stable cavitation energy distribution was obtained not in 35 kHz but in 72 kHz. However, the half-cavitation-energy distance was larger in the case of 35 kHz ultrasound than in the case of 72 kHz, demonstrating that cavitation energy for one cycle was higher for a lower frequency. This discrepancy was due to the large surface area of the cavitation-energy-meter probe. In addition, 110 and 170 kHz ultrasound showed a very low and poor cavitation energy distribution. Therefore larger input power was required to optimize the use of higher frequency ultrasound in the sonoreactor with long-irradiation distance. The relationship between cavitation energy and sonochemical efficiency using potassium iodide (KI) dosimetry was best fitted quadratically. From 7.77 × 10^?10 to 4.42 × 10^?9 mol/J of sonochemical efficiency was evaluated for the cavitation energy from 31.76 to 103. 67 W. In addition, the cavitation energy attenuation was estimated under the assumption that cavitation energy measured in this study would be equivalent to sound intensity, resulting in 0.10, 0.18 and 2.44 m^?1 of the attenuation coefficient (α) for 35, 72 and 110 kHz, respectively. Furthermore, α/(frequency)² was not constant, as some previous studies have suggested.     

Normal incidence sound transmission loss in impedance tube – Measurement and prediction methods using perforated plates

For the determination of the transmission loss of samples in an impedance tube, two different approaches is found in the literature, one based on determining the full transfer matrix (TM method) of the acoustic element, the other based on the wavefield decomposition theory (WD method). In this paper both methods are implemented and measured results are compared using samples which includes different types of perforated plates, also combined with porous material. Measurements are conducted in a tube of square cross section with dimensions 200 × 200 mm, thereby limiting the workable frequency range upwards to approximately 850 Hz. The main purpose of the paper is, however, to compare measured results with predictions using the transfer matrix method. For a bare plate with cylindrical apertures two models are compared as well; a “classical” one and another based on modeling the perforated plate as a porous material having a rigid frame. As for these transmission loss measurements, the two measurement approaches turn out to give identical results within the numerical accuracy. The fit between measured and predicted results are reasonably good with a maximum deviation mostly within 2 dB.     

Theoretical and experimental investigations of the dynamics of cantilevered flexible plates subjected to axial flow

In this paper, the dynamics of cantilevered flexible plates subjected to axial flow is investigated theoretically and experimentally. A nonlinear equation of motion of the plate based on the inextensibility assumption, coupled with an unsteady lumped vortex model for the aerodynamic part is used to analyze the instability and post-critical dynamical behaviour of this fluid–structure system theoretically. Experiments have been conducted in a 3 ft×2 ft (914 mm×610 mm) cross-section wind tunnel, using polypropylene carbonate (PPC) films, thin brass plates, polyethylene terephthalate (PET) sheets, and type 304 stainless steel sheets, with maximum dimensions 224 mm×168 mm. In the experiments, time traces, power spectral densities (PSDs), phase-plane plots, Poincaré maps, probability density functions (PDFs) and autocorrelations are used to characterize the motions of the system.Periodic and chaotic oscillations have been observed in the experiments. It has also been observed that flutter arises via a subcritical bifurcation involving hysteresis for large aspect ratio plates; this hysteresis does not occur for low aspect ratio plates. The hysteresis phenomenon is considered to be due to spanwise deformation of the plates. The effect of aspect ratio on critical flow velocity is investigated. The experimental critical flow velocities for flutter onset are in good agreement with the theoretically predicted values.     

Interaction of water molecules with bare and deuterated polycrystalline diamond surface studied by high resolution electron energy loss and X-ray photoelectron spectroscopies

In this work we study the interaction of water molecules with deuterated and bare polycrystalline diamond surfaces upon exposure to water vapor by X-ray photoelectron spectroscopy (XPS) and high resolution electron energy loss spectroscopy (HR-EELS). To distinguish the molecular origin of hydrogen bonds (i.e. C–H, O–H, C–O–H, etc.) formed on the diamond surface upon interaction with the water molecules, deuterated and hydrogenated gases were used in our experiments. Diamond films were deposited from a deuterated gas mixture to induce C(di)-D surface terminations. Water adsorption on bare diamond surface gives rise to the appearance of well defined and pronounced C–H and C–OH vibrational HR-EELS peaks and an intense O (1s) XPS peak. These chemically adsorbed water fragments survive 300 °C anneal temperature under ultra-high vacuum conditions. Annealing at 600 °C of the water exposed bare diamond surface results in disappearance of the C–OH vibrational modes alongside with a pronounced reduction of the C–H vibrational modes, whilst only upon annealing to ~ 800 °C the O (1s) XPS peak decreased substantially in intensity. We associate these effects with dissociative adsorption of the water molecules on the bare diamond surfaces.Water exposure onto a deuterated surface, on the other hand, does not result in the appearance of the C–OH vibrational peaks but only to an increase of the C–H vibrational HR-EELS mode along side with the appearance of a weaker XPS O (1) peak, as compared to the same experiment, performed on the bare surface. 300 °C anneal significantly diminishes surface oxygen concentration, as monitored by XPS. We associate these results with H₂O decomposition reactions and also with molecular adsorption on deuterated diamond surfaces. Annealing of the water exposed deuterated diamond surface, results in a pronounced decrease and disappearance of the O (1s) XPS peak at a temperature of ~ 800 °C.     

A new method for generation of synchronised capacitive sparks of low energy

Conventional tests for investigating the minimum ignition energy (MIE) of dust clouds are restricted to energies above a few mJ, due to the challenges of producing sparks of very low energies that can be synchronised with a transient dust cloud. In this paper, a new circuit for generating capacitive sparks of significantly lower energies than 1 mJ is presented. A measurement system for capturing voltage and current waveforms has been integrated in the circuit, offering the energy delivered to the spark by integration of the power-versus-time curve. When working with such low energy discharges, which are highly transient phenomena, attention must be paid to the measurement technique and methods of noise reduction in the measurement instruments.The measured spark energies range from 0.03 to 7 mJ, and they were found to constitute between 60 and 90 per cent of the energy stored on the discharge capacitors prior to breakdown. Losses to the measurement resistors are increasingly significant at higher energies and larger electrode gaps, due to the relatively large currents, and correspondingly small spark resistances.A simple circuit simulation, in which the spark conductivity is assumed proportional to the spark energy, offers voltage and current waveforms in good agreement with the measured ones, indicating that the spark is mainly resistive. In addition, the discharge channel's ability to carry current depends strongly on the supplied energy. The proportionality factor is found to depend on the breakdown voltage.     

Selective resonance population in high resolution electron energy loss spectroscopy of 4-ethylbenzenethiol self-assembled monolayers on Au(1 1 1)

We have investigated the vibrational frequencies and excitation cross-section of self-assembled monolayers (SAMs) of 4-ethylbenzenethiol (CH₃CH₂(C₆H₄)SH) on Au(1 1 1) by high resolution electron energy loss spectroscopy (HREELS). Negative ion resonances were observed in the energy loss intensities as a function of the incident electron energy. Analysis of the C–H stretching modes indicates resonances of different energies are localised in both the ethyl and phenyl functional groups of the SAM molecules, which regulate the observed vibrational lineshape.     

Design parameters of stainless steel plates for maximizing high frequency ultrasound wave transmission

This work validated, in a higher frequency range, the theoretical predictions made by Boyle around 1930, which state that the optimal transmission of sound pressure through a metal plate occurs when the plate thickness equals a multiple of half the wavelength of the sound wave. Several reactor design parameters influencing the transmission of high frequency ultrasonic waves through a stainless steel plate were examined. The transmission properties of steel plates of various thicknesses (1–7 mm) were studied for frequencies ranging from 400 kHz to 2 MHz and at different distances between plates and transducers. It was shown that transmission of sound pressure through a steel plate showed high dependence of the thickness of the plate to the frequency of the sound wave (thickness ratio). Maximum sound pressure transmission of ∼60% of the incident pressure was observed when the ratio of the plate thickness to the applied frequency was a multiple of a half wavelength (2 MHz, 6 mm stainless steel plate). In contrast, minimal sound pressure transmission (∼10–20%) was measured for thickness ratios that were not a multiple of a half wavelength. Furthermore, the attenuation of the sound pressure in the transmission region was also investigated. As expected, it was confirmed that higher frequencies have more pronounced sound pressure attenuation than lower frequencies. The spatial distribution of the sound pressure transmitted through the plate characterized by sonochemiluminescence measurements using luminol emission, supports the validity of the pressure measurements in this study.     

Rare earth free exchange spring magnet FeCo/FePt(001): Giant magnetic anisotropy and energy product

Using the full potential linearized augmented plane wave (FLAPW) method, we have investigated the thickness dependent magnetic properties of rare earth free exchange spring magnet FeCo/FePt(001). The FeCo adlayer thickness is increased from one monolayer (ML) to four ML coverage. It is observed that the FeCo adlayers and Fe atoms in FePt substrate show almost half metallic behavior, while an ordinary metallic feature is found in Pt atoms. The average magnetization increases with FeCo thickness and the estimated maximum energy product reaches 66 MGOe in FeCo(4 ML)/FePt(001). A giant perpendicular magnetocrystalline anisotropy (MCA) energy of 18.20 meV/cell is found in pure FePt(001) and it becomes 17.35 meV/cell even in FeCo(4 ML)/FePt(001). In addition, we find very large coercivity field in FeCo/FePt(001) systems. For instance, the calculated maximum coercivity field in FeCo(4 ML)/FePt(001) is about 188 kOe. Both energy product and coercivity field calculations may imply that the FeCo/FePt can be utilized for potential rare earth free exchange spring magnet material.     

Reflection electron energy loss spectroscopy of aluminum

Reflection electron energy loss spectra (REELS) of Al(111) single crystal and of the aluminum polycrystalline (poly Al) film were measured at 200 eV and 1000 eV electron energies for a variety of experimental geometries and were mutually compared. No anisotropy was found for the poly Al, as expected. Polar intensity plots evaluated from the elastic (no loss) and inelastic first surface plasmon- and first bulk plasmon-loss intensities of the Al(111) surface show clearly discernable peaks for both considered electron energies. Their positions on the angular axis are the same for the elastic as well as for the inelastic, surface and bulk plasmon-loss peaks. The polar plots of intensities of the elastically and inelastically reflected electrons were compared to calculated intensities of photoelectrons emitted from the Al 2s core level to the same kinetic energy. Peak positions in the theoretically determined polar plots of electron intensities agree with those obtained experimentally in REELS.     

Acoustics of the Chelys – An ancient Greek tortoise-shell lyre

The acoustics of an authentically reconstructed ancient Greek tortoise-shell lyre, known as Chelys, is investigated for the first time. Modern experimental methods are employed, such as electronic speckle pattern laser interferometry and impulse response, to extract the vibrational behavior of the instrument and its main parts. Additionally, the emitted sound from the instrument was recorded, under controlled conditions, and spectrally analyzed. Major findings include the concentration of the emitted sound between 400 Hz and 800 Hz, with an amplitude modified in a manner consistent with the experimentally measured vibrational characteristics of the instrument’s sound box and bridge. The experimental results validate the historical evidence that Chelys was used in Greek antiquity as an accompaniment instrument to the human voice.     

Mechanism of electrohydrodynamically induced flow in a wire-non-parallel plate electrode type gas pump

An experimental investigation and one-dimensional modeling have been conducted to study the mechanism of net flow direction induced by electrohydrodynamic (EHD) forces in a wire-non-parallel plate electrode type EHD gas pump. The experiments were conducted with various different locations of corona wire electrode for negative and positive applied voltage from 0 to 14 kV at atmospheric pressure and room temperature, where air was used as the working fluid. A one-dimensional cross-sectional averaged model based on mass and momentum conservation as well as Poisson electric field and ion transport equations was also developed. The results show that the net flow direction of electrohydrodynamically induced gas flow in a wire-non-parallel plate electrode system significantly depends on the location of the corona wire electrode relative to the grounded electrode position. The effect of conversion angle of non-parallel plate electrode on the net flow direction and pressure drop also was investigated and discussed in detail.     

Adsorption of molecular SiO2 on a clean Si(1 0 0) surface

We have investigated the adsorption of molecular (gaseous) SiO₂ on a clean Si(1 0 0) p(2 × 2) reconstructed surface using density functional theory based methods. The SiO₂ molecule is found to be chemisorbed on various sites on the Si surface and the most energetically favourable structure is on top of the dimers. The minimum energy pathways for the various adsorption channels indicate that the reaction is barrierless in all cases. The corresponding vibrational spectrum is also calculated and the adsorbed molecules are, as expected, found to have red-shifted vibrational frequencies. The energetically favourable adsorption sites and adsorption energies are comparable to the results found for SiO.     

Electrical effect of soot depositions in a co-axial wire pipe flow

An investigation was performed to study the electrical effects on the soot deposition in a co-axial wire cylinder with cooled walls. Experiments were performed for applied voltages from 0 to ?5 kV or +5 kV and a diesel exhaust mass flow rate of 20 kg/h or Reynolds number of approximately 9000. The outer wall was cooled using water with a temperature of approximately 40 °C, and the experiments were performed for exposure times of 2 h. The soot deposition layer thickness was measured using a non-destructive neutron radiography technique at the end of each experiment. The results show that the electric field had a significant effect on the soot deposition and increases it by a factor of approximately 4 at the applied voltage of 5 kV before spark on-set. The soot thickness was similar for the positive and negative polarities and the results show that there was significant deposition on the wire as well as the outer wall for both polarities. Since soot deposition even occurs on both corona wire and grounded pipe below corona on-set voltages of the clean system, there may be a significant pre-charging of the diesel soot with both polarities in the diesel exhaust gas as has been observed by the recent measurements of Marieq [On the electrical charge of motor vehicle exhaust particles, Journal of Aerosol Science 37 (7) (2006) 858–874].